TW201245259A - Moisture curable silylated polymer compositions with improved adhesion to concrete - Google Patents
Moisture curable silylated polymer compositions with improved adhesion to concrete Download PDFInfo
- Publication number
- TW201245259A TW201245259A TW101110912A TW101110912A TW201245259A TW 201245259 A TW201245259 A TW 201245259A TW 101110912 A TW101110912 A TW 101110912A TW 101110912 A TW101110912 A TW 101110912A TW 201245259 A TW201245259 A TW 201245259A
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- TW
- Taiwan
- Prior art keywords
- group
- decane
- moisture curable
- curable resin
- resin composition
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims abstract description 77
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000004567 concrete Substances 0.000 title claims abstract description 32
- -1 glycidoxy group Chemical group 0.000 claims abstract description 70
- 239000011342 resin composition Substances 0.000 claims abstract description 68
- 239000003054 catalyst Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 24
- 239000000945 filler Substances 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 239000000565 sealant Substances 0.000 claims abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 12
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 8
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 105
- 150000003077 polyols Chemical class 0.000 claims description 57
- 229920005862 polyol Polymers 0.000 claims description 56
- 125000004432 carbon atom Chemical group C* 0.000 claims description 45
- 125000000217 alkyl group Chemical group 0.000 claims description 41
- 239000001257 hydrogen Substances 0.000 claims description 37
- 229910052739 hydrogen Inorganic materials 0.000 claims description 37
- 125000003118 aryl group Chemical group 0.000 claims description 36
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 32
- 229910052760 oxygen Inorganic materials 0.000 claims description 27
- 239000001301 oxygen Substances 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 22
- 229910052717 sulfur Inorganic materials 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 125000003545 alkoxy group Chemical group 0.000 claims description 18
- 125000003342 alkenyl group Chemical group 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 13
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 13
- 150000002430 hydrocarbons Chemical group 0.000 claims description 13
- 239000000376 reactant Substances 0.000 claims description 13
- 239000011593 sulfur Substances 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 12
- 150000002431 hydrogen Chemical group 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 239000004814 polyurethane Substances 0.000 claims description 11
- 229920002635 polyurethane Polymers 0.000 claims description 11
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 10
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 10
- 125000004434 sulfur atom Chemical group 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 125000005442 diisocyanate group Chemical group 0.000 claims description 9
- 239000012948 isocyanate Substances 0.000 claims description 8
- 150000002513 isocyanates Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 150000002923 oximes Chemical class 0.000 claims description 8
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- 239000011347 resin Substances 0.000 claims description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 150000002829 nitrogen Chemical class 0.000 claims description 6
- 229920000620 organic polymer Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000012634 fragment Substances 0.000 claims description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine group Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 4
- 239000001993 wax Substances 0.000 claims description 4
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- QMOWYWSHERGNQQ-UHFFFAOYSA-N N=C=O.CCCCCCCCCC Chemical class N=C=O.CCCCCCCCCC QMOWYWSHERGNQQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 claims description 3
- CRGCAWOGRIKNFP-UHFFFAOYSA-N C(CCCCCCCCC)CCC(C(OC)(OC)OC)CCCCCCCC Chemical compound C(CCCCCCCCC)CCC(C(OC)(OC)OC)CCCCCCCC CRGCAWOGRIKNFP-UHFFFAOYSA-N 0.000 claims description 2
- UMUVKMNHJFWLQT-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)C(C(OC)(OC)OC)CCCCCCCC Chemical compound C(CCCCCCCCCCCCCCCCC)C(C(OC)(OC)OC)CCCCCCCC UMUVKMNHJFWLQT-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- LAENUTMFTKEICI-UHFFFAOYSA-N N(=C=O)CCCC(C(OCC)(OCC)OCC)CCCCCCCC Chemical compound N(=C=O)CCCC(C(OCC)(OCC)OCC)CCCCCCCC LAENUTMFTKEICI-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 125000006612 decyloxy group Chemical group 0.000 claims description 2
- 238000007665 sagging Methods 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 150000007970 thio esters Chemical class 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- GHTQBJZRHNNLIS-UHFFFAOYSA-N C(CCC)C(C(OC)(OC)OC)CCCCCCCC Chemical compound C(CCC)C(C(OC)(OC)OC)CCCCCCCC GHTQBJZRHNNLIS-UHFFFAOYSA-N 0.000 claims 2
- OMFCBRBHOCJKHX-UHFFFAOYSA-N 2-dodecyl-1,4-dioxane Chemical compound CCCCCCCCCCCCC1COCCO1 OMFCBRBHOCJKHX-UHFFFAOYSA-N 0.000 claims 1
- WQHMEGBWNFRWDH-UHFFFAOYSA-N 2-methoxy-2-methylundecane Chemical compound CCCCCCCCCC(C)(C)OC WQHMEGBWNFRWDH-UHFFFAOYSA-N 0.000 claims 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 1
- IKEVUICGDJISMI-UHFFFAOYSA-N C(CCCCCCCCC)C(C(OC)(OC)OC)CCCCCCCC Chemical compound C(CCCCCCCCC)C(C(OC)(OC)OC)CCCCCCCC IKEVUICGDJISMI-UHFFFAOYSA-N 0.000 claims 1
- FOQCUXBSLBHBET-UHFFFAOYSA-N C(CCCCCCCCC)C(CCCCCCCCC)OCCCCCCCCCC Chemical compound C(CCCCCCCCC)C(CCCCCCCCC)OCCCCCCCCCC FOQCUXBSLBHBET-UHFFFAOYSA-N 0.000 claims 1
- YWEKAQXJRFUJOY-UHFFFAOYSA-N COC(CCCCCCCCCCCCCCCCC)(OC)OC Chemical compound COC(CCCCCCCCCCCCCCCCC)(OC)OC YWEKAQXJRFUJOY-UHFFFAOYSA-N 0.000 claims 1
- 101100149678 Caenorhabditis elegans snr-3 gene Proteins 0.000 claims 1
- LWBRHYKETAYWMQ-UHFFFAOYSA-N N(=C=O)CC(C(OC)(OC)OC)CCCCCCCC Chemical compound N(=C=O)CC(C(OC)(OC)OC)CCCCCCCC LWBRHYKETAYWMQ-UHFFFAOYSA-N 0.000 claims 1
- CWCAPFCUFWZGDG-UHFFFAOYSA-N N(=C=O)CCCC(C(OC)(OC)OC)CCCCCCCC Chemical compound N(=C=O)CCCC(C(OC)(OC)OC)CCCCCCCC CWCAPFCUFWZGDG-UHFFFAOYSA-N 0.000 claims 1
- VYQUEWJCVKVHIW-UHFFFAOYSA-N N(=C=O)CCCCC(C(OC)(OC)OC)CCCCCCCC Chemical compound N(=C=O)CCCCC(C(OC)(OC)OC)CCCCCCCC VYQUEWJCVKVHIW-UHFFFAOYSA-N 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 1
- 125000005024 alkenyl aryl group Chemical group 0.000 claims 1
- OMOZGSRMZAYUCI-UHFFFAOYSA-N amino cyanate Chemical group NOC#N OMOZGSRMZAYUCI-UHFFFAOYSA-N 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 1
- ZYURHZPYMFLWSH-UHFFFAOYSA-N octacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC ZYURHZPYMFLWSH-UHFFFAOYSA-N 0.000 claims 1
- 125000003544 oxime group Chemical group 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical compound O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 11
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 9
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- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 6
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- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
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- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
- 125000006165 cyclic alkyl group Chemical group 0.000 description 3
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- 238000010998 test method Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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- FNWWOHKUXFTKGN-UHFFFAOYSA-N isoheptadecane Natural products CCCCCCCCCCCCCCC(C)C FNWWOHKUXFTKGN-UHFFFAOYSA-N 0.000 description 2
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 2
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- 238000010189 synthetic method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
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- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08L101/10—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
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- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
- C08G71/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
- C08L71/03—Polyepihalohydrins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
- C09J171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
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| US13/077,077 US8859674B2 (en) | 2011-03-31 | 2011-03-31 | Moisture curable silylated polymer compositions with improved adhesion to concrete |
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| TW201245259A true TW201245259A (en) | 2012-11-16 |
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| TW (1) | TW201245259A (enExample) |
| WO (1) | WO2012135443A1 (enExample) |
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| US9144796B1 (en) | 2009-04-01 | 2015-09-29 | Johnson Matthey Public Limited Company | Method of applying washcoat to monolithic substrate |
| US8859674B2 (en) * | 2011-03-31 | 2014-10-14 | Momentive Performance Materials Inc. | Moisture curable silylated polymer compositions with improved adhesion to concrete |
| CN103602304B (zh) * | 2013-11-11 | 2014-12-17 | 苏州毫邦新材料有限公司 | 湿气速固化组成物 |
| JP6587418B2 (ja) * | 2014-05-15 | 2019-10-09 | キヤノン株式会社 | 電子写真用部材、プロセスカートリッジ及び電子写真装置 |
| EP3012105B1 (en) * | 2014-10-23 | 2019-08-14 | Canon Kabushiki Kaisha | Recording method and recording apparatus |
| JP6391422B2 (ja) * | 2014-10-23 | 2018-09-19 | キヤノン株式会社 | 記録方法および記録装置 |
| AU2015100195A4 (en) * | 2015-02-20 | 2015-05-21 | Wolan Technologies Pty Ltd | Low viscosity innovative moisture cured polymer compositions with improved tensile and creep properties for Industrial coatings,adhesives and sealant applications |
| KR101886911B1 (ko) * | 2015-03-26 | 2018-08-08 | 동우 화인켐 주식회사 | 흑색 감광성 수지 조성물, 이를 사용하여 제조된 블랙 매트릭스 및/또는 칼럼스페이서를 포함하는 칼라필터, 및 상기 칼라필터를 포함하는 액정표시장치 |
| TWI637977B (zh) * | 2015-06-12 | 2018-10-11 | 大金工業股份有限公司 | 表面處理劑 |
| CN107922577B (zh) * | 2015-09-10 | 2021-02-12 | 陶氏环球技术有限责任公司 | 基于多甲硅烷基化聚醚以及钛(iv)催化剂和/或锌/环状脒催化剂混合物的可湿气固化的系统 |
| US10254650B2 (en) * | 2016-06-29 | 2019-04-09 | Honeywell International Inc. | Low temperature SC1 strippable oxysilane-containing coatings |
| PL3494188T3 (pl) * | 2016-08-03 | 2020-04-30 | Wacker Chemie Ag | Sieciowane masy powłokowe na bazie polimerów z terminalnymi grupami organylooksysilanowymi |
| KR101874705B1 (ko) * | 2016-11-15 | 2018-07-04 | 한국타이어 주식회사 | 공명음 저감 타이어 |
| FR3066765B1 (fr) * | 2017-05-23 | 2019-06-14 | Bostik Sa | Composition de mastic silyle bas module |
| US10233200B2 (en) * | 2017-08-21 | 2019-03-19 | Momentive Performance Matericals Inc. | Organomodified monosilyl compound, its preparation and applications thereof |
| WO2019114990A1 (de) * | 2017-12-15 | 2019-06-20 | Wacker Chemie Ag | Beschichtungszusammensetzung zum abdichten von oberflächen |
| CN112262164B (zh) * | 2018-05-24 | 2022-07-22 | Dic株式会社 | 湿气固化型氨基甲酸酯热熔树脂组合物及层叠体 |
| US11891546B2 (en) | 2018-06-25 | 2024-02-06 | Sika Technology Ag | Catalyst-free curable compositions based on silane-functional polymers |
| CN112262115A (zh) * | 2018-07-26 | 2021-01-22 | Sika技术股份公司 | 获得具有树脂改性的混凝土的表面层的混凝土结构的方法 |
| EP3617249A1 (en) | 2018-08-28 | 2020-03-04 | Soudal | Adhesive and/or sealant composition |
| CN111117489B (zh) * | 2018-10-31 | 2022-01-07 | 娄从江 | 一种快速成膜和高阻隔性硅烷改性类建筑密封胶的底涂剂 |
| CN109456725B (zh) * | 2018-11-02 | 2021-05-04 | 成都硅宝科技股份有限公司 | 一种家装用环保型硅烷改性聚醚密封胶及其制备方法 |
| CN111808511B (zh) * | 2019-04-11 | 2022-04-01 | 娄从江 | 硅氧烷改性类密封胶用底涂树脂及其配制的底涂组合物 |
| US20200332052A1 (en) * | 2019-04-19 | 2020-10-22 | Momentive Performance Materials Inc. | Stabile silane modified polymer composition and method |
| BE1027545B1 (nl) * | 2019-09-02 | 2021-03-31 | Fourny Nv | Adhesief en applicator voor het aanbrengen van dit adhesief |
| EP4134390B1 (en) * | 2020-04-09 | 2025-06-18 | Kaneka Corporation | Curable composition |
| WO2022075437A1 (ja) * | 2020-10-09 | 2022-04-14 | デンカ株式会社 | 樹脂組成物 |
| CN112210068A (zh) * | 2020-10-19 | 2021-01-12 | 肇庆市武大环境技术研究院 | 一种可湿气固化的改性聚硅氧烷及其制备方法和应用 |
| CN112375526A (zh) * | 2020-11-17 | 2021-02-19 | 格至控智能动力科技(上海)有限公司 | 湿气固化胶水的快速固化方法 |
| WO2024249895A1 (en) * | 2023-05-31 | 2024-12-05 | Kaneka Americas Holding, Inc. | Method of preparing a moisture curable resin composition |
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| US3627722A (en) | 1970-05-28 | 1971-12-14 | Minnesota Mining & Mfg | Polyurethane sealant containing trialkyloxysilane end groups |
| GB1439577A (en) | 1973-06-07 | 1976-06-16 | Kanegafuchi Chemical Ind | Process for preparing polyoxalkylene having allyl end-group |
| US3971751A (en) | 1975-06-09 | 1976-07-27 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Vulcanizable silylether terminated polymer |
| JP2558125B2 (ja) | 1987-09-18 | 1996-11-27 | 鐘淵化学工業株式会社 | 常温硬化性樹脂組成物 |
| US4810748A (en) | 1988-04-15 | 1989-03-07 | Dow Corning Corporation | Concrete joint sealant having improved adhesion |
| US5216057A (en) | 1988-05-27 | 1993-06-01 | General Electric Company | Silicone modified acrylic latex sealant |
| JPH0543789A (ja) * | 1991-08-09 | 1993-02-23 | Sekisui Chem Co Ltd | 室温硬化性組成物 |
| US6001946A (en) | 1996-09-23 | 1999-12-14 | Witco Corporation | Curable silane-encapped compositions having improved performances |
| US5990257A (en) | 1998-01-22 | 1999-11-23 | Witco Corporation | Process for producing prepolymers which cure to improved sealants, and products formed thereby |
| US6602964B2 (en) | 1998-04-17 | 2003-08-05 | Crompton Corporation | Reactive diluent in moisture curable system |
| US6197912B1 (en) | 1999-08-20 | 2001-03-06 | Ck Witco Corporation | Silane endcapped moisture curable compositions |
| JP2002012645A (ja) * | 2000-04-28 | 2002-01-15 | Yokohama Rubber Co Ltd:The | 一液湿気硬化型ポリウレタン組成物 |
| US6498210B1 (en) | 2000-07-13 | 2002-12-24 | Adco Products, Inc. | Silylated polyurethanes for adhesives and sealants with improved mechanical properties |
| EP1650261A4 (en) | 2003-07-18 | 2008-02-27 | Kaneka Corp | HARDENING COMPOSITION |
| DE10355318A1 (de) | 2003-11-27 | 2005-06-23 | Wacker-Chemie Gmbh | Verfahren zur Herstellung von organyloxysilylterminierten Polymeren |
| US8481668B2 (en) | 2005-09-16 | 2013-07-09 | Momentive Performance Materials Inc. | Silane-containing adhesion promoter composition and sealants, adhesives and coatings containing same |
| US7524915B2 (en) * | 2005-10-27 | 2009-04-28 | Momentive Performance Materials Inc. | Process for making moisture-curable silylated resin composition, the resulting composition and moisture-curable products containing the composition |
| US20070179236A1 (en) * | 2006-02-01 | 2007-08-02 | Landon Shayne J | Sealant composition having reduced permeability to gas |
| US7569653B2 (en) * | 2006-02-01 | 2009-08-04 | Momentive Performance Materials Inc. | Sealant composition having reduced permeability to gas |
| US8207252B2 (en) * | 2007-03-07 | 2012-06-26 | Momentive Performance Materials Inc. | Moisture-curable silylated polymer resin composition |
| US8809479B2 (en) * | 2009-05-01 | 2014-08-19 | Momentive Performance Materials Inc. | Moisture curable silylated polymer compositions containing reactive modifiers |
| US8859674B2 (en) * | 2011-03-31 | 2014-10-14 | Momentive Performance Materials Inc. | Moisture curable silylated polymer compositions with improved adhesion to concrete |
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| US20120251832A1 (en) | 2012-10-04 |
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| JP2017125188A (ja) | 2017-07-20 |
| US8859674B2 (en) | 2014-10-14 |
| BR112013024938B1 (pt) | 2020-03-10 |
| JP2014510816A (ja) | 2014-05-01 |
| CN103582674A (zh) | 2014-02-12 |
| EP2691464A1 (en) | 2014-02-05 |
| CN103582674B (zh) | 2016-06-15 |
| JP6329481B2 (ja) | 2018-05-23 |
| EP2691464B1 (en) | 2019-01-09 |
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