TW200424244A - Block copolymer composition and transparent elastomeric articles produced therefrom - Google Patents
Block copolymer composition and transparent elastomeric articles produced therefrom Download PDFInfo
- Publication number
- TW200424244A TW200424244A TW093110935A TW93110935A TW200424244A TW 200424244 A TW200424244 A TW 200424244A TW 093110935 A TW093110935 A TW 093110935A TW 93110935 A TW93110935 A TW 93110935A TW 200424244 A TW200424244 A TW 200424244A
- Authority
- TW
- Taiwan
- Prior art keywords
- block copolymer
- copolymer
- elastic
- styrene
- block
- Prior art date
Links
- 229920001400 block copolymer Polymers 0.000 title claims abstract description 162
- 239000000203 mixture Substances 0.000 title claims abstract description 106
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 88
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 81
- 125000003118 aryl group Chemical group 0.000 claims abstract description 46
- 150000001993 dienes Chemical class 0.000 claims abstract description 37
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 92
- 238000000034 method Methods 0.000 claims description 51
- 229920000642 polymer Polymers 0.000 claims description 51
- 239000000178 monomer Substances 0.000 claims description 50
- 238000006116 polymerization reaction Methods 0.000 claims description 38
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 30
- 229920001577 copolymer Polymers 0.000 claims description 30
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 229920000428 triblock copolymer Polymers 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
- 229920003046 tetrablock copolymer Polymers 0.000 claims 2
- NBZANZVJRKXVBH-GYDPHNCVSA-N alpha-Cryptoxanthin Natural products O[C@H]1CC(C)(C)C(/C=C/C(=C\C=C\C(=C/C=C/C=C(\C=C\C=C(/C=C/[C@H]2C(C)=CCCC2(C)C)\C)/C)\C)/C)=C(C)C1 NBZANZVJRKXVBH-GYDPHNCVSA-N 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 72
- 239000010408 film Substances 0.000 description 43
- 239000002480 mineral oil Substances 0.000 description 40
- 235000010446 mineral oil Nutrition 0.000 description 40
- 239000004793 Polystyrene Substances 0.000 description 23
- 239000000047 product Substances 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 21
- 229920002223 polystyrene Polymers 0.000 description 21
- 239000000243 solution Substances 0.000 description 20
- 239000010410 layer Substances 0.000 description 19
- 229920001971 elastomer Polymers 0.000 description 15
- 239000000806 elastomer Substances 0.000 description 15
- 239000000523 sample Substances 0.000 description 15
- -1 polypropylene Polymers 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- 239000003963 antioxidant agent Substances 0.000 description 13
- 238000001125 extrusion Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 238000002834 transmittance Methods 0.000 description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- 239000000314 lubricant Substances 0.000 description 9
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000005096 rolling process Methods 0.000 description 7
- 229920006132 styrene block copolymer Polymers 0.000 description 7
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 229920000359 diblock copolymer Polymers 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920002959 polymer blend Polymers 0.000 description 5
- IJYPHMXWKKKHGT-VAWYXSNFSA-N SIS3 free base Chemical compound C1C=2C=C(OC)C(OC)=CC=2CCN1C(=O)\C=C\C(C1=CC=CN=C1N1C)=C1C1=CC=CC=C1 IJYPHMXWKKKHGT-VAWYXSNFSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000004611 light stabiliser Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 description 4
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000013013 elastic material Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000001542 size-exclusion chromatography Methods 0.000 description 3
- 238000010561 standard procedure Methods 0.000 description 3
- 239000011115 styrene butadiene Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- PKHKSCDFQWKYKA-UHFFFAOYSA-N C=CC1=CC=CC=C1.C=CC=C.C=CC1=CC=CC=C1.C=CC=C.C=CC1=CC=CC=C1 Chemical compound C=CC1=CC=CC=C1.C=CC=C.C=CC1=CC=CC=C1.C=CC=C.C=CC1=CC=CC=C1 PKHKSCDFQWKYKA-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101100058191 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) bcp-1 gene Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000384008 Sisis Species 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- BLXLSQIOCCHAHJ-UHFFFAOYSA-N [2,3,4-tri(nonyl)phenyl] dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=C(OP(O)O)C(CCCCCCCCC)=C1CCCCCCCCC BLXLSQIOCCHAHJ-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- LOPSVNDIKSQVRX-UHFFFAOYSA-N benzene 2-methylbuta-1,3-diene styrene Chemical compound C1=CC=CC=C1.C=CC(C)=C.C=CC1=CC=CC=C1 LOPSVNDIKSQVRX-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical class C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- IFUGTTMILJKOQR-UHFFFAOYSA-N buta-1,3-diene styrene Chemical compound C=CC1=CC=CC=C1.C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1.C=CC=C.C=CC1=CC=CC=C1 IFUGTTMILJKOQR-UHFFFAOYSA-N 0.000 description 1
- JRKOSYZXHJZKLA-UHFFFAOYSA-N buta-1,3-diene styrene Chemical compound C=CC=C.C=Cc1ccccc1.C=Cc1ccccc1.C=Cc1ccccc1 JRKOSYZXHJZKLA-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 244000145845 chattering Species 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 239000013598 vector Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47046103P | 2003-05-14 | 2003-05-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200424244A true TW200424244A (en) | 2004-11-16 |
Family
ID=33476710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093110935A TW200424244A (en) | 2003-05-14 | 2004-04-20 | Block copolymer composition and transparent elastomeric articles produced therefrom |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7700688B2 (enExample) |
| EP (1) | EP1625178B1 (enExample) |
| JP (1) | JP4532496B2 (enExample) |
| CN (1) | CN100420713C (enExample) |
| AT (1) | ATE366283T1 (enExample) |
| CA (1) | CA2524852C (enExample) |
| DE (1) | DE602004007379T2 (enExample) |
| ES (1) | ES2289562T3 (enExample) |
| PL (1) | PL1625178T3 (enExample) |
| TW (1) | TW200424244A (enExample) |
| WO (1) | WO2004104095A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI607060B (zh) * | 2015-03-30 | 2017-12-01 | 科騰聚合物美國有限責任公司 | 經固化之透明橡膠製品及其製造方法 |
| TWI618750B (zh) * | 2015-03-30 | 2018-03-21 | 科騰聚合物美國有限責任公司 | 可固化透明橡膠組合物，由其製得之固化透明橡膠組合物及其製法 |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2391219T3 (es) * | 2004-06-22 | 2012-11-22 | Trimurti Holding Corporation | Copolímeros de bloques elastoméricos de monoalquenil areno-dieno conjugado |
| US20060147685A1 (en) * | 2004-12-30 | 2006-07-06 | Kimberly-Clark Worldwide, Inc. | Multilayer film structure with higher processability |
| JP5557531B2 (ja) | 2006-11-20 | 2014-07-23 | トリムルティ ホールディング コーポレイション | スチレンテトラブロックコポリマーおよびそのようなコポリマーをベースとするポリマーブレンド組成物 |
| WO2008109245A1 (en) * | 2007-03-08 | 2008-09-12 | Dow Global Technologies Inc. | Oil-extended, low styrene content styrene-butadiene-styrene triblock copolymer compositions and articles fabricated therefrom |
| JP5697997B2 (ja) * | 2008-02-29 | 2015-04-08 | ダウ グローバル テクノロジーズ エルエルシー | エチレン／α−オレフィンインターポリマーから作製される繊維及び布地 |
| CN101981121B (zh) | 2008-03-31 | 2013-02-06 | 日本瑞翁株式会社 | 嵌段共聚物组合物、其制备方法及薄膜 |
| EP2346678B1 (en) | 2008-10-07 | 2017-10-04 | Ross Technology Corporation | Spill resistant surfaces having hydrophobic and oleophobic borders |
| WO2010074267A1 (ja) | 2008-12-26 | 2010-07-01 | 日本ゼオン株式会社 | ブロック共重合体組成物およびホットメルト粘接着剤組成物 |
| US8598271B2 (en) | 2008-12-26 | 2013-12-03 | Zeon Corporation | Block copolymer composition, film, and method for producing block copolymer composition |
| JP5403048B2 (ja) | 2009-02-27 | 2014-01-29 | 日本ゼオン株式会社 | フレキソ版用ブロック共重合体組成物 |
| JP5772592B2 (ja) | 2009-03-31 | 2015-09-02 | 日本ゼオン株式会社 | ラベル用粘接着剤組成物 |
| US8470929B2 (en) | 2009-03-31 | 2013-06-25 | Zeon Corporation | Composition for stretchable film |
| KR101591131B1 (ko) | 2009-06-30 | 2016-02-02 | 제온 코포레이션 | 신축성 필름용 조성물 |
| CA2789784A1 (en) * | 2010-02-23 | 2011-09-01 | University Of Connecticut | Natural polymer-based orthopedic fixation screw for bone repair and regeneration |
| MX2012010669A (es) | 2010-03-15 | 2013-02-07 | Ross Technology Corp | Destacadores y metodos para producir supreficies hidrofobas. |
| JP5802669B2 (ja) | 2010-07-29 | 2015-10-28 | 株式会社クラレ | 熱可塑性重合体組成物および成形品 |
| CN102453304B (zh) * | 2010-10-28 | 2013-07-03 | 中国石油化工股份有限公司 | 单乙烯基芳烃和共轭二烯烃嵌段共聚物组合物、其制备方法及其应用 |
| US8980994B2 (en) * | 2010-12-30 | 2015-03-17 | Kraton Polymers U.S. Llc | Elastic film/fiber formulations |
| MX2013009609A (es) | 2011-02-21 | 2013-09-16 | Ross Technology Corp | Revestimiento suoerhidrofobos y oleofobos con sistemas aglutinantes con bajo contenido de compuestos organicos volatiles. |
| EP2791255B1 (en) | 2011-12-15 | 2017-11-01 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
| CN104520392A (zh) * | 2012-06-25 | 2015-04-15 | 罗斯科技公司 | 具有疏水和/或疏油性质的弹性体涂层 |
| TWI686441B (zh) * | 2014-11-14 | 2020-03-01 | 美商葛拉工業公司 | 黏性物質裝袋用的膜 |
| US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
| US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
| US9441090B1 (en) | 2015-03-12 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Methods for controlling hardness of styrene-butadiene block copolymers |
| US9758648B2 (en) * | 2015-03-30 | 2017-09-12 | Kraton Polymers U.S. Llc | Curable transparent rubber composition, a cured transparent rubber composition made thereof, and manufacturing process for the same |
| KR102432155B1 (ko) * | 2015-03-30 | 2022-08-11 | 카리플렉스 피티이 리미티드 | 경화성 투명 고무 조성물, 이것으로 제조된 경화된 투명 고무 조성물 및 제조방법 |
| US9738781B2 (en) * | 2015-09-03 | 2017-08-22 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications |
| US9828455B2 (en) | 2016-02-24 | 2017-11-28 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| ES2943117T3 (es) * | 2016-04-08 | 2023-06-09 | Nitto Advanced Film Gronau Gmbh | Lámina flexible para cintas de lámina |
| CN114929803A (zh) * | 2019-10-27 | 2022-08-19 | 埃万特公司 | 以压延法制备的具有薄膜的弹性薄膜层压材料 |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2550226C2 (de) | 1975-11-08 | 1984-12-13 | Basf Ag, 6700 Ludwigshafen | Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung |
| US4167545A (en) | 1975-11-08 | 1979-09-11 | Basf Aktiengesellschaft | Branched block copolymers and their manufacture |
| US4049595A (en) * | 1976-04-23 | 1977-09-20 | Shell Oil Company | Block copolymer compositions |
| US4173612A (en) | 1977-11-03 | 1979-11-06 | Johnson & Johnson | Extrusion process for thermoplastic rubber film |
| US4305990A (en) | 1977-11-03 | 1981-12-15 | Chicopee | Thermoplastic rubber film |
| US4329309A (en) | 1977-11-03 | 1982-05-11 | Johnson & Johnson | Producing reticulated thermoplastic rubber products |
| US4180530A (en) | 1979-02-05 | 1979-12-25 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4248983A (en) | 1979-02-05 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4248980A (en) | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4248982A (en) | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4248981A (en) | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4248984A (en) | 1979-05-11 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| US4221884A (en) | 1979-05-14 | 1980-09-09 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| DE2940861A1 (de) | 1979-10-09 | 1981-04-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen linearer dreiblockcopolymerisate sowie formteile aus diesen |
| AU537995B2 (en) * | 1980-01-30 | 1984-07-26 | Mitsubishi Rayon Company Limited | Graft polymerisation process |
| US4346198A (en) | 1980-07-14 | 1982-08-24 | Atlantic Richfield Company | Clear impact resistant thermoplastic star-block copolymers |
| DE3032832A1 (de) | 1980-08-30 | 1982-04-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von verzweigten blockcopolymerisaten, verwendung derselben und formteile aus diesen |
| US4476180A (en) | 1983-02-01 | 1984-10-09 | The Procter & Gamble Company | Nonblocking elastomeric polymer blends of ABA block copolymer and ethylene-vinyl acetate copolymer |
| US4572819A (en) | 1983-08-24 | 1986-02-25 | The Dow Chemical Company | Apparatus for anionic polymerization wherein the molecular weight of the polymer is closely controlled |
| US4585825A (en) | 1983-09-30 | 1986-04-29 | The Dow Chemical Company | Monovinylidene aromatic polymer resins having added amounts of high molecular weight polymer |
| JPS60223812A (ja) * | 1984-04-21 | 1985-11-08 | Asahi Chem Ind Co Ltd | ブロツク共重合体及び該ブロツク共重合体を含有する組成物 |
| US4666987A (en) | 1985-02-22 | 1987-05-19 | The Dow Chemical Company | In-mold polymerization of vinyl aromatic compound |
| US4732928A (en) * | 1985-10-02 | 1988-03-22 | Asahi Kasei Kogyo Kabushiki | Highly elastic thermoplastic elastomer composition |
| US5242894A (en) | 1989-02-08 | 1993-09-07 | Kureha Kagaku Kogyo K.K. | N-substituted-3-(nitrogen-containing 5-membered ring)-benzenesulfonamide derivatives, and herbicidal compositions |
| US5358783A (en) * | 1989-08-11 | 1994-10-25 | The Dow Chemical Company | Blends containing polystyrene-polyisoprene-polystyrene block copolymers and articles thereof |
| US4977014A (en) | 1989-08-22 | 1990-12-11 | Shell Oil Company | Thermoplastic block copolymer films |
| US5227419A (en) * | 1990-12-20 | 1993-07-13 | Phillips Petroleum Company | Tapered block styrene/butadiene copolymers |
| CA2055199C (en) * | 1991-02-12 | 2003-10-07 | William G. Blasius, Jr. | Transparent high impact alloy |
| US5134968A (en) | 1991-06-27 | 1992-08-04 | Yancy William C | Bird feeder device |
| CA2134026C (en) * | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
| USH1622H (en) * | 1995-05-30 | 1996-12-03 | Shell Oil Company | Hydrogenated diblock copolymers for adhesives and sealants with improved resistance to degradation |
| US6096828A (en) * | 1995-08-29 | 2000-08-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers, methods for preparing same, and polymer blends |
| JPH09316142A (ja) * | 1996-03-22 | 1997-12-09 | Idemitsu Petrochem Co Ltd | ゴム変性芳香族ビニル樹脂組成物 |
| PL329115A1 (en) | 1996-03-29 | 1999-03-15 | Dow Chemical Co | In situ production of a block copolymer during polymerisation of an aromatic vinyl monomer |
| US5750623A (en) | 1996-05-20 | 1998-05-12 | The Dow Chemical Co. | Hot-melt adhesives for disposable items and articles made therefrom |
| IL148540A0 (en) | 1999-09-17 | 2002-09-12 | Procter & Gamble | Low stress relaxation elastomeric materials |
| JP2001214025A (ja) * | 2000-02-01 | 2001-08-07 | Kuraray Plast Co Ltd | 複合成形体およびその製法 |
| DE10158500A1 (de) * | 2001-11-28 | 2003-06-12 | Basf Ag | Transparente Styrol-Butadien-Blockcopolymermischungen |
| DE102004014585A1 (de) * | 2004-03-23 | 2005-10-13 | Basf Ag | Blends aus Styrol-Butadien-Blockcopolymeren |
| US20070286818A1 (en) * | 2006-06-07 | 2007-12-13 | Wyeth | Treating cystic fibrosis with antibiotics via an aerosol drug |
-
2004
- 2004-04-13 PL PL04785478T patent/PL1625178T3/pl unknown
- 2004-04-13 ES ES04785478T patent/ES2289562T3/es not_active Expired - Lifetime
- 2004-04-13 CN CNB2004800128847A patent/CN100420713C/zh not_active Expired - Lifetime
- 2004-04-13 JP JP2006532402A patent/JP4532496B2/ja not_active Expired - Lifetime
- 2004-04-13 AT AT04785478T patent/ATE366283T1/de not_active IP Right Cessation
- 2004-04-13 DE DE602004007379T patent/DE602004007379T2/de not_active Expired - Lifetime
- 2004-04-13 EP EP04785478A patent/EP1625178B1/en not_active Expired - Lifetime
- 2004-04-13 WO PCT/US2004/011273 patent/WO2004104095A1/en not_active Ceased
- 2004-04-13 CA CA2524852A patent/CA2524852C/en not_active Expired - Fee Related
- 2004-04-13 US US10/554,588 patent/US7700688B2/en not_active Expired - Lifetime
- 2004-04-20 TW TW093110935A patent/TW200424244A/zh unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI607060B (zh) * | 2015-03-30 | 2017-12-01 | 科騰聚合物美國有限責任公司 | 經固化之透明橡膠製品及其製造方法 |
| TWI618750B (zh) * | 2015-03-30 | 2018-03-21 | 科騰聚合物美國有限責任公司 | 可固化透明橡膠組合物，由其製得之固化透明橡膠組合物及其製法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE602004007379D1 (de) | 2007-08-16 |
| US7700688B2 (en) | 2010-04-20 |
| US20060205874A1 (en) | 2006-09-14 |
| JP2006528273A (ja) | 2006-12-14 |
| EP1625178A1 (en) | 2006-02-15 |
| ATE366283T1 (de) | 2007-07-15 |
| CA2524852A1 (en) | 2004-12-02 |
| ES2289562T3 (es) | 2008-02-01 |
| CA2524852C (en) | 2012-02-21 |
| WO2004104095A1 (en) | 2004-12-02 |
| CN1788051A (zh) | 2006-06-14 |
| PL1625178T3 (pl) | 2007-11-30 |
| CN100420713C (zh) | 2008-09-24 |
| EP1625178B1 (en) | 2007-07-04 |
| JP4532496B2 (ja) | 2010-08-25 |
| DE602004007379T2 (de) | 2008-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW200424244A (en) | Block copolymer composition and transparent elastomeric articles produced therefrom | |
| EP1498455B1 (en) | Polymer composition and uses thereof | |
| CN107922557B (zh) | 氢化嵌段共聚物、聚丙烯树脂组合物和成型体 | |
| CN101583665B (zh) | 苯乙烯四嵌段共聚物以及基于该共聚物的聚合物共混组合物 | |
| EP4055101B1 (en) | Thermoplastic elastomer composition | |
| TWI731999B (zh) | 經改良性能之高乙烯基嵌段共聚物組合物及其用途 | |
| US20090062457A1 (en) | Styrenic block copolymers and compositions containing the same | |
| DE60308061T2 (de) | Zusammensetzungen von styrenblockcopolymeren für die herstellung transparenter gelfreier folien | |
| JPWO2002094932A1 (ja) | ブロック共重合体組成物 | |
| JP2010106200A (ja) | 樹脂組成物およびそれからなるシート状成形体 | |
| US7262248B2 (en) | Articles prepared from high molecular weight tetrablock copolymers | |
| JP2006282683A (ja) | 伸縮性フィルム | |
| JP4896306B2 (ja) | 熱収縮性多層フィルム | |
| JP4641636B2 (ja) | ブロック共重合体組成物 | |
| JP2005060564A (ja) | ブロック共重合体及びその熱収縮性フィルム | |
| JP4761690B2 (ja) | 熱収縮性フィルム | |
| WO2024257798A1 (ja) | 伸縮性シートおよび積層体 | |
| JP2008133314A (ja) | 熱収縮性フィルム |