US3678124A - Process for the production of mono- and diolefin hydrocarbons - Google Patents
Process for the production of mono- and diolefin hydrocarbons Download PDFInfo
- Publication number
- US3678124A US3678124A US770409A US3678124DA US3678124A US 3678124 A US3678124 A US 3678124A US 770409 A US770409 A US 770409A US 3678124D A US3678124D A US 3678124DA US 3678124 A US3678124 A US 3678124A
- Authority
- US
- United States
- Prior art keywords
- percent
- butane
- hydrocarbons
- molybdenum
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
Abstract
A process for the production of mono- and diolefin hydrocarbons by the catalytic oxidative dehydrogenation of paraffin hydrocarbons at 400*-700*C in the presence of catalysts comprising mixed oxide systems and consisting of oxides of molybdenum and/or tungsten and oxides of at least one of the following metals: chromium, manganese, iron, nickel and cadmium.
Description
United States Patent Stepanov et a].
[4 1 July 18,1972
[54] PROCESS FOR THE PRODUCTION OF MONO- AND DIOLEFIN HYDROCARBONS [72] Inventors: Gennady Arkadievich Stepanov, ulitsa Pervomaiskaya, 9, kv. 3; Anatoly Lvovich Tsaillngold, Schitovoi poselok, 4-a sektsia, 3, kv. 20; Fedor Semenovich Pilipenko, Volzhskaya naberezhnaya, 25/2, kv. 7, all of Yaroslavl; Valerian Mikhailovich Sobolev, Naberezhnaya M. Gorkogo, 25/2, kv. 7, Moscow; Georgy Konstantinovich Boreskov, ulitsa Zolotodolinskaya, 85, Novosibirsk; Roman Alexeevich Buyanov, ulitsa Zhemchuzhnaya, 8, kv. 27, Novosibirsk; Sergei Alexeevich Venyaminov, ulitsa Zhemchuzhnaya, 4, kv. 15, Novosibirsk, all of U.S.S.R.
22 Filed: on. 24, 1968 21 Appl.No.: 770,409
[52] U.S. Cl ..260/680 E, 252/457, 252/458,
Callahan et al. Callahan et a1.
Primary Examiner-Delbert E. Gantz Assistant Examiner-G. E. Schmitkons Attorney-Waters, Roditi, Schwartz & Nissen [5 7] ABSTRACT A process for the production of monoand diolefin hydrocar bons by the catalytic oxidative dehydrogenation of paraffin hydrocarbons at 400700C in the presence of catalysts comprising mixed oxide systems and consisting of oxides of molybdenum and/or tungsten and oxides of at least one of the following metals: chromium, manganese, iron, nickel and cadmiurn.
6 Claims, No Drawings This invention relates to processes for the production of monoand diolefin hydrocarbons. Said hydrocarbons are used for synthesizing various organic compounds but mainly for the production of synthetic rubbers.
Now it is known to produce monoand diolefin hydrocarbons by the catalytic oxidative dehydrogenation of paraffin hydrocarbons at a temperature of 400700C.
Thus, a process is known for the production of n-butenes and butadiene by the oxidative dehydrogenation of n-butane at a temperature of 550-700C in the presence of a calciumnickel-phosphate catalyst (cf. French Pat. No. 1,319,181). The overall yield of final products on the basis of the initial nbutane is 17.7 wt. percent, the overall selectivity being 35.9 wt. percent.
A process is likewise known for the production of n-butenes and butadiene by the oxidative dehydrogenation of n-butane at a temperature of 400650C inthe presence of a sodium phosphomolybdate or lithium molybdate catalyst (cf. U.S. Pat. No. 3,1 19,1 1 l The yield of n-butenes is 4.8 wt. percent, and the yield of butadiene, 17.2 wt. percent on the basis of the initial n-butane, the selectivity being 11.3 and 41 wt. percent respectively.
Deficiencies of the known processes are the low yield of final products as well as the necessity of periodically regenerating the catalysts.
It is an object of the present invention to eliminate the above deficiencies.
It is a further and more specific object of the invention to provide a process for the production of monoand diolefin hydrocarbons making it possible to increase the yield of final products and also to carry out the reaction continuously without regenerating the catalysts.
The foregoing and other objects have been accomplished by the provision of aprocess for the production of monoand diolefin hydrocarbons wherein the catalytic dehydrogenation of paraffin hydrocarbons atatemperature of 400 700C is carried out in the presence of catalysts which are mixed oxide systems consisting of oxides of molybdenum and/or tungsten and of oxides of at least one of the following metals: chromium, manganese, iron, nickel and cadmium.
It is preferable to use as catalyst a mixed oxide system consisting of oxides of molybdenum and nickel with an atomic ratio of molybdenum to nickel of 1:0.23 to 1:25.
To increase the mechanical strength of catalysts and enable carrying out the reaction over moving-bed catalysts, said catalysts are preferably employed on carriers of aluminosilicates, silica gel, alumina or mixtures of the same.
To lower the partial pressure of hydrocarbons, improve heat rejection conditions and increase selectivity, the process is preferably carried out in the presence of an inert diluent such as steam, nitrogen, argon, helium or mixtures of the same.
The inert diluent is preferably taken in a molar ratio of diluent to paraffin hydrocarbons of 1:1 to 40:1.
In the present process the oxidative dehydrogenation of paraffin hydrocarbons is carried out in a wide temperature range (400-700C with a molar ratio of oxygen to initial hydrocarbons of 0.1:1 to 3:1 and space velocity of paraffin hydrocarbons of 20-1 ,000 hr".
A preferred embodiment of the invention contemplates the following conditions in carrying out the process: temperature 400650C, molar ratio of oxygen to initial hydrocarbons of 0.1:1-2:1, space velocity of paraffin hydrocarbons of -400 hr.
The catalysts employed in the present process may be prepared by any of the known methods, e.g. by precipitation or evaporation of a mixture of the corresponding solutions of salts with subsequent heat treatment of the precipitate formed. The proportions of the active components in the catalysts may vary over wide ranges.
The monoolefin hydrocarbons produced as final products can be recycled in order to convert them into diolefin hydrocarbons in the conditions of the process.
For a better understanding of the present invention the following Examples of its concrete embodiment are given by way of illustration.
EXAMPLE 1 The oxidative dehydrogenation of n-butane was carried out in a reactor with a stationary bed of nickel-molybdenum catalyst which was prepared as follows.
A solution of 28.5 g of (NH,) Mo,O,,-4l-1,0 in 70 ml of water was mixed with a solution of 94.4 g of Ni(NO in 1,100 ml of water, whereupon a grey-green precipitate formed. The mixture was evaporated at C until a pasty light green mass was left. After drying at 120C this was ignited in a stream of air at 400500C for 4 hr and pelleted.
The atomic ratio of molybdenum to nickel in the finished catalyst was 1:2.
Oxidative dehydrogenation was carried out at a temperature of 590C, a molar ratio of n-butane to oxygen to steam of 1:025:10 and space velocity of n-butane of 100 hr. The charge of catalyst was 15 cm The yield of n-butenes on the basis of the n-butane passed was 4.5 wt. percent and that of butadiene, 21.6 wt. percent, the selectivity being 1 1.2 and 53.6 wt. percent, respectively.
EXAMPLE 2 The oxidative dehydrogenation of n-butane was carried out in a reactor with a stationary bed of nickel-molybdenum catalyst which was prepared as follows.
198 g of Ni(NO was dissolved in 300 ml of distilled water. Simultaneously 60 g of (NH Mo,O 4H O was dissolved in 300 ml of boiling distilled water, after which 56.5 ml of 25 percent ammonium hydroxide was added to the cooled solution of ammonium paramolybdate.
The solutions were then poured together with vigorous stirring, the pH during precipitation being 7.8, after which the mixture was stirred for another 2 hr. The precipitate which formed was filtered out, washed with water, press-filtered and dried for 8 hr at C, ground and ignited for 4-5 hr at 400-500C in a stream of air.
The atomic ratio of molybdenum to nickel in the finished catalyst was 1:0.68.
The process was carried out at a temperature of 597C, a molar ratio of n-butane to air and argon of 1:7.2120 and space velocity of n-butane of 100 hr". The charge of catalyst was 15 cm.
The yield of n-butenes on the basis of the n-butane passed was 4.8 wt. percent and that of butadiene, 12 wt. percent, the selectivity being 19.4 and 45.3 wt. percent, respectively.
EXAMPLE 3 The oxidative dehydrogenation of n-butane was carried out in a reactor with a stationary bed of nickel-molybdenum catalyst which was prepared as follows.
28.9 g of Ni(NO was dissolved in 10 ml of distilled water with heating, Simultaneously 8.77 g of (NH,) Mo,O -4l-l O was dissolved in 15 ml of a 30 percent hydrogen peroxide solution (water can also be used as solvent). The two solutions were combined and a carrier (silica gel) was impregnated with the mixture for 2 hr in the air at room temperature. The unabsorbed solution was decanted and the catalyst dried in the air for 24 hr and then at 1 10120C for 6-8 hr, after which it was ignited in a stream of airat 400-500C for 4 hr. The content of active mass in the catalyst was 15 wt. percent, The atomic ratio of molybdenum to nickel in the finished catalyst was 1:4.5.
The process was carried out at a temperature of 610C, molar ratio of n-butane to oxygen and steam of 1:2:20, and space velocity of n-butane of 25 hr". The charge of catalyst was 15 cm.
The yield of n-butenes on the basis of the n-butane passed was 4.7 wt. percent, and that of butadiene, 10.5 wt. percent, the selectivity being 13 and 29 wt. percent, respectively.
EXAMPLE 4 The oxidative dehydrogenation of n-butane was carried out in a reactor with a stationary bed of nickel-tungsten-molybdenum catalyst which was prepared in a way similar to that under which the process was canted out and the results are given in the table.
While the present invention has been described in a preferred embodiment it will be understood that there may be described in example 1. The atomic ratio of nickel to tungsten 5 changes and variations without departing from the spirit and and molybdenum in the finished catalyst was 220.1109. scope thereof, as those skilled in the art will be able to per- The process was carried out at 580C, the molar ratio of nceive. These changes and variations are to be considered as butane to oxygen and steam being 120.2511, and the space falling within the spirit and scope of the invention as defined in velocity of n-butane, 100 hr. the appended claims.
Catalyst Experimental conditions Results Yield 01 Yield 01' Molar n-butenes Seleetivbutadiene Selectiv- Atomic Space ratio, on basis 01 ity to 011 basis 01 ity to ratio of Temperavelocity n-butane n-butane 11-bute11es, n-butane butadiene, metals in ture, of n-bu to oxygen fed, mol mol fed, mol mol Type catalyst C. tane,hr.- and steam percent percent percent percent 2:1 013 200 2.64 6.68 1.71 4.3 2:1 621 200 4. 04 21. 2 0.118 2. a 2:1 558 200 0. 53 11.21 0.53 11. s 2:1 550 300 1.41 11.4 1.1111 15.0 Ni-W 2:1 550 300 1. 7 16.9 2. s 27.1
The yield of n-butenes on the basis of the n-butane passed What is claimed is: was 4.7 wt. percent, and that of butadiene, 13.5 wt. percent, l. A process for the production of monoand d1olefin the selectivity being 21.8 and 62.7 wt. percent, respectively. hydrocarbons which comprises subjecting paraffin hydrocarbons to oxidative dehydrogenation at 400-700C in the EXAMPLE 5 presence of catalysts comprising mixed oxide systems consisting of oxides of at least one metal selected from the group con- The oxidative dehydrogenation of n-butan w i d out sisting of molybdenum and tungstenand oxides of at least one in a reactor with a stationary bed of molybdenum-cadmiummetal silectedfrom the g (101151511118 f nickel catalyst which was prepared by a method similar to that gancse, mckel and cadmlum and w comwnallofl described in example 1. The atomic ratio of molybdenum to molybdenum P "lckel awmlc of NI/Mo cadmium and nickel in the finished catalyst was l:0.l:2. between 211 and v The process was carried out at 50 the molar ratio f 2. A process as clalmed 1n cla1m l, whereln the catalysts are butane to air and steam being 128.4:20, and the space velocity w q P" a l' selected'fl'om fl p conslsung of of butane, 200 -1 The charge of catalyst was 15 3 a|um1nos1l1cates,s1l1ca gel, alumma and m1xtures ofthe same.
The yield of n-butenes was 5.7 wt. percent, on the basis of A P a clawed m filalm L wherem oxldfmvc the n-butane passed, and that of butadiene, 15.1 wt. percent, dfihydmgenauon earned out m Presence of men the selectivity being 12.6 and 33.4 wt. percent, respectively. 40 dlluem selected the group conslstmg of steam argon, helium and m1xtures ofthe same.
EXAMPLE 6 4. A process as claimed in claim 2, wherein oxidative dehydrogenation is carried out in the presence of an inert The oxidative dehydrogenation of n-butane was carried out d'luem selected the group conslstmg of swam argon, helium and m1xtures of the same.
in reactors with a stationary bed of chromium-molybdenum, manganese-molybdenum, iron-molybdenum, cadmiummolybdenum and nickel-tungsten catalysts. The catalysts were prepared by methods similar to those described in examples 1,
2 and 3. The charge of catalyst was 15 cm. The conditions 5. A process as claimed in claim 3, wherein the molar ratio ofinert diluent to paraffin hydrocarbons is 1:1 -40: 1.
6. A process as claimed in claim 4, wherein the molar ratio of inert diluent to paraffin h ydaoca rbops is 1:1 40: l.
Claims (5)
- 2. A process as claimed in claim 1, wherein the catalysts are employed on a carrier selected from the group consisting of aluminosilicates, silica gel, alumina and mixtures of the same.
- 3. A process as claimed in claim 1, wherein oxidative dehydrogenation is carried out in the presence of an inert diluent selected from the group consisting of steam, nitrogen, argon, helium and mixtures of the same.
- 4. A process as claimed in claim 2, wherein oxidative dehydrogenation is carried out in the presence of an inert diluent selected from the group consisting of steam, nitrogen, argon, helium and mixtures of the same.
- 5. A process as claimed in claim 3, wherein the molar ratio of inert diluent to paraffin hydrocarbons is 1:1 - 40:1.
- 6. A process as claimed in claim 4, wherein the molar ratio of inert diluent to paraffin hydrocarbons is 1:1 - 40:1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77040968A | 1968-10-24 | 1968-10-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3678124A true US3678124A (en) | 1972-07-18 |
Family
ID=25088454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US770409A Expired - Lifetime US3678124A (en) | 1968-10-24 | 1968-10-24 | Process for the production of mono- and diolefin hydrocarbons |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3678124A (en) |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3862256A (en) * | 1972-08-07 | 1975-01-21 | Anatoly Lvovich Isailingold | Method for preparing mono- and di-olefine hydrocarbons |
| US3956181A (en) * | 1973-09-04 | 1976-05-11 | The Standard Oil Company (Ohio) | Oxidation catalyst |
| US3972954A (en) * | 1972-02-14 | 1976-08-03 | Phillips Petroleum Company | Process for oxidative dehydrogenation |
| US4250346A (en) * | 1980-04-14 | 1981-02-10 | Union Carbide Corporation | Low temperature oxydehydrogenation of ethane to ethylene |
| WO1999003578A1 (en) * | 1997-07-15 | 1999-01-28 | Exxon Research And Engineering Company | Nickel molybdotungstate hydrotreating catalysts |
| WO2000041810A1 (en) * | 1999-01-15 | 2000-07-20 | Akzo Nobel N.V. | A mixed metal catalyst composition, its preparation and use |
| WO2000048971A1 (en) * | 1999-02-22 | 2000-08-24 | Symyx Technologies, Inc. | Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes |
| US6162350A (en) * | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
| US6278030B1 (en) | 1997-07-15 | 2001-08-21 | Exxon Chemical Patents, Inc. | Process for preparing alcohols by the Oxo process |
| WO2002004117A1 (en) * | 2000-07-12 | 2002-01-17 | Akzo Nobel N.V. | Process for preparing an additive-based mixed metal catalyst |
| US6355854B1 (en) | 1999-02-22 | 2002-03-12 | Symyx Technologies, Inc. | Processes for oxidative dehydrogenation |
| US6436871B1 (en) | 1999-02-22 | 2002-08-20 | Symyx Technologies, Inc. | Catalysts for oxidative dehydrogenation |
| US6534437B2 (en) | 1999-01-15 | 2003-03-18 | Akzo Nobel N.V. | Process for preparing a mixed metal catalyst composition |
| US6566296B2 (en) | 2000-07-12 | 2003-05-20 | Akzo Nobel N.V. | Process for preparing an additive-based mixed metal catalyst, its composition and use |
| US6635599B1 (en) | 1997-07-15 | 2003-10-21 | Exxonmobil Research & Engineering Company | Mixed metal catalyst, its preparation by co-precipitation, and its use |
| US6677497B2 (en) | 2001-03-22 | 2004-01-13 | Symyx Technologies, Inc. | Ni catalysts and methods for alkane dehydrogenation |
| US20050040080A1 (en) * | 1997-07-15 | 2005-02-24 | Riley Kenneth L. | Process for upgrading naphtha |
| US20050113247A1 (en) * | 2003-11-21 | 2005-05-26 | Conocophillips Company | Copper modified catalysts for oxidative dehydrogenation |
| US6989348B2 (en) | 2000-07-12 | 2006-01-24 | Albemarle Corporation | Mixed metal catalyst comprising a combustible binder, its process of preparation and use |
| US7232515B1 (en) | 1997-07-15 | 2007-06-19 | Exxonmobil Research And Engineering Company | Hydrofining process using bulk group VIII/Group VIB catalysts |
| US7288182B1 (en) | 1997-07-15 | 2007-10-30 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts |
| US7513989B1 (en) | 1997-07-15 | 2009-04-07 | Exxonmobil Research And Engineering Company | Hydrocracking process using bulk group VIII/Group VIB catalysts |
| EP2103347A1 (en) | 2008-03-17 | 2009-09-23 | ExxonMobil Research and Engineering Company | Hydrocarbon hydroprocessing using bulk catalyst composition |
| WO2017106117A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Crystalline transition metal oxy-hydroxide molybdate |
| WO2017106133A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Crystalline transition metal oxy-hydroxide molybdotungstate |
| WO2017106137A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Crystalline bis-ammonia metal molybdate |
| US9708548B2 (en) | 2007-12-04 | 2017-07-18 | Exxonmobil Research And Engineering Company | Hydrocarbon hydroprocessing using bulk catalyst composition |
| EP3944893A1 (en) | 2020-07-27 | 2022-02-02 | Uop Llc | High activity and high distillate yield hydrocracking catalysts with intimate interaction between unsupported metal oxide and zeolite |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2486361A (en) * | 1944-10-20 | 1949-10-25 | Union Oil Co | Catalytic conversion of hydrocarbons |
| US3159688A (en) * | 1961-03-22 | 1964-12-01 | Shell Oil Co | Catalytic oxidative dehydrogenation of monoolefins |
| US3370103A (en) * | 1962-11-28 | 1968-02-20 | Standard Oil Co | Process for preparing diolefins |
| US3375291A (en) * | 1964-03-31 | 1968-03-26 | Standard Oil Co | Process for preparing diolefins |
| US3577477A (en) * | 1968-01-10 | 1971-05-04 | Inst Francais Du Petrole | Process for converting saturated hydrocarbons to unsaturated hydrocarbons by oxidation |
-
1968
- 1968-10-24 US US770409A patent/US3678124A/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2486361A (en) * | 1944-10-20 | 1949-10-25 | Union Oil Co | Catalytic conversion of hydrocarbons |
| US3159688A (en) * | 1961-03-22 | 1964-12-01 | Shell Oil Co | Catalytic oxidative dehydrogenation of monoolefins |
| US3370103A (en) * | 1962-11-28 | 1968-02-20 | Standard Oil Co | Process for preparing diolefins |
| US3375291A (en) * | 1964-03-31 | 1968-03-26 | Standard Oil Co | Process for preparing diolefins |
| US3577477A (en) * | 1968-01-10 | 1971-05-04 | Inst Francais Du Petrole | Process for converting saturated hydrocarbons to unsaturated hydrocarbons by oxidation |
Cited By (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3972954A (en) * | 1972-02-14 | 1976-08-03 | Phillips Petroleum Company | Process for oxidative dehydrogenation |
| US3862256A (en) * | 1972-08-07 | 1975-01-21 | Anatoly Lvovich Isailingold | Method for preparing mono- and di-olefine hydrocarbons |
| US3956181A (en) * | 1973-09-04 | 1976-05-11 | The Standard Oil Company (Ohio) | Oxidation catalyst |
| US4250346A (en) * | 1980-04-14 | 1981-02-10 | Union Carbide Corporation | Low temperature oxydehydrogenation of ethane to ethylene |
| US6162350A (en) * | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
| US7513989B1 (en) | 1997-07-15 | 2009-04-07 | Exxonmobil Research And Engineering Company | Hydrocracking process using bulk group VIII/Group VIB catalysts |
| US6156695A (en) * | 1997-07-15 | 2000-12-05 | Exxon Research And Engineering Company | Nickel molybdotungstate hydrotreating catalysts |
| US6635599B1 (en) | 1997-07-15 | 2003-10-21 | Exxonmobil Research & Engineering Company | Mixed metal catalyst, its preparation by co-precipitation, and its use |
| US6278030B1 (en) | 1997-07-15 | 2001-08-21 | Exxon Chemical Patents, Inc. | Process for preparing alcohols by the Oxo process |
| US7288182B1 (en) | 1997-07-15 | 2007-10-30 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts |
| WO1999003578A1 (en) * | 1997-07-15 | 1999-01-28 | Exxon Research And Engineering Company | Nickel molybdotungstate hydrotreating catalysts |
| US7232515B1 (en) | 1997-07-15 | 2007-06-19 | Exxonmobil Research And Engineering Company | Hydrofining process using bulk group VIII/Group VIB catalysts |
| US7229548B2 (en) | 1997-07-15 | 2007-06-12 | Exxonmobil Research And Engineering Company | Process for upgrading naphtha |
| US20050040080A1 (en) * | 1997-07-15 | 2005-02-24 | Riley Kenneth L. | Process for upgrading naphtha |
| WO2000041810A1 (en) * | 1999-01-15 | 2000-07-20 | Akzo Nobel N.V. | A mixed metal catalyst composition, its preparation and use |
| US6534437B2 (en) | 1999-01-15 | 2003-03-18 | Akzo Nobel N.V. | Process for preparing a mixed metal catalyst composition |
| US6652738B2 (en) | 1999-01-15 | 2003-11-25 | Akzo Nobel N.V. | Process for preparing a mixed metal catalyst composition |
| US6355854B1 (en) | 1999-02-22 | 2002-03-12 | Symyx Technologies, Inc. | Processes for oxidative dehydrogenation |
| US20070191665A1 (en) * | 1999-02-22 | 2007-08-16 | Yumin Liu | Ni catalysts and methods for alkane dehydrogenation |
| US7674944B2 (en) | 1999-02-22 | 2010-03-09 | Celanese International Corporation | Ni catalysts and methods for alkane dehydrogenation |
| US6777371B2 (en) | 1999-02-22 | 2004-08-17 | Yumin Liu | Ni catalysts and methods for alkane dehydrogenation |
| US7626068B2 (en) | 1999-02-22 | 2009-12-01 | Celanese International Corporation | Ni catalysts and methods for alkane dehydrogenation |
| WO2000048971A1 (en) * | 1999-02-22 | 2000-08-24 | Symyx Technologies, Inc. | Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes |
| US6891075B2 (en) | 1999-02-22 | 2005-05-10 | Symyx Technologies, Inc. | Processes for oxidative dehyrogenation |
| US7498289B2 (en) | 1999-02-22 | 2009-03-03 | Celanese International Corporation | Ni catalysts and methods for alkane dehydrogenation |
| US20070197378A1 (en) * | 1999-02-22 | 2007-08-23 | Yumin Liu | Ni catalysts and methods for alkane dehydrogenation |
| US20070197847A1 (en) * | 1999-02-22 | 2007-08-23 | Yumin Liu | Ni catalysts and methods for alkane dehydrogenation |
| US7227049B2 (en) | 1999-02-22 | 2007-06-05 | Celanese International Corporation | Ni catalysts and methods for alkane dehydrogenation |
| US6436871B1 (en) | 1999-02-22 | 2002-08-20 | Symyx Technologies, Inc. | Catalysts for oxidative dehydrogenation |
| US6417422B1 (en) | 1999-02-22 | 2002-07-09 | Symyx Technologies, Inc. | Ni catalysts and methods for alkane dehydrogenation |
| US6989348B2 (en) | 2000-07-12 | 2006-01-24 | Albemarle Corporation | Mixed metal catalyst comprising a combustible binder, its process of preparation and use |
| US20030178344A1 (en) * | 2000-07-12 | 2003-09-25 | Plantenga Frans Lodewijk | Process for the hydroprocessing of hydrocarbon feedstocks |
| WO2002004117A1 (en) * | 2000-07-12 | 2002-01-17 | Akzo Nobel N.V. | Process for preparing an additive-based mixed metal catalyst |
| US6860987B2 (en) | 2000-07-12 | 2005-03-01 | Akzo Nobel N.V. | Process for the hydroprocessing of hydrocarbon feedstocks |
| US6566296B2 (en) | 2000-07-12 | 2003-05-20 | Akzo Nobel N.V. | Process for preparing an additive-based mixed metal catalyst, its composition and use |
| US6677497B2 (en) | 2001-03-22 | 2004-01-13 | Symyx Technologies, Inc. | Ni catalysts and methods for alkane dehydrogenation |
| US20050113247A1 (en) * | 2003-11-21 | 2005-05-26 | Conocophillips Company | Copper modified catalysts for oxidative dehydrogenation |
| US7067455B2 (en) | 2003-11-21 | 2006-06-27 | Conocophillips Company | Copper modified catalysts for oxidative dehydrogenation |
| US9708548B2 (en) | 2007-12-04 | 2017-07-18 | Exxonmobil Research And Engineering Company | Hydrocarbon hydroprocessing using bulk catalyst composition |
| EP2103347A1 (en) | 2008-03-17 | 2009-09-23 | ExxonMobil Research and Engineering Company | Hydrocarbon hydroprocessing using bulk catalyst composition |
| WO2017106117A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Crystalline transition metal oxy-hydroxide molybdate |
| WO2017106137A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Crystalline bis-ammonia metal molybdate |
| WO2017106133A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Crystalline transition metal oxy-hydroxide molybdotungstate |
| RU2698819C1 (en) * | 2015-12-15 | 2019-08-30 | Юоп Ллк | Transition metal oxyhydroxide-molybdenungstate |
| RU2699794C1 (en) * | 2015-12-15 | 2019-09-11 | Юоп Ллк | Transition metal crystalline oxyhydroxide-molybdate |
| EP3944893A1 (en) | 2020-07-27 | 2022-02-02 | Uop Llc | High activity and high distillate yield hydrocracking catalysts with intimate interaction between unsupported metal oxide and zeolite |
| US11826738B2 (en) | 2020-07-27 | 2023-11-28 | Uop Llc | High activity and high distillate yield hydrocracking catalysts with intimate interaction between unsupported metal oxide and zeolite |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3678124A (en) | Process for the production of mono- and diolefin hydrocarbons | |
| US4425255A (en) | Regeneration method of catalysts | |
| US4423281A (en) | Process for producing conjugated diolefins | |
| US5086032A (en) | Catalyst for oxidative dehydrogenation of propane | |
| DE2631536C2 (en) | Process for the production of olefinic hydrocarbons | |
| US3810953A (en) | Dehydrogenation of organic compounds | |
| US3328478A (en) | Production of conjugated diolefines by oxidative dehydrogenation | |
| US3320331A (en) | Oxidative dehydrogenation of aliphatic hydrocarbons over aluminum phosphate supported molybdenum and vanadium | |
| US3784483A (en) | Cobalt,iron,phosphorus and oxygen containing oxidatice dehydrogenation catalyst | |
| US3752776A (en) | Multimetalite catalysts | |
| US3218368A (en) | Process for the preparation of unsaturated hydrocarbons | |
| US3992419A (en) | Method of preparing maleic anhydride and catalysts utilized therefor | |
| US5001291A (en) | Hydrocarbon dehydrogenation reactions | |
| US3907919A (en) | Dehydrogenation of hydrocarbons | |
| US4000176A (en) | Process for simultaneously producing methacrylo-nitrile and butadiene by vapor-phase catalytic oxidation of mixed butenes | |
| US3790501A (en) | Oxidative dehydrogenation catalyst | |
| US5254779A (en) | Process for oxidative dehydrogenation of propane | |
| US3792103A (en) | Processes for the dehydrogenation of organic feedstocks | |
| US3577477A (en) | Process for converting saturated hydrocarbons to unsaturated hydrocarbons by oxidation | |
| US3644549A (en) | Dehydrogenation of ethylbenzene to styrene using so2 and ferrite catalysis in the form of spinels or perovskites | |
| US2495700A (en) | Silica-alumina-nickel dehydrogenation catalyst | |
| US2397218A (en) | Conversion of hydrocarbons | |
| US3852369A (en) | Processes for dehydrogenation of hydrocarbons | |
| US3935126A (en) | Catalyst and method of oxydehydrogenation of alkyl aromatic compounds | |
| US3318966A (en) | Production of alkenyl benzenes |