TW201229048A - Oxygenated fused ring derivative and organic electroluminescence element containing the same - Google Patents
Oxygenated fused ring derivative and organic electroluminescence element containing the same Download PDFInfo
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- TW201229048A TW201229048A TW100142682A TW100142682A TW201229048A TW 201229048 A TW201229048 A TW 201229048A TW 100142682 A TW100142682 A TW 100142682A TW 100142682 A TW100142682 A TW 100142682A TW 201229048 A TW201229048 A TW 201229048A
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- 125000004354 sulfur functional group Chemical group 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- KTQYWNARBMKMCX-UHFFFAOYSA-N tetraphenylene Chemical group C1=CC=C2C3=CC=CC=C3C3=CC=CC=C3C3=CC=CC=C3C2=C1 KTQYWNARBMKMCX-UHFFFAOYSA-N 0.000 description 1
- HODRFAVLXIFVTR-RKDXNWHRSA-N tevenel Chemical compound NS(=O)(=O)C1=CC=C([C@@H](O)[C@@H](CO)NC(=O)C(Cl)Cl)C=C1 HODRFAVLXIFVTR-RKDXNWHRSA-N 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- SLGBZMMZGDRARJ-UHFFFAOYSA-N triphenylene Chemical group C1=CC=C2C3=CC=CC=C3C3=CC=CC=C3C2=C1 SLGBZMMZGDRARJ-UHFFFAOYSA-N 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
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- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
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- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Description
201229048 * ๅ
ญใ็ผๆ่ชชๆ๏ผ ใ็ผๆๆๅฑฌไนๆ่ก้ ๅใ โฆๆฌ็ผๆไฟ้ๆผโ็จฎๅซๆฐง็ธฎๅ็ฐ่ก็็ฉๅๅซ่ฉฒๅซๆฐง็ธฎๅ ่ฃฑ่ก็็ฉ่ๆไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถใ ใๅ
ๅๆ่กใ ๆๆฉ้ปๆฟ็ผๅ
๏ผEL)ๅ
ไปถไฟๅฉ็จๅฆไธๅ็ไน่ช็ผๅ
ๅ
ไปถ๏ผ่็ฑๆฝๅ ้ปๅ ด๏ผ่ไฝฟ็ผๅ
ๆง็ฉ่ณช่็ฑ่ช้ฝๆฅตๆณจๅ
ฅไน้ป ๆด่่ช็ถๆฅตๆณจๅ
ฅไน้ปๅญไนๅ็ตๅ่ฝ้่็ผๅ
ใ ๆๆฉELๅ
ไปถๅ
ทๅ็ฑ้ฝๆฅตๅ้ฐๆฅตๆงๆไนไธๅฐ้ปๆฅต๏ผๅๆผ ่ฉฒ็ญ้ปๆฅตไน้ๅ
ทๅๆๆฉ่่ๅฑคใๆๆฉ่่ๅฑคไฟ็ฑๅ
ทๆๅๅ ่ฝไนๅฑคไน็ฉๅฑค้ซๆๆงๆ๏ผไพๅฆ็บไพๅบ็ฉๅฑคๆ้ฝๆฅตใ้ปๆดๆณจ ๅ
ฅๅฑค้ป/ๅๅณ่ผธๅฑคใ็ผๅ
ๅฑคใ้ๅฃๅฑคใ้ปๅญๅณ่ผธๅฑคๅ้ปๅญ ๆณจๅ
ฅๅฑคไน็ฉๅฑค้ซใ ๆๆฉELๅ
ไปถไพๆๅ
ถ็ผๅ
ๅ็ๅฏๅ็บ่ขๅ
ๅๅๅกซๅ
ๅ2 ็จฎใ่ขๅ
ๅไนๆๆฉEL &ไปถไฟไฝฟ็จ็ฑๅฎ้ๆ
ๆฟๅญๅผ่ตทไน็ผ ๅ
็ฃทๅ
ๅไนๆๆฉEL (ไปถไฟไฝฟ็จ็ฑไธ้ๆ
ๆฟๅญๅผ่ตทไน็ผ ๅ
ๅทฒ็ฅ๏ผๆผ้ฑๅ
ๅๅ
ไปถไธญ๏ผ็บไบ้ฒๆญข่ๅฎ้ๆ
ๆฟๅญ็ธๆฏ ๆฟๅญๅฃฝๅฝ่ผ้ทไนไธ้ๆ
ๆฟๅญๅ็ผๅ
ๅฑคๅคๆดๆฃ๏ผ่็ฑๆผ็ผๅ
ๅฑคโ้ฐๆฅๆผ้ฐๆฅตๅด็้ขไนๅฑคไธญไฝฟ็จไธ้ๆ
่ฝ้่ผๅคงไนๆๆ ่้นๆ้ซๆ็ใ ๅฐๅฉๆ็ป1ไธญๆญ็คบๆๅฆไธๆ่ก๏ผ่็ฑ่จญ็ฝฎ้ฐๆฅๆผ็ผๅ
ๅฑคไน็ฑไฝ็บๅก็ณ่ก็็ฉไนBcp ( bathใcuprใine )ๆงๆ็้ๅฃ ๅฑคไพๅฐ้ไธ้ๆ
ๆฟๅญ๏ผๅพ่ๅฏฆ็พ้ซๆ็ๅใๅ๏ผๆผๅฐๅฉๆ ็ป2ไธญโๅฐ็นๅฎไน่ณ้ฆๆ็ฐๅๅ็ฉ็จๆผ้ปๆด้ๅฃๅฑค่ๅฏฆ็พ 201229048 ้ซๆ็ใ้ทๅฃฝๅฝๅใ ๅฆไธๆน้ขโ่ฟๅนดไพไบฆๅ ฑๅๆๆผๆฆฎๅ
ๅๆๆฉELๅ
ไปถไธญ ้ๅฐๅฉๆ็ป1ๅ2ใๅฐๅฉ ็ฑไธ้ๆ
ๆฟๅญๅผ่ตทไน็ผๅ
๏ผไพๅฆ ๆ็ป3 )ใ [ๅฐๅฉๆ็ป1]ๆฅๆฌ็น่กจ2002โ 525808่ๅ
ฌๅ ฑ [ๅฐๅฉๆ็ป2]็พๅๅฐๅฉ็ฌฌ7018723่่ชชๆๆธ [ๅฐๅฉๆ็ป3]ๆฅๆฌ็น้2004โ 214180่ๅ
ฌๅ ฑ [้ๅฐๅฉๆ็ป] [้ๅฐๅฉๆ็ป l]Journal of Applied Physics, 102, 1 14504 (2007) [้ๅฐๅฉๆ็ป 2]SID2008 DIGEST, 709 ( 2008) ใ็ผๆๅ
ๅฎนใ ๆฌ็ผๆไน็ฎ็ๅจๆผๆไพไธ็จฎๅฏ้ฒๆญขๆฝๅ ้ปๅฃไนไธๅไธฆ ๅฉ็จTTF ( TripletโTriplet Fusion)็พ่ฑกไฝฟๆๆฉELๅ
ไปถ้ซ ๆ็ๅฐ็ผๅ
ไนๆฐ็ฉไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉใ ๅโๆฌ็ผๆไน็ฎ็ๅจๆผๆไพไธ็จฎๅฐไฟ้ฒTTF็พ่ฑกๆไฝณ ไน้ๅฃๆๆใ ๆ นๆๆฌ็ผๆ๏ผๆไพไปฅไธไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ็ญใ 1 ยท ไธ็จฎๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผไปฅไธ่ฟฐๅผ๏ผ1 )่กจ็คบ๏ผ
(ๅผไธญโ Anไฟๅ
ทๆ1ๅไปฅไธ้ธ่ชๅๅ็ฐๅๅๅ็ฐไธญไน %็็ฑ4็ฐไปฅไธ็ธฎๅ่ๆไนmๅน็ธฎๅ็ฐๅบ๏ผ 201229048 :Alไฟไธ่ฟฐๅผ๏ผ2)ใ๏ผ5)่กจ็คบไนๅซๆฐฎ้็ฐๅบไธญไนไปป ่
๏ผ ๅ111ๅๅฅ็บ1ใ5ไนๆดๆธ๏ผไธญไน่ณๅฐไธ่
็บ1. Lไฟ้ธ่ช็ฑๅฎ้ตใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3 ใ ไนn f 1ๅ่ณๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ$ใไน ฮท + 1 4่ฒ้็ฐๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ ไน่ณๅบใๅ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐ ๅบๆ็ตๆไน็พคไธญไน2ๅใ3ๅไปฅๅฎ้ต้ฃ็ต่ๆ็n+ iๅนๅบ๏ผ
(4) (5) (ๅผไธญ๏ผRnใRi๏ผใR ฯ> ^ R21ใR22ใR3 ไธจใR4ใใๅ ใ ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใใฃๅๅญใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๆธใ1 Gไนใฃ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ ็งๅบ๏ผcycloaikyl)ใ็ขณ้ยท q ฮ , ๅฑๆฐ3ใ30ไน็ถๅไปฃไน็ฝๅบใๆฐฐๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใ Uไน็ทๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณ็พA ^ ^ ๆนๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธใ ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๅป ้ฃๆช็ถๅไปฃไน็ขณๆธฯใ30ไน่ณ็กซๅบ 201229048 (arylthio )ใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ (arylamino)ใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅ ๅบ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6 ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ3ใ R31ใR35ไธญไนไปปไธๅๅR36ใR4ใไธญไนไปปไธ ไน2ๅๅผๅถ็ฐๅฝผๆญค้ต็ตไนๅฎ้ต๏ผ 6ใ30ไน่ณ่บๅบ ใ20ไนๅฎๆไบ็ท ใ3 0ไน่ณๅบใๆ ไน้็ฐๅบ๏ผ ๅไฟๅฐๅผ๏ผ4 ) ้ธ่ชNๆCR|3โR13Sๆฐซๅๅญ /ฮทไฝๅใ็ถๅไปฃ ๆช็ถๅไปฃไน้ญไน้ขๅบ '็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ็ขณๆธ3ใ8ไน็ฐ้ขๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ณๅคๅบใๆฐๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน้ญๅ2()ไน็ๆฐงๅบใ็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐใฃ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใๆฃไน่ณ ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3Gไน่ณ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไน็ขณๆธๅโผไนๅฎๆไบ็งๅบ่บๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30ไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ ๅ ๆผๅ
ทๆ่คๆธๅR! 3ไนๆ
ๅฝขๆ ๅๅRuๅฏ็ธๅๆไบฆๅฏไธ Y้ธ่ชNๆCR23, R23ไฟๆฐซๅๅญใ้ฝ็ด ๅๅญใ็ถๅไปฃๆ ๆช็ถๅไปฃไน็ขณๆธiใ1ใไน็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ฝๅบใๆฐฐๅบใ< ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ20ไน็ทๆฐงๅบใ็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ 201229048 ็กซๅบใ็ถๅไปฃๆๆช็ถๅๆ ๅไปฃไน็ขณๆธ6ใ30ไน่ณ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใ ไธ ไนๆฉๆไบ็ทๅบ่บๅบใ็ถๅไปฃๆ ็ถยทๅไปฃไนๆ็ฐ็ขณๆธ6ใ3 ใ $ # ไนๆนๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃ ไนๆไธจ่กฃๅๅญๆธ5ใ3 0ไน้็ฐๅบ. ๆผๅ
ทๆ่คๆธๅR23ไนๆ
ๅฝขๆ๏ผๅๅ&ๅฏ็ธๅๆไบฆ ๅ๏ผ Zไฟไบค่ฏๅบ๏ผ็บ็ถๅไปฃๆๆช็ถๅไปฃไนไผธ็ทๅบ (a].kylene )ใๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนไผธ็ฏ^ (alkenylene)๏ผ
RiiใRI3ไธญไนไปปไธๅใr2iใRnไธญไนไปปไธๅใ . . Jไธจ ๅ
ซ40 ๅๅ1ใRmไธญไนไปปไธๅไฟ่l้ต็ตไนๅฎ้ต๏ผใ 2.ๅฆ1ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผๅ
ถไธญ๏ผAri็บไธ่ฟฐๅผ๏ผ6) ่กจ็คบไน็ธฎๅ็ฐๅบ๏ผ
(ๅผไธญ๏ผRS1ใR58ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธใใ๏ผใไน็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ30ไน็ถๅไปฃไน็ฝ็พใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใโไน็ทๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไน็ขณๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ30ไน่ณ่บๅ
ถใ็ถ 201229048 ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธiใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3ใไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ R52ใR52 ่ R53ใR53 ่ R54ใใ่ R55ใR55 ่ R56ใR56่R57ๅR57่r58ไธญไน่ณๅฐi็ตไฟไปฅไธ่ฟฐๅผ๏ผ7 ) ๆ๏ผ8 )่กจ็คบไนๅฝขๆ
็ธไบ้ต็ต่ๅฝขๆ็ฐ๏ผ ^65
R68 ^61 /ๆฌข:2 ^64 (8) โบ (ๅผไธญ๏ผๅฐบโใๅฐบ68ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅ1()ไน้ฒใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ฝๅบใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅ2()ไน็ซๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2Gไน่ณๆฐงๅบใ็ถๅไปฃๆๆชใฃ ไปฃไน็ขณๆธๅ20ไน็ง็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ๏ผ
ไนๆน็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ่บ็พ^ ๅ๏ผๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใไนๅฎๆไบ้ขๅบ่บๅบใ๏ผๅ๏ผ ๆt็ถๅtไนๆ็ฐ็ขณๆธ6ใฮไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ๏ผ
ๅๅญๆธ5ใ3 0ไน้็ฐๅบ๏ผยท L้ต็ตไนๅฎ้ต๏ผใ ๅ
ถไธญ๏ผAr,็บไธ่ฟฐๅผ ๅโ R0IใResไธญไนไปปๆmๅไฟ่ 3_ๅฆ1ๆ2ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ 201229048 (9)ๆ๏ผ10)่กจ็คบไน็ธฎๅ็ฐๅบ
ไธญR*7ใใๅฐบ9ใๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ็ถ ไปฃๆๆช็ถๅไปฃไน็ขณ& 1ใ10 t & 1ใ็ถ#ไปฃๆๆช็ถๅไปฃ ่กฃๅๆธ3ใ8ไน็ฐ็งๅบใ็ ดๆธ3ใ30ไน็ถๅไปฃไน็ณๅคๅบใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไน็ทๆฐงๅบใ็ถๅไปฃ ๆๆชใๅๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ ๅผไน็ญๆธ1ใ2 ใไน้ข็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3 ใ ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ30ไน่ณ่บๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30ไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ ๅ๏ผR7ไธจใRsoไธญไนไปปๆmๅๅR8ไธจใhoไธญไนไปปๆmๅ ไฟ่L้ต็ตไนๅฎ้ต๏ผใ 4ยทๅฆ1ๆ2ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผๅ
ถไธญ๏ผAri็บไธ่ฟฐๅผ (11)ใ๏ผ12)ใ๏ผ13)ๆ๏ผ14)่กจ็คบไน็ธฎๅ็ฐๅบ๏ผ 201229048 R91
(12)
D
(14) (ๅผไธญโ R91ใRไธจ3ใๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้ฝ็ด ๅๅญใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ1ใไน็ทๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ30ไน็ถๅไปฃไน็ณๅค ๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไน็ทๆฐกๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไน็ขณๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6 ใ30ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ30ไน่ณ่บๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅ ไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30ไน่ณๅบใๆ่
็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ ๅโ R9ไธจใR1ใใไธญไนไปปๆmๅใRiใไธจใRnใไธญไนไปปๆm 201229048 ๅใRlไธจไธจใRl20ไธญไนไปปๆๅๅRuไธจใRuใไธญไนไปปๆmๅไฟ ่Lยท่ธบ็ตไนๅฎ้ต๏ผใ :5ยทๅฆ1ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผไธญAri็บไธ่ฟฐๅผ๏ผ15)่กจ ็คบไน็ธฎๅ็ฐๅบโ
(15) k 'ๆฐไธๅ
ซไธจ3ไธจใฮบไธจ4ใๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ10ไน็ทๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ฝ ๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅโผไน็งๆฐงๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2ใไน่ณๆฐงๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไน็ขณๆธๅโผไน้ข็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6 ใ30ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ่บๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๅๅ2()ไนๅฎๆไบ้ขๅบ่บๅบใ^ๅ ไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณ| 6ใ3ใไน่ณๅบใๆ่
็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ3 0ไน้็ฐๅบ๏ผ ๅ
ถๅโ Rไธจ3ไธจใใใไธญไนไปปๆๅๅบไฟ่L้ต็ตไนๅฎ้ต๏ผใ ๅฆ1่ณ5ไธญไปป-้
ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ 1๏ผฮท ็บ 1ใ ใT m ้ฉฌ 201229048 7ยทๅฆ1่ณ6ไธญไปปไธ้
ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผๅ
ถ็บๆๆฉ้ป ๆฟ็ผๅ
ๅ
ไปถ็จๆๆใ 8.ๅฆ7ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉโๅ
ถไธญโไธ่ฟฐๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ็จๆๆ็บ้ๅฃๅฑคๆๆใ 9ยท ไธ็จฎๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไพๅบๅ
ทๅ้ฝๆฅตใ็ผๅ
ๅฑคใ ้ๅฃๅฑคๅ้ฐๆฅต๏ผ ไธ่ฟฐ้ๅฃๅฑคๅซๆ1่ณ6ไธญไปปไธ้
ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉใ 10.ๅฆ9ไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไธญ๏ผๆผไธ่ฟฐ้ๅฃๅฑค่ ้ฐๆฅตไน้ๅ
ทๆ้ปๅญๆณจๅ
ฅๅฑคๅ/ๆ้ปๅญๅณ่ผธๅฑค๏ผไธไธ่ฟฐ้ปๅญ ๆณจๅ
ฅๅฑคๅ้ปๅญๅณ่ผธๅฑคไธญไน่ณๅฐ1ๅฑคๅซๆๅซ้็ฐ่ก็็ฉใ 11 ยทๅฆ10ไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไธญ๏ผไธ่ฟฐ้ปๅญๆณจๅ
ฅๅฑค ๅ/ๆ้ปๅญๅณ่ผธๅฑคๅซๆไพ้ปๅญๆงๆป้็ฉใ 12 ยทๅฆ1 1ไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไธญ๏ผไธ่ฟฐไพ้ปๅญๆงๆป ้็ฉไฟ้ธ่ช็ฑ้นผ้ๅฑฌใ้นผๅ้ๅฑฌใ็จๅ้ๅฑฌใ้นผ้ๅฑฌไนๆฐง ๅ็ฉใ้นผ้ๅฑฌไน้ฝๅ็ฉใ้นผๅ้ๅฑฌไนๆฐงๅ็ฉใ้นผๅ้ๅฑฌไน ๅฝๅ็ฉใ็จๅ้ๅฑฌไนๆฐงๅ็ฉใ็จๅ้ๅฑฌไน้ฝๅ็ฉใ้นผ้ๅฑฌ ไนๆๆฉ้ฏๅ็ฉใ้นผๅ้ๅฑฌไนๆๆฉ้ฏๅ็ฉๅ็จๅ้ๅฑฌไนๆๆฉ ้ฏๅ็ฉๆ็ตๆไน็พคไธญไน1็จฎๆ2็จฎไปฅไธใ 13.ๅฆ9่ณ12ไธญไปปไธ้
ไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไธญ๏ผไธ ่ฟฐ็ผๅ
ๅฑคๅซๆไธ่ฟฐๅผ๏ผไธจ6 )่กจ็คบไน่ฝ่ก็็ฉ๏ผ 12 201229048 ^208 ^201 ^207-R 202
Ar12-^VAri1 (16)
Fv206~^_/-R203 R205 R204 (ๅผไธญโ ฮฮนยทฮทๅใๅๅฅ็บ็ถ ็ขณๆธ6ใ30ไน่ณๅบใๆ่
็ถๅไปฃๆๆชๅฟไปฃไนๆ๏ผ ใ3 0ไน้็ฐๅบ๏ผ ๆ็ฐๅๅญๆธ ้201ใฮ208ๅๅฅ ไน็กMl in ^ u. ^ 'ใ ็ถๅไปฃๆๆช็ถๅไปฃ ไน็ขณๆธ1ใ1ใไน็ทๅบใ็ถๅไปฃๆๆช ไปฃ
^ ^ t nไนๆ็ฐ็ขณๆธ3ใU ไน๏ผ
็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน , ๅๆธ3ใ3ใไน็ท็ฝๅบ (alkylSllyl)ใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ8ใ30ไน่ณ็ณๅค ๅบ๏ผarylsilyl)ใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธฮนใ2ใไนไฟจๆฐง็พ ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๅ6ใ2ใไน่ณๆฐงๅบ '็ถๅไบๆ ๆช็ถๅไปฃไนๆ็ฐ็ขณใ6ใ3Gไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐๅๅญๆธ5ใ3 0ไน้็ฐๅบ๏ผใ 14.ๅฆ13ไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไธญ๏ผๅซๆไธ่ฟฐๅผ๏ผ16) ่กจฯใไน่ฝ่ก็็ฉไน็ผๅ
ๅฑค่ๅซๆไธ่ฟฐๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไน ้ๅฃๅฑค็ธๆฅใ 15.ๅฆ9่ณ14ไธญไปปไธ้
ไนๆๆฉ้ปๆฟ็ผๅ
ๅ
ไปถ๏ผๅ
ถไธญ๏ผไธ ่ฟฐ็ผๅ
ๅฑคๅ
ทๆไธปๆณขๅณฐๆณข้ท็บ5ใใ nmไปฅไธไน่ขๅ
ๆป้็ฉใ ๆ นๆๆฌ็ผๆ๏ผๅฏๆไพไธ็จฎๅฏ้ฒๆญขๆฝๅ ้ปๅฃไนไธๅไธฆๅฉ ็จฮฮคฮ ( Tripletโ Triplet Fusion)็พ่ฑกไฝฟๆๆฉELๅ
ไปถ้ซๆ 13 201229048 ็ๅฐ็ผๅ
ไนๆฐ็ฉไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉใ ใๅฏฆๆฝๆนๅผใ ๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไฟ ๆปๅผ๏ผฮๆ่กจ็คบใ (ฮฮ1^~~(~ๅ HAr) (1) ใโฆ^ ^ ^ ๏ผ HArไฟไธ่ฟฐๅผ๏ผ2 )ใ (5)่กจไธไนๅซๆฐฎ้็ฐๅบไธญไนไปป ็ฐ็็ฑ4็ฐไปฅไธ็ธฎๅ่ๆไนmๅน็ธฎๅๅทง๏ผ็ฐๅ็ฅๅ็ฐไธญไน T4 ฮ๏ผVไน-T-ใไธ๏ผ^ ^ * ่
๏ผ Lไฟ้ธ่ช็ฑๅฎ้ตใ็ถๅไปฃๆๆช ไน่ณๅฐ-่
็บ ไนn +ไธจๅฝณs # I *"ใ.ๅไปฃไนๆ็ฐ็ขณๆธฯใ3 0 =ๆ ไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญโฆใไน้็ฐ ๅๆค๏ผ.ใๆไน็พคไธญไน2ๅๆ3ๅไปฅๅฎ้ต้ฃ็ต่ๆ็โฆๅนๅบ๏ผ
โฆๅน็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ3ใไน ๅน้็ฐๅบ'ๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธHO
Ri'i
Rl2A^xi (2)
(5) 14 (4) 201229048
(ๅผไธญ โ R"ใRl2ใR2|ใR22ใR31ใR4Gใๅ R ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญ4็ด ๅๅญใ็ถๅไปฃๆๆช็ถๅ4ไปฃใไน;6 ๆธ1ใ10ไน็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ ็งๅบใ็ขณi 3ใ30ไน็ถๅไปฃไน็ณๅคๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถ =ไน็ขณๆธไน็งๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณ ใ20ไนๆนๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไนๆต ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน้ญ6ใ3Gไน่ณ็กซๅบใ็ถๅ2 ๆๆช็ถๅไปฃไน็ขณๆธ6ใ3Qไน่ณ็ตฒใ็ถๅไปฃๆๆช็ถๅไปฃไน =ๆธ^20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ็ขณๆธ6ใ3Gไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ$ ใ30ไน้็ฐๅบ๏ผ ๅฐบ4ใไธญไนไปปไธๅไฟๅฐๅผ๏ผ4 ) ๅฐบ3.ใR35ไธญไนไปปไธๅๅr36, ไน2ๅๅกๅถ็ฐๅฝผๆญค้ต็ตไนๅฎ้ต๏ผ X้ธ่ชNๆCR13, Rl3ไฟๆฐซๅๅญใ่ช็ด ๅๅญใ็ถๅไปฃๆ ๆช็ถๅไปฃไน็ขณๆธไธจใ10ไน้ขๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ฝๅบใๆฐฐๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใๆฑไน็ทๆฐงๅบใ็ถๅไปฃๆ^็ถ ๅไปฃไนๆ็ฐ็ขณIt 6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไน็ขณๆธiใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30ไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ 15 201229048 ๅ๏ผ Y้ธ่ชNๆCr23 โ R23#tๅๅญใ้ฝ็ด ๅๅญใ็ถๅไปฃๆ ๆช็ถๅไปฃไน็บ1ใฮ )ไนๅธๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ็ขณๆธ3ใ8ไน็ฐ็งๅบ '็ขณๆธ3ใ3Gไน็ถๅไปฃไน็ณๅคๅบ' ๆฐฃๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน้ญiใ2Gไน็งๆฐงๅบใ็ถๅไปฃๆๆช็ถ ๅไปฃไนๆW 6ใ2ใไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๆธ1ใ20ไน็ง็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ ด้ฝก _ ใๅฟๅๆฐ6ใ30ไน่ณ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใไนๅฎๅฟ^ u _ ๆฉๆฌกไธ็ทๅบ่บๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3 0ไน^:็ V.. ใ ๆนๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ ๆผๅ
ทๆ่คๆธๅR_23ไนๆ
ๅผๅฝกHiยท Ar l ้ๅฝขๆ๏ผๅๅR23ๅฏ็ธๅๆไบฆๅฏไธ ๅ๏ผ zไฟไบค่ฏๅบโ็บ็ถๅไปฃๆ+ 4ใๅ/ n้ฃๆช็ถๅไปฃไนไผธ็ทๅบใๆ็ถๅไปฃ ๆๆช็ถๅไปฃไนไผธ็ฏๅบ๏ผ
RlไธจใR|3ไธญไนไปปไธๅใR ^ , R21ใR23ไธญไนไปปไธๅใR31ใR4ใ ไธญไนไปปไธๅใๅr41ใr46ไธญ -vr ^ ua ไปปไธๅไฟ่l้ต็ตไนๅฎ้ต๏ผใ ๅผโด่กจไธไน้ฉ่ผไฝณ็บไธ่ฟฐๅซๆฐฎ้็ฐๅบไธญไนไปปไธ่
ใ 16
S 201229048
(ๅผไธญ๏ผR2 ไธจไธจ่ณ R2ไธจ6ใR22ไธจ่ณ R225ใR231 ่ณ R235ใr24i ่ณ R245 R251 ่ณ R25 5ใR261 ่ณ R264ใR27i ่ณ r274ใไธจ่ณ R2^ใ 291่ณR_294ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ็ถๅไปฃๆๆช ็ถๅไปฃไน็ขณใๅ10ไน็งๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณ ๆธ3ใSไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ฝๅบใๆฐฐๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅ2()ไน้ขๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ :ไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธJ ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใไน่ณ็กซ็พใ SICๅไปฃไน็ขณๆธ6ใ30ไน่ณ่บๅบใ็ถๅไปฃๆ:็ถ ไธ 20ไนๆฉๆไบ็ทๅบ่บๅบใ็ถๅไปฃๆๆช็ถๅ ::ฮฮ:3ใไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ๅ๏ผๆธ5ใ30ไน้็ฐๅบ๏ผ ๆผๅ้็ฐๅบไธญ๏ผr2"่ณR2i6ใU R225ใใ่ณrใ 241 ่ณ R245ใR25i ่ณ ใIQ ่ณ ใr 235 ฮ ไธโฆ94ไธญไนไปปไธๅไฟh้ต็ตไนๅฎ้ต7;ใ 17 201229048 ๅผ๏ผ3 )่กจ็คบไนHAr่ผไฝณ็บไธ่ฟฐๅซๆฐฎ้็ฐๅบไธญไนไปปไธ่
(ๅผไธญ๏ผRๅท่ณ R3I6ใr321 ่ณ R3 25ใIโ ่ณใIโ ่ณR345ใR351่ณR355 ' R361่ณR364ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต ็ด ๅๅญใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ1ใไน็ทๅบใ็ถ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅ ไปฃไน็ฝๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ2ใไน็ทๆฐง ๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2ใไน่ณๆฐงๅบใ็ถๅ ไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ2ใไน็ท็กซๅบใ็ถๅไปฃๆ^็ถๅไปฃ ไน็ขณๆธ6ใ30ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ ไน่ณ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ2ใไนๅฎๆไบ็ทๅบ ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3ใไน่ณๅบใๆ^ fๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ3ใไน้็ฐๅบใๆผๅ้ ็ฐๅบไธญ โRๅท่ณ R3l6ใR32d R32 5ใr33i ่ณ R3 35ใR34ไธจ่ณ ๅโ่ณR3 55ใR36]่ณI64ไธญไนไปปไธๅไฟ่L้ต็ตไนๅฎ้ต ๅผ๏ผ4 )่กจ็คบไนHAr่ผไฝณ็บไธ่ฟฐๅซๆฐฎ้็ฐๅบไธญไนไปปไธ่
ใ 201229048
(ๅผไธญ โ R4 ไธจไธจ่ณ R418ใR421 ่ณ R428ใR43i ่ณ r438ใr44i ่ณR448 ' R45ไธจ่ณR458ใๅฐบ46ไธจ่ณR468ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต ็ด ๅๅญใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใi 0ไน็ทๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็งๅบใ็ขณๆธ3ใ3 ใไน็ถๅ ไปฃไน็ฝๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธใใไน็ทๆฐง ๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2ใไน่ณๆฐงๅบใ็ถๅ ไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใโไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไน็ขณๆธ6ใ3 0ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3 ใ ไน่ณ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไนๅฎๆไบ็ทๅบ ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3ใไน่ณๅบใๆ่
^ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบใๆผๅ้ ่กฃๅบไธญโR4ใไธจ่ณR418ใR42ไธจ่ณR428ใR43ไธจ่ณR438ใRโไธจ่ณRโ8ใ 451 458ใR46ใ่ณR468ไธญไนไปปไธๅไฟ่L้ต็ตไนๅฎ้ต๏ผใ โๅผ๏ผ4)่กจ็คบไนHAr่ผไฝณ็บ๏ผ4โไธจ๏ผ่กจ็คบไน็ตๆงใๆผ๏ผ4 :1)ไน็ตๆงไธญ๏ผๅฝขๆ2ๅๅกๅถ็ฐไนๆฐฎๅๅญๆฅ่ฟไน็ตๆงใๅจ ๅ
ทๆ่ฉฒ็ตๆงไนๆๆไธๅ
ฑ่ธ้ๅ
ทๆไปฅLiใNa็ญ็บไปฃ่กจไน้ๅฑฌ ๅญไนไพ้ปๅญๆงๆป้็ฉ่ไฝฟ็จไนๆ
ๅฝขๆๅฏๆผ๏ผ4 _ 1 )่กจ 19 201229048 ไธไน่ฏยฐๆฏ1^็ตๆงไน2ๅๆฐฎๅๅญๅฝขๆ้
ไฝๆผ้ๅฑฌๅๅญๆ้ๅฑฌ ้ขๅญไนfๅ็ตๆง๏ผๅ ๆญคๅฏ่ช็บ่ไธ่ฟฐไพ้ปๅญๆงๆป้็ฉไนๅ ๆๆงๅๅ
ฉ๏ผๅฏ่ช็บๅฏๆด็บๆๆๅฐ็ฒๅพไพ้ปๅญๆงๆป้็ฉไน ๆใ
ๅผ๏ผ5 )่กจ็คบไนHAr่ผไฝณ็บไธ่ฟฐๅซๆฐฎ้็ฐๅบไธญไนไปปไธ่
ใ
ๅฐ็บ๏ผ^๏ผโ่ณโ^่ณโโฆ่ณไปๅๅฅ็จ็ซ .ยท๏ผ้โใใ้ฝ็ด ๅๅญใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธH ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ้ขๅบใ็ขณ ไน็ด
ๅไปฃไน็ฝๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๅ
ถๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2ใ : = ไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ยฐไน็ง็กซๅบใ็ถ ==ๅไปฃไน็ขณๆธ6ใ3ใไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๅฅดๆธ6ใ30ไน่ณ่บๅบใ็ฆๅๆ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20 ไนๆฉๆไธ็ทๅบ่บๅบ' ็ถๅไปฃๆๆช็ถ ไธ#็ฌช -V & ๅ
ซไน็ๆ ธ็ณๅๆธ6ใ3 0 =ๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้ %::ๆผๅ้็ฐๅบไธญ๏ผRไนไปปโๅไฟไฝ็บๅฎ้ต่L้ต็ตใ R%ๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต่พ ^ t 1ฮ ^ , ไบฌๅๅญ '็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณโฆไน็ฐ ็ซๅบใ็ณๅๆธ30ไน็ถๅไปฃไน็ณๅคๅบใๆฐๅบใ็ถๅไปฃๆๆช็ถ 20 201229048 ๅไปฃไน้่ตต ใ1ใ20ไน็ทๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณ ๆธ6ใ2()ๅคๆๅนด# ็ๆนๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธiใ2ใไน็ท ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธiใ2ใ #. # ใๅ 4 ไธ ฮ ใใๅๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธฯใ30ไน่ณๅบใๆ ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ3ใไน้็ฐๅบ๏ผใ ่้่กฃA"ไนๅ
ทๆ1ๅไปฅไธ้ธ่ชๅๅ็ฐๅๅๅ็ฐ๏ผไปฅไธไบฆ ็ธฝ็จฑ็บๅซๆฐง็ฐใ๏ผไธญไน็ฐ็็ฑ4็ฐไปฅไธ็ธฎๅ่ๆไน็ผฉๅ็ฐ ๅบโใโ็ฐไปฅไธ็ธฎๅ่ๆไน็ธฎๅ็ฐๅบใไฟๆๅ
ทๆๅฆไธ๏ผๆง ไน็ธฎฮท %ๅบ.ๅ
ทๆใๅไปฅไธ้ธ่ชๅๅ็ฐๅๅๅ็ฐไปคไน็ฐ๏ผ ไธ้ธ่ช็ถๅไปฃๆๆช็ถๅไปฃไน่ฏ็ฐฮบ็ฐฮ็ฐ"ๆฏๅฃๅนถ ็ฐใๅฟไบ็ฐไน็ฐๆผๅซๆ่ฉฒๅซๆฐง็ฐไน็ตๆงไธ้ฒ่ก็ธฎ็ฐ๏ผๅ่จ ็ธฎ็ฐๆ4็ฐไปฅไธใ
At่ผไฝณ็บๅ
ทๆๅฆไธ็ตๆงไน็ธฎๅ็ฐๅบ๏ผๅ
ทๆไธจๅไปฅไธ้ธ ่ชๅณๅ็ฐๅๅๅ็ฐไธญไน็ฐโไธ่ฏ็ฐๆผๅซๆ่ฉฒๅซๆฐง็ฐ ไธ้ฒ่ก็ธฎ็ฐ๏ผๅ่จ็ธฎ็ฐt 4็ฐไปฅไธ๏ผๅฐคไฝณ็บๅ
ทๆๅฆไธ:ๆง ไน็ธฎๅ็ฐๅบ๏ผๅ
ทๆiๅๆ2ๅ้ธ่ชๅณๅ็ฐๅใฃ็ฐไธญไนไบ๏ผ ไธ็ฌจ็ฐๆผๅซๆ่ฉฒๅซๆฐง็ฐไน็ตๆงไธ้ฒ่ก็ธฎ็ฐ๏ผ็ธฎ็ฐๆ4 I ไธใ ๅ่
๏ผๆฌ่ชชๆๆธไธญใ็ธฎๅ็ฐใไฟๆ้ฐๆฅไน็ฐๅฝผๆญค ๅๅๅญไนๅค็ฐ็ณป็ฐใ $
Ariไน็ธฎ็ฐๆ4็ฐไปฅไธไน็ฐ็ตๆงๅ
ทๆ่ผ้ซไนๅนณ้ขๆง ่ช็บ๏ผ่ฅๆๆฉELๆๆๅ
ทๆๅนณ้ขๆง่ผ้ซไน็ตๆง๏ผๅๅๅญๅฝผ\ ไน้ๅๅขๅคง่ๅๅญๅฝผๆญคไน่ท้ข็ธฎ็ญ๏ผi็ฑๆผ ;๏ผ ๆง๏ผ่ๅฏๅฏฆ็พๅ
ไปถไนไฝ้ปๅฃ้ฉ
ๅใ 7ๅณ่ผธ 21 201229048 ๆฐ ๅ
ทๆ3ๆฐง็ฐไน็ธฎๅ็ฐ็ตๆงๅ
ทๆ่ผ้ซไนไธ้ๆ
่ฝ Sๅธถๆ๏ผใๆใไบฅ3ๆฐง็ฐไน็ธฎๅ็ฐไนๅๅ็ฉ็ฑๆผไธ้ๆ
่ฝ้ ๅขๅคง๏ผๆ
ๅฏ่็ฑ็จไฝไพๅฆ่ๆๆฉ่ๅ
ไปถไน็ผๅ
ๅฑค้ฃ็ตไน้ ๅฃๅฑคไนๆๆ่ไฟ้ฒTTF ฯๅค ็พ่ฑกใๅฐฑ่ฉฒ่ง้ป่่จ๏ผไฝ็บAr,ไน ๅซๆฐง็ธฎๅ็ฐ็ตๆง๏ผๆดไฝณไน ็& ็บไธๅซ็ฑ3ๅ่ฏ็ฐ็ด็ทๅฐ็ธฎ็ฐ่ๆ ไน่ฝ็ตๆงไฝ็บ้จๅ็ตๆง่
ใ ไพๅฆ๏ผๆผArไธจ็บๅ
ทๆ๏ผๅ lu Mไธๅคฉใๅ๏ผ
ไน็ฑ4็ฐไปฅไธ็ธฎไบบ ่ๆ็็ธฎๅ็ฐๅบไนๆ
ๅฝข็ ^ ไธๆฒฒฮฑ ใฃๆโๅฏๅ่ไธ่ฟฐ็ธฎๅ็ฐๅบใ
(ๅผไธญ๏ผฮฮนยทๅๅฅ่กจ็คบ็ถๅไปฃๆๆช็ถๅไปฃไน ๅฌ็ฐโฆๆฏ,ไบ็ฐๆๅใไบ็ฐ๏ผๅๅฅ โฆๆฏๅถ ็ฐใๅ๏ผ่ฉฒ็ญ็ธฎๅ็ฐไบฆๅฏ้ฒ่่่ฏ็ฐใ๏ผ่กฃๅฝขๆ็ธฎๅ ยฐๆฏยฐไบ็ฐๆๅกๅด็ฐๅฝขๆ็ธฎ็ฐ็ตๆง๏ผใ 1ๅฌ็ฐใ ไธ่ฟฐๅ
ซHๅ่ขซไน็ธฎๅ็ฐๅบ่ผไฝณ็บไธ ็ธฎๅ็ฐๅบ๏ผๆด4ๅปๆๅผ๏ผ6)็ฃ-ฮ ๆดไฝณ็บๅ
ทๆ1ๅ^ๅ็ฐไนไธ่ฟฐ ๏ผ่กจไธไน ไธญไนไปปไธ่
่กจ็คบไน็ผไบบไบง่ฃ
, )ใ๏ผ1ใใ riM , ็ธฎ0 J่กฃๅบ๏ผๆๅ
ทๆ2ๅใ1ใ) Dใ๏ผโทไธญไนไปป-่
่กจ็คบไน็ธฎๅ็ฐๅบใใไธ่ฟฐๅผ 22 (6) 201229048
VAT 1 > ๅไปฃ^ๆช็ถๅไปฃไน็ขณๆธๅ1()ไน็งๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็งๅบใ็ขณๆธ3ใ30ไน็ถๅไปฃไน็ๅบใ ๆฐฐๅบใ็ถๅไปฃๆๆช๏ผ็ถๅไปฃไน็ขณๆธๅโผไน้ขๆฐงๅบใ็ถไบไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2 0ไน่ธฯๅ
ถ ฮป- โ , ^ ^ โผไนๆนๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ ไน่กฉๆ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ๏ผ
็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3()ไน่ณ่บๅบใ็ถ ไปฃๆๆช็ถๅไปฃไน็ขณๆธ ๅ่็บซๆฃ& i ๆฉ$ ไธๅๅบ่บๅบใ็ถๅไปฃ ๅๆช็ตฐๅไปฃไนๆ็ฐ็ขณๆธ6ใ ^ . , ๆนๅบๆ็ถๅไปฃๆๆช็ถๅ ๆไนๆ่ฏฅๅๅญๆธ5ใ3 0ไน้็ฐๅบ๏ผ ๆฑ51 ๅ R52ใR52 ๅ R53ใR53 ๅ ๅ Fยท D โ 54 ฮบ54 ๅ๏ผI55ใR55
ๅๅฐบ56ๅR57ใๆ17ๅR (7 ) ๅฃซ r ใใ* - 8 ฮคไน่ณ๏ผ1็ตไฟไปฅไธ่ฟฐๅผ )่กจไธไนๅฝขๆ
็ธไบ้ต็ต่ๅฝขๆ็ฐ๏ผใ /0ใ ^61 I] ๏ผR62 R65 ็64 ใr63 ๆฑ68 โบ (8) (ๅผ ไธญ๏ผ ๅฐบ6ไธจใ / R68ๅๅฅ็จ
ๅฐ็บ ๆฐฃๅๅญใๅค็ด ๅๅญใ็ถ 23 201229048 ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ10ไน็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3 0ไน็ถๅไปฃไน็ขๅบใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใๆฑไน็ทๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไน็ขณๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ30ไน่ณ่บๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3 0ไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐๅๅญๆธ5ใ30ไน้็ฐๅบ๏ผ ๅโ Rs!ใR68ไธญไนไปปๆmๅไฟ่L้ต็ตไนๅฎ้ต๏ผใ
(ๅผไธญ๏ผRuใR9ใๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ1 ใไน็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ๏ผ
ๆฟๆธ3ใ8ไน็ฐ็งๅบใ็ขณๆธ3ใ3 0ไน็ถๅไปฃไนๅฆๅ
ถใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใไน็ทๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ 24 201229048 ไปฃไน็ขณๆธ1ใ2ใไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3 0ไน่ณ่บๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30ไน่ณๅบ 'ๆ่
็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐๅๅญๆธ5ใ3 0ไน้็ฐๅบ๏ผ ๅ.ไธจใr80ไธญไนไปปๆmๅๅR8iใR9ใไธญไนไปปๆ็ชๅ ไฟ่L้ต็ตไนๅฎ้ต๏ผใ R91
R
(12)
D
M19 118
R
(14) (ๅผไธญ๏ผR9!ใRnoๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญ' ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใ"ไน็ทๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃไน็ณๅค ๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใไน็งๆฐงๅบใ็ถ 25 201229048 ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไน็ขณๆธ1ใ20ไน็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6 ใ3 0ไน^โข็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3 ใไน่ณ่บๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅ ไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30ไน่ณๅบใๆ่
็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ3 ใไน้็ฐๅบ๏ผ ๅ๏ผR9IใRไธจ00ไธญไนไปปๆmๅใR|ใiใR||ใไธญไนไปปๆ็ช ๅใRiiไธจใRไธจ20ไธญไนไปปๆmๅๅRl2๏ผใR|3ใไธญไนไปปๆmๅไฟ ่L้ต็ตไนๅฎ้ต๏ผใ ๆผไธ่ฟฐๅ
ทๆๅๅ็ฐไน็ธฎๅ็ฐๅบไธญ๏ผๅฐคไฝณ็บๅ
ทๆ โผโฆฮท - jug '7 ๅ็ฐไนไธ่ฟฐๅผ๏ผ11)ใ๏ผ14)ไธญไนไปปไธ่
่กจ็คบไน็ธฎๅ็ฐๅบ ๅฏ่ช็บโๅ
ทๆ่ฉฒ็ญ็ธฎๅ็ฐๅบไนๆฌ็ณ่ซๆกไนๅๅ็ฉ็ฑๆผๅ
ท? ๆดๅคงไนไธ้ๆ
่ฝ้๏ผๆ
ๅฐ้ไธ้ๆ
ๆฟๅญไน่ฝๅ้ฒ่ๆ้ซ ๅฏ้็บ่ฉฒๆ
ๆณไฟ็บๆ็ๆดไฝณๅฐๅผ่ตทไธ& TTF็พ่ฑก่ๆๅฉๅฃซ ็ผๆฎๅ่ฝใๆ้ซๆๆฉELๅ
ไปถไน็ผๅ
ๆ็ไนไธ่ฆๅ ใ ไพๅฆ๏ผๆผArไธจ็บๅ
ทๆ1ๅไปฅไธ ไธ่ฃๅJ่กฃไน็ฑ4็ฐไปฅไธ็ธฎ1 ่ๆ็็ธฎๅ็ฐๅบไนๆ
ๅฝขๆ๏ผๅฏๅ้ถ ฯใๅ่ไธ4็ธฎๅ็ฐๅบใ
ไน่ฏ็ฐใๅกๅถ ๅค็ฐๅฝขๆ็ธฎๅ (ๅผไธญ๏ผฮฮๅๅฅ่กจ็คบ็ถๅไปฃๆๆช็ถๅไปฃ ๏ผๅฌ็ฐใยฐๆฏยฐไบ็ฐๆๅกโน๏ผๅๅฅ่้ฐๆฅ 26 201229048
ใๆฏๅถ็ฐใ ๆๅๅ็ฐไน็ธฎๅ็ฐๅบ่ผไฝณ ไน็ธฎๅ็ฐๅบใ ๅงๅถ็ฐใ ไฝณ็บไธ่ฟฐๅผ๏ผไธ5
Rl33 p R135Rl36 K134 (15) (ๅผไธญ๏ผใrmใๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธH0ไน็ทๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ3ใ8ไน็ฐ็ทๅบใ็ขณๆธ3ใ30ไน็ถๅไปฃไน็ฝ ๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2 ใไน้ขๆฐงๆใ็ถ ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไน็ขณๆธ1ใ2 0ไน็ง็กซๅบใ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไน็ขณๆธ1ใ20ไนๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ ็ฐ็ขณๆธ6ใ3 0ไน่ณๅบใๆ่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญ ๆธ3ใ30ไน้็ฐๅบ๏ผ ๅ๏ผR131ใR14 ใไธญไนไปปๆmๅไฟ่L้ต็ตไนๅฎ้ต๏ผใ ๆผๅผ๏ผ1 )ไธญ๏ผๆผฮท็บ2ไปฅไธไนๆ
ๅฝขๆ๏ผ่คๆธๅAri็ธ ไบๅฏ็ธๅๆไบฆๅฏไธๅใ็ธๅๅฐโๆผm็บ2ไปฅไธไนๆ
ๅฝขๆ๏ผ ่คๆธๅ๏ผL ไธ HAr)็ธไบๅฏ็ธๅๆไบฆๅฏไธๅใๅ๏ผๆผ็ช็บ2 27 201229048 ไปฅไธไนๆ
ๅฝขๅณ ' ่คๆธๅL่HAr็ธไบ4็ธๅๆไบฆๅฏไธๅใ 1 )ไนmๅn่ผไฝณ็บm= n= iใ
่ก่ชชๆ ้ๅฐๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไนๅๅไปฃๅบ้ฒ ไฝ็บR ใR X> ฮท 11 12ใR21ใR22ใR31 ใR40ใR41 ใฮยท46ใR5 ไธจใ
ใR61ใR 68ใR71ใR9ใใR9IใRไธจ30ใRmใRไธจ40ใRๅท่ณ 2'6 ' R22 1 ่ณ T5 ฮ 225 R23 ไธจ่ณ Rใ35ใR24 1 ่ณ ฮยท245ใฮยท251 ่ณ R255ใ
K26l ่ณ R e D 271 ่ณ R274ใๅฐบ281 ่ณ R284ใR291 ่ณ R294ใR3 1 1 ^ K316' R3?i $ p ๆ P 325 331 ่ณๅฐบ335ใๅฐบ341 ่ณๅฐบ345ใ1^351่ณ1:1355ใ ๆฐ3 61่ณ^ ^ ่ณ R 364ใR411 ่ณ R418ใR42i ่ณ R428ใR431 ่ณ R43 8ใR44i ๅ R, 45 ไธจ่ณ R458ใR46 ไธจ่ณ R468ใR5"่ณ R5 ไธจ 6ใR52 ไธจ่ณ R526ใ 1่ณR4ไนๆ็ฐ็ขณๆธ6ใ3ใไน่ณๅบ๏ผๅฏๅ่๏ผ่ฏๅบใ่ :=ๅบใ่ฏ่ฏๅบใ่ฏไธ่ฏๅบใๆฃๅบใ่ฏๅนถ่ฒ*ใ่ฏๅนถๆ
งๅบใ Lๅบ่ๅบใไธไบ็ฏๅ่ฌๅบใ่ๅบใ่ฏๅนถไธไบ็ฏๅ็ฌฌๅบใ ่ฏไผธไธ็ฌจๅบ็ญใไธ่ฟฐ่ณๅบไนๆ็ฐ็ขณๆธ่ผไฝณ็บ6ใ20,ๅฐคไฝณ็บ 6 ใ14ใ ไฝ็บ RuใR12ใr21ใR22ใR31ใR4ใใR41ใR46ใR51ใ R58ใR61ใr68ใR71ใR9ใใR9iใRi3ใใrโดใRโฝใR2n ่ณ R2I6ใR22i ่ณ R225ใR23 ไธจ่ณ IโใI"่ณๅฐบโฆใrโฆ่ณ R255ใ R26 ไธจ่ณ R264ใR27I ่ณ r274ใr28i ่ณ R284ใRโI ่ณ RwใR3" ่ณ RmใR321 ่ณ r325ใr33ไธจ่ณ r335ใR34ไธจ่ณ R345 'R35ใ่ณ R355ใ R361 ่ณ R3โใR4"่ณ R418ใR42ไธจ่ณ R428ใR431 ่ณ R438ใR44i ่ณ R448ใR451 ่ณ R458 'R46j r468ใr5"่ณ R5i6ใR52^ R526ใ ๅRใ่ณR'4ไนๆ็ฐๅๅญๆธ5ใ3ใไน้็ฐๅบ๏ผๅฏๅ่๏ผๅกๅถ 28 201229048 ๅบใDlt ฮฑไบๅบใฮฒๅฏๅฌๅบใๅกฮฑไบๅบใไธฮฑไบๅบใๅซไธจใๆตๅบใๅฅ็ณๅบใ ฯไธซๅฌๅบใยฐๆฏฯๅๅฌๅบใไบใๆก็งๅบใ11่พฐๅฌๅบใๅฆน็ณๅบใDๅบฮฑไบๅบใ ๅๅๅบใๅๅๅบใ11ๅกๅฉๅบใๅๅคๅบใยฐๆกไบๅพๅบใ่ฏๅนถๅๅค ๅบใUๅกฮฑๅๅบใๅไบๅณปๅบใ่ฏๅนถๅๅพๅบใไธฮฑๅๅบใใ็ฑณฯๅๅบใ ่ฏๅนถๅชใiiๅบใๅชๅๅนถๅกๅถๅบใ่ฏๅนถๅๅๅบใไบ่ฏๅนถๅๅๅบใ ไบ่ฏๅนถๅปๅฉๅบใๅกๅฏๅบใๅฒๅๅบ็ญใไธ่ฟฐ้็ฐๅบไนๆ็ฐๅ ๅญๆธ่ผไฝณ็บ5ใ20๏ผๅฐคไฝณ็บ5ใ1 4ใ ไฝ็บ RllใRl2ใฮยท21ใฮยท22ใๅฐบ31 ใฮยท40ใฮยท41 ใR46ใๅฐบ51 ใ ๅฐบ58ใๅฐบ61 ใๅฐบ68ใๅฐบ71 ใR90ใฮยท91 ใRl30ใฮยท131 ใRl40ใR211 ่ณ ฮยท216ใฮยท22 1 ่ณ R225ใๅฐบ231 ่ณ ฮยท23 5ใฮยท241 ่ณๅฐบ245ใๅฐบ251 ่ณๅฐบ25 5ใ R261 ่ณๅฐบ264ใๅฐบ27ไธจ่ณ ฮยท274ใๅฐบ281 ่ณๅฐบ284ใฮยท29 1 ่ณๅฐบ294ใฮยท311 ่ณ R3 16๏ผ_R321 ่ณ R>325ใR33 1 ่ณๅฐบ3 35ใๅฐบ341 ่ณ R345ใR351 ่ณ R355ใ ฮยท361 ่ณๅฐบ364ใๅฐบ411 ่ณ R418ใๅฐบ421 ่ณๅฐบ428ใๅฐบ431 ่ณๅฐบ438ใฮยท441 ่ณ R.4 48ใR4 5I ่ณ R4 58ใR4 61 ่ณ R468ใR511 ่ณ R516ใR521 ่ณ ฮยท526ใ ๅ่ณRโ4ไน็ขณๆธ1ใ10ไน็ทๅบ๏ผๅฏๅ่๏ผไนๅบใๆฑๅบใ ็ฐไธๅบใๆญฃไธๅบใไบ็ดไธๅบใไธ็ดไธๅบใๆๅบใๅทฑๅบ็ญใ ไธ่ฟฐ็ทๅบไน็ขณๆธ่ผไฝณ็บ1ใ8๏ผๅฐคไฝณ็บ1ใ6ใ ไฝ็บ RllใR12ใR2IใR22ใR31 ใฮยท40ใฮยท41 ใฮยท4 6ใฮยท51 ใ R58ใR61 ใๅฐบ68ใๅฐบ71 ใๅฐบ90ใR91 ใRl30ใRl31 ใRl40ใฮยท211 ่ณ ฮยท21<;ใฮฏใ221 ่ณ ฮยท225ใฮยท23ฮ ่ณๅฐบ23 5ใฮยท241 ่ณ ฮยท245ใR251 ่ณ R25 5ใ R26I ่ณ ฮยท264ใR271 ่ณๅฐบ274ใฮยท281 ่ณ ฮยท284ใฮยท291 ่ณ R294ใฮยท311 ่ณ](316ใฮยท321 ่ณ ฮยท325ใฮยท331 ่ณ R335ใR3 41 ่ณ R345ใR351 ่ณ ฮยท355ใ R36I ่ณๅฐบ364ใฮยท411 ่ณ ฮยท418ใๅฐบ421 ่ณ ฮยท428ใฮยท431 ่ณ ฮยท438ใฮยท441 ่ณ.ไน4 4!;ใ1^4 51่ณๅฐบ458ใ1^4 61่ณๅฐบ468ใๅฐบ511่ณๅฐบ516ใๅฐบ521่ณ1^526ใ 29 201229048 ๅR 1่ณR%ไน็ขณๆธ3ใ8ไน็ฐ็ทๅบ๏ผๅฏๅ่๏ผ็ฐไธๅบใ็ฐไธ ๅบใ็ฐๆๅบใ็ฐๅทฑๅบใ4 โ็ฒๅบ็ฐๅทฑๅบ็ญใไธ่ฟฐ็ฐ็ทๅบไน็ขณ ๆธ่ผไฝณ็บ3ใ6ใ
RuใRไธจ2ใR2ไธจใR22ใR3ไธจใR4ใใR41 ใr46ใr5 ใr58ใ R6 ไธจใR68ใR7I ใR9ใใR9ไธจใRi3ใใRi3 ไธจใ่ณ Rโ6ใ R221 ่ณ R225ใR231 ่ณ R2โใR24l ่ณ R245ใR251 ่ณ R2 5 5ใR26, ่ณ R264ใr27I ่ณ r274ใr28i ่ณๅฐบ284ใๅฐบ291่ณ r294ใrๅท่ณ R316ใ R32i ่ณ R3 25ใR331 ่ณ R33 5ใRโi ่ณ ใRโi ่ณ ใRwi ่ณ R364ใr4ไธจไธจ่ณ r4I8ใr42ไธจ่ณ r428ใR43ไธจ่ณ R43 8ใrโฆ่ณ โ8ใ Rๅท่ณR458ใR46ไธจ่ณr468ใR5ไธจไธจ่ณR5ใ6ใRโต่ณIโใๅR๏ผ, ่ณRโ4ไน็ขณๆธ3ใ30ไน็ถๅไปฃไน็ฝๅบ๏ผๅซๆ็ขณๆธ3ใ3ใไน็ท ็ผๅบๅๆ็ฐ็ขณๆธ8ใ30ไน่ณ็ณๅคๅบใ ไฝ็บไธ่ฟฐ็ขณๆธ3ใ30ไน็ท็ฝๅบ๏ผๅฏๅ่๏ผไธ็ฒๅบ็ฝๅบใ ไนๅบ็ณๅคๅบใไบ็ดไธๅบไบ็ฒๅบ็ณๅคๅบใไน็ฏๅบไบ็ฒๅบ็ณๅคๅบใ ไธๅบไธๆฑๅบ็ฝๅบ็ญใไธ่ฟฐ็ท็ฝๅบไน็ขณๆธ่ผไฝณ็บ3ใ2ใ๏ผๆดไฝณ ็บ3ใ1ใ๏ผๅฐคไฝณ็บ3ใ6ใ ไฝ็บไธ่ฟฐๆ็ฐ็ขณๆธ8ใ30ไน่ณ็ฝๅบ๏ผๅฏๅ่๏ผไธ่ฏๅบ ็ณๅคๅบใ่ฏๅบไบ็ฒๅบ็ฝๅบใไธ็ดไธๅบไบ่ฏๅบ็ฝๅบใไธๆฑ่ฏๅบ ็ฒ่ฏๅบ็ณๅคๅบใไธ่ๅบ็ณๅคๅบ็ญใไธ่ฟฐ่ณ็ณๅคๅบไนๆ %่ฑๆธ่ผไฝณ็บ8ใ20๏ผๅฐคไฝณ็บ8ใ1 8ใ 1 ไธจๆฑไธจ2ใR>2 1ใR>22ใฮยท3 ไธจใฮยท40ใฮยท41 ใฮยท46ใR_5 ไธจใR58ใ 68 ใR90ใR9I ใR|30ใRl3l ใRl40ใR21 ไธจ่ณ R216ใ
225ใR231 ่ณ R235ใR241 ่ณ R245ใR251 ่ณ R_2 5 5ใr261 ่ณๆฑ2โใR 271 ่ณ R274ใR281 ่ณ R284ใR29 ไธจ่ณ R294ใRๅท่ณ R316ใ 30 201229048 R>321 ่ณ R.325ใๅฐบ331 ่ณ ฮยท3 3 5ใๅฐบ341 ่ณ ฮยท345ใๅฐบ351 ่ณๅฐบ3 55ใR361 ่ณ R364ใ.R"411 ่ณ R418ใR421 ่ณ R~428ใR431 ่ณ ฮยท438ใฮยท441 ่ณ ฮยท448ใ R45I ่ณ R.458ใๅฐบ461 ่ณ R468ใR5 11 ่ณๅฐบ5ไธจ6ใๅฐบ521 ่ณ R526ใๅ R'l ่ณR'4ไน็ขณๆธ1ใ20ไน็ทๆฐงๅบไฟไธฮฮฅ่กจ็คบไนๅบ๏ผไฝ็บYไน ไพ๏ผๅฏๅ่่ไธ่ฟฐ็ทๅบ็ธๅไนไพๅญใ
RllใR12ใR2Iใๅฐบ22ใฮยท31 ใR40ใฮยท41 ใR46ใๅฐบ51 ใฮยท58ใ ๅฐบ61 ใๅฐบ6!!ใๅฐบ71 ใR90ใR91 ใRl30ใRl31 ใRl40ใฮยท211 ่ณๅฐบ216ใ R>221 ่ณ](225ใR231 ่ณ R23 5ใๅฐบ241 ่ณ ฮยท245ใR251 ่ณ ฮยท25 5ใR261 ่ณ R:!64ใR271 ่ณ R274ใR281 ่ณๅฐบ284ใๅฐบ291 ่ณ ฮยท294ใฮยท311 ่ณ ฮยท316ใ R32I ่ณๅ325ใๅฐบ331 ่ณๅฐบ335ใๅฐบ341 ่ณ ฮยท345ใๅฐบ351 ่ณๅฐบ355ใR361 ่ณ ฮยท364ใฮยท411 ่ณ R>418ใR421 ่ณๅฐบ428ใๅฐบ431 ่ณ R438ใR441 ่ณๅฐบ448ใ R451 ่ณ]ๆฏ458ใR461 ่ณ R468ใฮยท511 ่ณ R516ใฮยท521 ่ณ ฮยท526ใๅ R'l ่ณR'4ไนๆ็ฐ็ขณๆธ6ใ20ไน่ณๆฐงๅบไฟไธOAr่กจ็คบไนๅบ๏ผไฝ็บ Arไนไพ๏ผ่ไธ่ฟฐ่ณๅบ็ธๅใไธ่ฟฐ่ณๆฐงๅบไนๆ็ฐ็ขณๆธ่ผไฝณ็บ 6ใ].6๏ผๅฐคไฝณ็บ6ใ12ใ
Rl:ใR12ใR>21ใฮยท22ใๅฐบ31 ใR40ใๅฐบ41 ใR46ใR51 ใๅฐบ58ใ R61 ใRi;8ใR71 ใRsยป0ใฮยท91 ใRl30ใRl31 ใRl40ใฮยท211 ่ณๅฐบ216ใ R221 ่ณ R225ใๅฐบ231 ่ณ R23 5ใR241 ่ณ ฮยท245ใR~251 ่ณๅฐบ255ใR261 ่ณ R2 64ใR271 ่ณ ฮยท2 74ใฮ2 81 ่ณ R284ใR291 ่ณ R"2 94ใR311 ่ณๅฐบ316ใ R32I ่ณ ฮยท3 25ใR331 ่ณๅฐบ3 3 5ใฮยท341 ่ณ ฮยท345ใR351 ่ณ ฮยท3 5 5ใๅฐบ361 ่ณ11364ใๅฐบ411่ณๅฐบ4ไธจ8ใๅฐบ421่ณ๏ผ^428ใ1^431่ณๅฐบ438ใ1^441่ณ^"448ใ R45:.่ณ R458ใR46 1 ่ณ R468ใR511 ่ณ R5I6ใR521 ่ณ R526ใๅ Rโl ่ณไน็ทๅบ่บๅบไฟไธฮฮฅ,ฮฅฮถๆ่กจ็คบ๏ผไฝ็บYiๅY2ไนไพ๏ผ ๅฏๅ่ๆฐซๅๅญใไธ่ฟฐ็ทๅบไนไพใฮฅ!ๅฮฅ2ไบฆๅฏๅๅฅไธๅใ 31 201229048
RllใRl2ใฮยท21ใR22ใR31 ใR40ใR41 ใฮยท46ใๅฐบ51 ใR58ใ ๅฐบ61 ใฮยท68ใฮยท71 ใฮยท90ใๅฐบ91 ใRl30ใRl31 ใRl40ใR211 ่ณๅฐบ216ใ R_221 ่ณๅฐบ225ใR231 ่ณ ฮยท23 5ใฮยท241 ่ณ ฮยท245ใๅฐบ251 ่ณๅฐบ25 5ใR26I ่ณ R_2 64ใR2 71 ่ณ ฮยท274ใฮยท281 ่ณ R284ใR~291 ่ณ ฮยท294ใฮยท311 ่ณๅฐบ316ใ R_321 ่ณ ฮยท325ใฮยท331 ่ณ ฮยท33 5ใๅฐบ341 ่ณ ฮยท345ใๅฐบ351 ่ณ R3 5 5ใฮยท361 ่ณ R_3 64ใๅฐบ411 ่ณๅฐบ4ไธจ8ใR421 ่ณ R428ใR431 ่ณ ฮยท43 8ใR441 ่ณ ฮยท448ใ R_45 1 ่ณ ฮยท458ใๅฐบ46ไธจ่ณๅฐบ468ใR5n ่ณ ^516ใๅฐบ52ไธจ่ณ ฮยท526ใๅ R'l ่ณRUไน่ณ่บๅบไฟไธNZ,Z2ๆ่กจ็คบ๏ผไฝ็บ2,ๅZ2ไนไพ๏ผๅฏ ๅ่ๆฐซๅๅญใไธ่ฟฐ่ณๅบไนไพใZ,ๅZ2ไบฆๅฏๅๅฅไธๅใ R|1ใR12ใR>21ใR22ใR31 ใๅฐบ40ใๅฐบ41ใฮยท46ใR51 ใฮยท58ใ ฮยท61 ใR68ใๅฐบ71 ใๅฐบ90ใๅฐบ91 ใRl30ใRl31 ใRl40ใR211 ่ณ ฮยท216ใ R_221 ่ณ ฮยท225ใR231 ่ณๅฐบ235ใR241 ่ณ R245ใๅฐบ251 ่ณ ฮยท255ใฮยท261 ่ณ R_264ใR27 ไธจ่ณ R274ใR28 1 ่ณ R284ใR29 1 ่ณ ฮยท294ใฮยท311 ่ณ ฮยท316ใ R_321 ่ณๅฐบ3 25ใR33I ่ณ R3 3 5ใๅฐบ341 ่ณๅฐบ345ใๅฐบ351 ่ณ ฮยท3 5 5ใๅฐบ361 ่ณ R_3 64ใR411 ่ณ ฮยท418ใๅฐบ42ไธจ่ณ R428ใๅฐบ43ไธจ่ณ ฮยท438ใๅฐบ441 ่ณ ฮยท448ใ R451 ่ณ R458ใR461 ่ณ R468ใR511 ่ณ R516ใR521 ่ณ R526ใๅ R'i ่ณR'4ไน็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ1ใ20็็ท็กซๅบไฟไธ SAๆ่กจ็คบ๏ผA็บไธ่ฟฐ็ทๅบใ
Rl 1ใRl2ใฮยท21ใฮยท22ใฮยท31 ใR40ใR41 ~ ฮยท46ใR5 1 ใR58ใ R6 1 ใR68ใR7 1 ใR90ใ1 ใRl 30ใRl 3 1 ใRl 40ใๅฐบ2 1 1 ่ณๅฐบ2 1 6ใ R_221 ่ณ ฮยท225ใฮยท231 ่ณ R23 5ใๅฐบ241 ่ณ R245ใR251 ่ณ ฮยท25 5ใR261 ่ณ R2 64ใR"2 71 ่ณ ฮยท274ใฮยท281 ่ณๅฐบ284ใๅฐบ291 ่ณ R294ใR311 ่ณๅฐบ316ใ R_321 ่ณๅฐบ325ใฮยท331 ่ณ ฮยท335ใๅฐบ341 ่ณ ฮยท345ใฮยท351 ่ณ R3 5 5ใๅฐบ361 ่ณ R_364ใๅฐบ411 ่ณ ฮยท418ใฮยท421 ่ณๅฐบ428ใๅฐบ431 ่ณ ฮยท438ใๅฐบ441 ่ณๅฐบ448ใ 32 201229048 ฮยท45ฮ ่ณ 2- n 46ไธจ่ณR_ใR5ไธจไธจ่ณR516ใR521่ณR ่ณRใไน็ถๅ526ใๅRl
w๏ผB็บไธ่ฟฐ่ณๅบ ๆธ6ใ3ยฐ็W ไฝ็บLยทไนๆ็ฐ็ขณๆธ6ใ3ใไนฮท +็ชๅน่ณ็พ 2ๅนไผธ่ณๅบโๅฏๅ่๏ผไผธ่ฏ โฒ ฮฑๅฏๅ่ ,,ยซ ^ ไผธๅฅๅบใไผธ่ฏ่ฏๅบใไผธฮ _ ๆฌๅบใไผธ่ตทๅบใไผธๆณๅบใไผธ่ๅบใไผธ็ญทๅบ็ญใ ่ฌไบ ๆผL็บ3ๅนไปฅไธไนๆ
ๅฝขๆ๏ผ่ฉฒ[ ไผธ่ณๅบไนๆฎๅบใ ใฃๅฐๆไธ่ฟฐ2ๅน ไฝ็บLไนๆ็ฐๅๅญๆธ5ใ3ใ็ ้่กฃๅบ๏ผไพๅฆๆผ ็บ2 ^่ฒ้็ฐๅบไนๆ
ๅฝขๆ๏ผๅฏๅ่๏ผไผธใๆฏๅฌๅบใไผธๅผๅฃไบๅบใ ไผธๅงๅถๅบใไผธๅฮฑไบๅบใไผธไธDไบๅบใไผธๅฒๅๅๅบใไผธๅนๅๅบใ ไผธใไธซๅดๅบใไผธtๅ้ฒใไผธไบ้ขๅบใไผธฮๅบใไผธ^ ๅบใไผธๅใไบๅบใๅๅๅบใไผธๅๅๅบใไผธๅปๅฉๅบใไผธๅๅๅบใ ไผธๅไบๅๅบใไผธ่ฏๅนถๅๅๅบใไผธๅปๅๅบใไผธๅปไบๅๅบใไผธ ็ฌจๅนถๅปๅๅบใไผธไธๅๅบใไผธๅชๅๅบใไผธ่ฏๅนถๅชๅๅบใไผธๅช ๅๅนถๅผๅถๅบใไผธ่ฏๅนถๅๅๅบใไผธไบ่ฏๅนถๅๅๅบใไผธไบ่ฏๅนถ ๅปๅฉๅบใๅผๅฏๅบใๅฒๅๅบ็ญใ ๆผL็บ3ๅนไปฅไธไนๆ
ๅฝขๆ๏ผ่ฉฒLๅฏๅ่ๅฐๆไธ่ฟฐ2ๅน ้ๅฃๅบไนๆฎๅบใ ๆผ R"ใRไธจ2ใR2 ไธจใR22ใR3 ไธจใr4ใใR4iใrโใRdsใ R6ไธจใR68ใRโใR90ใR9ไธจใRไธจ3ใใR131ใRไธจ4ใใR2ไธจไธจ่ณR2 16ใ R22 ไธจ่ณ R225ใR23 ไธจ่ณ R235ใR24 ไธจ่ณ R245ใR25ไธจ่ณ R255ใR26ไธจ ่ณ](264ใฮยท271 ่ณ R274ใR28 1 ่ณ R284ใR29 ไธจ่ณ RmใRๅท่ณ r3i6ใ R32ไธจ่ณ r3 25ใr33ไธจ่ณ r335ใr341 ่ณ R345ใR35ไธจ่ณ R3 55ใR36ไธจ 33 201229048 ่ณ R364ใR411 ่ณ R+18ใฮยท421 ่ณ R428ใR431 ่ณๅฐบ438ใๅฐบ441 ่ณ ใ R45 ไธจ่ณ R458ใๅฐบ461 ่ณ R468ใRsi ไธจ่ณ R5 16ใไปฅ521 ่ณๅฐบ526ใๅ ่ณRโ4ไปฅๅLไนๅๅไปฃๅบ้ฒ่ๅ
ทๆๅไปฃๅบไนๆ
ๅฝขๆ๏ผไฝ็บๅคๆญน ๅไปฃๅบ๏ผๅฏๅ่๏ผไธ่ฟฐ็ทๅบใ็ท็ฝๅบใ้นตๅ็ทๅบใ่ณๅบใ ็ฐ็ทๅบใ็ทๆฐงๅบใ้็ฐๅบใ่ณ็ทๅบใ่ณๆฐงๅบใ่ณ็กซๅบใ็ท ๆฐงๅบๅนพๅบใ่ช็ด ๅๅญใ็ถๅบใ็กๅบใๆฐฐๅบใๅๅบใไบ่ฏๅนถ ๅๅๅบใ็ฌฌๅบ็ญใ ใ ๏ผ้ๆผๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไนๅๅไปฃๅบ :ไปฃใไฟโฆๆฐไปฅๆฐซๅๅญๅไปฃใๅ๏ผๆฌ็ผๆไนๅซๆฐง็ธฎๅ ไฝ็็ฉไนๆฐซๅๅญๅ
ๆฌไนใๆฐฃใ ๅฐๅผ๏ผ1)็ฃ-^ ่กฃไธไนๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไนๅ
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ๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก ๅ่ผไฝณ๏ผ่ฅ็จไฝๆๆฉELๅ
ไปถไน้ๅฃ็จ::ใฃๅ
ไปถ็จๆๆ ไปไน้ๅฃๆๆๅๆดไฝณใ (โใ่กจไน็ธฎๅ็ฐ่ก็็ฉไนๅบๆฌ้ชจๆถไนๅ
ทๆๅผ ่ๅฐ้โฆไน็ๅๅ็ฉ๏ผ็ฑๆผไธ้ๆ
่ฝ้่ผ้ซ EL _ โๅญๆๆ่ผ้ซโ &ๅฏ่็ฑ็จไฝไพๅฆ่ๆๆฉ ๅ
ไปถไน็ผๅ
ๅฑค็ธๆฅไน้ๅฃๅฑค็ๆๆ่ไฟ้ฒTTF็พ่ฑกใ โไฝ็บๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไนๅบๆฌ้ชจๆถ็ๅซๆฐง็ธฎ ฯ &็ตๆง๏ผ็ฑๆผๅ
ทๆ่่ไธญไนๅๅญๅ ็่็ฑๅ
ถ้ซๆง่ 201229048 ๆนๅ๏ผ้ปๅญๅณ่ผธๆงๅขๅคง็็นๅพต๏ผๆ
ๅฏไฟ้ฒๅฐ็ผๅ
ๅฑคไน้ปๅญ ๆณจๅ
ฅ๏ผๆ้ซ็ผๅ
ๅฑคไธญไนๅ็ตๅๆ็๏ผๆๆ็ๅฐๅผ่ตทTTF็พ ่ฑกใ ๅ
ๅ๏ผๆผ็จๆผ้ๅฃๅฑคไนๅๅ็ฉไธญๅ
ทๆๆไฝไธ้ๆ
่ฝ้ ็้จไฝ็บ็ดไน็ธฎๅ็ฐๅบไนๆ
ๅฝขๆ๏ผ้ๅฏ็ขบ่ชๅฐttf็พ่ฑก๏ผ ไฝ้ฒ่็ผ็พ๏ผๆผๅฆๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ่ฌ้็ฐ้จไฝ
ๅ
ทๆๆไฝไนไธ้ๆ
่ฝ้ไนๆ
ๅฝขๆ๏ผไบฆๅฏๆๆ็ๅฐๅผ่ตทTTF ็พ่ฑกใ ้ฒ่๏ผ็ฑๆผๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉๅซๆ่ช้ปๆฅต็ญ ๅซ้ๅฑฌๅฑคไน้ปๅญๆณจๅ
ฅๆง่ผ้ซไนๅซๆฐฎ้็ฐ๏ผๆ
ๅฏไธ้ฒ่็ฉๅฑค ้ปๅญ/ไธปๅ
ฅๅฑค่ๅฏฆ็พไฝ้ฉ
ๅ้ปๅฃไนๆๆฉELยทๅ
ไปถใ ไปฅไธ๏ผ้ๅฐTTF็พ่ฑก็ฐกๅฎๅฐ้ฒ่ก่ชชๆใ ่ฅๅฐๆๆฉELๅ
ไปถๆฝๅ ้ปๅฃ๏ผๅ้ปๅญๅ้ปๆด่ช้ฝๆฅตใ้ฐ ๆฅตไธปๅ
ฅ๏ผๆณจๅ
ฅไน้ปๅญๅ้ปๆดๆผ็ผๅ
ๅฑคๅ
ๅ็ตๅ็ๆๆฟๅญใ ้ๆผๅ
ถๆน็่ฝ็ๆ
โ |้ๆ
ๆฟๅญ& 25%๏ผไธ้ๆ
ๆฟๅญ็บใ ๆผๅ
ๅๅทฒ็ฅไน่ขๅ
ๅ
ไปถไธญ๏ผๅฎ้ๆ
ๆฟๅญๆผ็ทฉๅๆๅบๅบ็ๆ
ๅคบ็ผๅ
_ๆผๅฉไธไนไบ้ๆ
ๆฟๅญ๏ผๅๆฏไธ็ผๅ
่็ถ้็ฑๅคฑ ๆดป้่ๅๅพฉๅบๅบ็ๆ
ใ็ถ่๏ผๆ นๆs M. ็ญไบบ๏ผๅphys
Cemยท Aโ 104โ 771 1 ( 2000 ))๏ผๆๅ็ๆไน75%ไนไธ้ๆ
ๆฟๅญ ไธญ๏ผ1 /5่ฎๆๅฎ้ๆ
ๆฟๅญใ TTF็พ่ฑกไฟๆ่็ฑไธ้ๆ
ๆฟๅญไน็ขฐๆ่ๅ็ๆๅฎ้ๆ
ๆฟๅญไน็พ่ฑกโ่ฅๅฉ็จ่ฉฒTTF็พ่ฑก๏ผๅไธๅ
ๆๅ็ๆไน25% ๅฎ้ๆ
ๆฟๅญๅฏๅฉ็จๆผ็ผๅ
โ #็ฑไธ้ๆ
ๆฟๅญไน็ขฐๆ่ๅ่ ็ข็ไนๅฎ้ๆ
ๆฟๅญไบฆๅฏๅฉ็จๆผ็ผๅ
๏ผๅพ่ๅฏๆ้ซๅ
ไปถไน็ผ 82 201229048 ๅ
ๆ็ใ ็บๆ็่ผไฝณๅฐๅผ่ตทTTF็พ่ฑก๏ผๅฟ
้ ๅฐ่ๅฎ้ๆ
ๆธๅญ็ธ ๆฏๆฟๅญๅฃฝๅฝ้ๅธธ้ทไนไธ้ๆ
ๆฟๅญๅฐ้ๆผ็ผๅ
ๅฑคๅ
ใ ๆฌi.ๆไธญ๏ผ่ผไฝณ็บไฝฟๅซๆๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ ไน้ๅฃๅฑค้ฐๆฅๆผ่ขๅ
ๅ
ไปถไน็ผๅ
ๅฑคใๆผไปฅๆฟๅญๅฃฝๅฝ่ผ็ญไน ๅฎ้ๆ
ๆฟๅญ็บ่ตทๅ ไน่ขๅ
ๅ
ไปถไธญ๏ผ้ๅธธไธไฝฟ็จๅฐ่ดๆญฅ้ฉๆ ๅ ไน้ๅฃๅฑคโไฝ่็ฑๅฐๅซๆๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผ ๆไน้ๅฃๅฑค็จๆผ่ขๅ
ๅ
ไปถไธญโๅฏๅผ่ตทTTF็พ่ฑก๏ผๅฏฆ็พ้ซๆ ็ไนๆๆฉELๅ
ไปถใๅ๏ผๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ็ฑ๏ผ๏ผ ้ๆ
่ฝit่ผ้ซ๏ผๆ
ๅณไพฟๆผๅ
ๅไน็ขๅ
ๅ
ไปถไธญไบฆๅฏ็ผๆฎ้ๅฃ ๅฑคไนๅ่ฝโ้ฒๆญขไธ้ๆ
่ฝ้ไนๆดๆฃใ โฒๅ๏ผโๆผๆฌ็ผๆไธญ๏ผๅ
็จฑ็บ้ๅฃๅฑคๆไฟๆๅ
ทๆๅฐๆผไธ ้ๆ
่ฝ้ไน้ๅฃๅ่ฝไนๅฑคโๅๆด้ๅฃๅฑคๆ้ป่ท้ๅฃๅฑค่ๅ
ถ ๅ่ฝไธๅใ 3ๆๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไน้ๅฃๅฑค่ผไฝณ็บ้ฒ่ ๅซๆไพ้ปๅญๆงๆป้็ฉใ ไธ่ฟฐไพ้ปๅญๆงๆป้็ฉ่ผไฝณ็บ้ธ่ช็ฑ้นผ้ๅฑฌใ้นผๅ้ ๅฑฌใ็จๅ้ๅฑฌใ้นผ้ๅฑฌไนๆฐงๅ็ฉใ้นผ้ๅฑฌไนๅฝๅ็ฉใ้นผๅ ้ๅฑฌไนๆฐงๅ็ฉใ้ฉๅ้ๅฑฌไนๅๅไฝ a็ ้นผๅ้ๅฑฌไนๅฝๅ็ฉใ็จๅ้ๅฑฌไนๆฐงๅ็ฉใ ็จ้ๅฑฌไนๅนฝๅ็ฉใ้ฉ้ๅฑฌไนๆๆฉ้ฏๅ็ฉใ้ฉๅ้ๅฑฌไนๆ ๆฉ้ฏๅ็ฉๅ็จๅ้ๅฑฌ ๅณๅซฑไบบ ไปฐๅ้ๅฑฌไนๆๆฉ้ฏๅ็ฉๆ็ตๆไน็พคไธญไน1็จฎๆ2 ็จฎไปฅไธใ ๆฌ็ผๆไนๆๆฉ ๅ่ฏใ่ใ่็ญ๏ผ ELๅ
ไปถไน็ผๅ
ๅฑคๅฏไฝฟ็จ็ด
่ข็ฏใ่ฝใ่ฃฏ ่ผไฝณ็บ่ฝ่ก็็ฉ๏ผ$่่ผไฝณ็บๅซๆไธ่ฟฐ 83 201229048 ๅผ๏ผ16)่กจ็คบไน่ฝ่ก็็ฉใ ^208 R201 R207~~<^^-R2ใ2
Ar^-yVAr^ (16) R206~V_^~R203 ^205 R204 (ๅผไธญโๅ
ซใ,ๅAr|2ๅๅฅ็บ็ถๅ ็ขณๆธฯใ30ไน่ณๅบใๆ่
้ๅฒโใๅ ๅไปฃไนๆ๏ผ
ใ30ไน้็ฐf ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5 ไน็ทๅบใ็ถๅไปฃๆๆช็ถๅ ็ฐ็ซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน้ฑ3ใ3ใไน=ไบไน ไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ ๏ผ ใโโ^โขๅ , ไนๆน็ฝๅบใ็ถๅไปฃๆๆช็ถ 6 ^ ไน็ตฒๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆฮ ^ไบ่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธฮผใ ๆๆนๅ 4่
็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๅฆปๆ5ใ3ใไน้ ^ไบ:ๅAr|2ไน่ณๅบๅ้็ฐ็ๅบใ&ใใไน่ณๅบใ โ่กฃใ็ทๅบใ็ฐ็ทๅบใ็ท็ฝๅบใ่ณ็ฝๅบใ็ทๆฐงๅบใ่ณๆฐง ๅบๅๅฅ่ไธ่ฟฐ็ฌฌ28้ ็ฌฌ3่กใ็ฌฌ31้ ็ฌฌ15 ๆ็ธๅ๏ผใ ๆญค ๅซๆๅผ๏ผ16 )่กจ็คบไน่ฝ่ก็็ฉไน็ผๅ
ๅฑค่ผไฝณ็บ่ๅซๆ ๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไน้ๅฃๅฑค็ธๆฅใ็ผๅ
ๅฑค่ๅซๆ 84 201229048 ๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไน้ๅฃๅฑค็ธๆฅๆ๏ผๅฏๅฉ็จTTF ็พ่ฑกๆ้ซ็ผๅ
ๆ็ใ ๅ็จTTF็พ่ฑกๆ๏ผๆงๆ็ฑๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ ๆงๆไน้ฃใๅฑค็ๅๅ็ฉไนไธ้ๆ
่ฝ้โๅฟ
้ ้ซๆผไธป่ฆๆงๆ ็ผๅ
ๅฑคไนไธป้ซ๏ผhost)ไนไธ้ๆ
่ฝ้ใ่ผไฝณ็บ๏ผๆฌ็ผๆไนๅซ ๆฐง็ธฎQ %ไฝ็็ฉใ็ผๅ
ๅฑคไธญๆๅซไนไธป้ซๅๆป้็ฉๆปฟ่ถณไธ่ฟฐ ๅผ๏ผ1 )ๅ๏ผ2)ใ ETb>ETh โด ETd>ETh (2) (LThใETbๅETdๅๅฅ่กจ็คบไธป้ซๆๆใ้ๅฃๅฑคไนๅซๆฐง ็ธฎๅ๏ผ
่ก็็ฉๅๆป้็ฉไนไธ้ๆ
่ฝ้๏ผ ๅ1ไฟ่กจ็คบๆฌ็ผๆไน็ฌฌ1ๅฏฆๆฝๅฝขๆ
ไนโไพไนๆๆฉ ไปถ็ๆฆ็ฅๆงๆๅใๅ2Aไฟๆจกๅผๆงๅฐ่กจ็คบๅๅฑคไนๆไฝๆฟ็ผๅฎ ้ๆ
่ฝ้่ฝ้ๅๆไฝๆฟ็ผไธ้ๆ
่ฝ้่ฝ้ใๅ่
๏ผๆฌ็ผๆ ไธญ๏ผไบ้ๆ
่ฝ้ไฟๆๆไฝๆฟ็ผไธ้ๆ
็ๆ
ๆไน่ฝ้่ๅบๅบ ็ๆ
ๆไน่ฝ้็ๅทฎ๏ผๅฎ้ๆ
่ฝ้๏ผๆๆไบฆ็จฑ็บ่ฝ้๏ผไฟๆ ๆไฝๆฟ็ผๅฎ้ๆ
็ๆ
ๆไน่ฝ้่ๅบๅบ็ๆ
ๆไน่ฝ้็ๅทฎใ ๅ1ไธญ่กจ็คบไนๆๆฉELSไปถไฟ่ช้ฝๆฅต1Gไพๅบ็ฉๅฑคๆ้ปๆดๅณ ่ผธๅ50'็ผๅ
ๅฑค20ใ้ปๅญๅณ่ผธๅ3ใใ้ฐๆฅต4ใใ่ผไฝณ็บๆผ %ๆก1 0่็ผๅ
ๅฑค2 ใไน้่จญ็ฝฎ้ปๆดๅณ่ผธๅ5 ใใๅ2 Aไธญ่กจ็คบ ไนๅฏฆๆฝๅฝขๆ
ไธญโ้กฏ็คบไบ้ปๅญๅณ่ผธๅๅ
็บ้ๅฃๅฑคไนๆงๆ ่๏ผๅ
ๆ้ๅฃๅฑคไนๅฏฆๆฝๅฝขๆ
ไธฆไธๅฆจ็คๆณจๅ
ฅๆงๆด้ซไน้ปๅญใไธป ๅ
ฅๅฑคไนๆๅ
ฅใๅฝขๆ้ปๅญๆณจๅ
ฅๅฑคๆ๏ผๅฏไฝฟ็จๅ
ๅ็จไฝ้ปๅญๆณจ ๅ
ฅๅฑคไน้ๅธธไนๅๅ็ฉ๏ผ่ผไฝณ็บๅซ้็ฐๅๅ็ฉใ 85 201229048 ๆผๅ2Aไธญ๏ผ่ช้ฝๆฃ ๆฐๅทๆฅตๆณจๅ
ฅไน้ปๆดไฟ้้้ปๆดๅณ่ผชๅ ๅ
ฅ็ผๅ
ๅฑค๏ผ่ช้ฐๆฅตๆณจๅ
ฅๅคๅธฆๅทฅใ ่/ไธป ๅ
ฅไน้ปๅญไฟ้้้ปๅญๅณ่ผธๅ่ๆณจๅ
ฅ็ผ ๅ
ๅฑคใๆญคๅพ๏ผ้ปๆด่้ปๅญๆผ็ผๅ
ๅฑคไธญๅ็ตๅ๏ผ็ๆๅฎใฃ ๆฟๅญๅไธ้ๆ
ๆฟๅญใๅ็ตๅๅญๅจ็ผ็ๆผไธป้ซๅๅญไธไนๆ
ๅฝข ๅ็ผ็ๆผๆป้็ฉๅๅญไธไนๆ
ๅฝขโฆๆฌๅฏฆๆฝๅฝขๆ
ไธญ๏ผๅฆๅ 2:ๆไธ่ฌโๆผๅฐไธป้ซใๆป้็ฉไนไธ้ๆ
่ฝ้ๅๅฅ่จญ็บใ fdๆ๏ผ่ผไฝณ็บๆปฟ่ถณETh<ETdไน้ไฟใ่็ฑๆปฟ่ถณ่ฉฒ้ไฟ๏ผ ้ฒ่ๅฆๅ2B_ๆ็คบ่ฌ๏ผๆผไธป้ซไธๅ็ตๅ่็ข็ไนไธ้ๆ
ๆฟๅญ ไธๅๅ
ทๆๆด้ซไนไธ้ๆ
่ฝ้ไนๆป้็ฉ่ฝ็งปใ ๆผๆป้็ฉๅๅญไธๅ็ตๅ่็ข็ไนไธ้ๆ
ๆฟๅญๅ่ฟ
้ๅฐ ๅไธป้ซๅๅญ้ฒ่ก่ฝ้่ฝ็งปโฆไธป้ซไนไธ้ๆ
ๆฟๅญไธๅๆป ้็ฉ่ฝ็งป๏ผ่ๅฉ็จTTF็พ่ฑกโ่็ฑไธ้ๆ
ๆฟๅญๅฝผๆญคๆๆ็ ๅฐๆผ,้ซไธ็ผ็็ขฐๆ่็ๆๅฎ้ๆ
ๆฟๅญใ$่๏ผ็ฑๆผๆป้ ็ฉไนๅฎ้ๆ
่ฝ้Esdๅฐๆผไธป้ซไนๅฎ้ๆ
่ฝ้๏ผๆ
่็ฑ ็พ่ฑก็ๆไนๅฎ้ๆ
ๆฟๅญ่ชไธป้ซๅๆป้็ฉ้ฒ่ก่ฝ้่ฝ็งป ่ๆๅฉๆผๆป้็ฉไน่ขๅ
ๆง็ผๅ
ใๅๆฌ๏ผๆผ็จๆผ่ขๅ
ๅๅ
ไปถ ไนๆป้็ฉไธญโ่ชๆฟ็ผไธ้ๆ
็ๆ
ๅๅบๅบ็ๆ
ไน่บ้ท่ขซ็ฆ ๆญข๏ผ่ฉฒ็จฎ่บ้ทไธญไธ้ๆ
ๆฟๅญไธ็ผ็ๅ
ๅญธๆง่ฝ้ๅคฑๆดป๏ผ่็ผ ็็ฑๅคฑๆดปใ็ถ่โ II็ฑไฝฟไธป้ซ่ๆป้็ฉไนไธ้ๆ
่ฝ้ไน้ ไฟๅฆไธๆ่ฟฐโๆผไธ้ๆ
ๆฟๅญ็ผ็็ฑๅคฑๆดปไนๅ่็ฑ็ธไบ็ขฐๆ ไปฅๆๆ็ๅฐ็ๆๅฎ้ๆ
ๆฟๅญ่ๆๅ็ผๅ
ๆ็ใ ๆผ้ปๅญๅณ่ผธๅไธญ๏ผๆผ้ฐๆฅๆผ็ผๅ
ๅฑคไน้จๅ่จญ็ฝฎ้ๅฃ ๅฑคใ้ๅฃๅฑคๅ
ทๆๅฆไธๅ่ฝ๏ผ้ฒๆญข็ผๅ
ๅฑคไธญ็ๆไนไธ้ๆ
ๆฟ ๅญๅ้ปๅญๅณ่ผธๅๆดๆฃโ่็ฑๅฐไธ้ๆ
ๆฟๅญๅฐ้ๆผ็ผๅ
ๅฑคๅ
201229048 ่ๆ้ซไธ้ๆ
ๆฟๅญไนๅฏๅบฆโๆ็่ผไฝณๅฐๅผ่ตทttf็พ่ฑกใ ็บ้ฒๆญขไธ้ๆ
ๆฟๅญๆดๆฃ๏ผ่ผไฝณ็บๅฆๅ2aใ2bไธญๆ็คบ ่ฌ๏ผๆงๆ้ๅฃๅฑคไนๅๅ็ฉไนไธ้ๆ
่ฝ้ETbๅคงๆผETh๏ผ้ฒ่ ไบฆๅคงๆผใใ็ฑๆผ้ๅฃๅฑค้ฒๆญข็ผๅ
ๅฑคไธญ็ๆไนไธ้ๆ
ๆฟๅญๅ ้ปๅญๅณ่ผธๅๆดๆฃ๏ผๆ
ๆผ็ผๅ
ๅฑคๅ
ไธป้ซไนไธ้ๆ
ๆฟๅญๆๆ็ ๅฐๅฝขๆๅฎ้ๆ
ๆฟๅญ๏ผ่ฉฒๅฎ้ๆ
ๆฟๅญๅๆป้็ฉไธ่ฝ็งปไธฆ็ผ็ tๅญธๆง่ฝ้ๅคฑๆดปใๅฝขๆ้ๅฃๅฑคไนๆๆไฟๆฌ็ผๆไนๅซๆฐง็ธฎๅ ็ฐ่ก็็ฉใ ๅซๆๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉไน้ๅฃๅฑคไบฆๅฏๅฏฆ็พ้ป ๅญๆณจๅ
ฅใๅณ่ผธๅ่ฝไนไฝ็จใๅ
ถๅๅ ๅจๆผ๏ผ้ๅ
ฑๆ้ปๅญๅฐไฝ ็บไพ่ช้ฐๆฅๅฑคไน้ปๅญไนๆๅไนๅชไป'็นผ่๏ผๆณจๅ
ฅ้ๅฃๆๆ ไน้ปๅญ็ถ็ฑ้ปๅญๅณ่ผธ็ตๆง้จไฝๆดๅฎนๆไพ็ตฆ้ปๅญใๅณ๏ผ่็ฑ ๅLUMO่ฝ้่ผ้ซไน็ตๆง้จ ^ ^ ้ปๅญๆณจๅ
ฅใ ่ฝ็งป๏ผ่ๆๅฉๆผๅ็ผๅ
ๅฑคไน ไบบๆผไธ่ฟฐ้ปๅญๅณ่ผธๅ่้ฐๆฅตไน้๏ผไบฆๅฏๅ
ทๆๅซไฝๅๅฝๆธ ใๅซไฝๅๅฝๆธ้ๅฑฌๅฑคไฟๅซๆไฝๅๅฝๆธ้ๅฑฌๆไฝๅๅฝ ๆธ้ๅฑฌๅๅ็ฉไนๅฑคใๅฏๅ
ๅ
ไฝๅๅฝๆธ้ๅฑฌๆไฝๅๅฝๆธ้ๅฑฌ ๅๅ็ฉๅฝขๆ๏ผไบฆๅฏๆผ็จไฝfๅทฅ็ฑ A ^ ใ ้ปๅญๅณ่ผธๅฑคไนๆๆไธญๆทปๅ ไฝๅๅฝ ๆฐ้ๅฑฌใไฝๅๅฝๆธไปๅฑๅคไบบ1 ๅฑฌๅ5็ฉใๆไฝๅๅฝๆธ้ๅฑฌ้ฏๅ็ฉไฝ ็บไบ้ซ่ๅฝขๆใไฝๅๅฝๆธ้ๅฑฌไฟๆๅๅฝๆธ็บ3ยทโฮฝไปฅไธไน ้ๅฑฌใไฝๅๅฝๆธ็บ3.8 eVไปฅไธๅฐไบบฮท ไน้ๅฑฌๅฏๅ่้นผ้ๅฑฌใ้นผๅ ้ๅฑฌ็ญใไฝ็บ้นผ้ๅฑฌๅฏๅๅทยท ฯ ยท ฯฯ ^ ฮธ , ฮ่ยท LlใNaใฮใCs ็ญใไฝ็บ้นผ ๅ้ๅฑฌๅฏๅ่๏ผMgใCaใtRๅพ ใaๅฐใๅ
ถไปๅฏๅ่๏ผYbใEu ฯ ใๅโไฝ็บไฝๅๅฝๆธ้ๅฑฌๅๅ็ฉ๏ผ่ผไฝณ็บไฝๅๅฝๆธ 87 201229048 ้ๅฑฌไนๆฐงๅ็ฉใ้นตๅ็ฉใ็ขณ้
ธ้นฝใ็กผ้
ธ้นฝใไฝ็บๅฝๅ็ฉๅฏ ๅ่๏ผ่ชชๅ็ฉใๆฐฃๅ็ฉใๆผ ๅ็ฉโไฝ่ผไฝณ็บๆฐๅ็ฉใไพๅฆ ๅฏ่ผไฝณๅฐไฝฟ็จLiFใๅ๏ผไฝๅๅฝๆธ้ๅฑฌ้ฏๅ็ฉไฟไฝๅๅฝๆธ้ ๅฑฌไน้ฏๅ็ฉโ่ผไฝณ็บ้ฉ้ๅฑฌใ้ฉๅ้ๅฑฌๆ็จๅ้ๅฑฌไนๆๆฉ ้ๅฑฌ้ฏๅ็ฉใ ๅ่
๏ผๅฉ็จTTF็พ่ฑกๆ้ซๆ็็ๆๆ๏ผๆผ่่ฒๅๅ
ๅฑค ไธญ่ผ็บๆ้กฏใๆผๆ้ฃๆ้ซ็ผๅ
ๆ็ไน่่ฒ่ขๅ
ๅ
ไปถ๏ผไธปๆณข ๅณฐๆณข้ท้กฏ็คบ็บ500 nmไปฅไธ๏ผไธญ๏ผๅฏ่็ฑๅฐๆฌ็ผๆไนๅๅ็ฉ ็จไฝ้ๅฃๆๆ่็ฒๅพ่ผ้ซไน็ผๅ
ๆ็ๆๅๆๆใ ๆผ็ ดๅ
็ผๅ
ๅฑคไธญโๅฏ็ฒๅพๅฐไธ้ๆ
่ฝ้ๅฐ้ๆผ็ผๅ
ๅฑค ๅ
ไนๆๆโๅฏ้ฒๆญขไธ้ๆ
่ฝfไนๆดๆฃโไธฆๆๅฉๆผๆๅ็ขๅ
็ผๅ
ๆงๆป้็ฉไน็ผๅ
ๆ็ใ ๆฌ็ผๆไนๆๆฉELๅ
ไปถไนๅบๆฟใ้ฝๆฅตใ้ฐๆฅตใ้ปๆดๆณจไบบ ๅฑคใ้ปๆดๅณ่ผธๅฑค็ญๅ
ถไปๆงไปถๅฏ้ฉ็ถ้ธๆไธฆไฝฟ็จๅ้ๅฐๅฉ็ณ ่ซๆก็ฌฌPCT/ JP2009/ ใ53247่่ชชๆๆธใๅ้ๅฐๅฉ็ณ่ซๆก ็ฌฌPCT/JP2ใใ8/ใ73180่่ชชๆๆธใ็พๅๅฐๅฉ็ณ่ซๆก็ฌฌ12 / 376๏ผ236่่ชชๆๆธใ็พๅๅฐๅฉ็ณ่ซๆก็ฌฌ11/ 766 , 28 1่ ่ชชๆๆธใ็พๅๅฐๅฉ็ณ่ซๆก็ฌฌ12/280, 364่่ชชๆๆธ็ญไธญ่จ ่ผไนๅ
ฌ็ฅ่
ใ [ๅฏฆๆฝไพ] ๅๆไพ1 (a)็ฌจๅนถ[b]่[2๏ผl~d]ๅฑๅไธ 5~~็กผ้
ธไนๅๆ ไพๆไธ่ฟฐๆต็จๅๆ็ฌจๅนถ[b]่โ ๅๅโ5_็กผ้
ธ
8S S 201229048
HCIๆฐดๆบถๆถฒ
BuLi, ฮ(ฮฮฮธ)3 THF
B(ใH)2 (aโ 1) 7,8,9๏ผ10 โๅๆฐซ่ฏๅนถ[b]่[n โd]ๅๅไนๅๆ ๅฐ1-่้
144 g 'ๅฐ็ฒ่ฏ็ฃบ้
ธiๆฐดๅ็ฉ๏ผ19ใ g)ใ^ โ็ฐๅทฑไบ็ฏ๏ผ80ยท1 g)ใๆฑ่ฏ4 Lยท่ฃๅ
ฅ็็ถไธญ๏ผไธฆๅๆตๆชๆ 24ๅฐๆใๅฐๅๆๆบถๆถฒๅทๅป่ณๅฎคๆบซโๆญคๅพไปฅๆฐด6ใใmLๆธ
ๆดใ ๅฐๆๆฉๅฑคไปฅ็กซ้
ธ้้ฒ่กไนพ็ฅๅพๆธๅฃ้คพๅปๆบถๅใๅฐๆฎๆธฃไปฅ็ฝ ่ ็ฎกๆฑๅฑคๆๆณ้ฒ่ก็ดๅ๏ผ็ฒๅพ7,8,9๏ผ1Gโๅๆฐซ่ฏๅนถ้ฎ่กโฆ โd]ๅๅ 55.5 g (็ข็ 25%)ใ U ไธ 2)่ฏๅนถ[b]่[2๏ผ1 โd]ๅๅไนๅๆ ๆผๆฐฌๆฐฃ็ฐๅขไธโๅฐ7,8,9๏ผ1Gโๅๆฐซ่ฏๅนถๅซ่[2๏ผๅๅฆ ๅโธ^^^ไบๆฐฃไธ^ไธไบๆฐฃๅบโโฆ่ฏ้
ฟโบ^)ใ ็กๆฐดฮโไบๅผ็ท1L่ฃๅ
ฅ็็ถไธญ๏ผไธฆๅๆตๆๆi2ๅฐๆใๅฐ ๅๆๅทๆถฒๅท้จ่ณ่ณใๆบซ๏ผๆญคๅพไปฅ็ฒ่ฏ้ฒ่ก่ๅ๏ผไธฆ้ๆฟพๆๅบ ไน๏ผ้ซใๅฐๆฟพๆถฒไปฅๆ่ฝ่ธ็ผๅจ้ฒ่กๆฟ็ธฎ๏ผๆญคๅพๅฐๆฎๆธฃไปฅ็ฝ ่ ็ฎกๆฑๅฑคๆๆณ้ฒ่ก็ดๅ๏ผ็ฒๅพ่ฏๅนถ[b]่[2๏ผ1-_ๅ32ใ
(็ข็6 0 % )ใ (ฮใ3) 51็ฌจๅนถ[b]่ก[2๏ผ1 โd]ยฐๅคซๅไนๅๆ ไฝฟ่ฏๅนถ[b]่ก[2๏ผ๏ผ โd]ๅฌๅผ๏ผ32 7 g)ๆบถ่งฃๆผN๏ผN_ไบ็ฒ โข ใใ' ๅบๆฐ้
ฟ่บ3ใ0 mL ไธฆๆทปๅ N โๆผ ไปฃไธไบ้ฏไบ่บ๏ผ28.0 g) 89 201229048 ใไนN๏ผN-ไบ็ฒๅบ็ฒ้ฏ่บๆบถๆถฒ50 mL๏ผๆญคๅพๅฐๅๆๆบถๆถฒๆผ6ใ Cไธๅ ็ฑ_ 5ๅฐๆใๅฐๅๆๆบถๆถฒๅทๅป่ณๅฎคๆบซๅพ๏ผๆณจๅ
ฅๆฐด2 'ไธญใๅฐ็ฒๅพไนๅบ้ซไพๅบไปฅ็ฒ้ใๆฐดใ็ฒ้้ฒ่กๆธ
ๆดใๅฐๆ ็ฒๅพไน็ฒ็ๆ็ฉไปฅ็ฝ่ ็ฎกๆฑๅฑคๆๆณ้ฒ่ก็ดๅ๏ผ็ฒๅพ5 โๆบด่ฏ ๅนถ[b]่ก[2๏ผ1 โd]ๅๅ 36 5 g (็ข็ 82%)ใ (3ไธ4)่ฏๅนถ[b]่[2, l โ d]ๅๅไธ 5โ็กผ้
ธไนๅๆ ๅฐ5 โๆบด่ฏๅนถ[b]่[^ไธๅผๅๅ๏ผ29 7 g)ใๅๆฐซๅๅ๏ผ่ซ ๆฐด๏ผ500 mLๆทปๅ ๆผ็็ถไธญ๏ผไธฆๅทๅป่ณไธ 78ใc ^ๆญคๆๆทปๅ n -BuLi ((ๆผๅทฑ็ทไธญๆi 6ใ]Vใ 66mL)๏ผไธ้ขๅๆบซ่ณ ้ขๆชๆ2ๅฐๆใ็นผ่๏ผๅๅบฆๅทๅป่ณ_ 78ใc๏ผๆทปๅ B ( ใMe ) 3 ( 27.3 g)๏ผๆผโ78ใ(๏ผไธๆชๆ1ใๅ้ๅพ๏ผๆผๅฎคๆบซไธๆชๆ5 ๅฐๆใๅๆ็ตๆๅพ๏ผๆทปๅ ๏ผ N HCLๆฐดๆบถๆถฒ๏ผ200 mL )๏ผไธฆๆผ ๅฎคๆบซไธๆชๆ1ๅฐๆใๆญคๅพ๏ผๅฐๅๆๆถฒ็งปๅ
ฅๅๆถฒๆผๆไธญไธฆไปฅ ไน้
ธไน้้ฒ่ก่ๅใๅฐ่ฉฒๆบถๆถฒไปฅMgSใ4้ฒ่กไนพ็ฅ๏ผๆญคๅพๆฟ ็ธฎไธฆไปฅๅทฑ็ท้ฒ่กๆธ
ๆดโ็ฒๅพ่ฏๅนถ[b]่[2,1 โ d]ๅๅไธ5โ็กผ ้
ธไน็ฝ่ฒๅบ้ซl7.0g (็ข็65ใ/ใ๏ผใ ๅๆไพ2 (b)่ฏๅนถๅๅๅบ[3๏ผ2โb]ไบ่ฏๅนถๅๅไธ6โ็กผ้
ธไนๅๆ ไพๆไธ่ฟฐๅๆๆต็จๅๆ็ฌจๅนถๅๅๅบ[3,2 โ b]ไบ่ฏๅนถๅ ๅ_ 6 โๆฃ้
ธใ 90 201229048
(b โ 1) 2,4 ไธไบๆบด~ ฮน๏ผ5 โไบ็ฒๆฐงๅบ่ฏไนๅๆ ไฝฟL๏ผ3~ไบๆฑๆฐงๅบ็ฌจ๏ผ53.9g)ๆบถ่งฃๆผไบๆฐฏๆฑ็ง86ใmL ไธญไธฆ้ฒ่ก้ขจๅไปฃโๆผๅฐๆตดๅทๅปไธ็ถ้2ๅๅๅฐๆๆปดๅ ๆผ (129.3 g )ไนไบๆฐฃๆฑ็ทๆบถๆถฒi 5ใ mL๏ผๅ็ถ้3ๅฐๆ็ทฉ็ทฉๅฐ ๅๆบซ่ณๅฎคๆบซ๏ผ้ฒ่ๆชๆไธๅคฉใๅฐๅๆๆถฒ้ฒ่กๅฐๆตดๅทๅป๏ผไธฆ ไปฅ10 0/ใๆฐซๆฐงๅ็ดๆฐดๆบถๆถฒ้ฒ่กไธญๅใๅๆถไบๆฐฃๆฑ็งๅฑค๏ผไธฆไปฅ ไบๆฐฃๆฑ็ทๅฐๆฐดๅฑค้ฒ่ก่ๅ๏ผๅไฝตๆๆฉๅฑคไธฆไปฅ็กๆฐด็กซ้
ธ้้ฒ ่กไนพ็ฅใ้้ฝ๏ผๆญคๅพๆฟ็ธฎๆฟพๆถฒใๅฐ็ฒๅพไนๆฎๆฝฐไปฅๅทฑ็ง้ฒ่ก ๅๆฃๆธ
ๆด๏ผๆฟพๅ็ๆไน็ตๆถไธฆ้ฒ่กไนพ็ฅ๏ผ็ฒๅพ2,4 โไบๆผโ 1๏ผ5~ โ็ฒไนณๅบๆฌไน็ฝ่ฒ็ตๆถ110.5 g (็ข็97%)ใ (b_2) 2,4 ไธ้๏ผ2 โๆฐ่ฏๅบ๏ผโฮน๏ผ5 โไบ็ฒๆฐงๅบ่ฏไน ๅๆ ๅฐ2,4 โไบๆบด~ 1๏ผ5โไบ็ฒๆฐงๅบ่ฏ๏ผ88.8 g)ใ2 โๆฐ่ฏๅบ ็กผ้
ธ๏ผ]00.74 g )ใNa2C03 2 ฮ ๆฐดๆบถๆถฒ๏ผ600 mL )ใPd ( PPh3 ) 4(6.73g)ใ1๏ผ2-ไบ็ฒๆฐงๅบไน็ทi5ใmLใ็ฒ่ฏi5ใmL่ฃๅ
ฅ ็็ถไธญ๏ผไธฆๅๆต36ๅฐๆใๅๆ็ตๆๅพ๏ผๆทปๅ ๆฐด5ใใ mLๅ ็ฒ่ฏ1 Lไธฆ่ฝ็งป่ณๅๆถฒๆผๆไธญ๏ผๅๆถ็ฒ่ฏ็ธใไปฅMgS04้ฒ ่กไนพ็ฅโๆญคๅพ้้็ฝ่ ็ญ็ฎกๆฑ้คๅปๅ้ป้่ณช๏ผไธฆๆฟ็ธฎๆบถๆถฒใ 91 201229048 ไฝฟๅ
ถ่ชๆฑ็ฌจ/ๅทฑ็งๆททๅๆบถๅๅ็ตๆถ๏ผ็ฒๅพ2๏ผ4 โ้๏ผ2 ไธๆฐ ่ฏๅบ๏ผไธ1๏ผ5โไบ็ฒๆฐงๅบ่ฏไน็ฝ่ฒๅบ้ซ86 5 g (็ข็88%)ใ (bโ 3) 2,4โ้๏ผ2โๆฐ่ฏๅบ๏ผไบ็พฅๅบ่ฏไนๅ ๆ ๅฐ1๏ผ5โไบ็ฒๆฐงๅบไธ2,4 โ้๏ผ2ไธๆฐ่ฏๅบ๏ผ่ฏ๏ผ48 3 g)ใ ไบๆฐฏๆฑ็ง๏ผ่ซๆฐด๏ผ740 mL่ฃๅ
ฅ็็ถไธญ๏ผไธฆๅทๅป่ณไปฃใๆทป ๅ BBr3(89.0g)๏ผๆญคๅพๆผๅฎคๆบซไธใฃ24ๅฐๆใๅๆ็ตๆๅพ๏ผ ๅฐๆบถๆถฒๅทๅป่ณโ 78ยฐC โไธฆไปฅ็ฒ้ๆ
้ๅฐไฝฟๅ
ถๅคฑๆดป๏ผ้ฒ่ไปฅ ๅ
ๅไน้ไนๆฐดไฝฟๅ
ถๅคฑๆดปใๅฐๆบถๆถฒ่ฝ็งป่ณๅๆถฒๆผๆไธญ๏ผไธฆไปฅ ไบๆฐฃ็ฒ็ท้ฒ่ก่ๅ๏ผๅไปฅMgSใ4it่กไนพ็ฅ๏ผๆญคๅพ้้็ฝ่ ็ญ็ฎกๆฑ้คๅปๅ้ป้่ณชโๆฟ็ธฎๆบถๆถฒ๏ผๅพ่็ฒๅพ่ฉฆๆจฃ๏ผๅฐ่ฉฒ่ฉฆ ๆจฃๆผ6(TCไธ็็ฉบไนพ็ฅ5ๅฐๆโ็ฒๅพ2,4ไธ้๏ผ2โๆฐ่ฏๅนป โฮโไบ็ถๅบ่ฏไน็ฝ่ฒๅบ้ซ44 lg (็ข็1ใใ%)ใ (b_4)่ฏๅนถๅฌๅๅบ[3,2 ไธ b]ไบ่ฏๅนถๅฌใๅไนๅๆ ๅฐ2,4 -้๏ผ2 -ๆ่ฏๅบ๏ผโMโไบ็ถๅบ่ฏ๏ผ4414 ^ใ N-็ฒๅบ-2-ๅกๅฏใฃ๏ผ่ซๆฐด๏ผ_โฝใ่ฃๅ
ฅ็็ถไธญ๏ผไธฆ ไฝฟๅบ้ซๅฎๅ
จๆบถ่งฃใๆทปๅ ๅจโบๅท๏ผๆญคๅพๆผ่ทไธๆ ๆ2ๅฐๆใๅๆ็ตๆๅพ๏ผๅฐๆบถๆถฒๅทๅป่ณๅฎคๆบซ๏ผไธฆๆทปๅ ็ฒ็ฌจ2 โๅ่ฝ็งป่ณๅๆถฒๆผๆไธญโไปฅๆฐด้ฒ่กๆธ
ๆดใๅฐ่ฉฒๆบถๆถฒไปฅ้ฎใ4 :่กไนพ็ฅๅพ๏ผ้้็ณๅค่ ็ญ็ฎกๆฑ้คๅปๅ้ป้่ณช๏ผๆฟ็ธฎๆบถๆถฒ๏ผ b-5)็ฌจๅนถใฃๅบ[3,2โb]ไบ่ฏๅนถๅฌๅโ6_็้
ธไน ่ช็ฒ่ฏ/็ฒ้ๆททๅใฃๅ็ตๆถโ็ฒๅพ่ฏๅนถๅฌๅๅบm ]ไบ่ฏๅนถฮผไน็ฝ่ฒๅบ้ซ27.9g (็ข็73%) ๅๆ 92 201229048 ๅฐ่ฏๅนถๅๅๅบ[3,2 โ b]ไบ็ฌจๅนถๅๅ๏ผ12_9 g)ใๅๆฐซๅใๅ (่ซๆฐด๏ผ๏ผ300 mL )ๆทปๅ ๆผ็็ถไธญ๏ผไธฆๅทๅป่ณไธ 78ยฐcใๆญคๆ ๆทปๅ n โ BuLi ((ๆผๅทฑ็ทไธญๅญๅจ2.63 M) 20.0 mL)๏ผๆญคๅพๆผ ๅฎคๆบซไธ็ซ็ฝฎ1ๅฐๆใ็นผ่โๅๅบฆๅทๅป่ณโ78ใc๏ผๆทปๅ B( ใMe ) 3(10.4g)โไธฆๆผไธ78Cไธๆๆ1ใๅ้๏ผๆญคๅพๆผๅฎคๆบซไธๆพ็ฝฎ 1ๅฐๆใๅๆ็ตๆๅพ๏ผไปฅ่ธ็ผๅจๆฟ็ธฎ่ณไธๅๅทฆๅณไนๅฎน้๏ผๆญค ๅพๆทปๅ .[N HCLๆฐดๆบถๆถฒ๏ผ200 mL ) โไธฆๆผๅฎคๆบซไธๆชๆ1ๅฐๆใ ๆญคๅพ่ฝ็งป่ณๅๆถฒๆผๆไธญโไธฆไปฅไน้
ธไน้
ฏ้ฒ่ก่ๅใๅฐ่ฉฒๆบถ ๆถฒไปฅMgSใ4้ฒ่กไนพ็ฅๅพ้ฒ่กๆฟ็ธฎ๏ผไธฆไปฅ็ฒ่ฏ/ๅทฑ็งๆททๅๆบถ ๅ้ฒ่กๅๆฃๆธ
ๆด๏ผ็ฒๅพ่ฏๅนถๅๅๅบ[3,2_b]ไบ่ฏๅนถๅๅโ6 โ็กผ้
ธไน็ฝ่ฒๅบ้ซ13.7 g (็ข็91ใ/ใ๏ผใ ๅๆไพ3 (C) 2โ(่ฏๅนถ[kl]ไบ่ฏๅนถๆ
ๅ _4โๅบ๏ผไธ4,4,5,5__ ๅๆฑๅบไธ1๏ผ3,2 โไบๆฐง้ๅ ็งไนๅๆ ไพๆไธ่ฟฐๅๆๆต็จๅๆ2โ(่ฏๅนถ[kl]ไบ่ฏๅนถๅๅไธ 4 โๅบ๏ผไธ4,4,5,5_ๅๆฑๅบไธ^,2โไบๆฐง้็กผ็ทใ
(C โ 1)4 โ ๆฑๆฐงๅบ่ฏๅนถ[kl]ไบ่ฏๅนถๆดพๅไนๅๆ 93 201229048 ไฝฟ4ใ็ฒๆฐงๅบไธiโ่้
๏ผ6.97 g)ๅไบๆบด็ฌจ๏ผj i 3 ;ไธ็ฒๅบ็ฒ้ข่บ200 mLไธญ๏ผไธฆไพๆฌกๆทปๅ ็ขณ้
ธ้ ( g)ใไบ่ฏๅบ่ฆ๏ผ2.10g)ๅไน้
ธ็บช๏ผn)(0.4 5g)๏ผ ๆผ140'ไธๆชๆ15ๅฐๆใๅทๅป่ณๅฎคๆบซ๏ผๆทปๅ ๆฐดๅไน้
ธไน้ ๅ
ฅยท yไบๅๆถฒ๏ผๅฐๆฐดๅฑคไปฅไน้
ธไน้
ฏ้ฒ่ก่ๅ๏ผๅไปฅๆฐดๅ้ฃฝๅ ่ฎI Jc้ฒ่กๅๆด๏ผๅไฝตๆๆฉๅฑคไธฆไปฅ็กๆฐด็กซ้
ธ้้ฒ่กไนพ็ฅใ ้ๆฟพๅพ๏ผ้ฒ่กๆฟ็ธฎใๆผ็ฒๅพไนๆฎๆธฃไธญๆทปๅ ๆฐดๅ็ฒ้๏ผไธฆไปฅ ไบไนๅณปๅไน้
ธไนๆ่ก่$๏ผๅไปฅๅ้ฃฝๅ้ฃ้นฝๆฐด้ฒ่กๆธ
ๆดโๅไฝตๆๆฉๅฑคไธฆไปฅ็กๆฐด็กซ้
ธ้้ฒ่กไนพ็ฅใ้ๆฟพ๏ผๆญคๅพ้ฒ ็ฏๆฟ็ธฎใๅฐ็ฒๅพไนๆฎๆฝฐๆถ่ ๅฑคๆๆณ้ฒ่ก็ดๅๆ๏ผๅฐ็ฒๅพ ไนๆฎฮๅทฑ้ขโไน้
ธไน้
ทๆททๅๆบถๆถฒ้ฒ่กๅๆฃๆธ
ๆดไธฆ้ฒ่กไนพ ็ฅ๏ผ็ฒๅพ4-็ฒๆฐงๅบ่ฏๅนถ[kl]ไบ่ฏๅนถฮผไน้ป่ฒๅบ้ซ3 26 ยง (็ข็3 3 % ใ (Cโ2) 4โ็พฅๅบ่ฏๅนถๅไธจ]ไบ่ฏๅนถๅๅไนๅๆ ๅฐ4็ฒๆฐงๅบ่ฏๅนถ[ๅซไบ่ฏๅนถๅๅ๏ผ3.%็ฌ๏ผๆบถ่งฃๆผไบๆฐฃ ็ฒ็ง100 mLไธญโไธฆๆผๆฐฌๆฐฃ็ฐๅขไธไปฅไนพๅฐโ็ฒ้ๆตดๅทๅป่ณ_ 68ยฐC๏ผ็ถ้2Gๅ้ๆปดๅ ไธๆผๅไพงไนไบๆฐฏ็ฒ็งๆบถๆถฒ๏ผi m๏ผ 14 mL )ใ-้ข็ทฉ็ทฉๅฐๅๆบซ่ณๅฎคๆบซ__้ขๆๆ*ๅฐๆใๅฐ็ฒๅพ ไนๆททๅ็ฉ้ฒ่กๅฐๆๅป๏ผๆธๆปดๆธๆปดๅฐๆทปๅ ๆฐดๆ
้ๅฐไฝฟๅ
ถๅคฑ ๆดป้ฒ่ๆทปๅ 100 mLไนๆฐดใๆๅ็ๆไนๆฒๆฎฟ๏ผไปฅๆฐดๅไบๆฐฃ ็ฒ็ง้ฒ่กๆธ
ๆดไธฆ้ฒ่กไนพ็ฅ๏ผ็ฒๅพ4-ยซ่ฏ็ดฐ]ไบ่ฏๅนถๆ
ๅณไน็ตๆถ๏ผ2ยท35 g)ใๅฐๆๆถฒ้ฒ่กๅๆถฒ๏ผไปฅไบๆฐฃ็ฒ็งๅฐๆฐดๅฑค ้ฒ่ก่ๅโๅไฝตๆๆฉๅฑคไธฆไปฅ็กๆฐด็กซ้
ธ็ด้ฒ่กไนพ็ฅใ้ๆปค๏ผ ๆญคๅพ้ฒ่กๆฟ็ธฎใๅฐ็ฒๅพไนๆฎๆฝฐไปฅๅฐ้ไบๆฐฃ็ฒ็ท้ฒ่กๅๆฃๆธ
S 94 201229048 ๆด ( ๆ ไธฆ้ฒไปไนพ็ฅ๏ผ็ฒๅพ4 โ ใ a ๆฐฌๅบๆฌๅผ[kl]ไบ่ฏๅนถๅๅไน็ตๆถ 0.53 g)ใๅไฝตไบ่
๏ผ ็ข้็บ2.88 g๏ผ็ข็็บ94%ใ 3) 4ไบiL็ฒๅบ็บ้ๅบ่ฏๅนถๅไบ่ฏๅนถๅจๅไนๅ ไฝฟ&ๅบๆฌๅนถ[ๅซไบ่ฏๅนถๆดพๅ๏ผ2ๅฟ๏ผๅๆฃๆผไบๆฐฃ ้ข1 ใใ็คพไธญ๏ผๆผๆฐฃๆฐฃ็ฐๅขไธ้ฒ่กๅฐๆตดๅทๅปโๅๆทปๅ ใๆฏไปทใ mL )ใๆผ็ฒๅพไนๆบถๆถฒไธญ่ฑ ใๅ้ๆปดๅ ไธๆฐ็ฒ็ท็ฃบ้
ธ้
๏ผ3ใ mL)๏ผไธฆๆผใฃๅทๅปไธๆ5ๅ้ๅพ๏ผ-้ข็ทฉ็ทฉๅฐๅๆบซ่ณๅฎค ๆบซไธ้ขใฃ3ๅฐๆใๆผ็ฒๅพไนๆบถๆถฒไธญๆผๅฐๆๅปไธๆทปๅ i M ้นฝ้
ธ๏ผฮฏใโท๏ผไธฆๅฐๆททๅๆบถๆถฒไปฅไบๆฐฏ็ฒ็ง้ฒ่ก่ๅ๏ผๅไปฅ ้ฃฝๅ้ขๆฐซ่ฒก้ฒ่กๆธ
ๆด๏ผๆญคๅพไปฅ็กๆฐด็กซใฃ้ฒ่กไนพ็ฅใ ้ๆปคใ๏ผ่พฒ็ธฎใๅฐ่ฉฒๆฎๆธฃไปฅๅทฑ็ซ_ไน้
ธไนยง|ๆททๅๆบถๆถฒ้ฒ่กๅ ๆฃๆธ
ๆดไธฆไฝฟๅ
ถไนพ็ฅโ็ฒๅพ4โไธๆฐ็ฒๅบ็ขบ้ฏๅบ่ฏๅนถ้ดไบ่ฏ ๅนถๆ
ๅไนๅบ้ซใๆฟ็ธฎๆธ
ๆดๆฏๆถฒ๏ผไธฆๆถ่ ๅฑคๆๆณ้ฒ่ก็ดๅใ ๅฐ็ฒไปไนๆฎๆธฃไปฅๅทฑ็ท้ฒ่กๅๆฃๆธ
ๆดไธฆไฝฟๅ
ถไนพ็ฅ๏ผ็ฒๅพ4 ไธไธ ๆฐๆฑๅบ็ฃบ้ฏๅบ่ฏๅนถ[kl]ไบ่ฏๅนถๅๅไนๅบ้ซใๅไฝตไบ่
๏ผ็ฒๅพ 4ไธไธๆฐ็ฒๅบ็ฃบ้ฏๅบ่ฏๅนถ[]d]ไบ่ฏๅนถๅๅไน่ถ็ฝ่ฒๅบ้ซ3ใ1 g (็ข็ 67%)ใ (Cโ4) 2โ๏ผ่ฏๅนถ[kl]ไบ่ฏๅนถๅๅไธ4_ ๅบ๏ผ_4,4,5,5 โๅ็ฒๅบไธ 1๏ผ3,2_ไบๆฐง้็กผ็ทไนๅๆ ไฝฟ4 ไธไบๆฐ็ฒๅบ็ธพ้
ฟๅบ็ฌจๅนถ[kl]ไบ่ฏๅนถnๅบๅ๏ผ3.01 g)' ้ๆ้ฏไบๅ ๏ผbis (pinacol at ใ) diboron) (2.30 g)ใ[1 ฮน'_ ้๏ผไบ่ฏๅบ่ฆ๏ผไบ่้ต]้๏ผII)ไบๆฐฃๅ็ฉโไบๆฐฃ็ฒ็งๅ ๆ ็ฉ๏ผ0.:34 g)ใ1๏ผฮโ้๏ผไบ่ฏๅบ่ฆ๏ผไบ่้ต๏ผใ23 g)ๅไน 95 201229048 ้
ธ้๏ผ2.42 g)ๆบถ่งฃๆผ1,4 โไบๅ็ท50 mLไธญ๏ผไธฆๆผ80ใ(๏ผไธ ๆชๆ17ๅฐๆใๅๆทปๅ ้ๆ้ฏไบ็กผ๏ผ1.15 g)ใ๏ผไธ้๏ผไบ ่ฏๅบ่ฆ๏ผไบ่้ต]้๏ผฯ)ไบๆฐฃๅ็ฉไธไบๆฐฃ็ฒ็ทๅ ๆ็ฉ๏ผ0_34 g)ๅ1๏ผฮไธ้๏ผไบ่ฏๅบ่ฆ๏ผไบ่้ต๏ผ0.23g)๏ผไธฆๆผ8ใยฐCไธ ๆชๆ7ๅๅๅฐๆใๅฐๅๆๆถฒๅทๅป่ณๅฎคๆบซ๏ผๆทปๅ ๆฐดๅไน้
ธไน ้
ฏไธฆ้ฒ่ก้ๆฟพใๅฐ็ฒๅพไนๆททๅๆถฒ้ฒ่กๅๆถฒ๏ผไปฅไน้
ธๅทฑ้
ฏ้ฒ ่ก่ๅๅพ๏ผๅไฝตๆๆฉๅฑคไธฆไปฅ้ฃฝๅ้ฃ้นฝๆฐด้ฒ่กๆธ
ๆด๏ผๅไปฅ็ก ๆฐด็กซ้
ธ้้ฒ่กไนพ็ฅใ้ๆฟพโๆญคๅพ้ฒ่กๆฟ็ธฎใๅฐ็ฒๅพไนๆฎๆธฃ ไปฅ็ฝ่ ๅฑคๆๆณ้ฒ่ก็ดๅ๏ผ็ฒๅพ2 โ(่ฏๅนถ[ฮท]ไบ่ฏๅนถ็ฅๅไธ 4 ไธๅบ๏ผ_4,4,5,5โๅ็ฒๅบไธ1๏ผ3,2 โไบๆฐง้็กผ็ทไน้ป่ฒๅบ้ซ 1.47 g (็ข็ 52%)ใ ๅๆไพ4 (d ) 2 โ ( 3 โๆบด่ฏๅบ๏ผไธๅชๅ[1๏ผ2 โ a]ๅกๅถไนๅๆ ไพๆไธ่ฟฐๆต็จๅๆ2โ๏ผ3โๆบด็ฌจๅบ๏ผโๅชๅ[uโa] ใๆฏๅฌใ
h2n^
NaHCQ3
EtOH ไฝฟ 3 โๆผ ่ฏ้ขๆฑๅบๆผ ๏ผ3 โ bromophenacyl bromide ) 9.25 gใ2 โ่บๅบฮทๆฏๅฌ1 ใ ยท ใ gๅ็ขณ้
ธๆฐซ็ด4.1 9 gไนๆททๅ็ฉๆผไน้ 150 mLไธญๅๆต5ๅฐๆใๅๆ็ตๆๅพ๏ผๆฟพๅ็ๆไน็ตๆถ๏ผไปฅ ๆฐดๅไธ้
ฎ้ฒ่กๆธ
ๆด๏ผไธฆๆผๆธๅฃไธ้ฒ่กไนพ็ฅ๏ผ็ฒๅพ2โ (3 โ ๆบด่ฏๅบ๏ผไธๅชๅ[1๏ผ2โ a]ๅกๅถ7.91 g (็ข็87%)ใ 96 201229048 ฮน.ๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ] ๅฏฆๆฝไพ1 ๅๅ็ฉฮนไนๅๆ ๅฐใไธ๏ผ4 โๆบด็ฌจๅบ๏ผโ2 โ่ฏๅบโ1H_่ฏๅนถ[d]ๅชๅ๏ผ3 ใใ g)ใ่ฏๅนถ[b]่[2๏ผl-d]ใๅคซๅโ5โ็กผ้
ธ๏ผ2 94 g)ใๅไธ่ฏๅบ ่ฆ้๏ผ0) 0.50gใ1๏ผ2 -ไบ็ฒๆฐงๅบไน็ท26็คพๅ2]^็ขณ้
ธ้ ๆบถๆถฒ13 mLไนๆททๅ็ฉๅ ็ฑๅๆตๆๆ8ๅฐๆใๅฐๅๆๆถฒๅ็ฉ ๅทๅป่ณๅฎคๆบซโๆทปๅ ๆฐดๆชๆ3ใๅ้๏ผๅๆทปๅ ไน้
ธไน้ใๅทฑ็ท ไธฆ้ฒ่ๆผ30ๅ้ใๆธกฮผๆไนๅบ้ซ๏ผไธฆไปฅๆฐดใๆฑ้ใๅทฑ ็ง้ฒ่กๆธ
ๆด๏ผๆญคๅพๆผๆธๅฃไธ้ฒ่กไนพ็ฅใๅฐ็ฒๅพไนๅบ้ซ้ฒ่ ไปฅๅทฑ็ซไน้
ธไน้
ฏๆททๅๆถฒ่ฐ ไผ้ฒไปๅๆฃๆธ
ๆด๏ผๆญคๅพๅฉ็จ็ฝ่ ๅฑค ๆๆณ้ฒๅฝณไบ็ดๅ๏ผไธฆๆผ่ฝจ็ฒ่ดซๅฃซ ^ ๅทฅ"ใใTๆฌไธญ้ฒ่กๅๆฃๆธ
ๆด๏ผ่ๆญค็ฒๅพ็ฝ ่ฒๅบ้ซ3.01 gใ ๆ นๆ่ณช่ญๅๆไน็ตๆ๏ผ็ฒ ๅ็ฉ1 (็ธๅฐๆผๅๅญ้486 17๏ผ ๅพไนๅๅ็ฉไฟ้ๅฎ็บไธ่ฟฐๅ
B(OH)2 m/ e= 486 )ใ็ข็็บ 72%ใ
ๅๅ็ฉ2ไนๅๆ g) โใใ ๏ผ่ญ่ฏๅบๅ2ใ่ฏๅบ-1H-่ฏๅนถ[d]ๅชๅพ๏ผ ๅนถๅคซๅๅบ[3,2- b]ไบ็ฌจๅนถๅฌๅ_ 6_็ณๆ้
ธ๏ผ3 ไธจ 97 ๅคยท 201229048 ๅไธ่ฏๅบ่ฆ้๏ผ0) (ใ.60g)ใ1๏ผ2ใไบ็ฒๆฐงๅบไน็ท26็คพๅ 2M็ขณ้
ธ้ๆบถๆถฒ13 mLไนๆททๅ็ฉๅ ็ฑๅๆตๆชๆ13ๅฐๆใๅฐ ๅๆๆททๅ็ฉๅทๅป่ณๅฎคๆบซ๏ผๆทปๅ ๆฐดไธฆๆชๆ3ใๅ้๏ผๆฟพๅ็ๆ ไนๅบ้ซ๏ผไธฆไปฅๆฐดใ็ฒ้ใๅทฑๅ้ฒ่กๆธ
ๆด๏ผๆญคๅพๆผๆธๅฃไธ้ฒ ่กไนพ็ฅใๅฐ็ฒๅพไนๅบ้ซๅฉ็จ็ฝ่ ๅฑคๆๆณ้ฒ่ก็ดๅ๏ผ ่ฒๅบ้ซ4.42 gใ ๆ นๆ่ณช่ญๅๆไน็ตๆ๏ผ็ฒๅพไนๅๅ็ฉไฟ้ๅฎ็บไธ่ฟฐๅ ๅ็ฉ2(็ธๅฐๆผๅๅญ้526.17๏ผm/e= 526 )ใ็ข็็บ97%ใ
MPd(pPh3)4 Na2C03ๆฐดๆบถๅทง DME
ๅฏฆๆฝไพ3 ๅๅ็ฉ3ไนๅๆ ๅฐ1 โ ( 4 โๆบด่ฏๅบ๏ผโ2ไธ่ฏๅบ_ 1Hโ่ฏๅนถ[d]ๅชๅ๏ผไธจ36 g) 2 (ๆฌๅนถ[kl] ไธ่ฏๅนถใๅบใๅไธ 4_ๅบ๏ผไธ4,4,5,5 โๅๆฑๅบ ^3,2โไบๆฐง้็กผ็ท๏ผ147 g)ใๅไธ่ฏๅบ่ฆ้๏ผใ)( 0.14 g)ใ โใไบๆฑๆฐงๅบไน็ท12 mLๅ2M็ขณ้
ธ้ๆบถๆถฒ6 mLไนๆททๅ็ฉ ๅ ็ฑๅๆตๆๆ6ๅฐๆใๅฐๅๆๆททๅ็ฉๅทๅป่ณๅฎคๆบซ๏ผๆทปๅ ๆฐด ไธฆๆชๆ30ๅ้๏ผๆฟพๅ็ๆไนๅบ้ซ๏ผไปฅๆฐดใ็ฒ้ใๅทฑ็ท้ฒ่ก ๆธ
ๆด 1 โๆญคๅพๆผๆธๅฃไธ้ฒ่กไนพ็ฅใๅฐ็ฒๅพไนๅบ้ซๅฉ็จ็ฝ่ ๅฑค
JitL ใ๏ผๅฌ. '้ฒ่ก็ดๅโไธฆๆผไน้
ธไน้
ฏไธญ้ฒ่กๅๆฃๆธ
ๆด๏ผ่ๆญค็ฒๅพ ็ฝ่ฒๅบ้ซ1.67 gใ 98 201229048 ่ฃๆ่ณช่ญๅๆไน็ตๆโ็ฒๅพไนๅๅ็ฉไฟ้ๅฎ็บไธ่ฟฐๅ ๅ็ฉ3 (็ธๅฐๆผๅๅญ้486.17๏ผm/ e = 486 )ใ็ข็็บ88%ใ
ๅฏฆๆฝไพ4 ๅๅ็ฉ4ไนๅๆ ้คไฝฟ็จๅๆไพ4ไธญๅๆไน2 โ ( 3 _ๆผ ่ฏๅบ๏ผไธๅชใๅ[1๏ผ2 โa]ยฐitๅฌไปฃๆฟ1โ (4 โๆผ ่ฏๅบ๏ผโ2โ่ฏๅบไธ1H โ็ฌจๅนถ[d] ๅชๅไปฅๅค๏ผ่ๅฏฆๆฝไพ2็ธๅๅฐ้ฒ่กๅๆใ ๆ นๆ่ณช่ฐฑๅๆไน็ตๆโ็ฒๅพไนๅๅ็ฉไฟ้ๅฎ็บไธ่ฟฐๅ ๅ็ฉ4(็ธๅฐๆผๅๅญ้450.14๏ผm / e=450)ใ็ข็็บ73%ใ
(ๅๅ็ฉ4) ๅฐ็ฒๅฝณไบไนๅๅ็ฉ1ใ2ใ3ๅ4ไนๅ็ฉๆงไปฅไธ่ฟฐๆนๆณ้ฒ ่ก่ฉๅนใๅฐ็ตๆ็คบๆผ่กจ1ไธญใ (1 )ไธ้ๆ
่ฝ้๏ผฮฯ ) ไฝฟ็จๅธๅฎไน่ฃ็ฝฎF โ 4500 (ๆฅ็ซๅ
ฌๅธ่ฃฝ้ ๏ผ้ฒ่กๆธฌๅฎใ 99 201229048 Eไนๆ็ฎๅผๅฆไธใ ๆ็ฎๅผ ET(eV) = 1239.85/APh ใๅPhใไฟๆ๏ผๆผ็ธฑ่ปธไธ่จญ็บ็ฃทๅ
ๅผทๅบฆใๆฉซ่ปธไธ่จญ็บๆณข ้ท่่กจ็คบ็ฃทๅ
ๅ
่ญๆ๏ผๅฐๆผ็ฃทๅ
ๅ
่ญไน็ญๆณข้ทๅดไนไธๅ่ ๅผๅ็ท๏ผ่ฉฒๅ็ท่ๆฉซ่ปธไนไบค้ป็ๆณข้ทๅผ๏ผๅฎไฝ๏ผnm )ใ ไฝฟๅๅๅ็ฉๆบถ่งฃๆผๆบถๅไธญ๏ผ่ฉฆๆจฃ1 ใ " mol/ L ' EPA (ไบ ไน้๏ผ็ฐๆ็ท๏ผไน้=5 : 5 : 5 (้ซ็ฉๆฏ๏ผใๅๆบถๅ็บๅๅ
็จ็ญ็ด๏ผโ่ฃฝๆ็ฃทๅ
ๆธฌๅฎ็จ่ฉฆๆจฃใๅฐๆพๅ
ฅ็ณ่ฑๆงฝไน็ฃทๅ
ๆธฌๅฎ ็จ่ฉฆๆจฃๅทๅป่ณ77 ( K)๏ผๅฐ็ฃทๅ
ๆธฌๅฎ็จ่ฉฆๆจฃ็
งๅฐๆฟ็ผๅ
๏ผๆน ่ฎๆณข้ทไธฆไธๆธฌๅฎ็ฃทๅ
ๅผทๅบฆใ็ฃทๅ
ๅ
่ญไฟไปฅ็ธฑ่ปธไฝ็บ็ฃทๅ
ๅผท ๅบฆ๏ผไปฅๆฉซ่ปธไฝ็บๆณข้ทใ ๅฐๆผ่ฏฅ็ฃทๅ
ๅ
่ญไน็ญๆณข้ทๅดไนไธๅๅผๅ็ท๏ผๆฑๅพ่ฉฒๅ ็ท่ๆฉซ่ปธไนไบค้ปไนๆณข้ทๅผ๏ผl ph ( nm )ใ ๅฐๆผ็ฃทๅ
ๅ
่ญไน็ญๆณข้ทๅดไนไธๅ็ๅ็ทไฟไปฅๅฆไธๆนๅผ ๅผๅบใไธ่ฌ่ช็บไฟ่ช็ฃทๅ
ๅ
่ญไน็ญๆณข้ทๅด่ตทๅจๅ
่ญๆฒ็ทไธ ็งปๅ็ด่ณๅ
่ญไนๆฅตๅคงๅผไธญๆ้ ่ฟ็ญๆณข้ทๅดไนๆฅตๅคงๅผ๏ผๆญคๆ ้ขๅ้ทๆณข้ทๅดไนๆฒ็ทไธไนๅ้ปไธ็ๅ็ทใ่ฉฒๅ็ท้จ่ๆฒ็ท ไธๅ๏ผๅณ้จ่็ธฑ่ปธๅขๅ ๏ผ่ๅพๆๅบฆๅขๅ ใๆผ่ฉฒๅพๆๅบฆไนๅผ ๆ็บๆฅตๅคงๅผไน้ปไธๆๅผๅ็ท๏ผ็บๅฐๆผ่ฉฒ็ฃทๅ
ๅ
่ญไน็ญๆณข้ท ๅดไนไธๅ็ๅ็ทใ ๅ่
๏ผๅ
ทๆๅ
่ญไนๆๅคงๆณขๅณฐๅผทๅบฆไน1ใ%ไปฅไธไนๆณขๅณฐๅผท ๅบฆ็ๆฅตๅคง้ปไธๅ
ๅซๆผไธ่ฟฐๆ้ ่ฟ็ญๆณข้ทๅดไนๆฅตๅคงๅผไธญ๏ผๆผ ่ๆ้ ่ฟ็ญๆณข้ทๅดไนๆฅตๅคงๅผๆ่ฏ ใฮ ็ฉดๅผ็้ ่ฟใไธๅพๆๅบฆๅผ็บๆฅตๅคงๅผ ไน้ปไธๆๅผ็ๅ็ทโ็บๅฐๆผ่ฉฒ็ฃท ็ไนไน่ฐฑไน็ญๆณข้ทๅดไนไธๅ 201229048 ็ๅ็ทใ (2 )้ขๅญๅ้ปไฝ๏ผIp ) + ๅ้ปไฝไฟๅฐๅๅฑคไนๅฎ็จๅฑคๆผๅฆไธ็ป็ๅบๆฟไธไปฅ็ ไบ่ธ้้ฒไป่ฃฝไฝ๏ผๅไฝฟ็จ็ป็ๅบๆฟไธไน่่ไธฆๆผๅคงๆฐฃไธไฝฟ ็จๅ
ๆๅๅ
่ฃ็ฝฎ๏ผ็็ ่จๅจ๏ผ่ก๏ผๅ
ฌๅธ่ฃฝ้ ๏ผacโ3)้ฒ ่ฎขๆธฌไนโๅ
ท้ซ่่จโ่็ฑๅฆไธๆนๅผ้ฒ่กๆธฌๅฎ๏ผๅฐๆๆ็
งๅฐ ๅ
ๆญคๆๆธฌๅฎ่็ฑ้ป่ทๅ้ข่็ข็ไน้ปๅญ้ใๅฐๆผ็
งๅฐๅ
ไนๆๅ้ๅฐ้ๅบไนๅ
้ปๅญไปฅi/2ไนๆน้ฒ่ก็บทๅ๏ผไปฅๅ
้ปๅญ ้ๅบ่ฝ้ไน่จ้ๅผไฝ็บ้ขๅญๅ้ปไฝ๏ผIp)ใ (3 )่ฆชๅๅ๏ผAf) ๆ นๆ้ขๅญๅ้ปไฝ1p่่ฝ้Egไนๆธฌๅฎๅผ็ฎๅบใ็ฎๅบไนๅผ ๅฆไธใ
Af = Ip- Eg ่ฝ็ญEgไฟ่ชๆฑ่ฏๆบถๆถฒไธญไนๅธๆถๅ
่ญไนๅธๆถ็ซฏ้ฒ่กๆธฌ ๅฎใใ=้ซ่่จ๏ผไฝฟ็จๅธๅฎไนๅฏ่ฆโ็ดซๅคๅๅ
ๅ
ๅบฆ่จๆธฌๅฎๅธ ๆถๅ
^๏ผไธฆๆ นๆ่ฉฒๅ
่ญไน้ทๆณข้ทๅดไนไธ้ๆณข้ท็ฎๅบใ ๆ็ฎๅผๅฆไธใ
Eg ( eV) = 1239.85/ ฮป ab โฆไปฅ็ธฑ่ปธไธ่จญ็บๅธๅ
ๅบฆใๆฉซ่ปธไธ่จญ็บๆณข้ท่่กจ็คบๅธๆถๅ
่ฐฑ่
ไฝ็บๅธๆถๅ
่ญใๆผ้ๆผ่ฝ้Egไนไธ่ฟฐๆ็ฎๅผไธญ๏ผฮปไปฅ ใt nm )่กจ็คบๅฐๆผๅธๆถๅ
่ญไน้ทๆณข้ทๅดไนไธ้ๅผๅ็ท๏ผ ่ฉฒๅ็ท่ๆฉซ่ปธไนไบค้ปไนๆณข้ทๅผใ ไฝฟๅๅๅ็ฉๆบถ่งฃๆผ็ฒ่ฏๆบถๅ๏ผ่ฉฆๆจฃ2ฯ1ใ_5 ไธญโไปฅๅ
็จ้ทๆ็บlcmไนๆนๅผๆบๅ่ฉฆๆจฃใไธ้ขๆน่ฎๆณข้ทไธ 101 201229048 ้ขๆธฌๅฎๅธๅ
ๅบฆใ ๅฐๆผๅธๆถๅ
่ญไน้ทๆณข้ทๅดไนไธ้ๆๅผไนๅ็ทไฟไปฅๅฆไธ ๆนๅผๅผๅบใ ไธ่ฌ่ช็บไฟ่ชๅธๆถๅ
่ญไนๆฅตๅคงๅผไธญๆ้ ่ฟ้ทๆณข้ทๅดไน ๆฅตๅคงๅผ่ตทๆผ้ทๆณข้ทๆนๅไธๅจๅ
่ญๆฒ็ทไธ็งปๅ๏ผๆญคๆๆฒ็ทไธ ไนๅ้ปไธไนๅ็ทใ่ฉฒๅ็ท้จ่ๆฒ็ทไธๅณ้จ่็ธฑ่ปธๆธ ๅฐ๏ผ๏ผ้่คๅบ็พๅพๆๅบฆๆธๅฐไธฆๆผๆญคๅพๅขๅ ใๅฐๆผๅพๆๅบฆไนๅผ ๆผๆ้ ่ฟ้ทๆณข้ทๅด๏ผๅ
ถไธญ๏ผๅธๅ
ๅบฆ็บใ1ไปฅไธไนๆ
ๅฝข้คๅค๏ผ ๅๅพๆฅตๅฐๅผไน้ปไธๆๅผไนๅ็ทไฝ็บๅฐๆผ่ฉฒๅธๆถๅ
่ญไน้ทๆณข ้ทๅดไนไธ้ไนๅ็ทใ ๅ่
๏ผๅธๅ
ๅบฆไนๅผ็บ0.2ไปฅไธไนๆฅตๅคง้ปไธๅ
ๅซๆผไธ่ฟฐๆ ้ ่ฟ้ทๆณข้ทๅดไนๆฅตๅคงๅผใ [่กจ1]
[ๆๆฉELๅ
ไปถไน่ฃฝไฝ] ๅฏฆๆฝไพ5 ็จๆผๆๆฉELๅ
ไปถไธญไนๆๆๅฆไธ 1ใ2 201229048
ๅฐๅธถๆ 25 mm><75 mmx 1 ยท 1 mm ๅไน ITO ้ ๆฅต๏ผไน็ ด็ๅบๆฟ๏ผGiomaticๅ
ฌๅธ่ฃฝ้ ๏ผๆผ็ฐไธ้ไธญ้ฒ่กใ ๅ้่ถ
้ณๆณขๆธ
ๆด๏ผๆญคๅพ้ฒ่ก3ใๅ้uv่ญๆฐงๆธ
ๆดใๅฐๆธ
ๆด ๅพไนๅธถๆ้ๆ้ปๆฅต็ทไน็ป็ๅบๆฟ่ฃ่ๆผ็็ฉบ่ธ้่ฃ็ฝฎไนๅบ ๆฟๅบๆๅจยฑ โ้ฆๅ
ไปฅๆผๅฝขๆๆ้ๆ้ปๆฅต็ทไธๅดไน้ขไธ่ฆไบ ไธจ้ปๆฅตไนๆนๅผๆ่่ๅ5ใ nmไนๅๅ็ฉโ 1ใฮฯ โ 1 ็บ้ปๆดๆณจๅ
ฅๅฑค่็ผๆฎๅ่ฝใ็นผHT-1่ไนๆ่ๅพ๏ผ ไนฮฯยฐ ^ HTโ2้ฒ่ก่ธ้่ๆผHTโ1่ไธๆ่่ๅ45 nm ใHTโ 2่ไฟไฝ็บ้ปๆดๅณ่ผธๅฑค่็ผ ๆผH T โ ฮ *ฯ'ๅๆb (ๆป้:ๆ;=:^1 (ไธป้ซๆๆ ๅ25nm^| , . 1ไน่ๅๆฏ้ฒไป่ธ้๏ผๆ่่ โๅฑคใ้ฒ่ๆผ็ผๅ
ๅฑคไธ่ธ้ๅๅ็ฉๅๅฝขๆ่ 103 201229048 ๅ5 nmไน้ๅฃๅฑคใ้ฒ่่ธ้ไฝ็บ้ปๅญๅณ่ผธๆๆไน^ไธไธ๏ผ ๆผ็ผๅ
ๅฑคไธๅฝขๆ่ๅ20้บตไน้ปๅญๅณ่ผธๅฑคใๆญคๅพ๏ผๅฐUF ไปฅ่ๅ1 nmๆ่ใๆผ่ฉฒLiF่ไธ่ธ้150 nm้ๅฑฌA1ๅฝขๆ ้ๅฑฌ้ฐๆฅต๏ผๅพ่ๅฝขๆๆๆฉELยทๅ
ไปถใ ้ๆผ่ฃฝไฝไนๆๆฉELๅ
ไปถโๅฐ้ปๆตๅฏๅบฆ10 mA/ cm2ๆ ไน้ฉ
ๅๆไนๅ
ไปถๆง่ฝ๏ผ้ฉ
ๅ้ปๅฃใ็ผๅ
ๆ็ใๅค้จ้ๅญ็ข ็ๅ็ผๅ
ๆณข้ท๏ผ้ฒ่ก่ฉๅนใๅฐ็ตๆ็คบๆผ่กจ2ไธญใ ๅฏฆๆฝไพ6ใ7ใ8ๅ9ไปฅๅๆฏ่ผไพ1 ้คไฝฟ็จ่กจ2ไธญ่กจ็คบไนๅๅ็ฉไปฃๆฟๅๅ็ฉไธจ็ฉๅฑค้ๅฃ ๅฑค๏ผไธฆๆผๆป้็ฉๆๆไธญไฝฟ็จ่กจ2ไธญ่กจ็คบไนๅๅ็ฉไปฅๅค๏ผไปฅ ่ๅฏฆๆฝไพ5็ธๅไนๆนๅผ๏ผ่ฃฝไฝๆๆฉELๅ
ไปถไธฆ้ฒ่ก่ฉๅนใๅฐ ็ตๆ็คบๆผ่กจ2ไธญใ ๅ่
๏ผๅฏฆๆฝไพ8ไธญไฝฟ็จไนBD โ 2ๅๆฏ่ผไพ1ไธญไฝฟ็จไน ๅๅ็ฉET โ 2ไฟไธ่ฟฐๅๅ็ฉใ
104 201229048 [่กจ2] ้ๅฃๅฑค ๆป้็ฉๆๆ ้ฉ
ๅ้ปๅฃ (V) ็ผๅ
ๆ็ (Cd/A) ๅค้จ้ๅญ็ข็ (%) ็ผๅ
ๆณข้ท (nm) ๅฏฆๆฝไพ5 ๅๅ็ฉ1 1 BD1 4.3 9.1 9.3 450 ๅฏฆๆฝไพ6 ๅๅ็ฉ2 BD1 3.6 10.0 10.0 450 ๅฏฆๆฝไพ7 ๅๅ็ฉ3 BD1 3.6 10.1 10.0 451 ๅฏฆๆฝไพ8 ๅๅ็ฉ4 BD1 4.1 9.4 9.2 451 ๅฏฆๆฝไพ9 ๅๅ็ฉ4 BD2 4.2 H 10.2 9.5 464 ๆฏ่ผไพ1 ET-2 BD1 4.6 8.2 7.9 451 ๅฏ็ฅโ่็ฑๅฐๆฌ็ผๆไนๅๅ็ฉ็จไฝ้ๅฃๅฑค๏ผๅฏฆๆฝไพ5 ใ9 )๏ผๅถๅฏฆ็พ่ๅ
ๅไฝฟ็จ้ปๅญๅณ่ผธๆๆๆ๏ผๆฏ่ผไพไธจ๏ผ็ธๆฏ ่ผ้ซไน็ผๅ
ๆ็ใ ไธ่ฟฐ้ซๆ็ๆ็คบ้ๅฃๆไนๆๆๅ่ไนๅฏ่ฝๆงใๅฏ่ช ็บ๏ผไธป้ซๆๆไนBH โ 1ไนไธ้ๆ
่ฝ้่ฅไปฅ่ๅๅ็ฉไธจใ4็ธ ๅไนๆนๆณ็ฎๅบโๅ็บ183eV๏ผ็ฑๆผๅๅ็ฉๅ3ไนๅผ่ๆญค็ธ ๅค ๅคงๆ
็ข็ๅฐไบ้ๆ
ๆฟๅญๅฐๅ
ฅ็ผๅ
ๅฑคๅ
ไนๆๆใ ๅฏฆๆฝไพ1 ใ ๅ mmx75 mmๅไนฮฮคฮ้ๆ้ปๆฅต๏ผ =:ไน็ป็ๅบๆฟ๏ผGlใmaticๅ
ฌๅธ่ฃฝ้ ๏ผๆผ็ฐไธ้ไธญ้ฒ่ก =ๅ่ถ
ๆฅๆณขๆธ
ๆดโๆญคๅพ้ฒ่ก3Gๅ้UV่ญๆฐงๆธ
ๆดใๅฐๆธ
. 2้ๆ้ปๆฅต็ทไน็ ด็ๅบๆฟ่ฃ่ๆผ็็ฉบ่ธ้่ฃ็ฝฎไน; ๆๆไธโ้ฆๅ
ไปฅๆผๅฝขๆๆ้ๆ้ปๆฅต็ทไธๅดไน้ขไธ่ฆ: =้ปๆฅตไนๆนๅผๆ่่ๅ5ใnmไนๅๅ็ฉ็บโๅ็บใ ๅพ๏ผๅฐๅ^ ็ผๆฎๅ่ฝใใ็นผHTโ1่ไนๆ่ _ไนHTใ HTโ2้ฒ่ก่ธ้่ๆผHTโ 1่ไธๆ่่ๅ4 ๆผ/ ็บโ2่ไฟไฝ็บ้ปๆดๅณ่ผธๅฑค่็ผๆฎๅ่ฝ, ๆผHT~~2็ไธๅฐๅไบบ่ ใ็ฉBHโ 1 (ไธป้ซๆๆ๏ผๅๅๅ็ฉ 105 201229048 BD_ 2 (็ฉ้็ฉๆๆ๏ผไปฅ20: 1ไน่ๅๆฏ้ฒ่ก่ธ้๏ผๆ่้ช ๅ25 nmไน็ผๅ
ๅฑคใ้ฒ่ๆผ็ผๅ
ๅฑคไธ่ธ้ๅๅ็ฉๅๅฝขๆ่ ๅ25 ฮทฮฮไน้ปๅญๅณ่ผชๅฑคใๆญคๅพโๅฐLiFไปฅ่ๅ1 nmๆ่ใ ๆผ่ฏฅLiF่ไธ่ธ้15ใ nm้ๅฑฌA1ๅฝขๆ้ๅฑฌ้ฐๆฅต๏ผๅพ่ๅฝข ๆๆๆฉELๅ
ไปถใ ้ๆผ่ฃฝไฝไนๆๆฉELๅ
ไปถโๅฐ้ปๆตๅฏๅบฆ1ใ ๆ ไน้ฉ
ๅๆไนitไปถๆงg (้ฉ
ๅ้ปๅฃใ็ผๅ
ๆ็ใๅค้จ้ๅญ็ข ็ๅ็ผๅ
ๆณข้ท๏ผ้ฒ่ก่ฉๅนใๅฐ็ตๆ็คบๆผ่กจ3ไธญใ ๅฏฆๆฝไพ11ใ12ๅ13ไปฅๅๆฏ่ผไพ2 ้คไฝฟ็จ่กจ3ไธญ่กจ็คบไนๅๅ็ฉไปฃๆฟๅๅ็ฉiไธฆ็ฉๅฑค้ปๅญ ๅณ่ผธๅฑคไปฅๅค๏ผไปฅ่ๅฏฆๆฝไพ1ใ็ธๅไนๆนๅผ่ฃฝไฝๆๆฉ็ด
ๅ
ไปถ ไธฆ้ฒ่ก่ฉๅนใๅฐ็ตๆ็คบๆผ่กจ3ไธญใ [่กจ3]
ๅฏ็ฅ๏ผๆฌ็ผๆไนๅๅ็ฉๅณไพฟ็จไฝๅฎไธๅฐๅฝขๆ้ปๅญๅณ่ผธ ๅฑคไนๆๆโ่ๅ
ๅไน้ปๅญๅณ่ผธๆๆ็ธๆฏไบฆ็ฒๅพ่ผ้ซไน็ผๅ
ๆ็ใ่ฉฒ๏ผ้ๆณ้กฏ$:ๆฌ็ผๆใๅๅ็ฉไธๅ
ๅ
ทๆๅฆไธๆๆๆ ็คบไน็ฑ้ๅฃๆไนๆๆๅฐ่ดๅฐไธ้ๆ
ๆฟๅญๅฐๅ
ฅ็ผๅ
ๅฑคๅ
็ไบ ๆโ็ฑๆผๅ
ถไฟๆผๅ-ๅๅญๅ
ๅ
ทๆๅธถๆ้ปๅญๆณจๅ
ฅโๅณ่ผธๆงไน 106 201229048 :ๆฐฎ้็ฐ้จไฝไนๅๅ็ฉ๏ผๆ
ไบฆไฝ็บ้ปๅญๅณ่ผธๆ่็ผๆฎๅ :ใๆไธๅฆไธๅฏ่ฝๆง๏ผ่็ฑไฝฟ็จๆฌ็ผๆไนๅๅ็ฉ๏ผๅฏไปฅๆด ^ไน็ฉๅฑคๆธๅฝขๆๅ
ทๆ้ๅฃ่ฝไน้ปๅญๅณ่ผธๅใ ไธจ.็ขๆฅญไธไนๅฏๅฉ็จๆง] ๆณๆฌ็ผๆไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ่ๆไนๆๆฉๅ
ไปถๅฏ ็จๆผ้ๅฐๆๅพ
ไฝๆถ่้ปๅๅไนๅคงๅ้ป่ฆไน้กฏ็คบ้ขๆฟๆ็
งๆ ้ขๆฟ็ญ6ใ ไธไนไธญๅทฒๅฐๆฌ็ผๆไนๅฏฆๆฝๅฝขๆ
ๅ/ๆๅฏฆๆฝไพ้ฒ่ก่ฅๅนฒ ็ดฐ่ชชๆ๏ผไฝๆฌ้ ๅๅพf่
ๅฏๅฎนๆๅฐๅจๅฏฆ่ณชไธไธ่ซ้ขๆฌ็ผ ๆไนๆฐ็ฉไนๆ็คบๅๆๆ็ๆขไปถไธ่ๆผไฝ็บ่ฉฒ็ญไพ็คบไนๅฏฆๆฝ ๅฝขๆ
ๅ/ๆๅฏฆๆฝไพไธญๅ ๅ
ฅๅค็จฎ่ฎๆดใๅ ๆญค๏ผ่ฉฒ็ญๅค็จฎ่ฎๆด ๅ
ๅซๆผๆฌ็ผๆไน็ฏๅๅ
ใ ๆญค่ชชๆๆธไธญ่จ่ผไนๆ็ปๅ
ๅฎนๅ
จ้จๅผ็จ่ณๆญคใ ใฯๅผ็ฐกๅฎ่ชชๆใ ๅ1ไฟ่กจ็คบๆฌ็ผๆไน็ฌฌ1ๅฏฆๆฝๅฝขๆ
ไนไธไพ็ๅใ ๅ2Aไฟ่กจ็คบๆฌ็ผๆไนๅๅฑคไน่ฝ้้ไฟ็ๅใ ๅ2Bไฟ่กจ็คบๅบๆผๆฌ็ผๆไนๅๅฑคไน่ฝ้้ไฟไนไฝ็จ็ ๅ0 ๅ3ไฟ่กจ็คบ้ๆธกELๆณขๅฝขไนๆธฌๅฎๆนๆณ็ๅใ ๅ4ไฟ่กจ็คบๆบ่ชTTFไน็ผๅ
ๅผทๅบฆๆฏไนๆธฌๅฎๆนๆณ็ๅ ใไธป่ฆๅ
ไปถ็ฌฆ่่ชชๆใ *ใใใ 107
Claims (1)
- 201229048 ไธใ็ณ่ซๅฐๅฉ็ฏๅ๏ผ 1 ยท ไธ็จฎๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผไปฅไธ่ฟฐๅผ๏ผ1 )่กจ็คบ๏ผLโ HAr(1) (ๅผไธญ๏ผArไธจไฟๅ ทๆ1ๅไปฅไธ้ธ่ชๅๅ็ฐๅๅๅ็ฐไธญไน ็ฐ็็ฑ4็ฐไปฅไธ็ธฎๅ่ๆไนmๅน็ธฎๅ็ฐๅบ๏ผ HArไฟไธ่ฟฐๅผ๏ผ2)ใ๏ผ5)่กจ็คบไนๅซๆฐฎ้็ฐๅบไธญ็ไปปไธ ่ ๏ผ ฮทๅmๅๅฅ็บ1ใ5ไนๆดๆธ๏ผฮทๅmไธญไน่ณๅฐไธ่ ็บ1; Lไฟ้ธ่ช็ฑๅฎ้ตใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3 0 ็n+1ๅน่ณๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30็ n+ 1ๅน้็ฐๅบใๆ่ ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30 ็่ณๅบใๅ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30็้็ฐ ๅบ็ตๆไน็พคไธญไน2ๅๆ3ๅไปฅๅฎ้ต้ฃ็ต่ๆ็ฮท + 1ๅนๅบ๏ผR22R11\ N Rl2~^\ N (2)108 201229048 (ๅผไธญ โ RuใR12ใR21ใR22ใR31ใr4ใ ๅ r^ใr ๅ ซ ๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณโๅ1 ใ10็็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ8็็ฐ็ทๅ ต (โkyl ) mใ3ใไน็ถๅไปฃ็็ฝๅบใๆฐฐๅบใ๏ผไบ ๆๆช็ถๅไปฃไน็ขณๆธๅ2()ใฃๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน ๆ็ฐ็ขณๆธ6ใ20็่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธu ็็ท็กซๅบ '็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ็่ณ็กซๅบ Uryithio)ใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ็่ณ่บ (ar:/laniinใ)ใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20็ๅฎๆไบ^ ๅบ่บๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30็่ณๅบใๆ ่ ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ ๅฟไปป๏ผwไปปๅฐๅผโท ไน2ๅๅผๅถ็ฐๅฝผๆญค้ต็ตไนๅฎ้ต๏ผ x้ธ่ชNๆCR13๏ผR13ไฟใๆฐซๅๅญใ็ป็ด ๅๅญใ็ถๅไปฃๆ ใฃๅไปฃไน็ผไธจใ1()็็ตฒใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ๅๆธ3ใ8็็ฐ็ๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃ็็ณๅคๅบใๆฐๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน้ญ1ใ2G็็ตฒๅบใ็ถๅไปฃๆฮฏ็ถ ๅไปฃไนๆ็ฐ็ขณใ6ใ20็่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณ ๆธไธ20็็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅ3ใ็่ณ ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน้ญ6ใ3G็ใฃๅบใ็ถๅไปฃ 4็ถๅไปฃไน็ขณๆธ1ใ20็ๅฎๆไบ็งๅบ่บๅบใ็ถๅไปฃๆๆช ไนๆ็ฐ็ขณๆธ6ใ3ใ็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ่ฃฑๅๅญๆธ5ใ3 0็้็ฐๅบ๏ผ ๆผๅ ทๆ่คๆธๅR"ไนๆ ๅฝขๆ๏ผๅๅใๅฏ็ธๅๆไบฆๅฏไธ 109 201229048 ๅ๏ผ Y้ธ่ชNๆCR_23๏ผRยท23ไฟๆฐซๅๅญใ้นต็ด ๅๅญใ็ถๅไปฃๆ ๆช็ถๅไปฃไน็ขณๆธไธจใโบ็็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ= ็ขณๆธ3ใ8็็ฐ็งๅบใ็ขณๆธ3ใ30ไน็ถๅไปฃ็็ณๅคๅบใๆฐฐๅ ถ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20็็ทๆฐงๅบใ็ถๅไปฃๆ2็ถ ๅไปฃไนๆ็ฐ็ขณๆธ6ใ20็่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน= ๆธ1ใ20็็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ็= ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ็่ณ่บๅบใ็ถๅ= ๆๆช็ถๅไปฃไน็ขณๆธไธจใโ็ๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไนใ็ขณๆธ6ใ30็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐๅๅญๆธ5ใ30็้็ฐๅบ๏ผ ๆผๅ ทๆ่คๆธๅr23ไนๆ ๅฝขๆ๏ผๅๅR23ๅฏ็ธๅๆไบฆๅฏไธ ๅ๏ผ Zไฟไบค่ฏ|๏ผ็บ็ถๅไปฃๆๆช็ถๅไปฃ็ไผธ็ทๅบ (Xyleneๅๆ่ ็ถๅไปฃๆๆช็ถๅไปฃ็ไผธ็ฏๅบ (alkenylene); RiไธจใRnไธญไนไปปไธๅใr R 40 ๅฟไธจใR23ไธญไนไปปไธๅใ&ไธจใIใ ไธญไนไปปไธๅใๅR_4ไธจใR4fiไธญๅค็ด . 46ๅนฒไนไปปไธๅไฟ่L้ต็ตไนๅฎ้ต๏ผใ 2ยทๅฆ็ณ่ซๅฐๅฉ็ฏๅ็ฌฌ1้ ไนไบบๅคw ็ฐ็ฑณ่ฒไนๅซๆฐฃ็ธฎๅ็ฐ่ก็็ฉ๏ผๅ ถไธญ๏ผ ๅ ซโ็บไธ่ฟฐๅผ๏ผ6)่กจ็คบไน็ธฎๅ็ฐๅบ๏ผR 57 โน 110 201229048 (ๅผไธญ๏ผr51ใR58ๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้ฝ็ด ๅๅญ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใไธจใ ใ๏ผ โๆธ1 10็็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๅค้ขๆธ3ใ8็็ฐ็งๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃ็็ณๅคๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใ็็ทๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2Q็่ณๆฐงๅบใ็ถๅไปฃๆๆช ไปฃไน็ขณๆธ1ใ2ใใฃ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ^ ็่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ30็่ณ่บๅบใ็ฆ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2Q็mๅบ่บๅบใ็ถๅไปฃ ๆ๏ผ็ถๅ๏ผไนๆ็ฐ็ขณๆธ6ใ3ใ็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐๅๅญๆธ5ใ3 ใ็้็ฐๅบ๏ผ R51 ่ r52ใR52 ่ r53ใR53 ่ R54ใโ ่ ^^ ็ R56่R57ๅR57่^ไธญไน่ณๅฐi็ตไปฅไธ่ฟฐๅผ๏ผ7 )ๆ (8 J่กจ็คบไนๅฝขๆ ็ธไบ้ต็ต่ๅฝขๆ็ฐ๏ผ(ๅผไธญ๏ผใRuๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ_็ด ๅๅญใๅ ๅไปฃๆๆช็ถๅไปฃไนใฃ1ใ1Gใฃๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐ็ขณๆธ3ใ8็็ฐ็งๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃ็็ณๅคๅบใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธๅโผ็้ขๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2G็่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ 111 201229048 ไปฃ=ๅโผ็็็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใๆฃ ็ๆน็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3G็่ณ่บๅบใๆบ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใโผ็mๅบใใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ3G็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถ ๅไปฃไนๆ็ฐๅๅญๆธ5ใ30็้็ฐๅบ๏ผ ๏ผ Reiๅฐบ68ไธญไนไปปๆmๅไฟ่Lยท้ต็ตไนๅฎ้ต๏ผใ 3.ๅฆ็ณ่ฏทๅฐๅฉ็ฏๅ็ฌฌ}้ ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผๅ ถไธญ An็บไธ่ฟฐๅผ๏ผ9)ๆ๏ผ10)่กจ็คบไน็ธฎๅ็ฐๅบ๏ผ(ๅผไธญ๏ผๅฐบโใๅฐบโฝๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญ '้นต็ด ๅๅญใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ10็็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃ ไนๆ็ฐ็ขณๆธ3ใ8็็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃ็็ฝๅบใ ๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธไธจใโ็็ทๆฐงๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20็่ณๆฐงๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไน็ขณๆธ1ใ20็็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ ไน่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ็่ณ่บๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20็ๅฎๆไบ็ทๅบ่บๅบใ็ถๅไปฃ ๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถ 112 ฮด 201229048 ๅไปฃไนๆ็ฐๅๅญๆธ5ใ30็้็ฐๅบ๏ผ ๅ๏ผR7 1ใr8ใไธญไนไปปๆmๅๅR8ไธจใR90ไธญไนไปปๆmๅ ไฟ่Lยท้ต็ตไนๅฎ้ต๏ผใ 4.ๅฆ็ณ่ซๅฐๅฉ็ฏๅ็ฌฌ1้ ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉโๅ ถไธญ๏ผ Ar,็บไธ่ฟฐๅผ๏ผ11 )ใ๏ผ 12 )ใ๏ผ 1 3 )ๆ๏ผ1 4 )่กจ็คบไน็ธฎๅ็ฐๅบ๏ผ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใไธจใ็็ทๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ3ใ8็็ฐ็ทๅบใ็ขณๆธ3ใ3ใไน็ถๅไปฃ็็ฝ ๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธใใ2ใ็็ทๆฐงๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2ใ็่ณๆฐงๅบใ็ถๅไปฃๆๆช 1ๅไปฃไนๅฅดๆธ1ใ20็็ท็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6 ใ3ใ็่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3ใ็่ณ่บๅบใ 113 201229048 ็ถๅไปฃๆๆช็ถๅไปฃไนใฃๅโผ็ๅฎๆไบ็งๅบ่บๅบใ็ถๅ ไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30็่ณๅบใๆ่ ็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30็้็ฐๅบ๏ผ ๅ๏ผใR100ไธญไนไปปๆmๅใRmใRnใไธญไนไปปๆ็ช ๅใRnไธจใR120ไธญไนไปปๆmๅๅๆฑโดใๅฐบๆงไธญไนไปปๆmๅไฟ ่L้ต็ตไนๅฎ้ต๏ผใ 5ยทๅฆ็ณ่ซๅฐๅฉ็ฏๅ็ฌฌ1้ ไนๅซๆฐง็ธฎๅ็ฐ่ก็็ฉ๏ผๅ ถไธญ๏ผ Arไธจ็บไธ่ฟฐๅผ๏ผ15)่กจ็คบไน็ธฎๅ็ฐๅบ๏ผ(ๅผไธญโ R!3 iใR i 4ใๅๅฅ็จ็ซๅฐ็บๆฐซๅๅญใ้นต็ด ๅๅญใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ1 ใ็็ทๅบใ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐ็ขณๆธ3ใ8็็ฐ็ทๅบใ็ขณๆธ3ใ30ไน็ถๅไปฃ็็ณๅค ๅบใๆฐฐๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ2ใ็็ทๆฐงๅบใ็ถ ๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ20็่ณๆฐงๅบใ็ถๅไปฃๆๆช ็ถๅไปฃไน็ขณๆธ1ใ2 ใ็้ข็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6 ใ3 0็่ณ็กซๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ6ใ3 ใ็่ณ่บๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ1ใ20็ๅฎๆไบ็ทๅบ่บๅบใ็ถๅ ไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ30็่ณๅบใๆ่ ็ถๅไปฃๆๆช ็ถๅไปฃไนๆ็ฐๅๅญๆธ5ใ30็้็ฐๅบ๏ผ ฮ 4 S 201229048 ๅ ถไธญ๏ผโใR"ใไธญไนไปปๆmๅไฟ่ ไปๅฆๅฐน่ซๅฐๅฉ็ฏๅ็ฌฌi้ ไนๅซๆฐงๅขa s ใ ่ฒไน4็ธฎๅ็ฐ่ก็็ฉ๏ผๅ ถไธญ๏ผ โยทๅฆ็ณๅๅฐๅฉ็ฏๅ็ฌฌ๏ผ้ ไนๅซๆฐง็ธฎๅ็ฐ ๆฉ้ปๆซ็ผๅ ๅ ไปถ็จๆๆใ #ๅ ถ็บๆ :ๅฆ็ณ่ซๅฐๅฉ็ฏๅ็ฌฌ7้ ไนๅซๆฐง็ธฎ ่ฉฒๆๆฉtๆฟ็ผๅ ๅ ไปถ็จๆๆ็บ้ๅฃๅฑคๆๆใ็ฉ/ใไธญ 9. ไธ็จฎๆๆฉ้ปๆฟ็ผๅ ๅ ไปถ๏ผๅ ถไพ ้ๅฃๅฑคๅ้ฐๆฅต๏ผ ่ตๅ ๅขใ โ๏ผ้ๅฃๅฑคๅซๆ็ณ่ซๅฐๅฉ็ฏๅ็ฌฌ1็บ6้ ไธญไปปไธ้ ไนๅซ ๆฐง็ธฎๅ็ฐ่ก็็ฉใ ใ3 1 ใ ยทๅฆ็ณ่ซๅฐๅฉ็ฏin็ฌธ0 tS . ไนพๅ็ฌฌ9้ ไนๆๆฉ้ปๆฟ็ผๅ ๅ ไปถ๏ผๅ ถ ไธญ๏ผๆผ่ฉฒ้ๅฃๅฑค่้ฐๆฅต ใ 4ๅ ทๆ้ปๅญๆณจๅ ฅๅฑคๅ/ๆ้ปๅญๅณ ่ผธๅฑค๏ผ่ฉฒ้ปๅญๆณจๅ ฅๅฑคๅ้ท ๅฅ ็ฐ่ก็็ฉใโฆๅญๅณ่ผธๅฑคไธญไน่ณๅฐ1ๅฑคๅซๆๅซ้ ไนๅฆ็ณๆๅฐๅฉ็ฏๅ็ฌฌ10้ ไนๆๆฉ้ปๆฟ็ผๅ ๅ ไปถ๏ผๅ ถ ไธญโ่ฉฒ้ปๅญๆณจๅ ฅๅฑคๅ/ๆ้ปๅญๅณ่ผธๅฑคๅซๆไพ้ปๅญๆงๆป้็ฉ๏ผ 12.ๅฆ็ณ่ซๅฐๅฉ็ฏๅ็ฌฌu้ ไนๆๆฉ้ปๆฟ็ผๅ ๅ ไปถ๏ผๅ ถ ไธญฮฒไพ้ปๅญๆงๆป้็ฉ็บ้ธ่ช็ฑ้นผ้ๅฑฌใ้นผๅ้ๅฑฌใ็จๅ ้ๅฑฌ้นผ้ๅฑฌไนๆฐงๅ็ฉใ้นผ้ๅฑฌไน้นตๅ็ฉใ้นผๅ้ๅฑฌไนๆฐง ๅ็ฉใ้ฉๅ้ๅฑฌไน้ฝๅ็ฉใ็จๅ้ๅฑฌไนๆฐงๅ็ฉใ็จๅ้ๅฑฌ ไน้ฝๅ็ฉใ้ฉ้ๅฑฌไนๆๆฉ้ฏๅ็ฉใ้ฉๅ้ๅฑฌไนๆๆฉ้ฏๅ็ฉ ๅ็จๅ้ๅฑฌ๏ผๆๆฉ้ฏๅ็ฉ็ตๆไน็พคไธญ็i็จฎๆ2็จฎไปฅไธใ 13โๅฆ็ณๅปๅฐๅฉ็ฏๅๅธ9้ ไนๆๆฉ้ปๆฟ็ผๅ ๅ ไปถ๏ผๅ ถ 115 201229048 ไธญ๏ผ่ฉฒ็ผๅ ๅฑคๅซๆไธ่ฟฐๅผ๏ผ16)่กจ็คบไน่ฝ่ก็็ฉ ^208 R201 R207 1^R202 ฮฮ|2 ^206 _^R203 R205 R204 (ๅผไธญโ ฮฮน*ฮทๅAl<i2ๅๅฅ็บ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ ็ขณๆธ6ใ30็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐๅๅญๆธ; ใ30็้็ฐๅบ๏ผ R2ใไธจใR208ๅๅฅ็บๆฐซๅๅญใๆฐๅๅญใ็ถๅไปฃๆๆช็ถๅไปฃ ไน็ขณๆธๅH)็็งๅบใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ3ใ1ใ ็็ฐ็ทๅบใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ3ใ3ใ็็ท็ฝๅบ (alkylsilyl)ใ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ8ใ3ใ็่ณ็ฝ ๅบ๏ผarylsilyไธจ๏ผใ็ถๅไปฃๆๆช็ถๅไปฃไน็ขณๆธ็็ทๆฐงๅบใ ็ถๅไปฃๆๆช็ถๅไปฃไนๆ็ฐ็ขณๆธ6ใ2ใ็่ณๆฐงๅบใ็ถๅไปฃๆ ๆช็ถๅไปฃไนๆ็ฐ็ขณt 6ใ30็่ณๅบใๆ่ ็ถๅไปฃๆๆช็ถๅ ไปฃไนๆ็ฐๅๅญๆธ5ใ30็้็ฐๅบ 1 4.ๅฆ็ณๆๅฐๅฉ็ฏๅ็ฌฌไธจ3้ ไนๆๆฉ้ปๆฟ็ผๅ ๅ ไปถๅ ถ ไธญ๏ผๅซๆ่ฉฒๅผ๏ผ16)่กจ็คบไน่ฝ่ก็็ฉ็็ผๅ ๅฑค่ๅซๆ่ฉฒๅซ ๆฐง็ธฎๅ็ฐ่ก็็ฉไน้ๅฃๅฑค็ธๆฅใ 1 5.ๅฆ็ณๅๅฐๅฉ็ฏๅ็ฌฌ9้ ไนๆๆฉ้ปๆฟ็ผๅ ๅ ไปถ๏ผๅ ถ ไธญๅ็ผๅ ๅฑคๅซๆไธปๆณขๅณฐๆณข้ท็บ5ใใnmไปฅไธไน่ขๅ ๆป้็ฉใ 116
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TWI723007B (zh) * | 2015-02-18 | 2021-04-01 | ๅพทๅ่ซพ็ฆ็ผๅ ไบๆฅต้ซๆ้ๅ ฌๅธ | ๅๅฐ้ซๆๆๅๅ ถ่ๅนถๅๅๅบ่ณชๅๅ็ฉ |
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KR101511072B1 (ko) * | 2009-03-20 | 2015-04-10 | ๋กฌ์๋ํ์ค์ ์์ฌ๋ฃ์ฝ๋ฆฌ์์ ํํ์ฌ | ์ ๊ทํ ์ ๊ธฐ ๋ฐ๊ด ํํฉ๋ฌผ ๋ฐ ์ด๋ฅผ ํฌํจํ๋ ์ ๊ธฐ ์ ๊ณ ๋ฐ๊ด์์ |
US9579402B2 (en) | 2009-12-04 | 2017-02-28 | Biotium, Inc. | Heterocycle-substituted xanthene dyes |
KR101791022B1 (ko) | 2010-04-02 | 2017-10-30 | ์์ค์ํ์จ ์ฃผ์ํ์ฌ | ์คํผ๋ก ํํฉ๋ฌผ ๋ฐ ์ด๋ฅผ ํฌํจํ๋ ์ ๊ธฐ์ ๊ณ๋ฐ๊ด์์ |
KR20110113470A (ko) | 2010-04-09 | 2011-10-17 | ์์ค์ํ์จ ์ฃผ์ํ์ฌ | ์ดํ๊ณ ๋ฆฌ ํํฉ๋ฌผ ๋ฐ ์ด๋ฅผ ํฌํจํ๋ ์ ๊ธฐ์ ๊ณ๋ฐ๊ด์์ |
-
2011
- 2011-11-22 EP EP11842678.2A patent/EP2644607A4/en not_active Withdrawn
- 2011-11-22 US US13/988,920 patent/US9484540B2/en active Active
- 2011-11-22 CN CN2011800560934A patent/CN103221407A/zh active Pending
- 2011-11-22 KR KR1020137012966A patent/KR20140032948A/ko not_active Application Discontinuation
- 2011-11-22 JP JP2012545613A patent/JPWO2012070226A1/ja not_active Withdrawn
- 2011-11-22 TW TW100142682A patent/TW201229048A/zh unknown
- 2011-11-22 WO PCT/JP2011/006486 patent/WO2012070226A1/ja active Application Filing
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI723007B (zh) * | 2015-02-18 | 2021-04-01 | ๅพทๅ่ซพ็ฆ็ผๅ ไบๆฅต้ซๆ้ๅ ฌๅธ | ๅๅฐ้ซๆๆๅๅ ถ่ๅนถๅๅๅบ่ณชๅๅ็ฉ |
TWI761457B (zh) * | 2017-02-20 | 2022-04-21 | ๅพทๅ่ซพ็ฆ็ผๅ ไบๆฅต้ซๆ้ๅ ฌๅธ | ้ปๅญๅๅฐ้ซๅ ไปถๅๅ ถ่ฃฝๅๆนๆณ |
TWI732692B (zh) * | 2019-11-25 | 2021-07-01 | ๅคง้ธๅๅปฃๆฑ้ฟๆ ผ่พ้ ๅ ้ปๆๆๆ้ๅ ฌๅธ | ไธ็จฎๅๅ็ฉๅๅซ่ฉฒๅๅ็ฉ็ๆๆฉ้ป่ด็ผๅ ๅจไปถ |
Also Published As
Publication number | Publication date |
---|---|
US20130306958A1 (en) | 2013-11-21 |
WO2012070226A1 (ja) | 2012-05-31 |
EP2644607A1 (en) | 2013-10-02 |
CN103221407A (zh) | 2013-07-24 |
US9484540B2 (en) | 2016-11-01 |
JPWO2012070226A1 (ja) | 2014-05-19 |
EP2644607A4 (en) | 2014-05-28 |
KR20140032948A (ko) | 2014-03-17 |
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