SE403104B - Forfarande for ammoxidation eller oxidation av propen eller i-buten eller dehydrogenering av olefiner innehallande 4-10 kolatomer vid en temperatur av 200Ÿc-600Ÿc i nervaro av en katalysator, samt katalysator herfor - Google Patents

Forfarande for ammoxidation eller oxidation av propen eller i-buten eller dehydrogenering av olefiner innehallande 4-10 kolatomer vid en temperatur av 200Ÿc-600Ÿc i nervaro av en katalysator, samt katalysator herfor

Info

Publication number
SE403104B
SE403104B SE7410289A SE7410289A SE403104B SE 403104 B SE403104 B SE 403104B SE 7410289 A SE7410289 A SE 7410289A SE 7410289 A SE7410289 A SE 7410289A SE 403104 B SE403104 B SE 403104B
Authority
SE
Sweden
Prior art keywords
catalyst
propellen
colatomes
ammoxidation
dehydrogenation
Prior art date
Application number
SE7410289A
Other languages
English (en)
Swedish (sv)
Other versions
SE7410289L (da
Inventor
R K Grasselli
A F Miller
W G Shaw
Original Assignee
Standard Oil Co Ohio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co Ohio filed Critical Standard Oil Co Ohio
Publication of SE7410289L publication Critical patent/SE7410289L/xx
Publication of SE403104B publication Critical patent/SE403104B/xx

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19Molybdenum
    • B01J27/192Molybdenum with bismuth
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/24Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00Chemistry of hydrocarbon compounds
    • Y10S585/8995Catalyst and recycle considerations
    • Y10S585/906Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SE7410289A 1973-09-04 1974-08-12 Forfarande for ammoxidation eller oxidation av propen eller i-buten eller dehydrogenering av olefiner innehallande 4-10 kolatomer vid en temperatur av 200Ÿc-600Ÿc i nervaro av en katalysator, samt katalysator herfor SE403104B (sv)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/393,732 US3956181A (en) 1973-09-04 1973-09-04 Oxidation catalyst

Publications (2)

Publication Number Publication Date
SE7410289L SE7410289L (da) 1975-03-05
SE403104B true SE403104B (sv) 1978-07-31

Family

ID=23556013

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7410289A SE403104B (sv) 1973-09-04 1974-08-12 Forfarande for ammoxidation eller oxidation av propen eller i-buten eller dehydrogenering av olefiner innehallande 4-10 kolatomer vid en temperatur av 200Ÿc-600Ÿc i nervaro av en katalysator, samt katalysator herfor

Country Status (32)

Country Link
US (1) US3956181A (da)
JP (1) JPS5064191A (da)
AR (1) AR205351A1 (da)
BE (1) BE819533A (da)
BG (1) BG36494A3 (da)
BR (1) BR7407285D0 (da)
CA (1) CA1048481A (da)
CH (3) CH605477A5 (da)
CS (1) CS220305B2 (da)
DD (1) DD112906A5 (da)
DE (1) DE2440329C2 (da)
DK (1) DK146583C (da)
EG (1) EG11372A (da)
ES (1) ES429744A1 (da)
FI (1) FI62959C (da)
FR (1) FR2242146B1 (da)
GB (1) GB1473530A (da)
HU (2) HU181732B (da)
IE (1) IE39886B1 (da)
IL (1) IL45503A (da)
IN (1) IN143036B (da)
IT (1) IT1020135B (da)
MY (1) MY7800190A (da)
NL (1) NL186138C (da)
NO (1) NO141830C (da)
PH (1) PH12128A (da)
PL (1) PL108045B1 (da)
RO (1) RO66352A (da)
SE (1) SE403104B (da)
SU (1) SU588906A3 (da)
TR (1) TR18345A (da)
ZA (1) ZA745492B (da)

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US4444906A (en) * 1981-06-08 1984-04-24 The Standard Oil Company Method for the preparation of high activity phosphomolybdic acid based catalysts
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JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
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US4855275A (en) * 1988-02-18 1989-08-08 The Standard Oil Company Catalyst performance improvement via separate boron addition
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JP2013505997A (ja) * 2010-07-09 2013-02-21 住友化学株式会社 酸化オレフィンの製造方法
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JP6138161B2 (ja) 2012-01-30 2017-05-31 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se n−ブタンからのブタジエンおよび/またはブテン類の製造方法
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JP2015530394A (ja) 2012-09-20 2015-10-15 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se C4炭化水素流からの酸素の除去によるブタジエンの製造方法
WO2014086768A1 (de) 2012-12-06 2014-06-12 Basf Se Verfahren zur oxidativen dehydrierung von n-butenen zu butadien
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
WO2014111409A1 (de) 2013-01-15 2014-07-24 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
EP2945921B1 (de) 2013-01-16 2017-03-22 Basf Se Verfahren zur herstellung von butadien durch oxidative dehydrierung von n-butenen mit überwachung des peroxid-gehalts bei der produktaufarbeitung
JP2016526565A (ja) 2013-07-10 2016-09-05 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se n−ブテンをブタジエンへと酸化脱水素化する方法
CN105683136B (zh) 2013-10-30 2018-06-01 巴斯夫欧洲公司 由正丁烯通过氧化脱氢制备1,3-丁二烯的方法
EP3094611A1 (de) 2014-01-13 2016-11-23 Basf Se Verfahren zum anfahren eines reaktors zur oxidativen dehydrierung von n-butenen
DE102014203725A1 (de) 2014-02-28 2015-09-03 Basf Se Oxidationskatalysator mit sattelförmigem Trägerformkörper
JP2017524011A (ja) 2014-08-12 2017-08-24 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 酸化的脱水素反応によりn−ブテン類から1,3−ブタジエンを製造するための方法
JP6608916B2 (ja) 2014-09-26 2019-11-20 ビーエーエスエフ ソシエタス・ヨーロピア 酸化的脱水素化によりn−ブテン類から1,3−ブタジエンを製造するための方法
WO2016071268A1 (en) 2014-11-03 2016-05-12 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
KR20170084076A (ko) 2014-11-14 2017-07-19 바스프 에스이 부탄 및 2-부텐을 포함하는 스트림의 제공 하에 n-부텐의 탈수소화에 의한 1,3-부타디엔의 제조 방법
EA201792147A1 (ru) 2015-03-26 2018-05-31 Басф Се Способ получения 1,3-бутадиена из н-бутенов путем окислительного дегидрирования
WO2016150940A1 (de) 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
WO2016151074A1 (de) 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
CN107667084A (zh) 2015-03-26 2018-02-06 巴斯夫欧洲公司 由正丁烯通过氧化脱氢生产1,3‑丁二烯
US20180354872A1 (en) 2015-12-03 2018-12-13 Basf Se Method for producing butadiene by oxidatively dehydrogenating n-butenes
EP3402769B1 (de) 2016-01-13 2020-03-25 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
CN108884003A (zh) 2016-02-04 2018-11-23 巴斯夫欧洲公司 通过氧化脱氢由n-丁烯制备1,3-丁二烯的方法
CN109843836A (zh) 2016-08-09 2019-06-04 巴斯夫欧洲公司 启动用于正丁烯的氧化脱氢的反应器的方法
WO2018095856A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung
WO2018095840A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine furan-abtrennung bei der aufarbeitung
WO2018095776A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms
EP3323797A1 (de) 2016-11-22 2018-05-23 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine saure wäsche des c4-produktgasstroms
WO2018219996A1 (de) 2017-06-02 2018-12-06 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung in kreisgasfahrweise mit co2-angereichertem kreisgas
WO2018234158A1 (de) 2017-06-19 2018-12-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms

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Also Published As

Publication number Publication date
BE819533A (fr) 1975-03-04
FI257074A (da) 1975-03-05
BR7407285D0 (pt) 1975-07-01
CH603514A5 (da) 1978-08-15
NO743150L (da) 1975-04-01
RO66352A (fr) 1979-07-15
CS220305B2 (en) 1983-03-25
CH605477A5 (da) 1978-09-29
IN143036B (da) 1977-09-24
IL45503A (en) 1977-06-30
NL186138B (nl) 1990-05-01
FI62959C (fi) 1983-04-11
EG11372A (en) 1977-08-15
AR205351A1 (es) 1976-04-30
MY7800190A (en) 1978-12-31
ES429744A1 (es) 1977-06-16
IE39886B1 (en) 1979-01-17
NO141830C (no) 1980-05-21
DK146583C (da) 1984-04-30
JPS5064191A (da) 1975-05-31
ZA745492B (en) 1975-09-24
IE39886L (en) 1975-03-04
IL45503A0 (en) 1974-11-29
FR2242146B1 (da) 1980-10-24
NO141830B (no) 1980-02-11
FR2242146A1 (da) 1975-03-28
NL7411580A (nl) 1975-03-06
CA1048481A (en) 1979-02-13
DK146583B (da) 1983-11-14
IT1020135B (it) 1977-12-20
AU7283974A (en) 1976-03-04
DE2440329C2 (de) 1982-10-21
TR18345A (tr) 1977-01-12
HU181732B (en) 1983-11-28
HU181951B (en) 1983-11-28
DD112906A5 (da) 1975-05-12
GB1473530A (en) 1977-05-11
DE2440329A1 (de) 1975-03-13
SU588906A3 (ru) 1978-01-15
FI62959B (fi) 1982-12-31
SE7410289L (da) 1975-03-05
BG36494A3 (en) 1984-11-15
DK465074A (da) 1975-05-05
US3956181A (en) 1976-05-11
CH600946A5 (da) 1978-06-30
PH12128A (en) 1978-11-07
NL186138C (nl) 1990-10-01
PL108045B1 (pl) 1980-03-31

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