RU2534364C2 - Способ приготовления динамически вулканизованных сплавов - Google Patents
Способ приготовления динамически вулканизованных сплавов Download PDFInfo
- Publication number
- RU2534364C2 RU2534364C2 RU2010152297/04A RU2010152297A RU2534364C2 RU 2534364 C2 RU2534364 C2 RU 2534364C2 RU 2010152297/04 A RU2010152297/04 A RU 2010152297/04A RU 2010152297 A RU2010152297 A RU 2010152297A RU 2534364 C2 RU2534364 C2 RU 2534364C2
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- Prior art keywords
- elastomer
- thermoplastic resin
- melt
- mixing
- resin
- Prior art date
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7466—Combinations of similar mixers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
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- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
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- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/139,248 US8158721B2 (en) | 2008-06-13 | 2008-06-13 | Process for preparing dynamically vulcanized alloys |
| US12/139,248 | 2008-06-13 | ||
| PCT/US2009/043777 WO2009151859A1 (en) | 2008-06-13 | 2009-05-13 | Process for preparing dynamically vulcanized alloys |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010152297A RU2010152297A (ru) | 2012-07-20 |
| RU2534364C2 true RU2534364C2 (ru) | 2014-11-27 |
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ID=40848766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010152297/04A RU2534364C2 (ru) | 2008-06-13 | 2009-05-13 | Способ приготовления динамически вулканизованных сплавов |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8158721B2 (enExample) |
| EP (1) | EP2285894B1 (enExample) |
| JP (1) | JP5463353B2 (enExample) |
| CN (1) | CN102066475B (enExample) |
| CA (1) | CA2727387C (enExample) |
| RU (1) | RU2534364C2 (enExample) |
| WO (1) | WO2009151859A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150065625A1 (en) * | 2011-03-11 | 2015-03-05 | Exxonmobil Chemical Patents Inc. | Method of Forming Dynamically Vulcanized Thermoplastic Elastomer Films and Films Formed Therefrom |
| EP2574635A1 (en) | 2011-09-28 | 2013-04-03 | Lanxess Inc. | Process for continuous production of halogen-free thermoplastic elastomer compositions |
| US9975378B2 (en) | 2011-11-15 | 2018-05-22 | Bridgestone Americas Tire Operations, Llc | Rolled multilayer tire inner liner product and methods for preparing |
| US8871125B2 (en) | 2011-12-19 | 2014-10-28 | Exxonmobil Chemical Patents Inc. | Laminates of partially scorched adhesive and DVA film |
| IN2015DN00395A (enExample) * | 2012-06-19 | 2015-06-19 | Yokohama Rubber Co Ltd | |
| US9312047B2 (en) | 2012-06-22 | 2016-04-12 | Honeywell International Inc. | Method and compositions for producing polymer blends |
| WO2014099117A1 (en) | 2012-12-20 | 2014-06-26 | Exxonmobil Chemical Patents Inc. | Process for preparing dynamically vulcanized alloys |
| US10792956B2 (en) | 2013-03-15 | 2020-10-06 | Bridgestone Americas Tire Operations, Llc | Light-weight inner tube and related methods |
| JP5659288B1 (ja) | 2013-12-26 | 2015-01-28 | 東芝機械株式会社 | ポリカーボネート樹脂とアクリル樹脂を含む透明樹脂組成物の製造方法 |
| JP5668876B2 (ja) * | 2014-02-07 | 2015-02-12 | 横浜ゴム株式会社 | 熱可塑性エラストマー組成物の製造方法 |
| CN105524357B (zh) * | 2014-09-29 | 2017-12-22 | 中国石油化工股份有限公司 | 一种热塑性硫化橡胶及其制备方法 |
| CN105524361B (zh) * | 2014-09-29 | 2017-12-22 | 中国石油化工股份有限公司 | 一种热塑性硫化橡胶组合物及其制备方法和薄膜 |
| CN105524362B (zh) * | 2014-09-29 | 2017-12-22 | 中国石油化工股份有限公司 | 一种橡塑组合物的制备方法 |
| CA2907297A1 (en) * | 2014-11-04 | 2016-05-04 | Exxonmobil Chemical Patents Inc. | Method of forming dynamically vulcanized thermoplastic elastomer films and films formed therefrom |
| US11738606B2 (en) | 2014-12-16 | 2023-08-29 | Triangle Tyre Co. Ltd. | Multilayer intrinsic sealants based on ionic butyl |
| US10589478B2 (en) | 2014-12-16 | 2020-03-17 | Triangle Tyre Co. Ltd. | Pneumatic tire having sealant layer |
| US10919242B2 (en) | 2014-12-16 | 2021-02-16 | Triangle Tyre Co. Ltd. | Pneumatic tire with in-situ generated sealant composition by chain cessation of ionic butyl |
| US10399391B2 (en) | 2014-12-16 | 2019-09-03 | Triangle Tyre Co., Ltd. | Pneumatic tire having multiple built-in sealant layers and preparation thereof |
| CN106239765B (zh) * | 2016-08-05 | 2017-11-28 | 常州瑞安普新材料有限公司 | 一种连续方式制备动态硫化热塑性弹性体的方法 |
| US10875267B2 (en) | 2017-06-08 | 2020-12-29 | Exxonmobil Chemical Patents Inc. | Methods of making a film of dynamically vulcanized thermoplastic elastomeric materials |
| US11292298B2 (en) | 2017-11-10 | 2022-04-05 | Triangle Tyre Co. Ltd. | Noise damper bonded to tire using adhesives |
| JP7335483B2 (ja) * | 2018-12-26 | 2023-08-30 | 横浜ゴム株式会社 | 冷媒輸送配管用熱可塑性樹脂組成物の製造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19905292A1 (de) * | 1998-02-10 | 1999-10-21 | Sumitomo Chemical Co | Copolymermasse auf Olefinbasis |
| RU2225421C2 (ru) * | 1998-07-01 | 2004-03-10 | Эдванст Эластомер Системс, Л.П | Модификация термопластичных вулканизатов с применением статистических пропиленовых сополимеров |
| EP1897912A1 (en) * | 2006-09-08 | 2008-03-12 | Lanxess Inc. | Peroxide cured thermoplastic vulcanizates comprising butyl rubber |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4594390A (en) * | 1982-08-23 | 1986-06-10 | Monsanto Company | Process for the preparation of thermoplastic elastomers |
| US5244972A (en) * | 1987-01-16 | 1993-09-14 | General Electric Company | Single step bulk process for high impact polyester masterbatches, products thereof and blends with polyesters |
| CA1338546C (en) | 1988-05-27 | 1996-08-20 | Kenneth William Powers | Para-alkylstyrene/isoolefin copolymers |
| US6013727A (en) * | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
| JPH10292067A (ja) * | 1997-04-17 | 1998-11-04 | Yokohama Rubber Co Ltd:The | 流動性を改良した熱可塑性エラストマー組成物とその製造方法 |
| DK1537908T3 (da) | 1997-09-30 | 2012-06-18 | Cabot Corp | Blandinger af elastomersammensætning og fremgangsmåde til fremstilling deraf |
| KR100703576B1 (ko) * | 1998-01-13 | 2007-04-05 | 요코하마 고무 가부시키가이샤 | 열가소성 탄성중합체 조성물, 이의 제조방법 및 이를 사용한 공기 타이어 |
| JP3236257B2 (ja) * | 1998-01-13 | 2001-12-10 | 横浜ゴム株式会社 | 熱可塑性エラストマー組成物およびそれを使用した空気入りタイヤ |
| JP3957394B2 (ja) | 1998-04-27 | 2007-08-15 | 横浜ゴム株式会社 | 熱可塑性エラストマー組成物 |
| JP4942253B2 (ja) * | 2000-04-11 | 2012-05-30 | 横浜ゴム株式会社 | 加工性が改良された熱可塑性エラストマー組成物およびそれを用いたタイヤ |
| JP4372539B2 (ja) * | 2001-06-15 | 2009-11-25 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 熱可塑性ポリオレフィンエラストマー組成物の架橋方法 |
| US7169849B2 (en) * | 2001-06-18 | 2007-01-30 | Kuraray Co., Ltd. | Process for production of thermoplatic elastomer composition |
| EP1362681B1 (de) | 2002-06-04 | 2004-01-02 | Chemplast GmbH | Verfahren und Einrichtung zur Herstellung hochaktiver Gummipulver aus Gummiabfällen |
| CA2490046A1 (en) * | 2004-12-10 | 2006-06-10 | Lanxess Inc. | Multistage process for the manufacture of peroxide-cured hxnbr-polyamide thermoplastic vulcanizates |
| US7655728B2 (en) * | 2005-06-27 | 2010-02-02 | Exxonmobil Chemical Patents Inc. | Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders |
| US8653170B2 (en) * | 2005-06-27 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Dynamic vulcanization process for preparing thermoplastic elastomers |
| CN101296997B (zh) * | 2005-10-27 | 2011-12-07 | 埃克森美孚化学专利公司 | 低渗透性热塑性弹性体组合物 |
| US7954528B2 (en) | 2005-10-27 | 2011-06-07 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer composition and process for producing same |
| US7655727B2 (en) * | 2005-12-09 | 2010-02-02 | Exxonmobil Chemical Patents Inc. | Method for preparing thermoplastic vulcanizates with improved extrusion surfaces |
| WO2009048472A1 (en) | 2007-10-11 | 2009-04-16 | Exxonmobil Chemical Patents Inc. | Efficient mixing process for producing thermoplastic elastomer composition |
-
2008
- 2008-06-13 US US12/139,248 patent/US8158721B2/en active Active
-
2009
- 2009-05-13 RU RU2010152297/04A patent/RU2534364C2/ru active
- 2009-05-13 WO PCT/US2009/043777 patent/WO2009151859A1/en not_active Ceased
- 2009-05-13 CA CA2727387A patent/CA2727387C/en not_active Expired - Fee Related
- 2009-05-13 JP JP2011513529A patent/JP5463353B2/ja active Active
- 2009-05-13 EP EP09763150.1A patent/EP2285894B1/en not_active Not-in-force
- 2009-05-13 CN CN2009801215703A patent/CN102066475B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19905292A1 (de) * | 1998-02-10 | 1999-10-21 | Sumitomo Chemical Co | Copolymermasse auf Olefinbasis |
| RU2225421C2 (ru) * | 1998-07-01 | 2004-03-10 | Эдванст Эластомер Системс, Л.П | Модификация термопластичных вулканизатов с применением статистических пропиленовых сополимеров |
| EP1897912A1 (en) * | 2006-09-08 | 2008-03-12 | Lanxess Inc. | Peroxide cured thermoplastic vulcanizates comprising butyl rubber |
Non-Patent Citations (1)
| Title |
|---|
| ). * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2285894A1 (en) | 2011-02-23 |
| JP2011522955A (ja) | 2011-08-04 |
| JP5463353B2 (ja) | 2014-04-09 |
| EP2285894B1 (en) | 2013-06-26 |
| CN102066475A (zh) | 2011-05-18 |
| US20090312458A1 (en) | 2009-12-17 |
| RU2010152297A (ru) | 2012-07-20 |
| WO2009151859A1 (en) | 2009-12-17 |
| US8158721B2 (en) | 2012-04-17 |
| CA2727387A1 (en) | 2009-12-17 |
| CA2727387C (en) | 2013-08-13 |
| CN102066475B (zh) | 2013-07-31 |
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