CN102598378B - 具有固体的碱性离子传导电解质和水性电解质的电化学装置 - Google Patents

具有固体的碱性离子传导电解质和水性电解质的电化学装置 Download PDF

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CN102598378B
CN102598378B CN201080048653.7A CN201080048653A CN102598378B CN 102598378 B CN102598378 B CN 102598378B CN 201080048653 A CN201080048653 A CN 201080048653A CN 102598378 B CN102598378 B CN 102598378B
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ceramic membrane
lithium
polymer
organic cation
conducting polymer
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CN102598378A (zh
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G·图桑
P·史蒂文斯
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Electricite de France SA
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/185—Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/26—Selection of materials as electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/187—Solid electrolyte characterised by the form
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/24—Cells comprising two different electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0094—Composites in the form of layered products, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/188—Processes of manufacture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hybrid Cells (AREA)
  • Conductive Materials (AREA)
  • Primary Cells (AREA)
  • Silicon Compounds (AREA)
  • Secondary Cells (AREA)
CN201080048653.7A 2009-10-27 2010-10-21 具有固体的碱性离子传导电解质和水性电解质的电化学装置 Active CN102598378B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0957528A FR2951714B1 (fr) 2009-10-27 2009-10-27 Dispositif electrochimique a electrolyte solide conducteur d'ions alcalins et a electrolyte aqueux
FR0957528 2009-10-27
PCT/FR2010/052246 WO2011051597A1 (fr) 2009-10-27 2010-10-21 Dispositif électrochimique à électrolyte solide conducteur d'ions alcalins et à électrolyte aqueux

Publications (2)

Publication Number Publication Date
CN102598378A CN102598378A (zh) 2012-07-18
CN102598378B true CN102598378B (zh) 2016-12-21

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Country Link
US (1) US9178221B2 (enExample)
EP (1) EP2494638B1 (enExample)
JP (1) JP5643830B2 (enExample)
KR (1) KR101342677B1 (enExample)
CN (1) CN102598378B (enExample)
BR (1) BR112012010050B1 (enExample)
FR (1) FR2951714B1 (enExample)
IN (1) IN2012DN03378A (enExample)
RU (1) RU2521042C2 (enExample)
WO (1) WO2011051597A1 (enExample)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101861212B1 (ko) 2010-09-09 2018-06-29 캘리포니아 인스티튜트 오브 테크놀로지 전기화학적 에너지 저장 시스템 및 방법
JP5691875B2 (ja) * 2011-06-20 2015-04-01 アイシン精機株式会社 水系リチウム−空気二次電池
US9379368B2 (en) 2011-07-11 2016-06-28 California Institute Of Technology Electrochemical systems with electronically conductive layers
US10158110B2 (en) 2011-07-11 2018-12-18 California Institute Of Technology Separators for electrochemical systems
GB2495279A (en) * 2011-09-30 2013-04-10 Faradion Ltd A condensed polyanion electrode material
FR2982427B1 (fr) 2011-11-09 2013-12-20 Electricite De France Electrolyte aqueux pour batterie lithium-air
JP2013149452A (ja) * 2012-01-19 2013-08-01 Nissan Motor Co Ltd 空気電池
KR102392086B1 (ko) 2012-04-10 2022-04-28 캘리포니아 인스티튜트 오브 테크놀로지 전기화학 시스템들용 신규 세퍼레이터들
US10164284B2 (en) 2012-07-27 2018-12-25 Lockheed Martin Energy, Llc Aqueous redox flow batteries featuring improved cell design characteristics
US9865893B2 (en) 2012-07-27 2018-01-09 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring optimal membrane systems
US9559374B2 (en) 2012-07-27 2017-01-31 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring large negative half-cell potentials
US9768463B2 (en) 2012-07-27 2017-09-19 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries comprising metal ligand coordination compounds
US9382274B2 (en) 2012-07-27 2016-07-05 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries featuring improved cell design characteristics
US9899694B2 (en) 2012-07-27 2018-02-20 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring high open circuit potential
EP2883268B1 (en) 2012-08-08 2016-11-23 Robert Bosch GmbH Metal/air flow battery
JP2015222613A (ja) * 2012-09-11 2015-12-10 国立大学法人東京工業大学 金属Ｎａ電池
WO2014182251A1 (en) * 2013-05-10 2014-11-13 Nanyang Technological University Electrolyte membrane for liquid anode cell battery
US20150014184A1 (en) * 2013-07-10 2015-01-15 Lawence Ralph Swonger Producing lithium
US10714724B2 (en) 2013-11-18 2020-07-14 California Institute Of Technology Membranes for electrochemical cells
US20150171398A1 (en) 2013-11-18 2015-06-18 California Institute Of Technology Electrochemical separators with inserted conductive layers
MX2017004888A (es) 2014-11-26 2017-07-27 Lockheed Martin Advanced Energy Storage Llc Complejos de metales de catecolatos sustituidos y baterias de flujo redox que los contienen.
US10253051B2 (en) 2015-03-16 2019-04-09 Lockheed Martin Energy, Llc Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride
KR101747402B1 (ko) 2015-10-12 2017-06-14 주식회사 엘지화학 전기화학소자용 전극, 이의 제조 방법, 및 이를 포함하는 전기화학 소자
US10340528B2 (en) 2015-12-02 2019-07-02 California Institute Of Technology Three-dimensional ion transport networks and current collectors for electrochemical cells
US10644342B2 (en) 2016-03-03 2020-05-05 Lockheed Martin Energy, Llc Coordination complexes containing monosulfonated catecholate ligands and methods for producing the same
US10316047B2 (en) 2016-03-03 2019-06-11 Lockheed Martin Energy, Llc Processes for forming coordination complexes containing monosulfonated catecholate ligands
US9938308B2 (en) 2016-04-07 2018-04-10 Lockheed Martin Energy, Llc Coordination compounds having redox non-innocent ligands and flow batteries containing the same
DE102016212736A1 (de) * 2016-07-13 2018-01-18 Bayerische Motoren Werke Aktiengesellschaft Verfahren zur Herstellung eines Festkörperelektrolyten, Festkörperelektrolyt und Lithiumionenbatterie
US10343964B2 (en) 2016-07-26 2019-07-09 Lockheed Martin Energy, Llc Processes for forming titanium catechol complexes
US10377687B2 (en) 2016-07-26 2019-08-13 Lockheed Martin Energy, Llc Processes for forming titanium catechol complexes
US10065977B2 (en) 2016-10-19 2018-09-04 Lockheed Martin Advanced Energy Storage, Llc Concerted processes for forming 1,2,4-trihydroxybenzene from hydroquinone
US10930937B2 (en) 2016-11-23 2021-02-23 Lockheed Martin Energy, Llc Flow batteries incorporating active materials containing doubly bridged aromatic groups
CN108172953A (zh) * 2016-12-07 2018-06-15 中国科学院大连化学物理研究所 一种锌空气电池及锌空气电池组
US10497958B2 (en) 2016-12-14 2019-12-03 Lockheed Martin Energy, Llc Coordinatively unsaturated titanium catecholate complexes and processes associated therewith
US10741864B2 (en) 2016-12-30 2020-08-11 Lockheed Martin Energy, Llc Aqueous methods for forming titanium catecholate complexes and associated compositions
US10320023B2 (en) 2017-02-16 2019-06-11 Lockheed Martin Energy, Llc Neat methods for forming titanium catecholate complexes and associated compositions
JP6383038B1 (ja) * 2017-03-22 2018-08-29 株式会社東芝 二次電池、電池パック及び車両
WO2018193630A1 (ja) * 2017-04-21 2018-10-25 日立化成株式会社 電気化学デバイス用電極及び電気化学デバイス
CN109428138B (zh) * 2017-08-24 2020-12-01 上海交通大学 锂空气电池的制备方法及锂空气电池
WO2019055730A1 (en) 2017-09-14 2019-03-21 Ampcera Inc. SYSTEMS AND METHODS FOR SELECTIVE EXTRACTION OF ALKALI METALS FROM RICH METAL SOLUTIONS USING SOLID STATE ION CONDUCTIVE ELECTROLYTIC MEMBRANE
JP6911774B2 (ja) * 2018-01-09 2021-07-28 トヨタ自動車株式会社 水系電解液及び水系リチウムイオン二次電池
KR102602422B1 (ko) * 2018-10-11 2023-11-14 현대자동차주식회사 리튬공기전지 및 그 제조방법
EP3900097A1 (en) 2018-12-21 2021-10-27 Solvay Sa Solid composite electrolyte

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080182157A1 (en) * 2005-08-09 2008-07-31 Polyplus Battery Company Compliant seal structures for protected active metal anodes
CN101350416A (zh) * 2008-07-22 2009-01-21 山东东岳神舟新材料有限公司 一种微孔膜增强的多层含氟交联离子膜及其制备方法
TW200933953A (en) * 2007-11-19 2009-08-01 Excellatron Solid State Llc Non-volatile cathodes for lithium oxygen batteries and method of producing same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4057675A (en) 1974-02-19 1977-11-08 Lockheed Missiles & Space Company, Inc. Electrochemical cell
JPS601768A (ja) * 1983-06-20 1985-01-07 Hitachi Ltd 複数のイオン伝導層を用いた固体電池
US5804329A (en) * 1995-12-28 1998-09-08 National Patent Development Corporation Electroconversion cell
JP4745472B2 (ja) * 1998-07-16 2011-08-10 株式会社オハラ リチウムイオン伝導性ガラスセラミックスおよびこれを用いた電池、ガスセンサー
US7070632B1 (en) * 2001-07-25 2006-07-04 Polyplus Battery Company Electrochemical device separator structures with barrier layer on non-swelling membrane
JP4783537B2 (ja) * 2002-05-20 2011-09-28 財団法人電力中央研究所 二次電池
FR2843235B1 (fr) * 2002-07-30 2006-07-28 Conseil Et De Prospective Scie Ceramique conductrice pretraitee par oxydation pour anode de zinc de generateurs electrochimiques secondaires alcalins
US20080057386A1 (en) * 2002-10-15 2008-03-06 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
WO2004049491A1 (en) * 2002-10-25 2004-06-10 Antonino Salvatore Arico SOLID OXIDE FUEL CELL WITH CERMET Cu/Ni ALLOY ANODE
KR100509298B1 (ko) * 2003-05-31 2005-08-22 한국과학기술연구원 무기질 박막이 코팅된 직접메탄올 연료전지용 복합고분자 전해질막의 제조 방법
US7282295B2 (en) * 2004-02-06 2007-10-16 Polyplus Battery Company Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
US8231810B2 (en) * 2004-04-15 2012-07-31 Fmc Corporation Composite materials of nano-dispersed silicon and tin and methods of making the same
GB2412484B (en) * 2004-07-27 2006-03-22 Intellikraft Ltd Improvements relating to electrode structures in batteries
JP2009181872A (ja) * 2008-01-31 2009-08-13 Ohara Inc リチウムイオン二次電池およびその製造方法
JP5271668B2 (ja) * 2008-10-31 2013-08-21 株式会社オハラ 金属／水電池又は金属／空気電池

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080182157A1 (en) * 2005-08-09 2008-07-31 Polyplus Battery Company Compliant seal structures for protected active metal anodes
TW200933953A (en) * 2007-11-19 2009-08-01 Excellatron Solid State Llc Non-volatile cathodes for lithium oxygen batteries and method of producing same
CN101350416A (zh) * 2008-07-22 2009-01-21 山东东岳神舟新材料有限公司 一种微孔膜增强的多层含氟交联离子膜及其制备方法

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Publication number Publication date
KR20120092119A (ko) 2012-08-20
EP2494638A1 (fr) 2012-09-05
BR112012010050A2 (pt) 2016-05-24
RU2012121878A (ru) 2013-12-10
FR2951714A1 (fr) 2011-04-29
CN102598378A (zh) 2012-07-18
BR112012010050B1 (pt) 2019-12-03
IN2012DN03378A (enExample) 2015-10-23
RU2521042C2 (ru) 2014-06-27
KR101342677B1 (ko) 2013-12-17
EP2494638B1 (fr) 2016-05-04
US20120183868A1 (en) 2012-07-19
FR2951714B1 (fr) 2013-05-24
JP2013508930A (ja) 2013-03-07
WO2011051597A1 (fr) 2011-05-05
US9178221B2 (en) 2015-11-03
JP5643830B2 (ja) 2014-12-17

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