BR112012010050B1 - dispositivo eletroquímico tendo um eletrólito alcalino condutor de íon sólido e um eletrólito aquoso. - Google Patents
dispositivo eletroquímico tendo um eletrólito alcalino condutor de íon sólido e um eletrólito aquoso. Download PDFInfo
- Publication number
- BR112012010050B1 BR112012010050B1 BR112012010050A BR112012010050A BR112012010050B1 BR 112012010050 B1 BR112012010050 B1 BR 112012010050B1 BR 112012010050 A BR112012010050 A BR 112012010050A BR 112012010050 A BR112012010050 A BR 112012010050A BR 112012010050 B1 BR112012010050 B1 BR 112012010050B1
- Authority
- BR
- Brazil
- Prior art keywords
- fact
- ceramic membrane
- electrochemical device
- lithium
- polymer
- Prior art date
Links
- 239000003792 electrolyte Substances 0.000 title abstract description 30
- 239000007787 solid Substances 0.000 title abstract description 5
- 239000012528 membrane Substances 0.000 claims abstract description 62
- 239000000919 ceramic Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 16
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 12
- 239000011244 liquid electrolyte Substances 0.000 claims abstract description 4
- 229920000642 polymer Polymers 0.000 claims description 32
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 23
- 229910052744 lithium Inorganic materials 0.000 claims description 20
- 229920000620 organic polymer Polymers 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 14
- 239000002322 conducting polymer Substances 0.000 claims description 14
- 229920001940 conductive polymer Polymers 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 238000005868 electrolysis reaction Methods 0.000 claims description 7
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 6
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 6
- 239000011253 protective coating Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 229910019385 NaPON Inorganic materials 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- -1 alkali metal cations Chemical class 0.000 claims description 4
- FZRNJOXQNWVMIH-UHFFFAOYSA-N lithium;hydrate Chemical group [Li].O FZRNJOXQNWVMIH-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229910052771 Terbium Inorganic materials 0.000 claims description 2
- 229910052775 Thulium Inorganic materials 0.000 claims description 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229920002313 fluoropolymer Polymers 0.000 claims description 2
- 239000004811 fluoropolymer Substances 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052693 Europium Inorganic materials 0.000 claims 1
- 229910005932 Ge1−yTiy Inorganic materials 0.000 claims 1
- 229910004675 Na1+xZr2SixP3-xO12 Inorganic materials 0.000 claims 1
- 229910004678 Na1+xZr2SixP3−xO12 Inorganic materials 0.000 claims 1
- 229910006067 SO3−M Inorganic materials 0.000 claims 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims 1
- IDBFBDSKYCUNPW-UHFFFAOYSA-N lithium nitride Chemical compound [Li]N([Li])[Li] IDBFBDSKYCUNPW-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 abstract description 16
- 150000002500 ions Chemical class 0.000 abstract description 5
- 229920000867 polyelectrolyte Polymers 0.000 abstract description 5
- 150000002892 organic cations Chemical class 0.000 abstract description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Inorganic materials [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 51
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 29
- 239000003570 air Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910001416 lithium ion Inorganic materials 0.000 description 7
- 239000002227 LISICON Substances 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 229910001415 sodium ion Inorganic materials 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000557 Nafion® Polymers 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 102000005393 Sodium-Potassium-Exchanging ATPase Human genes 0.000 description 2
- 108010006431 Sodium-Potassium-Exchanging ATPase Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002241 glass-ceramic Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002226 superionic conductor Substances 0.000 description 2
- BHZCMUVGYXEBMY-UHFFFAOYSA-N trilithium;azanide Chemical compound [Li+].[Li+].[Li+].[NH2-] BHZCMUVGYXEBMY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/185—Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/187—Solid electrolyte characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/24—Cells comprising two different electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0094—Composites in the form of layered products, e.g. coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/188—Processes of manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Conductive Materials (AREA)
- Silicon Compounds (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0957528A FR2951714B1 (fr) | 2009-10-27 | 2009-10-27 | Dispositif electrochimique a electrolyte solide conducteur d'ions alcalins et a electrolyte aqueux |
| PCT/FR2010/052246 WO2011051597A1 (fr) | 2009-10-27 | 2010-10-21 | Dispositif électrochimique à électrolyte solide conducteur d'ions alcalins et à électrolyte aqueux |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012010050A2 BR112012010050A2 (pt) | 2016-05-24 |
| BR112012010050B1 true BR112012010050B1 (pt) | 2019-12-03 |
Family
ID=42236607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012010050A BR112012010050B1 (pt) | 2009-10-27 | 2010-10-21 | dispositivo eletroquímico tendo um eletrólito alcalino condutor de íon sólido e um eletrólito aquoso. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9178221B2 (enExample) |
| EP (1) | EP2494638B1 (enExample) |
| JP (1) | JP5643830B2 (enExample) |
| KR (1) | KR101342677B1 (enExample) |
| CN (1) | CN102598378B (enExample) |
| BR (1) | BR112012010050B1 (enExample) |
| FR (1) | FR2951714B1 (enExample) |
| IN (1) | IN2012DN03378A (enExample) |
| RU (1) | RU2521042C2 (enExample) |
| WO (1) | WO2011051597A1 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6138687B2 (ja) | 2010-09-09 | 2017-05-31 | カリフォルニア インスティチュート オブ テクノロジー | 電気化学エネルギー貯蔵システム及びその方法 |
| JP5691875B2 (ja) * | 2011-06-20 | 2015-04-01 | アイシン精機株式会社 | 水系リチウム−空気二次電池 |
| CN103650204B (zh) | 2011-07-11 | 2016-11-16 | 加州理工学院 | 用于电化学系统的新颖分隔物 |
| US9379368B2 (en) | 2011-07-11 | 2016-06-28 | California Institute Of Technology | Electrochemical systems with electronically conductive layers |
| GB2495279A (en) * | 2011-09-30 | 2013-04-10 | Faradion Ltd | A condensed polyanion electrode material |
| FR2982427B1 (fr) | 2011-11-09 | 2013-12-20 | Electricite De France | Electrolyte aqueux pour batterie lithium-air |
| JP2013149452A (ja) * | 2012-01-19 | 2013-08-01 | Nissan Motor Co Ltd | 空気電池 |
| EP3951967A1 (en) | 2012-04-10 | 2022-02-09 | California Institute of Technology | Novel separators for electrochemical systems |
| US9865893B2 (en) | 2012-07-27 | 2018-01-09 | Lockheed Martin Advanced Energy Storage, Llc | Electrochemical energy storage systems and methods featuring optimal membrane systems |
| US9768463B2 (en) | 2012-07-27 | 2017-09-19 | Lockheed Martin Advanced Energy Storage, Llc | Aqueous redox flow batteries comprising metal ligand coordination compounds |
| US9899694B2 (en) | 2012-07-27 | 2018-02-20 | Lockheed Martin Advanced Energy Storage, Llc | Electrochemical energy storage systems and methods featuring high open circuit potential |
| US10164284B2 (en) | 2012-07-27 | 2018-12-25 | Lockheed Martin Energy, Llc | Aqueous redox flow batteries featuring improved cell design characteristics |
| US9559374B2 (en) | 2012-07-27 | 2017-01-31 | Lockheed Martin Advanced Energy Storage, Llc | Electrochemical energy storage systems and methods featuring large negative half-cell potentials |
| US9382274B2 (en) | 2012-07-27 | 2016-07-05 | Lockheed Martin Advanced Energy Storage, Llc | Aqueous redox flow batteries featuring improved cell design characteristics |
| EP2883268B1 (en) | 2012-08-08 | 2016-11-23 | Robert Bosch GmbH | Metal/air flow battery |
| JP2015222613A (ja) * | 2012-09-11 | 2015-12-10 | 国立大学法人東京工業大学 | 金属Ｎａ電池 |
| WO2014182251A1 (en) * | 2013-05-10 | 2014-11-13 | Nanyang Technological University | Electrolyte membrane for liquid anode cell battery |
| US20150014184A1 (en) * | 2013-07-10 | 2015-01-15 | Lawence Ralph Swonger | Producing lithium |
| US10714724B2 (en) | 2013-11-18 | 2020-07-14 | California Institute Of Technology | Membranes for electrochemical cells |
| US9991492B2 (en) | 2013-11-18 | 2018-06-05 | California Institute Of Technology | Separator enclosures for electrodes and electrochemical cells |
| MX2017004888A (es) | 2014-11-26 | 2017-07-27 | Lockheed Martin Advanced Energy Storage Llc | Complejos de metales de catecolatos sustituidos y baterias de flujo redox que los contienen. |
| US10253051B2 (en) | 2015-03-16 | 2019-04-09 | Lockheed Martin Energy, Llc | Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride |
| KR101747402B1 (ko) | 2015-10-12 | 2017-06-14 | 주식회사 엘지화학 | 전기화학소자용 전극, 이의 제조 방법, 및 이를 포함하는 전기화학 소자 |
| WO2017096258A1 (en) | 2015-12-02 | 2017-06-08 | California Institute Of Technology | Three-dimensional ion transport networks and current collectors for electrochemical cells |
| US10316047B2 (en) | 2016-03-03 | 2019-06-11 | Lockheed Martin Energy, Llc | Processes for forming coordination complexes containing monosulfonated catecholate ligands |
| US10644342B2 (en) | 2016-03-03 | 2020-05-05 | Lockheed Martin Energy, Llc | Coordination complexes containing monosulfonated catecholate ligands and methods for producing the same |
| US9938308B2 (en) | 2016-04-07 | 2018-04-10 | Lockheed Martin Energy, Llc | Coordination compounds having redox non-innocent ligands and flow batteries containing the same |
| DE102016212736A1 (de) * | 2016-07-13 | 2018-01-18 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung eines Festkörperelektrolyten, Festkörperelektrolyt und Lithiumionenbatterie |
| US10377687B2 (en) | 2016-07-26 | 2019-08-13 | Lockheed Martin Energy, Llc | Processes for forming titanium catechol complexes |
| US10343964B2 (en) | 2016-07-26 | 2019-07-09 | Lockheed Martin Energy, Llc | Processes for forming titanium catechol complexes |
| US10065977B2 (en) | 2016-10-19 | 2018-09-04 | Lockheed Martin Advanced Energy Storage, Llc | Concerted processes for forming 1,2,4-trihydroxybenzene from hydroquinone |
| US10930937B2 (en) | 2016-11-23 | 2021-02-23 | Lockheed Martin Energy, Llc | Flow batteries incorporating active materials containing doubly bridged aromatic groups |
| CN108172953A (zh) * | 2016-12-07 | 2018-06-15 | 中国科学院大连化学物理研究所 | 一种锌空气电池及锌空气电池组 |
| US10497958B2 (en) | 2016-12-14 | 2019-12-03 | Lockheed Martin Energy, Llc | Coordinatively unsaturated titanium catecholate complexes and processes associated therewith |
| US10741864B2 (en) | 2016-12-30 | 2020-08-11 | Lockheed Martin Energy, Llc | Aqueous methods for forming titanium catecholate complexes and associated compositions |
| US10320023B2 (en) | 2017-02-16 | 2019-06-11 | Lockheed Martin Energy, Llc | Neat methods for forming titanium catecholate complexes and associated compositions |
| JP6383038B1 (ja) * | 2017-03-22 | 2018-08-29 | 株式会社東芝 | 二次電池、電池パック及び車両 |
| WO2018193630A1 (ja) * | 2017-04-21 | 2018-10-25 | 日立化成株式会社 | 電気化学デバイス用電極及び電気化学デバイス |
| CN109428138B (zh) * | 2017-08-24 | 2020-12-01 | 上海交通大学 | 锂空气电池的制备方法及锂空气电池 |
| WO2019055730A1 (en) | 2017-09-14 | 2019-03-21 | Ampcera Inc. | SYSTEMS AND METHODS FOR SELECTIVE EXTRACTION OF ALKALI METALS FROM RICH METAL SOLUTIONS USING SOLID STATE ION CONDUCTIVE ELECTROLYTIC MEMBRANE |
| JP6911774B2 (ja) * | 2018-01-09 | 2021-07-28 | トヨタ自動車株式会社 | 水系電解液及び水系リチウムイオン二次電池 |
| KR102602422B1 (ko) * | 2018-10-11 | 2023-11-14 | 현대자동차주식회사 | 리튬공기전지 및 그 제조방법 |
| JP2022514278A (ja) | 2018-12-21 | 2022-02-10 | ソルヴェイ（ソシエテ アノニム） | 固体複合電解質 |
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| US4057675A (en) | 1974-02-19 | 1977-11-08 | Lockheed Missiles & Space Company, Inc. | Electrochemical cell |
| JPS601768A (ja) * | 1983-06-20 | 1985-01-07 | Hitachi Ltd | 複数のイオン伝導層を用いた固体電池 |
| US5804329A (en) * | 1995-12-28 | 1998-09-08 | National Patent Development Corporation | Electroconversion cell |
| JP4745472B2 (ja) | 1998-07-16 | 2011-08-10 | 株式会社オハラ | リチウムイオン伝導性ガラスセラミックスおよびこれを用いた電池、ガスセンサー |
| US7070632B1 (en) * | 2001-07-25 | 2006-07-04 | Polyplus Battery Company | Electrochemical device separator structures with barrier layer on non-swelling membrane |
| JP4783537B2 (ja) * | 2002-05-20 | 2011-09-28 | 財団法人電力中央研究所 | 二次電池 |
| FR2843235B1 (fr) * | 2002-07-30 | 2006-07-28 | Conseil Et De Prospective Scie | Ceramique conductrice pretraitee par oxydation pour anode de zinc de generateurs electrochimiques secondaires alcalins |
| US20080057386A1 (en) * | 2002-10-15 | 2008-03-06 | Polyplus Battery Company | Ionically conductive membranes for protection of active metal anodes and battery cells |
| WO2004049491A1 (en) * | 2002-10-25 | 2004-06-10 | Antonino Salvatore Arico | SOLID OXIDE FUEL CELL WITH CERMET Cu/Ni ALLOY ANODE |
| KR100509298B1 (ko) * | 2003-05-31 | 2005-08-22 | 한국과학기술연구원 | 무기질 박막이 코팅된 직접메탄올 연료전지용 복합고분자 전해질막의 제조 방법 |
| US7282295B2 (en) * | 2004-02-06 | 2007-10-16 | Polyplus Battery Company | Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture |
| US20080070087A1 (en) * | 2004-02-20 | 2008-03-20 | Excellatron Solid State, Llc | Non-volatile cathodes for lithium oxygen batteries and method of producing same |
| US8231810B2 (en) * | 2004-04-15 | 2012-07-31 | Fmc Corporation | Composite materials of nano-dispersed silicon and tin and methods of making the same |
| GB2412484B (en) * | 2004-07-27 | 2006-03-22 | Intellikraft Ltd | Improvements relating to electrode structures in batteries |
| US8048570B2 (en) * | 2005-08-09 | 2011-11-01 | Polyplus Battery Company | Compliant seal structures for protected active metal anodes |
| JP2009181872A (ja) * | 2008-01-31 | 2009-08-13 | Ohara Inc | リチウムイオン二次電池およびその製造方法 |
| CN100595960C (zh) * | 2008-07-22 | 2010-03-24 | 山东东岳神舟新材料有限公司 | 一种微孔膜增强的多层含氟交联离子膜及其制备方法 |
| JP5271668B2 (ja) * | 2008-10-31 | 2013-08-21 | 株式会社オハラ | 金属／水電池又は金属／空気電池 |
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2009
- 2009-10-27 FR FR0957528A patent/FR2951714B1/fr active Active
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2010
- 2010-10-21 WO PCT/FR2010/052246 patent/WO2011051597A1/fr not_active Ceased
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- 2010-10-21 EP EP10785154.5A patent/EP2494638B1/fr active Active
- 2010-10-21 KR KR1020127011076A patent/KR101342677B1/ko active Active
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- 2010-10-21 BR BR112012010050A patent/BR112012010050B1/pt active IP Right Grant
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- 2010-10-21 JP JP2012535898A patent/JP5643830B2/ja active Active
- 2010-10-21 CN CN201080048653.7A patent/CN102598378B/zh active Active
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| WO2011051597A1 (fr) | 2011-05-05 |
| EP2494638A1 (fr) | 2012-09-05 |
| KR101342677B1 (ko) | 2013-12-17 |
| EP2494638B1 (fr) | 2016-05-04 |
| IN2012DN03378A (enExample) | 2015-10-23 |
| RU2012121878A (ru) | 2013-12-10 |
| US20120183868A1 (en) | 2012-07-19 |
| JP2013508930A (ja) | 2013-03-07 |
| JP5643830B2 (ja) | 2014-12-17 |
| CN102598378B (zh) | 2016-12-21 |
| CN102598378A (zh) | 2012-07-18 |
| FR2951714A1 (fr) | 2011-04-29 |
| KR20120092119A (ko) | 2012-08-20 |
| RU2521042C2 (ru) | 2014-06-27 |
| US9178221B2 (en) | 2015-11-03 |
| FR2951714B1 (fr) | 2013-05-24 |
| BR112012010050A2 (pt) | 2016-05-24 |
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