RU2573899C2 - Композиции самогасящихся вспениваемых винилароматических (со)полимеров и способ их получения - Google Patents
Композиции самогасящихся вспениваемых винилароматических (со)полимеров и способ их получения Download PDFInfo
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- RU2573899C2 RU2573899C2 RU2013113928/05A RU2013113928A RU2573899C2 RU 2573899 C2 RU2573899 C2 RU 2573899C2 RU 2013113928/05 A RU2013113928/05 A RU 2013113928/05A RU 2013113928 A RU2013113928 A RU 2013113928A RU 2573899 C2 RU2573899 C2 RU 2573899C2
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 11
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- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0019—Use of organic additives halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/5205—Salts of P-acids with N-bases
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2010A001718 | 2010-09-21 | ||
| ITMI2010A001718A IT1401950B1 (it) | 2010-09-21 | 2010-09-21 | Composizioni di (co)polimeri vinilaromatici espansibili autoestinguenti e procedimento per la loro preparazione. |
| PCT/IB2011/002216 WO2012038817A2 (en) | 2010-09-21 | 2011-09-20 | Compositions of self-extinguishing expandable vinyl aromatic (co) polymers and process for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2013113928A RU2013113928A (ru) | 2014-10-27 |
| RU2573899C2 true RU2573899C2 (ru) | 2016-01-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2013113928/05A RU2573899C2 (ru) | 2010-09-21 | 2011-09-20 | Композиции самогасящихся вспениваемых винилароматических (со)полимеров и способ их получения |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9695295B2 (enExample) |
| EP (1) | EP2619263B2 (enExample) |
| JP (1) | JP6010031B2 (enExample) |
| CN (1) | CN103189432B (enExample) |
| BR (1) | BR112013006456B1 (enExample) |
| ES (1) | ES2605992T5 (enExample) |
| HU (1) | HUE032146T2 (enExample) |
| IT (1) | IT1401950B1 (enExample) |
| MX (1) | MX366211B (enExample) |
| PL (1) | PL2619263T5 (enExample) |
| RS (1) | RS55425B1 (enExample) |
| RU (1) | RU2573899C2 (enExample) |
| SI (1) | SI2619263T1 (enExample) |
| WO (1) | WO2012038817A2 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109312108A (zh) | 2016-05-11 | 2019-02-05 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| IT201700090608A1 (it) * | 2017-08-04 | 2019-02-04 | Micaela Lorenzi | Metodo ed impianto per la preparazione di una composizione polimerica antifiamma |
| JP7098754B2 (ja) * | 2018-12-27 | 2022-07-11 | 積水化成品工業株式会社 | 難燃性発泡複合樹脂粒子、その製造方法及び発泡成形体 |
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| US5010111A (en) * | 1989-08-26 | 1991-04-23 | Basf Aktiengesellschaft | Flame resistant, expandable styrene polymers and foams, and flame retardants |
| RU2283323C2 (ru) * | 2001-10-18 | 2006-09-10 | Полимери Эуропа С.П.А. | Вспениваемые винилароматические полимеры и способ их получения |
| RU2307844C2 (ru) * | 2002-03-20 | 2007-10-10 | Полимери Эуропа С.П.А. | Композиции на основе вспениваемых винилароматических полимеров с улучшенной вспениваемостью |
| WO2009135695A1 (en) * | 2008-05-07 | 2009-11-12 | Polimeri Europa S.P.A. | Compositions of expandable vinyl aromatic polymers with an improved thermal insulation capacity, process for their preparation and expanded articles obtained therefrom |
| WO2010128369A1 (en) * | 2009-05-05 | 2010-11-11 | Polimeri Europa S.P.A. | Expanded articles with excellent resistance to solar radiation and optimum thermoinsulating and mechanical properties |
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| US2857341A (en) * | 1955-12-28 | 1958-10-21 | Monsanto Chemicals | Steeping process for preparing foamable styrene polymer particles containing fatty acid compound |
| LU78663A1 (fr) | 1977-12-09 | 1979-06-13 | Labofina Sa | Compositions de resines styreniques ignifuges et leurs procedes de preparation |
| JPS6086146A (ja) * | 1983-10-19 | 1985-05-15 | Sankyo Yuki Gosei Kk | 含ハロゲン系難燃剤含有スチレン系樹脂組成物の安定化法 |
| US4769397A (en) | 1986-09-18 | 1988-09-06 | Enron Chemical Company | Chemical blowing agent compositions |
| DE3640877A1 (de) † | 1986-11-29 | 1988-06-09 | Basf Ag | Expandierbare styrolpolymerisate und styrolpolymerisat-schaumstoffe |
| DE3827238A1 (de) | 1988-08-11 | 1990-02-15 | Grimm Christian | Verfahren zur herstellung von formstuecken aus aufschaeumbarem polystyrol |
| DE3914292A1 (de) † | 1989-04-29 | 1990-10-31 | Basf Ag | Expandierbare styrolpolymerisate |
| CA2024094A1 (en) * | 1989-09-06 | 1991-03-07 | Robert A. Schleifstein | Thermally stabilized polypropylene- or styrenic polymer-based thermoplastic formulations |
| US4963606A (en) | 1989-09-06 | 1990-10-16 | Ethyl Corporation | Thermally stabilized styrenic polymer-based thermoplastic formulations |
| JPH04117443A (ja) * | 1990-09-06 | 1992-04-17 | Toray Ind Inc | 難燃性スチレン系熱可塑性樹脂組成物 |
| JPH08863B2 (ja) * | 1990-12-27 | 1996-01-10 | 積水化成品工業株式会社 | ポリスチレン系樹脂発泡体の製造方法 |
| US5445893A (en) | 1992-01-30 | 1995-08-29 | W.R. Grace & Co.-Conn | pH control polymer |
| JPH08169996A (ja) * | 1994-12-16 | 1996-07-02 | Daicel Chem Ind Ltd | 難燃性スチレン系樹脂組成物 |
| CA2295070C (en) * | 1998-04-23 | 2005-08-16 | Kaneka Corporation | Extruded styrene resin foams, and methods for producing the same |
| CN1247674C (zh) * | 1999-10-27 | 2006-03-29 | 钟渊化学工业株式会社 | 苯乙烯系树脂挤出发泡体及其制造方法 |
| DE10101432A1 (de) | 2001-01-13 | 2002-07-18 | Basf Ag | Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate |
| DE10150405A1 (de) | 2001-10-11 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| ITMI20012708A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Dispositivo per la granulazione a caldo di polimeri termolastici |
| ITMI20012706A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Procedimento per la produzione di granuli di polimeri termoplastici espandibili ed apparecchiatura adatta allo scopo |
| ITMI20030627A1 (it) | 2003-03-31 | 2004-10-01 | Polimeri Europa Spa | Polimeri vinilaromatici espandibili e procedimento per la loro preparazione. |
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-
2010
- 2010-09-21 IT ITMI2010A001718A patent/IT1401950B1/it active
-
2011
- 2011-09-20 SI SI201131042A patent/SI2619263T1/sl unknown
- 2011-09-20 MX MX2013003183A patent/MX366211B/es active IP Right Grant
- 2011-09-20 WO PCT/IB2011/002216 patent/WO2012038817A2/en not_active Ceased
- 2011-09-20 RS RS20161054A patent/RS55425B1/sr unknown
- 2011-09-20 CN CN201180045359.5A patent/CN103189432B/zh active Active
- 2011-09-20 BR BR112013006456-0A patent/BR112013006456B1/pt active IP Right Grant
- 2011-09-20 PL PL11776857.2T patent/PL2619263T5/pl unknown
- 2011-09-20 HU HUE11776857A patent/HUE032146T2/hu unknown
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- 2011-09-20 JP JP2013529724A patent/JP6010031B2/ja not_active Expired - Fee Related
- 2011-09-20 US US13/824,698 patent/US9695295B2/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5010111A (en) * | 1989-08-26 | 1991-04-23 | Basf Aktiengesellschaft | Flame resistant, expandable styrene polymers and foams, and flame retardants |
| RU2283323C2 (ru) * | 2001-10-18 | 2006-09-10 | Полимери Эуропа С.П.А. | Вспениваемые винилароматические полимеры и способ их получения |
| RU2307844C2 (ru) * | 2002-03-20 | 2007-10-10 | Полимери Эуропа С.П.А. | Композиции на основе вспениваемых винилароматических полимеров с улучшенной вспениваемостью |
| WO2009135695A1 (en) * | 2008-05-07 | 2009-11-12 | Polimeri Europa S.P.A. | Compositions of expandable vinyl aromatic polymers with an improved thermal insulation capacity, process for their preparation and expanded articles obtained therefrom |
| WO2010128369A1 (en) * | 2009-05-05 | 2010-11-11 | Polimeri Europa S.P.A. | Expanded articles with excellent resistance to solar radiation and optimum thermoinsulating and mechanical properties |
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI20101718A1 (it) | 2012-03-22 |
| CN103189432B (zh) | 2014-08-06 |
| HUE032146T2 (hu) | 2017-09-28 |
| BR112013006456A2 (pt) | 2016-07-26 |
| PL2619263T3 (pl) | 2017-06-30 |
| EP2619263B2 (en) | 2022-06-15 |
| US20130225703A1 (en) | 2013-08-29 |
| RS55425B1 (sr) | 2017-04-28 |
| PL2619263T5 (pl) | 2023-01-09 |
| SI2619263T1 (sl) | 2017-01-31 |
| BR112013006456B1 (pt) | 2020-11-03 |
| MX366211B (es) | 2019-07-02 |
| MX2013003183A (es) | 2013-07-30 |
| US9695295B2 (en) | 2017-07-04 |
| EP2619263A2 (en) | 2013-07-31 |
| JP2013537929A (ja) | 2013-10-07 |
| WO2012038817A3 (en) | 2012-11-01 |
| EP2619263B1 (en) | 2016-09-14 |
| WO2012038817A2 (en) | 2012-03-29 |
| IT1401950B1 (it) | 2013-08-28 |
| RU2013113928A (ru) | 2014-10-27 |
| JP6010031B2 (ja) | 2016-10-19 |
| ES2605992T3 (es) | 2017-03-17 |
| CN103189432A (zh) | 2013-07-03 |
| ES2605992T5 (es) | 2022-09-07 |
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