RU2521042C2 - Электрохимическое устройство с твердым щелочным ионопроводящим электролитом и водным электролитом - Google Patents
Электрохимическое устройство с твердым щелочным ионопроводящим электролитом и водным электролитом Download PDFInfo
- Publication number
- RU2521042C2 RU2521042C2 RU2012121878/07A RU2012121878A RU2521042C2 RU 2521042 C2 RU2521042 C2 RU 2521042C2 RU 2012121878/07 A RU2012121878/07 A RU 2012121878/07A RU 2012121878 A RU2012121878 A RU 2012121878A RU 2521042 C2 RU2521042 C2 RU 2521042C2
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- Prior art keywords
- ceramic membrane
- water
- lithium
- electrolyte
- polymer
- Prior art date
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- 239000012528 membrane Substances 0.000 claims abstract description 55
- 239000000919 ceramic Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 150000001768 cations Chemical class 0.000 claims abstract description 18
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 16
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 7
- 229920000867 polyelectrolyte Polymers 0.000 claims abstract description 6
- 239000011244 liquid electrolyte Substances 0.000 claims abstract description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 23
- 229920000620 organic polymer Polymers 0.000 claims description 18
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 11
- 125000002091 cationic group Chemical group 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 6
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 6
- 229910019385 NaPON Inorganic materials 0.000 claims description 5
- 239000011253 protective coating Substances 0.000 claims description 5
- 229920001940 conductive polymer Polymers 0.000 claims description 4
- FZRNJOXQNWVMIH-UHFFFAOYSA-N lithium;hydrate Chemical compound [Li].O FZRNJOXQNWVMIH-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 102000005393 Sodium-Potassium-Exchanging ATPase Human genes 0.000 claims description 3
- 108010006431 Sodium-Potassium-Exchanging ATPase Proteins 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 229910052693 Europium Inorganic materials 0.000 claims description 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 2
- 229910005700 Ge 1-y Ti Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229910052771 Terbium Inorganic materials 0.000 claims description 2
- 229910052775 Thulium Inorganic materials 0.000 claims description 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229920002313 fluoropolymer Polymers 0.000 claims description 2
- 239000004811 fluoropolymer Substances 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 33
- 239000003792 electrolyte Substances 0.000 abstract description 26
- 230000000694 effects Effects 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 52
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 29
- 229910001416 lithium ion Inorganic materials 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 229910010293 ceramic material Inorganic materials 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229910001415 sodium ion Inorganic materials 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 230000008021 deposition Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000002226 superionic conductor Substances 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000002200 LIPON - lithium phosphorus oxynitride Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002241 glass-ceramic Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- -1 hydroxide ions Chemical class 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/185—Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/187—Solid electrolyte characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/24—Cells comprising two different electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0094—Composites in the form of layered products, e.g. coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/188—Processes of manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Conductive Materials (AREA)
- Primary Cells (AREA)
- Silicon Compounds (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0957528A FR2951714B1 (fr) | 2009-10-27 | 2009-10-27 | Dispositif electrochimique a electrolyte solide conducteur d'ions alcalins et a electrolyte aqueux |
| FR0957528 | 2009-10-27 | ||
| PCT/FR2010/052246 WO2011051597A1 (fr) | 2009-10-27 | 2010-10-21 | Dispositif électrochimique à électrolyte solide conducteur d'ions alcalins et à électrolyte aqueux |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012121878A RU2012121878A (ru) | 2013-12-10 |
| RU2521042C2 true RU2521042C2 (ru) | 2014-06-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012121878/07A RU2521042C2 (ru) | 2009-10-27 | 2010-10-21 | Электрохимическое устройство с твердым щелочным ионопроводящим электролитом и водным электролитом |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9178221B2 (enExample) |
| EP (1) | EP2494638B1 (enExample) |
| JP (1) | JP5643830B2 (enExample) |
| KR (1) | KR101342677B1 (enExample) |
| CN (1) | CN102598378B (enExample) |
| BR (1) | BR112012010050B1 (enExample) |
| FR (1) | FR2951714B1 (enExample) |
| IN (1) | IN2012DN03378A (enExample) |
| RU (1) | RU2521042C2 (enExample) |
| WO (1) | WO2011051597A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2693853C1 (ru) * | 2018-01-09 | 2019-07-05 | Тойота Дзидося Кабусики Кайся | Водный электролитический раствор и водная литий-ионная аккумуляторная батарея |
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| KR101861212B1 (ko) | 2010-09-09 | 2018-06-29 | 캘리포니아 인스티튜트 오브 테크놀로지 | 전기화학적 에너지 저장 시스템 및 방법 |
| JP5691875B2 (ja) * | 2011-06-20 | 2015-04-01 | アイシン精機株式会社 | 水系リチウム−空気二次電池 |
| US9379368B2 (en) | 2011-07-11 | 2016-06-28 | California Institute Of Technology | Electrochemical systems with electronically conductive layers |
| US10158110B2 (en) | 2011-07-11 | 2018-12-18 | California Institute Of Technology | Separators for electrochemical systems |
| GB2495279A (en) * | 2011-09-30 | 2013-04-10 | Faradion Ltd | A condensed polyanion electrode material |
| FR2982427B1 (fr) | 2011-11-09 | 2013-12-20 | Electricite De France | Electrolyte aqueux pour batterie lithium-air |
| JP2013149452A (ja) * | 2012-01-19 | 2013-08-01 | Nissan Motor Co Ltd | 空気電池 |
| KR102392086B1 (ko) | 2012-04-10 | 2022-04-28 | 캘리포니아 인스티튜트 오브 테크놀로지 | 전기화학 시스템들용 신규 세퍼레이터들 |
| US10164284B2 (en) | 2012-07-27 | 2018-12-25 | Lockheed Martin Energy, Llc | Aqueous redox flow batteries featuring improved cell design characteristics |
| US9865893B2 (en) | 2012-07-27 | 2018-01-09 | Lockheed Martin Advanced Energy Storage, Llc | Electrochemical energy storage systems and methods featuring optimal membrane systems |
| US9559374B2 (en) | 2012-07-27 | 2017-01-31 | Lockheed Martin Advanced Energy Storage, Llc | Electrochemical energy storage systems and methods featuring large negative half-cell potentials |
| US9768463B2 (en) | 2012-07-27 | 2017-09-19 | Lockheed Martin Advanced Energy Storage, Llc | Aqueous redox flow batteries comprising metal ligand coordination compounds |
| US9382274B2 (en) | 2012-07-27 | 2016-07-05 | Lockheed Martin Advanced Energy Storage, Llc | Aqueous redox flow batteries featuring improved cell design characteristics |
| US9899694B2 (en) | 2012-07-27 | 2018-02-20 | Lockheed Martin Advanced Energy Storage, Llc | Electrochemical energy storage systems and methods featuring high open circuit potential |
| EP2883268B1 (en) | 2012-08-08 | 2016-11-23 | Robert Bosch GmbH | Metal/air flow battery |
| JP2015222613A (ja) * | 2012-09-11 | 2015-12-10 | 国立大学法人東京工業大学 | 金属Ｎａ電池 |
| WO2014182251A1 (en) * | 2013-05-10 | 2014-11-13 | Nanyang Technological University | Electrolyte membrane for liquid anode cell battery |
| US20150014184A1 (en) * | 2013-07-10 | 2015-01-15 | Lawence Ralph Swonger | Producing lithium |
| US10714724B2 (en) | 2013-11-18 | 2020-07-14 | California Institute Of Technology | Membranes for electrochemical cells |
| US20150171398A1 (en) | 2013-11-18 | 2015-06-18 | California Institute Of Technology | Electrochemical separators with inserted conductive layers |
| MX2017004888A (es) | 2014-11-26 | 2017-07-27 | Lockheed Martin Advanced Energy Storage Llc | Complejos de metales de catecolatos sustituidos y baterias de flujo redox que los contienen. |
| US10253051B2 (en) | 2015-03-16 | 2019-04-09 | Lockheed Martin Energy, Llc | Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride |
| KR101747402B1 (ko) | 2015-10-12 | 2017-06-14 | 주식회사 엘지화학 | 전기화학소자용 전극, 이의 제조 방법, 및 이를 포함하는 전기화학 소자 |
| US10340528B2 (en) | 2015-12-02 | 2019-07-02 | California Institute Of Technology | Three-dimensional ion transport networks and current collectors for electrochemical cells |
| US10644342B2 (en) | 2016-03-03 | 2020-05-05 | Lockheed Martin Energy, Llc | Coordination complexes containing monosulfonated catecholate ligands and methods for producing the same |
| US10316047B2 (en) | 2016-03-03 | 2019-06-11 | Lockheed Martin Energy, Llc | Processes for forming coordination complexes containing monosulfonated catecholate ligands |
| US9938308B2 (en) | 2016-04-07 | 2018-04-10 | Lockheed Martin Energy, Llc | Coordination compounds having redox non-innocent ligands and flow batteries containing the same |
| DE102016212736A1 (de) * | 2016-07-13 | 2018-01-18 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung eines Festkörperelektrolyten, Festkörperelektrolyt und Lithiumionenbatterie |
| US10343964B2 (en) | 2016-07-26 | 2019-07-09 | Lockheed Martin Energy, Llc | Processes for forming titanium catechol complexes |
| US10377687B2 (en) | 2016-07-26 | 2019-08-13 | Lockheed Martin Energy, Llc | Processes for forming titanium catechol complexes |
| US10065977B2 (en) | 2016-10-19 | 2018-09-04 | Lockheed Martin Advanced Energy Storage, Llc | Concerted processes for forming 1,2,4-trihydroxybenzene from hydroquinone |
| US10930937B2 (en) | 2016-11-23 | 2021-02-23 | Lockheed Martin Energy, Llc | Flow batteries incorporating active materials containing doubly bridged aromatic groups |
| CN108172953A (zh) * | 2016-12-07 | 2018-06-15 | 中国科学院大连化学物理研究所 | 一种锌空气电池及锌空气电池组 |
| US10497958B2 (en) | 2016-12-14 | 2019-12-03 | Lockheed Martin Energy, Llc | Coordinatively unsaturated titanium catecholate complexes and processes associated therewith |
| US10741864B2 (en) | 2016-12-30 | 2020-08-11 | Lockheed Martin Energy, Llc | Aqueous methods for forming titanium catecholate complexes and associated compositions |
| US10320023B2 (en) | 2017-02-16 | 2019-06-11 | Lockheed Martin Energy, Llc | Neat methods for forming titanium catecholate complexes and associated compositions |
| JP6383038B1 (ja) * | 2017-03-22 | 2018-08-29 | 株式会社東芝 | 二次電池、電池パック及び車両 |
| WO2018193630A1 (ja) * | 2017-04-21 | 2018-10-25 | 日立化成株式会社 | 電気化学デバイス用電極及び電気化学デバイス |
| CN109428138B (zh) * | 2017-08-24 | 2020-12-01 | 上海交通大学 | 锂空气电池的制备方法及锂空气电池 |
| WO2019055730A1 (en) | 2017-09-14 | 2019-03-21 | Ampcera Inc. | SYSTEMS AND METHODS FOR SELECTIVE EXTRACTION OF ALKALI METALS FROM RICH METAL SOLUTIONS USING SOLID STATE ION CONDUCTIVE ELECTROLYTIC MEMBRANE |
| KR102602422B1 (ko) * | 2018-10-11 | 2023-11-14 | 현대자동차주식회사 | 리튬공기전지 및 그 제조방법 |
| EP3900097A1 (en) | 2018-12-21 | 2021-10-27 | Solvay Sa | Solid composite electrolyte |
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| EP1088796A1 (en) * | 1998-07-16 | 2001-04-04 | Kabushiki Kaisha Ohara | Lithium ion conductive glass-ceramics and electric cells and gas sensor using the same |
| RU2186442C2 (ru) * | 1995-12-28 | 2002-07-27 | Миллениум Селл, Инк., | Электропреобразовательная ячейка |
| RU2323506C2 (ru) * | 2002-10-25 | 2008-04-27 | Пирелли Энд К. С.П.А. | Твердооксидный топливный элемент с керамическим анодом |
| RU2335482C2 (ru) * | 2002-07-30 | 2008-10-10 | С.К.П.С. Сосьете де Консей э де Проспектив Сьентифик С.А. | Цинковый анод |
| RU2352029C2 (ru) * | 2004-07-27 | 2009-04-10 | Оксис Энерджи Лимитед | Электрод, способ его изготовления и содержащая его аккумуляторная батарея |
| RU2370858C2 (ru) * | 2004-04-15 | 2009-10-20 | Фмк Корпорейшн | Композиционные материалы нанодисперсных кремния и олова и способы их получения |
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| US20080057386A1 (en) * | 2002-10-15 | 2008-03-06 | Polyplus Battery Company | Ionically conductive membranes for protection of active metal anodes and battery cells |
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| US7282295B2 (en) * | 2004-02-06 | 2007-10-16 | Polyplus Battery Company | Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture |
| US20080070087A1 (en) * | 2004-02-20 | 2008-03-20 | Excellatron Solid State, Llc | Non-volatile cathodes for lithium oxygen batteries and method of producing same |
| US8048570B2 (en) * | 2005-08-09 | 2011-11-01 | Polyplus Battery Company | Compliant seal structures for protected active metal anodes |
| JP2009181872A (ja) * | 2008-01-31 | 2009-08-13 | Ohara Inc | リチウムイオン二次電池およびその製造方法 |
| CN100595960C (zh) * | 2008-07-22 | 2010-03-24 | 山东东岳神舟新材料有限公司 | 一种微孔膜增强的多层含氟交联离子膜及其制备方法 |
| JP5271668B2 (ja) * | 2008-10-31 | 2013-08-21 | 株式会社オハラ | 金属／水電池又は金属／空気電池 |
-
2009
- 2009-10-27 FR FR0957528A patent/FR2951714B1/fr active Active
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2010
- 2010-10-21 KR KR1020127011076A patent/KR101342677B1/ko active Active
- 2010-10-21 JP JP2012535898A patent/JP5643830B2/ja active Active
- 2010-10-21 US US13/499,394 patent/US9178221B2/en active Active
- 2010-10-21 RU RU2012121878/07A patent/RU2521042C2/ru active
- 2010-10-21 WO PCT/FR2010/052246 patent/WO2011051597A1/fr not_active Ceased
- 2010-10-21 CN CN201080048653.7A patent/CN102598378B/zh active Active
- 2010-10-21 EP EP10785154.5A patent/EP2494638B1/fr active Active
- 2010-10-21 IN IN3378DEN2012 patent/IN2012DN03378A/en unknown
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|---|---|---|---|---|
| RU2186442C2 (ru) * | 1995-12-28 | 2002-07-27 | Миллениум Селл, Инк., | Электропреобразовательная ячейка |
| EP1088796A1 (en) * | 1998-07-16 | 2001-04-04 | Kabushiki Kaisha Ohara | Lithium ion conductive glass-ceramics and electric cells and gas sensor using the same |
| RU2335482C2 (ru) * | 2002-07-30 | 2008-10-10 | С.К.П.С. Сосьете де Консей э де Проспектив Сьентифик С.А. | Цинковый анод |
| RU2323506C2 (ru) * | 2002-10-25 | 2008-04-27 | Пирелли Энд К. С.П.А. | Твердооксидный топливный элемент с керамическим анодом |
| RU2370858C2 (ru) * | 2004-04-15 | 2009-10-20 | Фмк Корпорейшн | Композиционные материалы нанодисперсных кремния и олова и способы их получения |
| RU2352029C2 (ru) * | 2004-07-27 | 2009-04-10 | Оксис Энерджи Лимитед | Электрод, способ его изготовления и содержащая его аккумуляторная батарея |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| RU2693853C1 (ru) * | 2018-01-09 | 2019-07-05 | Тойота Дзидося Кабусики Кайся | Водный электролитический раствор и водная литий-ионная аккумуляторная батарея |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20120092119A (ko) | 2012-08-20 |
| EP2494638A1 (fr) | 2012-09-05 |
| BR112012010050A2 (pt) | 2016-05-24 |
| RU2012121878A (ru) | 2013-12-10 |
| FR2951714A1 (fr) | 2011-04-29 |
| CN102598378A (zh) | 2012-07-18 |
| BR112012010050B1 (pt) | 2019-12-03 |
| IN2012DN03378A (enExample) | 2015-10-23 |
| CN102598378B (zh) | 2016-12-21 |
| KR101342677B1 (ko) | 2013-12-17 |
| EP2494638B1 (fr) | 2016-05-04 |
| US20120183868A1 (en) | 2012-07-19 |
| FR2951714B1 (fr) | 2013-05-24 |
| JP2013508930A (ja) | 2013-03-07 |
| WO2011051597A1 (fr) | 2011-05-05 |
| US9178221B2 (en) | 2015-11-03 |
| JP5643830B2 (ja) | 2014-12-17 |
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