SK128997A3 - Phosphating process with a metalliferous re-rinsing stage - Google Patents
Phosphating process with a metalliferous re-rinsing stage Download PDFInfo
- Publication number
- SK128997A3 SK128997A3 SK1289-97A SK128997A SK128997A3 SK 128997 A3 SK128997 A3 SK 128997A3 SK 128997 A SK128997 A SK 128997A SK 128997 A3 SK128997 A3 SK 128997A3
- Authority
- SK
- Slovakia
- Prior art keywords
- phosphating
- sub
- ions
- solution
- rinsing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 55
- 230000008569 process Effects 0.000 title claims abstract description 31
- 239000000243 solution Substances 0.000 claims abstract description 59
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- 239000011701 zinc Substances 0.000 claims abstract description 24
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 13
- 150000001768 cations Chemical class 0.000 claims abstract description 12
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 29
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 29
- 229910019142 PO4 Inorganic materials 0.000 claims description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
- -1 m-nitrobenzenesulfonate ions Chemical class 0.000 claims description 24
- 239000010452 phosphate Substances 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 16
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 15
- 229910000831 Steel Inorganic materials 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- 239000010959 steel Substances 0.000 claims description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 13
- 239000012487 rinsing solution Substances 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 239000008397 galvanized steel Substances 0.000 claims description 10
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 8
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 claims description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims description 2
- XQTIWNLDFPPCIU-UHFFFAOYSA-N cerium(3+) Chemical compound [Ce+3] XQTIWNLDFPPCIU-UHFFFAOYSA-N 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 description 23
- 238000005260 corrosion Methods 0.000 description 21
- 230000007797 corrosion Effects 0.000 description 21
- 239000002253 acid Substances 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003973 paint Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 239000011572 manganese Substances 0.000 description 11
- 229910002651 NO3 Inorganic materials 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 8
- 239000004922 lacquer Substances 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000010422 painting Methods 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000002161 passivation Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 150000002222 fluorine compounds Chemical class 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 229910001437 manganese ion Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 229910001453 nickel ion Inorganic materials 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 230000008092 positive effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- ONMOULMPIIOVTQ-UHFFFAOYSA-M 3-Nitrobenzene sulphonate Chemical compound [O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 ONMOULMPIIOVTQ-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 150000001844 chromium Chemical class 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 150000002816 nickel compounds Chemical class 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 150000003388 sodium compounds Chemical class 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- AFPHTEQTJZKQAQ-UHFFFAOYSA-N 3-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1 AFPHTEQTJZKQAQ-UHFFFAOYSA-N 0.000 description 1
- ONMOULMPIIOVTQ-UHFFFAOYSA-N 98-47-5 Chemical compound OS(=O)(=O)C1=CC=CC([N+]([O-])=O)=C1 ONMOULMPIIOVTQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910000680 Aluminized steel Inorganic materials 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 101100229963 Drosophila melanogaster grau gene Proteins 0.000 description 1
- MGKOSOIDPUKBRW-UHFFFAOYSA-H F[Ti](F)(F)(F)(F)F Chemical compound F[Ti](F)(F)(F)(F)F MGKOSOIDPUKBRW-UHFFFAOYSA-H 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920001665 Poly-4-vinylphenol Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- RVGMCVRSUKTFHN-UHFFFAOYSA-G [F-].[Zr+4].[Al+3].[F-].[F-].[F-].[F-].[F-].[F-] Chemical class [F-].[Zr+4].[Al+3].[F-].[F-].[F-].[F-].[F-].[F-] RVGMCVRSUKTFHN-UHFFFAOYSA-G 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000004973 alkali metal peroxides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- VGYYSIDKAKXZEE-UHFFFAOYSA-L hydroxylammonium sulfate Chemical compound O[NH3+].O[NH3+].[O-]S([O-])(=O)=O VGYYSIDKAKXZEE-UHFFFAOYSA-L 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- UJJUJHTVDYXQON-UHFFFAOYSA-N nitro benzenesulfonate Chemical compound [O-][N+](=O)OS(=O)(=O)C1=CC=CC=C1 UJJUJHTVDYXQON-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- FZFRVZDLZISPFJ-UHFFFAOYSA-N tungsten(6+) Chemical compound [W+6] FZFRVZDLZISPFJ-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Chemically Coating (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Removal Of Specific Substances (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19511573A DE19511573A1 (de) | 1995-03-29 | 1995-03-29 | Verfahren zur Phosphatierung mit metallhaltiger Nachspülung |
| PCT/EP1996/001196 WO1996030559A1 (de) | 1995-03-29 | 1996-03-20 | Verfahren zur phosphatierung mit metallhaltiger nachspülung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK128997A3 true SK128997A3 (en) | 1998-12-02 |
Family
ID=7758087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1289-97A SK128997A3 (en) | 1995-03-29 | 1996-03-20 | Phosphating process with a metalliferous re-rinsing stage |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6090224A (xx) |
| EP (1) | EP0817872B1 (xx) |
| JP (1) | JP3883571B2 (xx) |
| KR (1) | KR100362549B1 (xx) |
| CN (1) | CN1079845C (xx) |
| AT (1) | ATE189010T1 (xx) |
| AU (1) | AU697424B2 (xx) |
| BR (1) | BR9607767A (xx) |
| CA (1) | CA2216925A1 (xx) |
| CZ (1) | CZ287867B6 (xx) |
| DE (2) | DE19511573A1 (xx) |
| ES (1) | ES2143186T3 (xx) |
| HU (1) | HUP9802380A3 (xx) |
| PL (1) | PL179316B1 (xx) |
| PT (1) | PT817872E (xx) |
| SK (1) | SK128997A3 (xx) |
| TR (1) | TR199701061T1 (xx) |
| WO (1) | WO1996030559A1 (xx) |
| ZA (1) | ZA962504B (xx) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19511573A1 (de) * | 1995-03-29 | 1996-10-02 | Henkel Kgaa | Verfahren zur Phosphatierung mit metallhaltiger Nachspülung |
| ZA983867B (en) * | 1997-05-16 | 1998-11-13 | Henkel Corp | Lithium and vanadium containing sealing composition and process therewith |
| US6315823B1 (en) | 1998-05-15 | 2001-11-13 | Henkel Corporation | Lithium and vanadium containing sealing composition and process therewith |
| DE19834796A1 (de) * | 1998-08-01 | 2000-02-03 | Henkel Kgaa | Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung |
| DE19933189A1 (de) * | 1999-07-15 | 2001-01-18 | Henkel Kgaa | Verfahren zur korrosionsschützenden Behandlung oder Nachbehandlung von Metalloberflächen |
| DE10056628B4 (de) * | 2000-11-15 | 2004-07-22 | Henkel Kgaa | Fraktionierte Regenerierung eines mit Nickelionen beladenen schwach sauren Ionenaustauschers |
| DE102005047424A1 (de) * | 2005-09-30 | 2007-04-05 | Henkel Kgaa | Phosphatierlösung mit Wasserstoffperoxid und chelatbildenden Carbonsäuren |
| DE102006052919A1 (de) * | 2006-11-08 | 2008-05-15 | Henkel Kgaa | Zr-/Ti-haltige Phosphatierlösung zur Passivierung von Metallverbundoberflächen |
| US8673091B2 (en) | 2007-08-03 | 2014-03-18 | Ppg Industries Ohio, Inc | Pretreatment compositions and methods for coating a metal substrate |
| JP5526664B2 (ja) * | 2009-09-03 | 2014-06-18 | マツダ株式会社 | 金属部材の表面処理方法 |
| US8506728B2 (en) * | 2009-09-03 | 2013-08-13 | Mazda Motor Corporation | Surface treatment method of metal material |
| DE102010001686A1 (de) | 2010-02-09 | 2011-08-11 | Henkel AG & Co. KGaA, 40589 | Zusammensetzung für die alkalische Passivierung von Zinkoberflächen |
| JP5481705B2 (ja) * | 2010-03-19 | 2014-04-23 | 富士化学株式会社 | 鉄鋼材用非クロム酸系防食剤及び当該防食剤を用いた鉄鋼材の防食処理方法 |
| DE102010030697A1 (de) * | 2010-06-30 | 2012-01-05 | Henkel Ag & Co. Kgaa | Verfahren zur selektiven Phosphatierung einer Verbundmetallkonstruktion |
| EP2405031A1 (de) * | 2010-07-07 | 2012-01-11 | Mattthias Koch | Verfahren zur Beschichtung von Formkörpern sowie beschichteter Formkörper |
| PL2503025T3 (pl) | 2011-03-22 | 2013-12-31 | Henkel Ag & Co Kgaa | Chroniąca przed korozją, wielostopniowa obróbka metalowych elementów konstrukcyjnych o powierzchniach cynkowych |
| US9273399B2 (en) * | 2013-03-15 | 2016-03-01 | Ppg Industries Ohio, Inc. | Pretreatment compositions and methods for coating a battery electrode |
| DE102014210708A1 (de) * | 2014-06-05 | 2015-12-17 | Siemens Aktiengesellschaft | Verfahren zur Korrosionsschutzbehandlung |
| CN104313562B (zh) * | 2014-09-30 | 2017-12-26 | 泰州龙谷信息科技有限公司 | 一种常温磷化液及其制备方法 |
| KR102689368B1 (ko) * | 2015-04-07 | 2024-07-30 | 케메탈 게엠베하 | 전환 코팅의 전기 전도도를 특정하게 조정하는 방법 |
| US10435806B2 (en) | 2015-10-12 | 2019-10-08 | Prc-Desoto International, Inc. | Methods for electrolytically depositing pretreatment compositions |
| US11124880B2 (en) | 2016-04-07 | 2021-09-21 | Chemetall Gmbh | Method for nickel-free phosphating metal surfaces |
| DE102016206417A1 (de) | 2016-04-15 | 2017-10-19 | Henkel Ag & Co. Kgaa | Fördergestellbehandlung zur unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung |
| MX2020002343A (es) * | 2017-08-31 | 2020-07-13 | Chemetall Gmbh | Metodo mejorado para superficies metalicas fosfatadas sin niquel. |
| WO2021235083A1 (ja) * | 2020-05-18 | 2021-11-25 | 日本製鉄株式会社 | Ａｌめっきホットスタンプ鋼材 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3579429A (en) * | 1967-04-14 | 1971-05-18 | Amchem Prod | Process for applying a white paint electrophoretically |
| CA950402A (en) * | 1970-01-06 | 1974-07-02 | Amchem Products | Process for applying a white paint electrophoretically |
| US3695942A (en) * | 1970-12-02 | 1972-10-03 | Amchem Prod | Zirconium rinse for phosphate coated metal surfaces |
| JPS535622B2 (xx) * | 1973-02-12 | 1978-03-01 | ||
| US3895970A (en) * | 1973-06-11 | 1975-07-22 | Pennwalt Corp | Sealing rinse for phosphate coatings of metal |
| JPS5292836A (en) * | 1976-01-30 | 1977-08-04 | Nippon Packaging Kk | Zinc or its alloys subjected to chemical conversion |
| FR2352895A1 (fr) * | 1976-04-21 | 1977-12-23 | Diversey France | Nouveau procede de traitement de surfaces metalliques au moyen de composes oxyfluores du phosphore 5 |
| US4153478A (en) * | 1976-04-21 | 1979-05-08 | The Diversey Corporation | Process for treatment of metallic surfaces by means of fluorophosphate salts |
| US4110129A (en) * | 1977-02-03 | 1978-08-29 | Oxy Metal Industries Corporation | Post treatment of conversion-coated zinc surfaces |
| SU914652A1 (ru) * | 1980-04-07 | 1982-03-23 | Inst Mekhaniki Metallopolimern | Способ дополнительной обработки пористых фосфатных покрытий1 |
| JPS57152472A (en) * | 1981-03-16 | 1982-09-20 | Nippon Paint Co Ltd | Phosphating method for metallic surface for cation type electrodeposition painting |
| DE3400339A1 (de) * | 1984-01-07 | 1985-08-29 | Gerhard Collardin GmbH, 5000 Köln | Verfahren zur nachpassivierung von phosphatierten metalloberflaechen unter verwendung von nickel- und/oder kupfer-kationen enthaltenden loesungen |
| SG52645A1 (en) * | 1985-08-27 | 1998-09-28 | Henkel Corp | A process for phosphate-coating metal surfaces |
| US4865653A (en) * | 1987-10-30 | 1989-09-12 | Henkel Corporation | Zinc phosphate coating process |
| AU610313B2 (en) * | 1987-12-18 | 1991-05-16 | Nippon Paint Co., Ltd. | Process for phosphating metal surfaces |
| DE3920296A1 (de) * | 1989-06-21 | 1991-01-10 | Henkel Kgaa | Verfahren zur herstellung von mangan- und magnesiumhaltigen zinkphosphatueberzuegen |
| DE3924984A1 (de) * | 1989-07-28 | 1991-01-31 | Metallgesellschaft Ag | Verfahren zur passivierenden nachspuelung von phosphatschichten |
| US5294266A (en) * | 1989-07-28 | 1994-03-15 | Metallgesellschaft Aktiengesellschaft | Process for a passivating postrinsing of conversion layers |
| DE4013483A1 (de) * | 1990-04-27 | 1991-10-31 | Metallgesellschaft Ag | Verfahren zur phosphatierung von metalloberflaechen |
| US5268041A (en) * | 1990-04-27 | 1993-12-07 | Metallgesellschaft Ag | Process for phosphating metal surfaces |
| US5209788A (en) * | 1990-11-21 | 1993-05-11 | Ppg Industries, Inc. | Non-chrome final rinse for phosphated metal |
| DE4041091A1 (de) * | 1990-12-21 | 1992-06-25 | Metallgesellschaft Ag | Verfahren zur nachspuelung von konversionsschichten |
| US5128211A (en) * | 1991-02-28 | 1992-07-07 | Diversey Corporation | Aluminum based phosphate final rinse |
| DE69326021T2 (de) * | 1992-12-22 | 1999-12-23 | Henkel Corp., Plymouth Meeting | Im wesentlichen nickelfreier phosphatkonversionsüberzug-zusammensetzung und verfahren |
| CN1041001C (zh) * | 1993-09-06 | 1998-12-02 | 汉克尔股份两合公司 | 无镍的磷酸盐化处理金属表面的方法 |
| DE4330104A1 (de) * | 1993-09-06 | 1995-03-09 | Henkel Kgaa | Nickel- und Kupfer-freies Phosphatierverfahren |
| DE4341041A1 (de) * | 1993-12-02 | 1995-06-08 | Henkel Kgaa | Nickelfreies Phosphatierverfahren mit m-Nitrobenzolsulfonat |
| JPH07278891A (ja) * | 1994-04-12 | 1995-10-24 | Nippon Parkerizing Co Ltd | 金属材料の塗装前処理方法 |
| BR9507776A (pt) * | 1994-05-27 | 1997-08-19 | Herberts & Co Gmbh | Processo para o revestimento de substratos de metal fosfatizados |
| DE19511573A1 (de) * | 1995-03-29 | 1996-10-02 | Henkel Kgaa | Verfahren zur Phosphatierung mit metallhaltiger Nachspülung |
-
1995
- 1995-03-29 DE DE19511573A patent/DE19511573A1/de not_active Withdrawn
-
1996
- 1996-03-20 SK SK1289-97A patent/SK128997A3/sk unknown
- 1996-03-20 CA CA002216925A patent/CA2216925A1/en not_active Abandoned
- 1996-03-20 ES ES96908083T patent/ES2143186T3/es not_active Expired - Lifetime
- 1996-03-20 WO PCT/EP1996/001196 patent/WO1996030559A1/de active IP Right Grant
- 1996-03-20 AU AU51464/96A patent/AU697424B2/en not_active Ceased
- 1996-03-20 KR KR1019970706149A patent/KR100362549B1/ko not_active IP Right Cessation
- 1996-03-20 CN CN96192795A patent/CN1079845C/zh not_active Expired - Fee Related
- 1996-03-20 PT PT96908083T patent/PT817872E/pt unknown
- 1996-03-20 TR TR97/01061T patent/TR199701061T1/xx unknown
- 1996-03-20 CZ CZ19973061A patent/CZ287867B6/cs not_active IP Right Cessation
- 1996-03-20 EP EP96908083A patent/EP0817872B1/de not_active Expired - Lifetime
- 1996-03-20 BR BR9607767A patent/BR9607767A/pt not_active Application Discontinuation
- 1996-03-20 HU HU9802380A patent/HUP9802380A3/hu unknown
- 1996-03-20 JP JP52888296A patent/JP3883571B2/ja not_active Expired - Fee Related
- 1996-03-20 PL PL96321960A patent/PL179316B1/pl not_active IP Right Cessation
- 1996-03-20 AT AT96908083T patent/ATE189010T1/de not_active IP Right Cessation
- 1996-03-20 US US08/930,565 patent/US6090224A/en not_active Expired - Fee Related
- 1996-03-20 DE DE59604232T patent/DE59604232D1/de not_active Expired - Fee Related
- 1996-03-28 ZA ZA962504A patent/ZA962504B/xx unknown
-
2000
- 2000-07-17 US US09/617,886 patent/US6395105B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1179183A (zh) | 1998-04-15 |
| ATE189010T1 (de) | 2000-02-15 |
| PL321960A1 (en) | 1998-01-05 |
| AU5146496A (en) | 1996-10-16 |
| US6395105B1 (en) | 2002-05-28 |
| KR100362549B1 (ko) | 2003-02-11 |
| EP0817872B1 (de) | 2000-01-19 |
| PT817872E (pt) | 2000-07-31 |
| TR199701061T1 (xx) | 1998-01-21 |
| CN1079845C (zh) | 2002-02-27 |
| CA2216925A1 (en) | 1996-10-03 |
| DE59604232D1 (de) | 2000-02-24 |
| HUP9802380A2 (hu) | 1999-02-01 |
| JPH11502569A (ja) | 1999-03-02 |
| US6090224A (en) | 2000-07-18 |
| CZ287867B6 (en) | 2001-02-14 |
| WO1996030559A1 (de) | 1996-10-03 |
| ZA962504B (en) | 1996-09-30 |
| CZ306197A3 (cs) | 1998-03-18 |
| JP3883571B2 (ja) | 2007-02-21 |
| MX9707328A (es) | 1998-07-31 |
| KR19980702742A (ko) | 1998-08-05 |
| PL179316B1 (pl) | 2000-08-31 |
| BR9607767A (pt) | 1999-01-19 |
| EP0817872A1 (de) | 1998-01-14 |
| ES2143186T3 (es) | 2000-05-01 |
| HUP9802380A3 (en) | 1999-03-29 |
| DE19511573A1 (de) | 1996-10-02 |
| AU697424B2 (en) | 1998-10-08 |
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