RU2690373C2 - Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты - Google Patents

Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты Download PDF

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RU2690373C2
RU2690373C2 RU2016147087A RU2016147087A RU2690373C2 RU 2690373 C2 RU2690373 C2 RU 2690373C2 RU 2016147087 A RU2016147087 A RU 2016147087A RU 2016147087 A RU2016147087 A RU 2016147087A RU 2690373 C2 RU2690373 C2 RU 2690373C2
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polymer
polymerization
ethylene
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RU2016147087A
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RU2016147087A3 (enExample
RU2016147087A (ru
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Джошуа П. АБЕЛЬ
Цзенцюань ЦИНЬ
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Бриджстоун Корпорейшн
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/03—Cp or analog not bridged to a non-Cp X ancillary neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
RU2016147087A 2014-05-31 2015-05-26 Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты RU2690373C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462006119P 2014-05-31 2014-05-31
US62/006,119 2014-05-31
US201562136302P 2015-03-20 2015-03-20
US62/136,302 2015-03-20
PCT/US2015/032373 WO2015183781A1 (en) 2014-05-31 2015-05-26 Metallic complex catalyst, polymerization methods employing same and polymer products thereof

Related Child Applications (1)

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RU2019115933A Division RU2723019C2 (ru) 2014-05-31 2015-05-26 Интерполимер и содержащая его композиция

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RU2016147087A RU2016147087A (ru) 2018-05-30
RU2016147087A3 RU2016147087A3 (enExample) 2018-12-11
RU2690373C2 true RU2690373C2 (ru) 2019-06-03

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RU2016147087A RU2690373C2 (ru) 2014-05-31 2015-05-26 Металлокомплексный катализатор, способы полимеризации с его использованием и полученные полимерные продукты
RU2019115933A RU2723019C2 (ru) 2014-05-31 2015-05-26 Интерполимер и содержащая его композиция
RU2020117998A RU2020117998A (ru) 2014-05-31 2020-06-01 Интерполимер и содержащая его композиция

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RU2020117998A RU2020117998A (ru) 2014-05-31 2020-06-01 Интерполимер и содержащая его композиция

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US (2) US10457765B2 (enExample)
EP (2) EP3738927A1 (enExample)
JP (2) JP6673596B2 (enExample)
CN (2) CN106660819B (enExample)
BR (1) BR112016027987B1 (enExample)
RU (3) RU2690373C2 (enExample)
WO (1) WO2015183781A1 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3148937B1 (en) 2014-05-30 2019-09-18 Bridgestone Corporation Metallic complex catalyst and polymerization methods employing same
US11279785B2 (en) * 2017-09-04 2022-03-22 Bridgestone Corporation Production method for copolymer, copolymer, rubber composition, and tire
JP7495880B2 (ja) * 2018-03-30 2024-06-05 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のための助触媒としての高溶解性アルキル置換ホウ酸カルベニウム
US12037440B2 (en) 2018-03-30 2024-07-16 Dow Global Technologies Llc Highly soluble bis-borate as binuclear co-catalysts for olefin polymerization
JP7009307B2 (ja) * 2018-05-21 2022-01-25 株式会社ブリヂストン 重合触媒、及び、共重合体の製造方法
JP7041585B2 (ja) * 2018-05-21 2022-03-24 株式会社ブリヂストン 重合触媒、及び、共重合体の製造方法
PT4005782T (pt) 2020-11-25 2023-03-15 Nidek Kk Aparelho para fabricar um corpo de base com corante depositado e sistema de tingimento
JP7654963B2 (ja) 2020-11-25 2025-04-02 株式会社ニデック 染料付基体製造装置および染色システム
CN120981495A (zh) 2023-02-08 2025-11-18 埃克森美孚技术与工程公司 用于共聚的催化剂
KR20260015988A (ko) 2023-06-06 2026-02-03 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 용액 촉매계 및 이의 용도

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2145612C1 (ru) * 1992-12-17 2000-02-20 Солвей Полиолефинс Юроп-Бельгия Каталитическая система, предшественник этой каталитической системы, способ получения этой каталитической системы и способ (со)полимеризации олефинов
EP2463313A1 (en) * 2009-08-07 2012-06-13 Bridgestone Corporation Method for producing copolymer
EP2599804A1 (en) * 2010-07-30 2013-06-05 Bridgestone Corporation Copolymer, rubber composition, cross-linked rubber composition, and tire
EP2671896A1 (en) * 2011-02-04 2013-12-11 Bridgestone Corporation Copolymer, rubber composition, crosslinked rubber composition, and tire

Family Cites Families (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4926307B1 (enExample) * 1970-06-10 1974-07-08
US3978103A (en) 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
US3873489A (en) 1971-08-17 1975-03-25 Degussa Rubber compositions containing silica and an organosilane
US3901862A (en) * 1972-12-20 1975-08-26 Snam Progetti Process for the preparation of ethylene-butadiene copolymers
SU580840A3 (ru) 1974-02-07 1977-11-15 Дегусса (Фирма) Способ получени серосодержащих кремнийорганических соединений
US4015061A (en) 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4002594A (en) 1975-07-08 1977-01-11 Ppg Industries, Inc. Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent
DE3021273A1 (de) * 1979-06-12 1981-01-08 Mitsubishi Petrochemical Co Ungesaettigte mischpolymerisate
DE2943129A1 (de) * 1979-10-25 1981-05-07 Bayer Ag, 5090 Leverkusen Alternierende isopren-ethylen-copolymere sowie ein verfahren zu ihrer herstellung
DE3017539A1 (de) * 1980-05-08 1981-11-12 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von alternierenden butadien-propylen-copolymeren
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
US5191052A (en) * 1985-06-21 1993-03-02 Exxon Chemical Patents Inc. Copolymers of ethylene and 1,3-butadiene
US5064910A (en) 1986-09-05 1991-11-12 Japan Synthetic Rubber Co., Ltd. Preparation of conjugated diene polymers modified with an organo-tin or germanium halide
US4906706A (en) 1986-09-05 1990-03-06 Japan Synthetic Rubber Co., Ltd. Modified conjugated diene polymer and process for production thereof
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
IT1230756B (it) 1989-02-17 1991-10-29 Enichem Elastomers Metodo per la preparazione di polibutadiene a lavorabilita' migliorata.
US5196138A (en) 1989-06-30 1993-03-23 Cyprus Foote Mineral Company Preparation of mixed lithium amide reagents
US5149457A (en) 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5153159A (en) 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
EP0713885B1 (en) 1993-07-30 1998-05-20 Nippon Zeon Co., Ltd. Modified conjugated diene copolymer, process for producing the same, and composition thereof
WO1996020225A2 (en) * 1994-12-20 1996-07-04 Montell Technology Company B.V. Reactor blend polypropylene, process for the preparation thereof and process for preparing metallocene ligands
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
DE4436059A1 (de) 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
US5521309A (en) 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5496940A (en) 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5580919A (en) 1995-03-14 1996-12-03 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and use in tires
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5583245A (en) 1996-03-06 1996-12-10 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
RU2178422C2 (ru) 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
US5663398A (en) 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5696197A (en) 1996-06-21 1997-12-09 The Goodyear Tire & Rubber Company Heterogeneous silica carbon black-filled rubber compound
US5663396A (en) 1996-10-31 1997-09-02 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5786441A (en) 1996-12-31 1998-07-28 Bridgestone Corporation Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties
US5684172A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US5684171A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
ES2198651T3 (es) 1997-03-05 2004-02-01 Jsr Corporation Metodo para producir polimeros dieno conjugados.
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6525118B2 (en) 1997-07-11 2003-02-25 Bridgestone Corporation Processability of silica-filled rubber stocks with reduced hysteresis
US6288191B1 (en) * 1998-03-06 2001-09-11 Sumitomo Chemical Company, Limited Ethylene-isoprene random copolymer
JP3577978B2 (ja) * 1998-03-06 2004-10-20 住友化学工業株式会社 エチレン−イソプレンランダム共重合体、エラストマー組成物及び架橋エラストマー組成物
JP2001081143A (ja) 1999-09-17 2001-03-27 Nippon Zeon Co Ltd 共役ジエン単量体と極性ビニル単量体との交互共重合体および交互共重合体の製造方法
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
US6977281B1 (en) 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
EP1099711B1 (en) 1999-11-12 2006-03-29 JSR Corporation Modified conjugated diene polymer, method of producing it and rubber composition comprising the same
WO2001034658A1 (en) 1999-11-12 2001-05-17 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
WO2002038615A1 (en) 2000-11-10 2002-05-16 Bridgestone Corporation Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents
MXPA01001160A (es) 2001-01-31 2002-08-05 Ct De Investigacion En Quimica Poli(metacrilato de metilo) semicristalino con alta temperatura de fusion y proceso para su separacion.
WO2002060958A2 (en) 2001-02-01 2002-08-08 Fmc Corporation Functionalized initiators for anionic polymerization, protected funtionalized polymers, deprotected analogues thereof, and methods of making the same
CA2502345A1 (fr) 2002-10-16 2004-04-29 Michelin Recherche Et Technique S.A. Copolymeres ethylene/ butadiene, system catalytique et les produires et production desdits polymers
JP4522947B2 (ja) 2002-10-30 2010-08-11 株式会社ブリヂストン モノマーのアニオン重合に硫黄含有開始剤を使用する方法
FR2858817B1 (fr) 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
JP5111101B2 (ja) 2004-03-02 2012-12-26 株式会社ブリヂストン バルク重合プロセス
KR20080092459A (ko) * 2004-04-28 2008-10-15 미쓰이 가가쿠 가부시키가이샤 비공액 폴리엔계 공중합체 및 고무 조성물
WO2006004068A1 (ja) * 2004-07-02 2006-01-12 Riken メタロセン錯体を含む重合触媒組成物、およびそれを用いて製造される重合体
CN101445568B (zh) 2004-10-26 2014-11-19 株式会社普利司通 具有连接基团的官能化聚合物
US7816483B2 (en) 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP5079294B2 (ja) 2005-10-04 2012-11-21 株式会社ブリヂストン アミンで官能化されたポリマー
US7879952B2 (en) 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
BRPI0711436B1 (pt) 2006-05-09 2018-04-17 Riken Complexo de metaloceno, composição de catalisador de polimerização, e, métodos de produzir um polímero de adição
US7671138B2 (en) 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US7732534B2 (en) 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
US8715270B2 (en) * 2006-12-01 2014-05-06 Boston Scientific Scimed, Inc. Multi-part instrument systems and methods
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
ZA200711158B (en) 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
US7879958B2 (en) 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
US8324329B2 (en) 2007-08-07 2012-12-04 Bridgestone Corporation Process for producing functionalized polymers
CN101220060B (zh) * 2008-01-23 2012-08-29 中国科学院上海有机化学研究所 单茚基稀土配合物、合成方法以及应用
WO2009152772A1 (en) * 2008-06-18 2009-12-23 Dow Global Technologies Inc. Polymeric compositions, methods of making the same, and articles prepared from the same
EP2243870B1 (en) 2008-07-16 2012-10-10 Japan Exlan Co., Ltd. An antistatic acrylic fiber and a method for manufacturing the same
JP5557835B2 (ja) * 2009-03-30 2014-07-23 三井化学株式会社 オレフィンと共役ジエンとの共重合体、およびその製造方法
EP2599802B1 (en) 2010-07-30 2015-09-30 Bridgestone Corporation Copolymer of conjugated diene compounds and non-conjugated olefins, rubber composition, cross-linked rubber composition, and tyre
JP5918132B2 (ja) 2010-07-30 2016-05-18 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5918134B2 (ja) 2010-07-30 2016-05-18 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、及びタイヤ
CN103140521B (zh) * 2010-07-30 2015-07-01 株式会社普利司通 共聚物中链结构的控制方法
US9266978B2 (en) 2010-07-30 2016-02-23 Bridgestone Corporation Copolymer and method of manufacturing the same
RU2537385C2 (ru) 2010-07-30 2015-01-10 Бриджстоун Корпорейшн Сополимер, каучуковая композиция, сшитая каучуковая композиция и покрышка
CN103562301B (zh) * 2010-12-30 2017-10-20 陶氏环球技术有限责任公司 组合物、其制备方法和由其制备的制品
JP5731217B2 (ja) * 2011-02-04 2015-06-10 株式会社ブリヂストン 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5722664B2 (ja) 2011-03-01 2015-05-27 株式会社ブリヂストン 積層体
CN104169313B (zh) * 2011-12-20 2016-09-21 陶氏环球技术有限责任公司 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法
CN104583304B (zh) * 2012-06-29 2017-06-16 陶氏环球技术有限责任公司 用于热塑性硫化橡胶的乙烯/α‑烯烃/非共轭多烯基组合物
JP5902587B2 (ja) 2012-08-20 2016-04-13 株式会社ブリヂストン 共重合体の製造方法
JP6267575B2 (ja) 2014-05-02 2018-01-24 株式会社ブリヂストン マルチブロック共重合体、ゴム組成物及びタイヤ
EP3148937B1 (en) 2014-05-30 2019-09-18 Bridgestone Corporation Metallic complex catalyst and polymerization methods employing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2145612C1 (ru) * 1992-12-17 2000-02-20 Солвей Полиолефинс Юроп-Бельгия Каталитическая система, предшественник этой каталитической системы, способ получения этой каталитической системы и способ (со)полимеризации олефинов
EP2463313A1 (en) * 2009-08-07 2012-06-13 Bridgestone Corporation Method for producing copolymer
EP2599804A1 (en) * 2010-07-30 2013-06-05 Bridgestone Corporation Copolymer, rubber composition, cross-linked rubber composition, and tire
EP2671896A1 (en) * 2011-02-04 2013-12-11 Bridgestone Corporation Copolymer, rubber composition, crosslinked rubber composition, and tire

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
XU Х. et al, Indenyl Abstraction versus Alkyl Abstraction of [(Indenyl)ScR2(thf)] by [Ph3C] [B(C6F5)4]: Aspecific and Syndiospecific Styrene Polymerization, Chem. Eur. J., 2009, v. 15, p. 846-850 (реферат). *

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