SK5482002A3 - Catalyst systems and their use in a polymerization process - Google Patents

Catalyst systems and their use in a polymerization process Download PDF

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Publication number
SK5482002A3
SK5482002A3 SK548-2002A SK5482002A SK5482002A3 SK 5482002 A3 SK5482002 A3 SK 5482002A3 SK 5482002 A SK5482002 A SK 5482002A SK 5482002 A3 SK5482002 A3 SK 5482002A3
Authority
SK
Slovakia
Prior art keywords
group
catalyst
hafnium
compound
polymerization
Prior art date
Application number
SK548-2002A
Other languages
English (en)
Slovak (sk)
Inventor
David H Mcconville
Donald R Loveday
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/425,390 external-priority patent/US6300438B1/en
Priority claimed from US09/428,576 external-priority patent/US6271323B1/en
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of SK5482002A3 publication Critical patent/SK5482002A3/sk

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
SK548-2002A 1999-10-22 2000-05-15 Catalyst systems and their use in a polymerization process SK5482002A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/425,390 US6300438B1 (en) 1999-10-22 1999-10-22 Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US09/428,576 US6271323B1 (en) 1999-10-28 1999-10-28 Mixed catalyst compounds, catalyst systems and their use in a polymerization process
PCT/US2000/013310 WO2001030860A1 (en) 1999-10-22 2000-05-15 Catalyst systems and their use in a polymerization process

Publications (1)

Publication Number Publication Date
SK5482002A3 true SK5482002A3 (en) 2003-02-04

Family

ID=27026667

Family Applications (1)

Application Number Title Priority Date Filing Date
SK548-2002A SK5482002A3 (en) 1999-10-22 2000-05-15 Catalyst systems and their use in a polymerization process

Country Status (23)

Country Link
EP (1) EP1226191B1 (zh)
JP (1) JP3746234B2 (zh)
KR (1) KR100567304B1 (zh)
CN (1) CN1184242C (zh)
AR (1) AR025163A1 (zh)
AT (1) ATE299898T1 (zh)
AU (1) AU764962B2 (zh)
BR (1) BR0015241B1 (zh)
CA (1) CA2387877C (zh)
CZ (1) CZ20021401A3 (zh)
DE (1) DE60021405T2 (zh)
EG (1) EG22573A (zh)
IL (1) IL149174A0 (zh)
MX (1) MXPA02004000A (zh)
MY (1) MY126752A (zh)
NO (1) NO20021863L (zh)
PL (1) PL354578A1 (zh)
RU (1) RU2241717C2 (zh)
SA (1) SA00210261B1 (zh)
SK (1) SK5482002A3 (zh)
TR (1) TR200201083T2 (zh)
TW (1) TW538051B (zh)
WO (1) WO2001030860A1 (zh)

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AU2002246517A1 (en) 2001-01-16 2002-08-12 Exxonmobil Chemical Patents Inc. Catalysts with at least two transition metal compounds and polymerization processes using them
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US7094848B2 (en) 2003-05-13 2006-08-22 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system
US7045583B2 (en) 2003-12-22 2006-05-16 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalyst system
EP1805226A1 (en) 2004-10-29 2007-07-11 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
US7323526B2 (en) * 2005-07-29 2008-01-29 Univation Technologies, Llc Supported metallocene-alkyl catalyst composition
EP1803747A1 (en) * 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
EP2081968B1 (en) * 2006-11-14 2015-09-16 Univation Technologies, LLC Catalyst systems and polymerization processes
US8362163B2 (en) 2007-03-07 2013-01-29 Dow Global Technologies, Llc Tethered supported transition metal complex
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
CN102712701A (zh) 2009-12-07 2012-10-03 尤尼威蒂恩技术有限责任公司 减少催化剂的静电荷的方法和使用该催化剂生产聚烯烃的方法
EP2536767B1 (en) 2010-02-18 2015-05-06 Univation Technologies, LLC Methods for operating a polymerization reactor
KR20130026531A (ko) 2010-02-22 2013-03-13 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 생산물을 생산하기 위한 촉매 시스템 및 이의 사용 방법
BR112012025925B1 (pt) 2010-04-13 2020-03-17 Univation Technologies, Llc Mistura polimérica e filme
EP2593217B1 (en) 2010-07-16 2014-07-02 Univation Technologies, LLC Systems and methods for measuring particle accumulation on reactor surfaces
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
RU2587080C2 (ru) 2010-11-30 2016-06-10 Юнивейшн Текнолоджиз, Ллк Способы полимеризации олефинов с использованием экстрагированных карбоксилатов металлов
BR112013012545B1 (pt) 2010-11-30 2020-04-14 Univation Tech Llc composição catalisadora, processo de produção de uma composição catalisadora e processo de polimerização
CN103298842B (zh) 2010-12-17 2016-08-31 尤尼威蒂恩技术有限责任公司 从聚烯烃吹扫气体产物回收烃的系统以及方法
ES2640318T3 (es) 2010-12-22 2017-11-02 Univation Technologies, Llc Aditivo para procedimientos de polimerización de olefinas
US9637567B2 (en) 2011-05-13 2017-05-02 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
BR112014010906B1 (pt) 2011-11-08 2020-12-01 Univation Technologies, Llc método para produzir uma poliolefina
CN103917292B (zh) 2011-11-08 2016-11-23 尤尼威蒂恩技术有限责任公司 制备催化剂体系的方法
ES2918582T3 (es) 2012-12-28 2022-07-19 Univation Tech Llc Catalizador soportado con fluidez mejorada
RU2656343C2 (ru) 2013-01-30 2018-06-05 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Способы изготовления каталитических композиций, имеющих улучшенную текучесть
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US9809667B2 (en) * 2014-02-11 2017-11-07 Univation Technologies, Llc Producing polyolefin products
BR112016022780B1 (pt) 2014-04-02 2021-08-17 Univation Technologies, Llc Composição de continuidade
CA2958435C (en) 2014-08-19 2023-06-13 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
BR112017003170B1 (pt) 2014-08-19 2022-02-15 Univation Technologies, Llc Método para fazer um suporte de catalisador de alumina-sílica fluorado e sistema de catalisador de alumina-sílica fluorado
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SG11201707037TA (en) 2015-03-10 2017-09-28 Univation Tech Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
ES2719407T3 (es) 2015-04-08 2019-07-10 Univation Tech Llc Transiciones en reactor cerrado entre catalizadores de metaloceno
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CN109174190B (zh) * 2018-09-17 2021-06-08 天津科技大学 用于乙烯选择性齐聚的催化剂体系
KR102547229B1 (ko) * 2019-10-16 2023-06-26 한화솔루션 주식회사 올레핀 중합용 혼성 촉매의 제조방법, 올레핀 중합용 혼성 촉매 및 올레핀계 중합체
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Also Published As

Publication number Publication date
AU5134800A (en) 2001-05-08
KR20020081207A (ko) 2002-10-26
AU764962B2 (en) 2003-09-04
BR0015241B1 (pt) 2010-10-05
JP3746234B2 (ja) 2006-02-15
WO2001030860A1 (en) 2001-05-03
EP1226191A1 (en) 2002-07-31
JP2003513113A (ja) 2003-04-08
IL149174A0 (en) 2002-11-10
EG22573A (en) 2003-04-30
CZ20021401A3 (cs) 2002-10-16
NO20021863D0 (no) 2002-04-19
ATE299898T1 (de) 2005-08-15
KR100567304B1 (ko) 2006-04-04
PL354578A1 (en) 2004-01-26
CA2387877C (en) 2006-12-19
TR200201083T2 (tr) 2002-10-21
TW538051B (en) 2003-06-21
BR0015241A (pt) 2002-12-24
RU2002112853A (ru) 2004-01-20
SA00210261B1 (ar) 2005-11-23
MXPA02004000A (es) 2002-10-23
NO20021863L (no) 2002-06-21
AR025163A1 (es) 2002-11-13
DE60021405D1 (de) 2005-08-25
RU2241717C2 (ru) 2004-12-10
CN1382162A (zh) 2002-11-27
EP1226191B1 (en) 2005-07-20
DE60021405T2 (de) 2006-05-18
CA2387877A1 (en) 2001-05-03
MY126752A (en) 2006-10-31
CN1184242C (zh) 2005-01-12

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