RU2017135874A - Молекулы с пестицидной функцией и промежуточные соединения, композиции и способы, связанные с ними - Google Patents

Молекулы с пестицидной функцией и промежуточные соединения, композиции и способы, связанные с ними Download PDF

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RU2017135874A
RU2017135874A RU2017135874A RU2017135874A RU2017135874A RU 2017135874 A RU2017135874 A RU 2017135874A RU 2017135874 A RU2017135874 A RU 2017135874A RU 2017135874 A RU2017135874 A RU 2017135874A RU 2017135874 A RU2017135874 A RU 2017135874A
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alkyl
haloalkyl
group
och
alkenyl
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RU2017135874A
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RU2017135874A3 (ru
RU2735602C2 (ru
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Тимоти П. Мартин
Джозеф Д. ЭККЕЛЬБАРДЖЕР
Рональд РОСС
Кайл А. ДЕКОРВЕР
Рональд Дж. ХЕМСТРА
Дэниэл И. КНЮППЕЛЬ
Питер ВЕДНОР
Рики ХАНТЕР
Дэвид А. ДЕМЕТЕР
Тони К. ТРАЛЛИНГЕР
Эрих В. БАУМ
Золтан Л. БЕНКО
Накиен ЧОЙ
Гари Д. КРАУЗ
Джон Ф. ДЭУБЛ
Фанчжэн ЛИ
Джеффри НИССЕН
Мишелль РЕЙНЕР
Томас К. СПАРКС
Фрэнк Дж. УЭССЕЛЗ
Морис К. АЙЭП
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ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи
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Claims (64)

1. Молекула, имеющая следующую формулу:
Figure 00000001
формула один,
где
(A) R1 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(B) R2 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(C) R3 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(D) R4 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(E) R5 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(F) R6 выбран из группы, состоящей из H и (C1-C4)алкила;
(G) R7 выбран из группы, состоящей из H, F, Cl, Br и I;
(H) R8 выбран из группы, состоящей из F, Cl, Br и I;
(I) R9 выбран из группы, состоящей из H и (C1-C4)алкила;
(J) R10 выбран из группы, состоящей из H, (C1-C4)алкила, (C2-C4)алкенила, (C1-C4)галогеналкила, (C1-C4)алкил(C1-C4)алкокси, C(=O)(C1-C4)алкила и (C1-C4)алкокси(=O)(C1-C4)алкила;
(K) R11 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(L) R12 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(M) R13 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(N) R14 выбран из группы, состоящей из H, F, Cl, Br, I, CN, NH2, NO2, (C1-C4)алкила, (C3-C6)циклоалкила, (C2-C4)алкенила, (C3-C6)циклоалкенила, (C2-C4)алкинила, (C1-C4)алкокси, (C1-C4)галогеналкила, (C3-C6)галогенциклоалкила, (C2-C4)галогеналкенила, (C3-C6)галогенциклоалкенила, (C1-C4)галогеналкокси, S(C1-C4)алкила, S(O)(C1-C4)алкила, S(O)2(C1-C4)алкила, S(C1-C4)галогеналкила, S(O)(C1-C4)галогеналкила, S(O)2(C1-C4)галогеналкила, (C1-C4)алкил-S(O)2NH2 и (C1-C4)галогеналкил-S(O)2NH2;
(O) R15 выбран из группы, состоящей из (Q), H, (C1-C4)алкила, (C2-C4)алкенила, (C1-C4)галогеналкила, (C1-C4)алкил(C1-C4)алкокси, C(=O)(C1-C4)алкила и (C1-C4)алкокси-C(=O)(C1-C4)алкила;
(P) R16 выбран из группы, состоящей из (Q), (C1-C8)алкила, (C1-C8)алкил-O-(C1-C8)алкила, (C1-C8)алкил(C3-C8)циклоалкила, (C1-C8)алкилфенила, (C2-C8)алкенила, (C2-C8)алкинила, (C1-C8)галогеналкила, (C1-C8)алкил-S-(C1-C8)алкила, (C1-C8)алкил-S(O)-(C1-C8)алкила, (C1-C8)алкил-S(O)2-(C1-C8)алкила, O-фенила, O-(C2-C8)алкенила, O-(C1-C8)алкил(C3-C8)циклоалкила, O-(C1-C8)алкилфенила, (C1-C8)алкил-O-(C1-C8)алкил(C3-C8)циклоалкила, (C1-C8)алкил-O-(C1-C8)галогеналкила, (C1-C8)алкил-C(=O)NH-(C1-C8)галогеналкила, (C1-C8)алкил-NHC(O)-(C1-C8)алкила, (C1-C8)алкил-S-(C1-C8)галогеналкила, (C1-C8)алкил-S(O)-(C1-C8)галогеналкила, (C1-C8)алкил-S(O)2-(C1-C8)галогеналкила и (C1-C8)алкил-S(O)2-NH2,
при этом каждый алкил, алкенил, алкинил, циклоалкил, галогеналкил и фенил может быть необязательно замещен одним или более заместителями, выбранными из группы, состоящей из F, Cl, Br, I, CN, OH, NH2, NO2, (C1-C8)алкила, (C1-C8)алкокси, (C1-C8)галогеналкила, N((C1-C8)алкил)2, C(O)O(C1-C8)алкила, бензотиоенила, 2,3-дигидро-1H-имидазолонила, фуранила, пиразолила, пиридинила, тиазолила и триазолила;
(Q) R15 и R16 вместе могут необязательно образовывать 2-5-членное насыщенное или ненасыщенное гидрокарбильное звено, которое может содержать один или более гетероатомов, выбранных из группы, состоящей из азота, серы и кислорода,
при этом указанное гидрокарбильное звено может быть необязательно замещено одним или более заместителями, выбранными из группы, состоящей из F, Cl, Br, I, CN, NH2 и NO2;
(R) каждый из Q1 и Q2 независимо выбран из группы, состоящей из O и S; и
N-оксиды, пригодные для применения в сельском хозяйстве соли присоединения кислоты, солевые производные, сольваты, сложноэфирные производные, кристаллические полиморфы, изотопы, разделенные стереоизомеры и таутомеры молекул формулы один.
2. Молекула по п. 1, где R1, R2, R3, R4 и R5 выбраны из группы, состоящей из H, F и Cl.
3. Молекула по любому из предыдущих пунктов, где R7 и R8 выбраны из группы, состоящей из Cl и Br.
4. Молекула по любому из предыдущих пунктов, где R13 выбран из группы, состоящей из H, Cl и CF3.
5. Молекула по любому из предыдущих пунктов, где R15 выбран из группы, состоящей из H и CH3.
6. Молекула по любому из предыдущих пунктов, где R16 выбран из группы, состоящей из CH2, CH2CH2, CH2CH2CH2, CH2CH2CH2CH2, CH2CH2CH2OCH2CH2, CH3, CH2CH3, CH2CH2CH3, CH2CH2CH2CH3, CH2CH2CH2CH2CH3, CH2CH2CH2CH2CH2CH3, CH2CH(CH3)2, CH2циклопропила, CH2CH2циклопропила, CH2циклобутила, CH2фенила, CH2CH2фенила, CH2C=CH, CH2C=CH, CH2CF3, CH2CHF2, CH2CH2CF3, CH2CF2CF3, CH2CH2CH2CF3, CH2CH2CF2CF3, CH2CF2CF2CF3, CH2CH2CH2CH2F, CH2CH2SCH3, CH2CH2S(O)CH3, CH2CH2S(O)2CH3, C(CH3)2CH2S(O)2CH3, O-фенила, OCH2CH=CH2, OCH2циклопропила, OCH2фенила, CH2CH2OCH2циклопропила, CH2CH2CH2OCH2CF3, CH2C(=O)NHCH2CF3 или CH2CH2NHC(=O)CH3,
при этом каждый CH2, CH2CH2, CH2CH2CH2, CH2CH2CH2CH2, циклопропил, циклобутил и фенил может быть необязательно замещен одним или более заместителями, выбранными из группы, состоящей из F, Cl, CN, C(CH3)3, CF3, OCH3, OCH2CH3, N(CH3)2 и пиридинила.
7. Молекула по любому из предыдущих пунктов, где R15 и R16 вместе представляют собой -CH2CH2CF2CH2-.
8. Молекула по любому из предыдущих пунктов, где Q1 и Q2 представляют собой O.
9. Молекула по п. 1, где:
(A) R1 представляет собой H;
(B) R2 выбран из группы, состоящей из H и Cl;
(C) R3 выбран из группы, состоящей из H и Cl;
(D) R4 представляет собой Cl;
(E) R5 представляет собой H;
(F) R6 представляет собой H;
(G) R7 выбран из группы, состоящей из Cl и Br;
(H) R8 выбран из группы, состоящей из Cl и Br;
(I) R9 представляет собой H;
(J) R10 представляет собой H;
(K) R11 представляет собой H;
(L) R12 представляет собой H;
(M) R13 выбран из группы, состоящей из H, Cl и CF3;
(N) R14 представляет собой H;
(O) R15 выбран из группы, состоящей из H и CH3;
(P) R16 выбран из группы, состоящей из CH2, CH2CH2, CH2CH2CH2, CH2CH2CH2CH2, CH2CH2CH2OCH2CH2, CH3, CH2CH3, CH2CH2CH3, CH2CH2CH2CH3, CH2CH2CH2CH2CH3, CH2CH2CH2CH2CH2CH3, CH2CH(CH3)2, CH2циклопропила, CH2CH2циклопропила, CH2циклобутила, CH2фенила, CH2CH2фенила, CH2C=CH, CH2C=CH, CH2CF3, CH2CHF2, CH2CH2CF3, CH2CF2CF3, CH2CH2CH2CF3, CH2CH2CF2CF3, CH2CF2CF2CF3, CH2CH2CH2CH2F, CH2CH2SCH3, CH2CH2S(O)CH3, CH2CH2S(O)2CH3, C(CH3)2CH2S(O)2CH3, O-фенила, OCH2CH=CH2, OCH2циклопропила, OCH2фенила, CH2CH2OCH2циклопропила, CH2CH2CH2OCH2CF3, CH2C(=O)NHCH2CF3 и CH2CH2NHC(=O)CH3,
при этом каждый CH2, CH2CH2, CH2CH2CH2, CH2CH2CH2CH2, циклопропил, циклобутил и фенил может быть необязательно замещен одним или более заместителями, выбранными из группы, состоящей из F, Cl, CN, C(CH3)3, CF3, OCH3, OCH2CH3, N(CH3)2 и пиридинила; и
(Q) R15 и R16 вместе предпочтительно представляют собой 4-членное насыщенное гидрокарбильное звено,
при этом указанное гидрокарбильное звено замещено одним или более F;
(R) Q1 и Q2 представляют собой O.
10. Молекула по п. 1, где указанная молекула выбрана из группы, состоящей из F1-F75, F78, F79, F84-F88, F91-F100, F102-F109, F111-F135, PF1-PF7 и PF10-PF16.
11. Молекула по п. 1, где указанная молекула выбрана из группы, состоящей из F4, F15, F28, F30, F35, F38, F39, F40, F44, F45, F46, F47, F49 и P16.
12. Композиция, содержащая:
(a) молекулу по любому из предыдущих пунктов и
(b) носитель.
13. Композиция, содержащая:
(a) молекулу по любому из пп. 1-11 и
(b) активный ингредиент.
14. Способ, включающий внесение в место произрастания пестицидно эффективного количества: (a) молекулы по любому из пп. 1-11 или (b) композиции по любому из п. 12 и п. 13.
15.Способ по п. 14, где указанный вредитель представляет собой жующего вредителя.
RU2017135874A 2015-04-17 2016-04-07 Молекулы с пестицидной функцией и промежуточные соединения, композиции и способы, связанные с ними RU2735602C2 (ru)

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