RU2690373C2 - Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты - Google Patents

Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты Download PDF

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RU2690373C2
RU2690373C2 RU2016147087A RU2016147087A RU2690373C2 RU 2690373 C2 RU2690373 C2 RU 2690373C2 RU 2016147087 A RU2016147087 A RU 2016147087A RU 2016147087 A RU2016147087 A RU 2016147087A RU 2690373 C2 RU2690373 C2 RU 2690373C2
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group
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polymer
polymerization
ethylene
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RU2016147087A
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RU2016147087A3 (enExample
RU2016147087A (ru
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Джошуа П. АБЕЛЬ
Цзенцюань ЦИНЬ
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Бриджстоун Корпорейшн
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/03—Cp or analog not bridged to a non-Cp X ancillary neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
RU2016147087A 2014-05-31 2015-05-26 Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты RU2690373C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462006119P 2014-05-31 2014-05-31
US62/006,119 2014-05-31
US201562136302P 2015-03-20 2015-03-20
US62/136,302 2015-03-20
PCT/US2015/032373 WO2015183781A1 (en) 2014-05-31 2015-05-26 Metallic complex catalyst, polymerization methods employing same and polymer products thereof

Related Child Applications (1)

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RU2019115933A Division RU2723019C2 (ru) 2014-05-31 2015-05-26 Интерполимер и содержащая его композиция

Publications (3)

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RU2016147087A RU2016147087A (ru) 2018-05-30
RU2016147087A3 RU2016147087A3 (enExample) 2018-12-11
RU2690373C2 true RU2690373C2 (ru) 2019-06-03

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RU2016147087A RU2690373C2 (ru) 2014-05-31 2015-05-26 Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты
RU2019115933A RU2723019C2 (ru) 2014-05-31 2015-05-26 Интерполимер и содержащая его композиция
RU2020117998A RU2020117998A (ru) 2014-05-31 2020-06-01 Интерполимер и содержащая его композиция

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RU2020117998A RU2020117998A (ru) 2014-05-31 2020-06-01 Интерполимер и содержащая его композиция

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US (2) US10457765B2 (enExample)
EP (2) EP3148938B1 (enExample)
JP (2) JP6673596B2 (enExample)
CN (2) CN110283280B (enExample)
BR (1) BR112016027987B1 (enExample)
RU (3) RU2690373C2 (enExample)
WO (1) WO2015183781A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2689990C2 (ru) 2014-05-30 2019-05-30 Бриджстоун Корпорейшн Металлокомплексный катализатор и способы полимеризации с его использованием
EP3680265B1 (en) * 2017-09-04 2024-01-17 Bridgestone Corporation Method for producing copolymer, copolymer, rubber composition, and tire
JP7364585B2 (ja) 2018-03-30 2023-10-18 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のための二核助触媒としての高溶解性ビスホウ酸
WO2019191539A1 (en) * 2018-03-30 2019-10-03 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
JP7041585B2 (ja) * 2018-05-21 2022-03-24 株式会社ブリヂストン 重合触媒、及び、共重合体の製造方法
JP7009307B2 (ja) * 2018-05-21 2022-01-25 株式会社ブリヂストン 重合触媒、及び、共重合体の製造方法
JP7654963B2 (ja) 2020-11-25 2025-04-02 株式会社ニデック 染料付基体製造装置および染色システム
US12227018B2 (en) 2020-11-25 2025-02-18 Nidek Co., Ltd. Dye-deposited base body manufacturing apparatus and dyeing system
US20260234300A1 (en) 2023-02-08 2026-08-13 ExxonMobil Technology and Engineering Company Catalysts for Copolymerizations
WO2024253829A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Solution catalyst systems and uses thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2145612C1 (ru) * 1992-12-17 2000-02-20 Солвей Полиолефинс Юроп-Бельгия Каталитическая система, предшественник этой каталитической системы, способ получения этой каталитической системы и способ (со)полимеризации олефинов
EP2463313A1 (en) * 2009-08-07 2012-06-13 Bridgestone Corporation Method for producing copolymer
EP2599804A1 (en) * 2010-07-30 2013-06-05 Bridgestone Corporation Copolymer, rubber composition, cross-linked rubber composition, and tire
EP2671896A1 (en) * 2011-02-04 2013-12-11 Bridgestone Corporation Copolymer, rubber composition, crosslinked rubber composition, and tire

Family Cites Families (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4926307B1 (enExample) * 1970-06-10 1974-07-08
US3978103A (en) 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
US3873489A (en) 1971-08-17 1975-03-25 Degussa Rubber compositions containing silica and an organosilane
US3901862A (en) * 1972-12-20 1975-08-26 Snam Progetti Process for the preparation of ethylene-butadiene copolymers
SU580840A3 (ru) 1974-02-07 1977-11-15 Дегусса (Фирма) Способ получени серосодержащих кремнийорганических соединений
US4015061A (en) 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4002594A (en) 1975-07-08 1977-01-11 Ppg Industries, Inc. Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent
DE3021273A1 (de) * 1979-06-12 1981-01-08 Mitsubishi Petrochemical Co Ungesaettigte mischpolymerisate
DE2943129A1 (de) * 1979-10-25 1981-05-07 Bayer Ag, 5090 Leverkusen Alternierende isopren-ethylen-copolymere sowie ein verfahren zu ihrer herstellung
DE3017539A1 (de) * 1980-05-08 1981-11-12 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von alternierenden butadien-propylen-copolymeren
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
US5191052A (en) * 1985-06-21 1993-03-02 Exxon Chemical Patents Inc. Copolymers of ethylene and 1,3-butadiene
US5064910A (en) 1986-09-05 1991-11-12 Japan Synthetic Rubber Co., Ltd. Preparation of conjugated diene polymers modified with an organo-tin or germanium halide
US4906706A (en) 1986-09-05 1990-03-06 Japan Synthetic Rubber Co., Ltd. Modified conjugated diene polymer and process for production thereof
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
IT1230756B (it) 1989-02-17 1991-10-29 Enichem Elastomers Metodo per la preparazione di polibutadiene a lavorabilita' migliorata.
US5149457A (en) 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5196138A (en) 1989-06-30 1993-03-23 Cyprus Foote Mineral Company Preparation of mixed lithium amide reagents
US5153159A (en) 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
EP0713885B1 (en) 1993-07-30 1998-05-20 Nippon Zeon Co., Ltd. Modified conjugated diene copolymer, process for producing the same, and composition thereof
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
DE4436059A1 (de) 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
CN1147822A (zh) * 1994-12-20 1997-04-16 蒙特尔技术有限公司 反应器掺混聚丙烯,其制备方法和金属茂配位体的制备方法
US5521309A (en) 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5496940A (en) 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5580919A (en) 1995-03-14 1996-12-03 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and use in tires
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5583245A (en) 1996-03-06 1996-12-10 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
ATE194629T1 (de) 1996-03-27 2000-07-15 Dow Chemical Co Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator
US5663398A (en) 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5696197A (en) 1996-06-21 1997-12-09 The Goodyear Tire & Rubber Company Heterogeneous silica carbon black-filled rubber compound
US5663396A (en) 1996-10-31 1997-09-02 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5786441A (en) 1996-12-31 1998-07-28 Bridgestone Corporation Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties
US5684172A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US5684171A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
EP0863165B1 (en) 1997-03-05 2003-06-04 JSR Corporation Method of producing conjugated diene polymers
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6525118B2 (en) 1997-07-11 2003-02-25 Bridgestone Corporation Processability of silica-filled rubber stocks with reduced hysteresis
JP3577978B2 (ja) * 1998-03-06 2004-10-20 住友化学工業株式会社 エチレン−イソプレンランダム共重合体、エラストマー組成物及び架橋エラストマー組成物
SG75157A1 (en) * 1998-03-06 2000-09-19 Sumitomo Chemical Co Etylene-isoprene random copolymer
JP2001081143A (ja) * 1999-09-17 2001-03-27 Nippon Zeon Co Ltd 共役ジエン単量体と極性ビニル単量体との交互共重合体および交互共重合体の製造方法
FR2799468B1 (fr) * 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
DE60041550D1 (de) 1999-11-12 2009-03-26 Bridgestone Corp Modifizierte polymere hergestellt mit katalysator auf basys von lanthaniden
EP1099711B1 (en) 1999-11-12 2006-03-29 JSR Corporation Modified conjugated diene polymer, method of producing it and rubber composition comprising the same
US6977281B1 (en) 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
WO2002038615A1 (en) 2000-11-10 2002-05-16 Bridgestone Corporation Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents
MXPA01001160A (es) 2001-01-31 2002-08-05 Ct De Investigacion En Quimica Poli(metacrilato de metilo) semicristalino con alta temperatura de fusion y proceso para su separacion.
EP1363953A2 (en) 2001-02-01 2003-11-26 Fmc Corporation Functionalized initiators for anionic polymerization, protected funtionalized polymers, deprotected analogues thereof, and methods of making the same
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
US7153919B2 (en) 2002-10-30 2006-12-26 Bridgestone Corporation Use of sulfur containing initiators for anionic polymerization of monomers
FR2858817B1 (fr) 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
WO2005087824A1 (en) 2004-03-02 2005-09-22 Bridgestone Corporation Bulk polymerization process
JPWO2005105867A1 (ja) * 2004-04-28 2008-03-13 三井化学株式会社 非共役ポリエン系共重合体、ゴム組成物およびこれらの用途
US7994267B2 (en) * 2004-07-02 2011-08-09 Riken Polymerization catalyst compositions containing metallocene complexes and polymers produced by using the same
CN101445568B (zh) 2004-10-26 2014-11-19 株式会社普利司通 具有连接基团的官能化聚合物
US7816483B2 (en) 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP5079294B2 (ja) 2005-10-04 2012-11-21 株式会社ブリヂストン アミンで官能化されたポリマー
US7879952B2 (en) 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
WO2007129670A1 (ja) * 2006-05-09 2007-11-15 Riken メタロセン錯体、およびそれを含む重合触媒組成物
US7671138B2 (en) 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US7732534B2 (en) 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
US8715270B2 (en) * 2006-12-01 2014-05-06 Boston Scientific Scimed, Inc. Multi-part instrument systems and methods
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
ZA200711158B (en) 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
US8324329B2 (en) 2007-08-07 2012-12-04 Bridgestone Corporation Process for producing functionalized polymers
US7879958B2 (en) 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
CN101220060B (zh) * 2008-01-23 2012-08-29 中国科学院上海有机化学研究所 单茚基稀土配合物、合成方法以及应用
US8524793B2 (en) 2008-06-18 2013-09-03 Dow Global Technologies, Llc Interpolymer compositions of ethylene, α-olefin and nonconjugated polyene, methods of making the same, and foam and articles prepared from the same
JP4962619B2 (ja) 2008-07-16 2012-06-27 日本エクスラン工業株式会社 制電性アクリル繊維およびその製造方法
JP5557835B2 (ja) * 2009-03-30 2014-07-23 三井化学株式会社 オレフィンと共役ジエンとの共重合体、およびその製造方法
US9266978B2 (en) 2010-07-30 2016-02-23 Bridgestone Corporation Copolymer and method of manufacturing the same
US9056936B2 (en) 2010-07-30 2015-06-16 Bridgestone Corporation Copolymer of a conjugated diene compound and a non-conjugated olefin, rubber composition, crosslinked rubber composition, and tire
RU2537385C2 (ru) 2010-07-30 2015-01-10 Бриджстоун Корпорейшн Сополимер, каучуковая композиция, сшитая каучуковая композиция и покрышка
CN103154059B (zh) 2010-07-30 2014-12-24 株式会社普利司通 共轭二烯化合物与非共轭烯烃的共聚物、橡胶组合物、交联橡胶组合物和轮胎
CN103140521B (zh) * 2010-07-30 2015-07-01 株式会社普利司通 共聚物中链结构的控制方法
US8962743B2 (en) 2010-07-30 2015-02-24 Bridgestone Corporation Copolymer of conjugated diene compound and non-conjugated olefin, rubber composition and tire
US10072146B2 (en) 2010-12-30 2018-09-11 Dow Global Technologies Llc Compositions, methods of making the same, and articles prepared from the same
JP5731217B2 (ja) * 2011-02-04 2015-06-10 株式会社ブリヂストン 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5722664B2 (ja) * 2011-03-01 2015-05-27 株式会社ブリヂストン 積層体
IN2014CN04444A (enExample) 2011-12-20 2015-09-04 Dow Global Technologies Llc
WO2014003857A1 (en) * 2012-06-29 2014-01-03 Dow Global Technologies Llc Ethylene/alpha-olefin/nonconjugated polyene based compositions for thermoplastic vulcanizates
JP5902587B2 (ja) 2012-08-20 2016-04-13 株式会社ブリヂストン 共重合体の製造方法
JP6267575B2 (ja) * 2014-05-02 2018-01-24 株式会社ブリヂストン マルチブロック共重合体、ゴム組成物及びタイヤ
RU2689990C2 (ru) 2014-05-30 2019-05-30 Бриджстоун Корпорейшн Металлокомплексный катализатор и способы полимеризации с его использованием

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2145612C1 (ru) * 1992-12-17 2000-02-20 Солвей Полиолефинс Юроп-Бельгия Каталитическая система, предшественник этой каталитической системы, способ получения этой каталитической системы и способ (со)полимеризации олефинов
EP2463313A1 (en) * 2009-08-07 2012-06-13 Bridgestone Corporation Method for producing copolymer
EP2599804A1 (en) * 2010-07-30 2013-06-05 Bridgestone Corporation Copolymer, rubber composition, cross-linked rubber composition, and tire
EP2671896A1 (en) * 2011-02-04 2013-12-11 Bridgestone Corporation Copolymer, rubber composition, crosslinked rubber composition, and tire

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
XU Х. et al, Indenyl Abstraction versus Alkyl Abstraction of [(Indenyl)ScR2(thf)] by [Ph3C] [B(C6F5)4]: Aspecific and Syndiospecific Styrene Polymerization, Chem. Eur. J., 2009, v. 15, p. 846-850 (реферат). *

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