RU96109188A - Способ карбонилирования алкиловых спиртов и/или их реакционноспособных производных - Google Patents
Способ карбонилирования алкиловых спиртов и/или их реакционноспособных производныхInfo
- Publication number
- RU96109188A RU96109188A RU96109188/04A RU96109188A RU96109188A RU 96109188 A RU96109188 A RU 96109188A RU 96109188/04 A RU96109188/04 A RU 96109188/04A RU 96109188 A RU96109188 A RU 96109188A RU 96109188 A RU96109188 A RU 96109188A
- Authority
- RU
- Russia
- Prior art keywords
- reaction mixture
- preceding paragraphs
- liquid reaction
- concentration
- alkyl
- Prior art date
Links
- 150000001298 alcohols Chemical class 0.000 title 1
- 239000007788 liquid Substances 0.000 claims 5
- 239000011541 reaction mixture Substances 0.000 claims 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 150000001350 alkyl halides Chemical class 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 3
- 229910052741 iridium Inorganic materials 0.000 claims 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N Methyl acetate Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims 2
- -1 alkyl aliphatic alcohol Chemical compound 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 238000005810 carbonylation reaction Methods 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N Methyl iodide Chemical group IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N Rhenium Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- 239000005092 Ruthenium Substances 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 claims 1
- 229910052762 osmium Inorganic materials 0.000 claims 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Claims (9)
1. Способ карбонилирования алкилалифатического спирта и/или его реакционноспособного производного, включающий введение в контакт в реакторе для карбонилирования спирта и/или его реакционноспособного производного с моноокисью углерода в жидкой реакционной смеси, содержащей: (а) иридиевый катализатор, (б) алкилгалогенид, (в) воду по меньшей мере в ограниченной концентрации и (г) промотор, выбранный из группы, состоящей из кадмия, ртути, цинка, галлия, индия и вольфрама.
2. Способ по п. 1, в котором молярное соотношение каждого промотора и иридиевого катализатора составляет (0,1-20): 1, предпочтительно (0,5-10):1.
3. Способ по п. 1 или 2, в котором в жидкой реакционной смеси содержится сопромотор, выбранный из рутения, осмия и рения.
4. Способ по п. 3, в котором молярное соотношение каждого сопромотора и иридиевого катализатора составляет (0,1-20) :1, предпочтительно (0,5-10):1.
5. Способ по любому из предыдущих пунктов, в котором концентрация воды в жидкой реакционной смеси составляет 1-15 вес.%, предпочтительно 1-10 вес.%.
6. Способ по любому из предыдущих пунктов, в котором в жидкой реакционной смеси содержится алкиловый эфир в концентрации в пределах 1-70 вес.%, предпочтительно 2-50 вес.%, более предпочтительно 3-35 вес.%.
7. Способ по любому из предыдущих пунктов, в котором концентрация алкилгалогенида в жидкой реакционной смеси составляет 1-20 вес.%, предпочтительно 2-16 вес.%.
8. Способ по любому из предыдущих пунктов, в котором парциальное давление моноокиси углерода в реакторе составляет 1-70 бар, предпочтительно 1-35 бар, более предпочтительно 1-15 бар.
9. Способ по любому из предыдущих пунктов, в котором алкилалифатический спирт представляет собой метанол, алкилгалогенидом является метилиодид, а продукт реакции включает уксусную кислоту и/или метилацетат.
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9512606.6A GB9512606D0 (en) | 1995-06-21 | 1995-06-21 | Process |
| GB9512606.6 | 1995-06-21 | ||
| GB9514745.0 | 1995-07-19 | ||
| GBGB9514745.0A GB9514745D0 (en) | 1995-07-19 | 1995-07-19 | Process |
| GB9520441.8 | 1995-10-06 | ||
| GBGB9520441.8A GB9520441D0 (en) | 1995-10-06 | 1995-10-06 | Process |
| GB9524037.0 | 1995-11-23 | ||
| GBGB9524037.0A GB9524037D0 (en) | 1995-11-23 | 1995-11-23 | Process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU96109188A true RU96109188A (ru) | 1998-08-20 |
| RU2167850C2 RU2167850C2 (ru) | 2001-05-27 |
Family
ID=27451298
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU96109707/04A RU2160248C2 (ru) | 1995-06-21 | 1996-05-13 | Способ получения уксусной кислоты путем карбонилирования |
| RU96109188/04A RU2167850C2 (ru) | 1995-06-21 | 1996-05-13 | Способ карбонилирования алкилалифатических спиртов и/или их реакционноспособных производных |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU96109707/04A RU2160248C2 (ru) | 1995-06-21 | 1996-05-13 | Способ получения уксусной кислоты путем карбонилирования |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5696284A (ru) |
| EP (2) | EP0749948B1 (ru) |
| JP (2) | JP3884504B2 (ru) |
| KR (2) | KR100404644B1 (ru) |
| CN (2) | CN1068576C (ru) |
| AR (2) | AR002559A1 (ru) |
| AT (2) | ATE212970T1 (ru) |
| CA (2) | CA2175028C (ru) |
| DE (2) | DE69609381T2 (ru) |
| MX (2) | MX9602082A (ru) |
| MY (2) | MY113453A (ru) |
| NO (2) | NO961723L (ru) |
| NZ (2) | NZ286473A (ru) |
| RU (2) | RU2160248C2 (ru) |
| TW (2) | TW396150B (ru) |
| UA (2) | UA50713C2 (ru) |
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| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| KR102438920B1 (ko) | 2015-10-02 | 2022-08-31 | 셀라니즈 인터내셔날 코포레이션 | 물의 재순환과 함께 아세트산을 생산하는 방법 |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| US10457622B2 (en) | 2017-03-08 | 2019-10-29 | Daicel Corporation | Method for producing acetic acid |
| BR112019017819A2 (pt) * | 2017-03-08 | 2020-03-31 | Daicel Corporation | Método para produzir ácido acético |
| JP6588657B1 (ja) | 2018-05-02 | 2019-10-09 | 株式会社ダイセル | 酢酸の製造方法 |
| CN115916735A (zh) | 2020-06-03 | 2023-04-04 | 国际人造丝公司 | 乙酸的生产和纯化 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE364254B (ru) * | 1967-04-05 | 1974-02-18 | Monsanto Co | |
| DE1941449C3 (de) * | 1968-08-15 | 1979-07-26 | Monsanto Co., St. Louis, Mo. (V.St.A.) | Verfahren zur Herstellung von Monocarbonsäuren |
| US3772380A (en) * | 1970-03-12 | 1973-11-13 | Monsanto Co | Production of carboxylic acids and esters |
| FR2317269A1 (fr) * | 1975-07-10 | 1977-02-04 | Metaux Precieux Cie | Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium |
| US4096164A (en) * | 1976-08-30 | 1978-06-20 | Union Carbide Corporation | Process for producing ethanol, acetic acid and/or acetaldehyde, from synthesis gas |
| US4358411A (en) * | 1979-06-29 | 1982-11-09 | The Halcon Sd Group, Inc. | Preparation of carbonylation products |
| DE3064657D1 (en) * | 1979-12-21 | 1983-09-29 | Shell Int Research | Process for the co-production of carboxylic acids and carboxylic acid esters |
| JPS6054334A (ja) * | 1983-09-02 | 1985-03-28 | Daicel Chem Ind Ltd | カルボン酸の製造法 |
| CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
| GB9306409D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process |
| US5672743A (en) * | 1993-09-10 | 1997-09-30 | Bp Chemicals Limited | Process for the production of acetic acid |
| FR2703351A1 (fr) * | 1993-03-31 | 1994-10-07 | Rhone Poulenc Chimie | Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium. |
| BR9401362A (pt) * | 1993-03-31 | 1994-11-01 | Rhone Poulenc Chimie | Processo de preparação de ácidos carboxílicos, ou dos ésteres correspondentes |
| FR2725443B1 (fr) * | 1994-10-05 | 1996-12-20 | Rhone Poulenc Chimie | Preparation d'acides carboxyliques ou des esters correspondants par carbonylation en presence d'iridium |
| US5510524A (en) * | 1995-02-21 | 1996-04-23 | Bp Chemicals Limited | Process for the production of a carboxylic acid |
-
1996
- 1996-02-05 US US08/596,488 patent/US5696284A/en not_active Expired - Lifetime
- 1996-04-18 DE DE69609381T patent/DE69609381T2/de not_active Expired - Lifetime
- 1996-04-18 EP EP96302733A patent/EP0749948B1/en not_active Expired - Lifetime
- 1996-04-18 EP EP96302734A patent/EP0752406B1/en not_active Expired - Lifetime
- 1996-04-18 AT AT96302734T patent/ATE212970T1/de not_active IP Right Cessation
- 1996-04-18 AT AT96302733T patent/ATE194825T1/de not_active IP Right Cessation
- 1996-04-18 DE DE69619030T patent/DE69619030T2/de not_active Expired - Lifetime
- 1996-04-24 MY MYPI96001568A patent/MY113453A/en unknown
- 1996-04-24 MY MYPI96001567A patent/MY115799A/en unknown
- 1996-04-25 CA CA002175028A patent/CA2175028C/en not_active Expired - Fee Related
- 1996-04-25 CA CA002175031A patent/CA2175031C/en not_active Expired - Fee Related
- 1996-04-29 NO NO961723A patent/NO961723L/no not_active Application Discontinuation
- 1996-04-29 TW TW085105092A patent/TW396150B/zh not_active IP Right Cessation
- 1996-04-29 TW TW085105091A patent/TW338763B/zh not_active IP Right Cessation
- 1996-04-29 NO NO961722A patent/NO961722L/no not_active Application Discontinuation
- 1996-04-30 NZ NZ286473A patent/NZ286473A/en unknown
- 1996-04-30 NZ NZ286474A patent/NZ286474A/en unknown
- 1996-05-13 RU RU96109707/04A patent/RU2160248C2/ru not_active IP Right Cessation
- 1996-05-13 RU RU96109188/04A patent/RU2167850C2/ru not_active IP Right Cessation
- 1996-05-17 KR KR1019960016758A patent/KR100404644B1/ko not_active IP Right Cessation
- 1996-05-17 KR KR1019960016759A patent/KR970001296A/ko not_active Application Discontinuation
- 1996-05-21 CN CN96108432A patent/CN1068576C/zh not_active Expired - Fee Related
- 1996-05-21 CN CN96110366A patent/CN1106377C/zh not_active Expired - Fee Related
- 1996-05-31 MX MX9602082A patent/MX9602082A/es unknown
- 1996-05-31 MX MX9602083A patent/MX9602083A/es unknown
- 1996-06-04 JP JP14204696A patent/JP3884504B2/ja not_active Expired - Fee Related
- 1996-06-04 JP JP8142047A patent/JPH092993A/ja active Pending
- 1996-06-20 UA UA96062441A patent/UA50713C2/ru unknown
- 1996-06-20 UA UA96062442A patent/UA46724C2/uk unknown
- 1996-06-21 AR ARP960103264A patent/AR002559A1/es unknown
- 1996-06-21 AR ARP960103265A patent/AR002560A1/es unknown
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