DE69619030T2 - Verfahren zur Herstellung von Essigsäure durch Carbonylierung - Google Patents

Verfahren zur Herstellung von Essigsäure durch Carbonylierung

Info

Publication number
DE69619030T2
DE69619030T2 DE69619030T DE69619030T DE69619030T2 DE 69619030 T2 DE69619030 T2 DE 69619030T2 DE 69619030 T DE69619030 T DE 69619030T DE 69619030 T DE69619030 T DE 69619030T DE 69619030 T2 DE69619030 T2 DE 69619030T2
Authority
DE
Germany
Prior art keywords
carbonylation
production
acetic acid
acetic
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69619030T
Other languages
English (en)
Other versions
DE69619030D1 (de
Inventor
Michael James Baker
Martin Francis Giles
Carl Sherman Garland
Michael James Muskett
Georgios Rafeletos
James Smith
Glenn Sunley
John Watt
Bruce Leo Williams
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9512606.6A external-priority patent/GB9512606D0/en
Priority claimed from GBGB9514745.0A external-priority patent/GB9514745D0/en
Priority claimed from GBGB9520441.8A external-priority patent/GB9520441D0/en
Priority claimed from GBGB9524037.0A external-priority patent/GB9524037D0/en
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of DE69619030D1 publication Critical patent/DE69619030D1/de
Publication of DE69619030T2 publication Critical patent/DE69619030T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
DE69619030T 1995-06-21 1996-04-18 Verfahren zur Herstellung von Essigsäure durch Carbonylierung Expired - Lifetime DE69619030T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB9512606.6A GB9512606D0 (en) 1995-06-21 1995-06-21 Process
GBGB9514745.0A GB9514745D0 (en) 1995-07-19 1995-07-19 Process
GBGB9520441.8A GB9520441D0 (en) 1995-10-06 1995-10-06 Process
GBGB9524037.0A GB9524037D0 (en) 1995-11-23 1995-11-23 Process

Publications (2)

Publication Number Publication Date
DE69619030D1 DE69619030D1 (de) 2002-03-21
DE69619030T2 true DE69619030T2 (de) 2002-06-27

Family

ID=27451298

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69619030T Expired - Lifetime DE69619030T2 (de) 1995-06-21 1996-04-18 Verfahren zur Herstellung von Essigsäure durch Carbonylierung
DE69609381T Expired - Lifetime DE69609381T2 (de) 1995-06-21 1996-04-18 Verfahren zur Carbonylierung von Alkylalkoholen und/oder deren reaktionsfähigen Derivaten

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69609381T Expired - Lifetime DE69609381T2 (de) 1995-06-21 1996-04-18 Verfahren zur Carbonylierung von Alkylalkoholen und/oder deren reaktionsfähigen Derivaten

Country Status (16)

Country Link
US (1) US5696284A (de)
EP (2) EP0752406B1 (de)
JP (2) JP3884504B2 (de)
KR (2) KR970001296A (de)
CN (2) CN1068576C (de)
AR (2) AR002560A1 (de)
AT (2) ATE194825T1 (de)
CA (2) CA2175031C (de)
DE (2) DE69619030T2 (de)
MX (2) MX9602082A (de)
MY (2) MY115799A (de)
NO (2) NO961723L (de)
NZ (2) NZ286473A (de)
RU (2) RU2160248C2 (de)
TW (2) TW396150B (de)
UA (2) UA46724C2 (de)

Families Citing this family (118)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9626317D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626429D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626324D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
US5900505A (en) * 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
GB9816385D0 (en) * 1998-07-29 1998-09-23 Bp Chem Int Ltd Process
GB9819079D0 (en) * 1998-09-03 1998-10-28 Bp Chem Int Ltd Carbonylation process
GB9824011D0 (en) * 1998-11-03 1998-12-30 Bp Chem Int Ltd Process for the production of acetic acid
GB9825424D0 (en) * 1998-11-19 1999-01-13 Bp Chem Int Ltd Process
US6103934A (en) * 1998-12-18 2000-08-15 Millennium Petrochemicals, Inc. Manufacturing and process control methods
US6251256B1 (en) 1999-02-04 2001-06-26 Celanese International Corporation Process for electrochemical oxidation of an aldehyde to an ester
JP2002536695A (ja) * 1999-02-05 2002-10-29 エイリアン・テクノロジイ・コーポレーション アセンブリを形成するための装置および方法
US6137000A (en) * 1999-02-16 2000-10-24 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst
US6160163A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter
US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols
US6353132B1 (en) 1999-08-25 2002-03-05 Eastman Chemical Company Vapor phase carbonylation process using group 5 metal promoted iridium catalyst
US6355595B1 (en) 1999-08-25 2002-03-12 Eastman Chemical Company Group 5 metal promoted iridium carbonylation catalyst
US6355837B1 (en) 1999-08-25 2002-03-12 Eastman Chemical Company Vapor phase carbonylation process using group 4 metal promoted iridium catalyst
GB9926855D0 (en) * 1999-11-12 2000-01-12 Bp Chem Int Ltd Process
US6458995B1 (en) 2000-03-31 2002-10-01 Celanese International Corporation Catalytic composition for carbonylation including iridium and pyridine polymers
US6177380B1 (en) 2000-05-22 2001-01-23 Eastman Chemical Company Iridium-gold carbonylation co-catalysts
US6537944B1 (en) 2001-06-20 2003-03-25 Eastman Chemical Company Tungsten promoted catalyst for carbonylation of lower alkyl alcohols
US6646154B2 (en) 2001-06-20 2003-11-11 Eastman Chemical Company Method for carbonylation of lower alkyl alcohols using tungsten promoted group VIII catalyst
US6617471B2 (en) 2001-06-20 2003-09-09 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst
US6548444B2 (en) 2001-06-20 2003-04-15 Eastman Chemical Company Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols
KR100441011B1 (ko) * 2001-12-28 2004-07-21 삼성전자주식회사 냉장고
EP1501779B1 (de) 2002-05-06 2009-12-23 Eastman Chemical Company Kontinuierlicher carbonylierungsprozess
GB0212974D0 (en) * 2002-06-06 2002-07-17 Bp Chem Int Ltd Process
GB0213485D0 (en) * 2002-06-12 2002-07-24 Bp Chem Int Ltd Process
GB0221800D0 (en) * 2002-09-19 2002-10-30 Bp Chem Int Ltd Process
GB0222618D0 (en) * 2002-09-30 2002-11-06 Bp Chem Int Ltd Process
GB0316756D0 (en) * 2003-07-17 2003-08-20 Bp Chem Int Ltd Process
JP4489487B2 (ja) * 2004-04-02 2010-06-23 ダイセル化学工業株式会社 ヨウ化水素の分離方法
CA2496839A1 (en) 2004-07-19 2006-01-19 Woodland Chemical Systems Inc. Process for producing ethanol from synthesis gas rich in carbon monoxide
CN100443173C (zh) * 2004-11-22 2008-12-17 中国科学院化学研究所 甲醇合成乙酸或乙酸甲酯合成乙酐的催化剂体系及应用
US7053241B1 (en) 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
GB0601863D0 (en) 2006-01-30 2006-03-08 Bp Chem Int Ltd Process
GB0601861D0 (en) * 2006-01-30 2006-03-08 Bp Chem Int Ltd Process
GB0601865D0 (en) * 2006-01-30 2006-03-08 Bp Chem Int Ltd Process
CA2682778C (en) 2006-04-05 2017-03-07 Woodland Biofuels Inc. System and method for converting biomass to ethanol via syngas
GB0607394D0 (en) * 2006-04-12 2006-05-24 Bp Chem Int Ltd Process
US7737298B2 (en) 2006-06-09 2010-06-15 Eastman Chemical Company Production of acetic acid and mixtures of acetic acid and acetic anhydride
US7582792B2 (en) 2006-06-15 2009-09-01 Eastman Chemical Company Carbonylation process
US7253304B1 (en) 2006-06-20 2007-08-07 Eastman Chemical Company Carbonylation process
US7629491B2 (en) 2006-06-26 2009-12-08 Eastman Chemical Company Hydrocarboxylation process
US7902398B2 (en) 2007-04-25 2011-03-08 Celanese International Corporation Method and apparatus for carbonylation with reduced catalyst loss
US7989659B2 (en) 2007-05-17 2011-08-02 Celanese International Corporation Method and apparatus for making acetic acid with improved light ends column productivity
US7902397B2 (en) * 2007-10-11 2011-03-08 Celanese International Corporation Method and apparatus for making acetic acid with improved productivity
EP2093209A1 (de) * 2008-02-19 2009-08-26 BP Chemicals Limited Verfahren zur Herstellung von Essigsäure
US7820855B2 (en) 2008-04-29 2010-10-26 Celanese International Corporation Method and apparatus for carbonylating methanol with acetic acid enriched flash stream
US8318977B2 (en) 2008-04-29 2012-11-27 Celanese International Corporation Methanol carbonylation system having absorber with multiple solvent options
US7884237B2 (en) * 2008-11-07 2011-02-08 Celanese International Corp. Methanol carbonylation with improved aldehyde removal
EP2189215A1 (de) * 2008-11-19 2010-05-26 BP Chemicals Limited Carbonylierungsverfahren katalysiert durch Mordenit aufgebracht auf inorganische Oxiden
KR20100062019A (ko) * 2008-12-01 2010-06-10 엘지전자 주식회사 냉장고
EP2198963A1 (de) * 2008-12-10 2010-06-23 BP Chemicals Limited Gebundener Mordenit-Zeolith-Katalysator zur Carbonylierung
US8168822B2 (en) * 2009-07-07 2012-05-01 Celanese International Corporation Acetic acid production by way of carbonylation with enhanced reaction and flashing
US8455685B2 (en) * 2009-07-07 2013-06-04 Celanese International Corporation Acetic anhydride production by way of carbonylation with enhanced reaction and flashing
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
JP5636691B2 (ja) 2010-02-26 2014-12-10 富士ゼロックス株式会社 画像処理装置及び画像処理プログラム
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8859827B2 (en) 2011-11-18 2014-10-14 Celanese International Corporation Esterifying acetic acid to produce ester feed for hydrogenolysis
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8378141B2 (en) 2010-08-16 2013-02-19 Celanese International Corporation Process and system for supplying vapor from drying column to light ends column
US8530696B2 (en) 2010-09-24 2013-09-10 Celanese International Corporation Pump around reactor for production of acetic acid
US8394988B2 (en) 2010-09-28 2013-03-12 Celanese International Corporation Production of acetic acid with high conversion rate
US8877963B2 (en) 2010-09-28 2014-11-04 Celanese International Corporation Production of acetic acid with high conversion rate
US8461379B2 (en) 2010-10-12 2013-06-11 Celanese International Corporation Production of acetic acid comprising feeding at least one reactant to a recycle stream
AR083441A1 (es) 2010-10-13 2013-02-27 Celanese Int Corp Proceso para la recuperacion de promotores de halogeno y para la eliminacion de los compuestos reductores de permanganato
US9012683B2 (en) 2010-11-12 2015-04-21 Eastman Chemical Company Coproduction of acetic acid and acetic anhydride
US8637698B2 (en) 2010-11-19 2014-01-28 Celanese International Corporation Production of acetic acid with an increased production rate
US8563773B2 (en) 2010-12-16 2013-10-22 Celanese International Corporation Eductor-based reactor and pump around loops for production of acetic acid
CN103080053B (zh) 2011-04-26 2015-08-12 国际人造丝公司 使用叠置床反应器生产乙醇的方法
TW201302684A (zh) 2011-04-26 2013-01-16 Celanese Int Corp 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程
US8686199B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process for reducing the concentration of acetic acid in a crude alcohol product
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US8697908B2 (en) 2011-05-05 2014-04-15 Celanese International Corporation Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants
WO2012151377A1 (en) 2011-05-05 2012-11-08 Celanese International Corporation Removal of aromatics from carbonylation process
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US9663437B2 (en) 2011-09-13 2017-05-30 Celanese International Corporation Production of acetic acid with high conversion rate
WO2013070209A1 (en) 2011-11-09 2013-05-16 Celanese International Corporation Integrated carbonylation and hydrogenation process to obtain ethanol
WO2013070210A1 (en) 2011-11-09 2013-05-16 Celanese International Corporation Integrated carbonylation and hydrogenation process to obtain ethanol having flashing to recover acid production catalyst
US8686201B2 (en) 2011-11-09 2014-04-01 Celanese International Corporation Integrated acid and alcohol production process having flashing to recover acid production catalyst
US8614359B2 (en) 2011-11-09 2013-12-24 Celanese International Corporation Integrated acid and alcohol production process
US8748673B2 (en) 2011-11-18 2014-06-10 Celanese International Corporation Process of recovery of ethanol from hydrogenolysis process
US8853470B2 (en) 2011-11-22 2014-10-07 Celanese International Corporation Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis
US20130131400A1 (en) 2011-11-22 2013-05-23 Celanese International Corporation Hydrogenating Acetic Acid to Produce Ethyl Acetate and Reducing Ethyl Acetate to Ethanol
CN102366724B (zh) * 2011-12-01 2013-05-15 重庆大学 一种甲醇羰基化合成醋酸的催化剂体系及应用
WO2013089990A1 (en) 2011-12-14 2013-06-20 Celanese International Corporation Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol
US9421522B2 (en) * 2011-12-28 2016-08-23 Eastman Chemical Company Iridium catalysts for carbonylation
US20130172633A1 (en) 2011-12-29 2013-07-04 Celanese International Corporation Process For Producing Ethanol From Impure Methanol
WO2013119275A1 (en) 2012-02-08 2013-08-15 Celanese International Corporation Production of acetic acid from methanol
US8859810B2 (en) 2012-08-21 2014-10-14 Celanese International Corporation Process for recovering permanganate reducing compounds from an acetic acid production process
CN103724179B (zh) * 2012-10-11 2015-07-22 中国石油化工股份有限公司 一种制备乙酸的方法
MX363829B (es) 2013-03-15 2019-04-03 Celanese Int Corp Proceso para separar gas de producto usando proceso de carbonilación.
SG11201610487PA (en) * 2014-06-17 2017-01-27 Bp Chem Int Ltd Method and apparatus for treating offgases in a acetic acid production unit
CN106715379B (zh) 2014-10-02 2020-05-19 国际人造丝公司 用于生产乙酸的方法
US9302975B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for flashing a reaction medium
US9260369B1 (en) 2014-11-14 2016-02-16 Celanese International Corporation Processes for producing acetic acid product having low butyl acetate content
CN107001222B (zh) 2014-11-14 2021-05-11 国际人造丝公司 用于从具有低乙基碘含量的反应介质生产乙酸的方法
SG11201704348WA (en) * 2014-12-12 2017-06-29 Lyondellbasell Acetyls Llc Improved water control in acetic acid production processes
KR101667222B1 (ko) 2014-12-29 2016-10-18 한국화학연구원 카보닐화 반응에 의한 초산 제조용 Rh-C3N4 불균일 촉매
KR101667223B1 (ko) 2014-12-29 2016-10-18 한국화학연구원 카보닐화 반응에 의한 초산 제조용 Ｒｈ/ＷｘＣ 불균일 촉매
US9561994B2 (en) 2015-01-30 2017-02-07 Celanese International Corporation Processes for producing acetic acid
US9487464B2 (en) 2015-01-30 2016-11-08 Celanese International Corporation Processes for producing acetic acid
US9505696B2 (en) 2015-02-04 2016-11-29 Celanese International Corporation Process to control HI concentration in residuum stream
US9302974B1 (en) 2015-07-01 2016-04-05 Celanese International Corporation Process for producing acetic acid
US9382183B1 (en) 2015-07-01 2016-07-05 Celanese International Corporation Process for flashing a reaction medium
US10526270B2 (en) 2015-10-02 2020-01-07 Celanese International Corporation Process to produce acetic acid with recycle of water
US9908835B2 (en) 2015-11-13 2018-03-06 Celanese International Corporation Processes for purifying acetic and hydrating anhydride
US9957216B2 (en) 2015-11-13 2018-05-01 Celanese International Corporation Processes for producing acetic acid
US10457622B2 (en) 2017-03-08 2019-10-29 Daicel Corporation Method for producing acetic acid
CN110114331A (zh) * 2017-03-08 2019-08-09 株式会社大赛璐 乙酸的制备方法
KR20210005196A (ko) 2018-05-02 2021-01-13 주식회사 다이셀 아세트산의 제조 방법
TW202208315A (zh) 2020-06-03 2022-03-01 美商瑟蘭斯國際股份有限公司 低雜質液態流

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE364254B (de) * 1967-04-05 1974-02-18 Monsanto Co
DE1941449C3 (de) * 1968-08-15 1979-07-26 Monsanto Co., St. Louis, Mo. (V.St.A.) Verfahren zur Herstellung von Monocarbonsäuren
US3772380A (en) * 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
FR2317269A1 (fr) * 1975-07-10 1977-02-04 Metaux Precieux Cie Procede de fabrication d'acides et d'esters alcane carboxyliques par reaction d'alcools avec le monoxyde de carbone en presence de catalyseurs contenant de l'iridium
US4096164A (en) * 1976-08-30 1978-06-20 Union Carbide Corporation Process for producing ethanol, acetic acid and/or acetaldehyde, from synthesis gas
US4358411A (en) * 1979-06-29 1982-11-09 The Halcon Sd Group, Inc. Preparation of carbonylation products
DE3064657D1 (en) * 1979-12-21 1983-09-29 Shell Int Research Process for the co-production of carboxylic acids and carboxylic acid esters
JPS6054334A (ja) * 1983-09-02 1985-03-28 Daicel Chem Ind Ltd カルボン酸の製造法
CA1228867A (en) * 1984-05-03 1987-11-03 G. Paull Torrence Methanol carbonylation process
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
GB9306409D0 (en) * 1993-03-26 1993-05-19 Bp Chem Int Ltd Process
FR2703351A1 (fr) * 1993-03-31 1994-10-07 Rhone Poulenc Chimie Procédé de préparation d'acides carboxyliques ou des esters correspondants en présence d'un catalyseur à base de rhodium et d'iridium.
BR9401362A (pt) * 1993-03-31 1994-11-01 Rhone Poulenc Chimie Processo de preparação de ácidos carboxílicos, ou dos ésteres correspondentes
FR2725443B1 (fr) * 1994-10-05 1996-12-20 Rhone Poulenc Chimie Preparation d'acides carboxyliques ou des esters correspondants par carbonylation en presence d'iridium
US5510524A (en) * 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid

Also Published As

Publication number Publication date
DE69609381D1 (de) 2000-08-24
UA46724C2 (uk) 2002-06-17
MY115799A (en) 2003-09-30
CN1068576C (zh) 2001-07-18
NZ286473A (en) 1997-06-24
JP3884504B2 (ja) 2007-02-21
UA50713C2 (uk) 2002-11-15
AR002559A1 (es) 1998-03-25
ATE212970T1 (de) 2002-02-15
RU2167850C2 (ru) 2001-05-27
TW396150B (en) 2000-07-01
JPH092993A (ja) 1997-01-07
JPH092992A (ja) 1997-01-07
CN1139097A (zh) 1997-01-01
CN1141910A (zh) 1997-02-05
NO961723L (no) 1996-12-23
EP0752406A1 (de) 1997-01-08
KR970001296A (ko) 1997-01-24
CA2175031A1 (en) 1996-12-22
CA2175028C (en) 2008-06-17
DE69609381T2 (de) 2000-12-28
AR002560A1 (es) 1998-03-25
NO961722L (no) 1996-12-23
MX9602082A (es) 1997-08-30
NO961722D0 (no) 1996-04-29
ATE194825T1 (de) 2000-08-15
US5696284A (en) 1997-12-09
EP0749948A1 (de) 1996-12-27
NO961723D0 (no) 1996-04-29
NZ286474A (en) 1997-05-26
MY113453A (en) 2002-02-28
DE69619030D1 (de) 2002-03-21
CA2175028A1 (en) 1996-12-22
RU2160248C2 (ru) 2000-12-10
CN1106377C (zh) 2003-04-23
CA2175031C (en) 2007-12-04
KR100404644B1 (ko) 2004-03-18
EP0749948B1 (de) 2000-07-19
TW338763B (en) 1998-08-21
KR970001295A (ko) 1997-01-24
MX9602083A (es) 1997-08-30
EP0752406B1 (de) 2002-02-06

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