RU2017132153A - Сополимер и медицинское устройство, разделительный мембранный модуль медицинского назначения и устройство для очистки крови, включающее этот сополимер - Google Patents
Сополимер и медицинское устройство, разделительный мембранный модуль медицинского назначения и устройство для очистки крови, включающее этот сополимер Download PDFInfo
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- RU2017132153A RU2017132153A RU2017132153A RU2017132153A RU2017132153A RU 2017132153 A RU2017132153 A RU 2017132153A RU 2017132153 A RU2017132153 A RU 2017132153A RU 2017132153 A RU2017132153 A RU 2017132153A RU 2017132153 A RU2017132153 A RU 2017132153A
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- 229920001577 copolymer Polymers 0.000 title claims 14
- 239000008280 blood Substances 0.000 title claims 5
- 210000004369 blood Anatomy 0.000 title claims 5
- 239000012528 membrane Substances 0.000 title claims 5
- 238000004140 cleaning Methods 0.000 title 1
- 238000000926 separation method Methods 0.000 claims 4
- 230000002209 hydrophobic effect Effects 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 238000000746 purification Methods 0.000 claims 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229920002492 poly(sulfone) Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000012959 renal replacement therapy Methods 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
- C08F226/10—N-Vinyl-pyrrolidone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K35/00—Medicinal preparations containing materials or reaction products thereof with undetermined constitution
- A61K35/12—Materials from mammals; Compositions comprising non-specified tissues or cells; Compositions comprising non-embryonic stem cells; Genetically modified cells
- A61K35/14—Blood; Artificial blood
- A61K35/16—Blood plasma; Blood serum
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L33/00—Antithrombogenic treatment of surgical articles, e.g. sutures, catheters, prostheses, or of articles for the manipulation or conditioning of blood; Materials for such treatment
- A61L33/06—Use of macromolecular materials
- A61L33/064—Use of macromolecular materials obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M1/00—Suction or pumping devices for medical purposes; Devices for carrying-off, for treatment of, or for carrying-over, body-liquids; Drainage systems
- A61M1/14—Dialysis systems; Artificial kidneys; Blood oxygenators ; Reciprocating systems for treatment of body fluids, e.g. single needle systems for hemofiltration or pheresis
- A61M1/16—Dialysis systems; Artificial kidneys; Blood oxygenators ; Reciprocating systems for treatment of body fluids, e.g. single needle systems for hemofiltration or pheresis with membranes
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- A—HUMAN NECESSITIES
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- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M1/00—Suction or pumping devices for medical purposes; Devices for carrying-off, for treatment of, or for carrying-over, body-liquids; Drainage systems
- A61M1/14—Dialysis systems; Artificial kidneys; Blood oxygenators ; Reciprocating systems for treatment of body fluids, e.g. single needle systems for hemofiltration or pheresis
- A61M1/16—Dialysis systems; Artificial kidneys; Blood oxygenators ; Reciprocating systems for treatment of body fluids, e.g. single needle systems for hemofiltration or pheresis with membranes
- A61M1/1621—Constructional aspects thereof
- A61M1/1623—Disposition or location of membranes relative to fluids
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M1/00—Suction or pumping devices for medical purposes; Devices for carrying-off, for treatment of, or for carrying-over, body-liquids; Drainage systems
- A61M1/34—Filtering material out of the blood by passing it through a membrane, i.e. hemofiltration or diafiltration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/009—After-treatment of organic or inorganic membranes with wave-energy, particle-radiation or plasma
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/06—Flat membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D69/10—Supported membranes; Membrane supports
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D69/12—Composite membranes; Ultra-thin membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/38—Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
- B01D71/381—Polyvinylalcohol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/44—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of groups B01D71/26-B01D71/42
- B01D71/441—Polyvinylpyrrolidone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
- B01D71/68—Polysulfones; Polyethersulfones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/10—Vinyl esters of monocarboxylic acids containing three or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
- C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2205/00—General characteristics of the apparatus
- A61M2205/75—General characteristics of the apparatus with filters
- A61M2205/7563—General characteristics of the apparatus with filters with means preventing clogging of filters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hematology (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Polymers & Plastics (AREA)
- Biomedical Technology (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Epidemiology (AREA)
- Anesthesiology (AREA)
- Vascular Medicine (AREA)
- Urology & Nephrology (AREA)
- Materials Engineering (AREA)
- Cell Biology (AREA)
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- Surgery (AREA)
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- Developmental Biology & Embryology (AREA)
- Biotechnology (AREA)
- Wood Science & Technology (AREA)
- External Artificial Organs (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Artificial Filaments (AREA)
Claims (15)
1. Сополимер, включающий гидрофильное звено и гидрофобное звено,
где гидрофобное звено включает, по меньшей мере, одно винилкарбоксилатное звено, и
винилкарбоксилатное звено имеет 2 или более и 7 или менее углеродных атомов на конце его боковой цепи.
2. Сополимер по п. 1, в котором гидрофильное звено включает винилпирролидоновое звено.
3. Сополимер по п. 1 или 2, имеющий среднечисленную молекулярную массу 2000 или более.
4. Сополимер по любому одному из пп. 1-3, в котором гидрофильное звено составляет мольную долю 30% или более и 90% или менее в расчете на сополимер в целом.
5. Сополимер по любому одному из пп. 1-4, в котором гидрофильное звено и гидрофобное звено расположены в произвольном порядке или поочередно.
6. Сополимер по любому одному из пп. 1-5, который применяют в медицинском устройстве.
7. Медицинское устройство, содержащее сополимер по любому одному из пп. 1-6.
8. Медицинское устройство по п. 7, содержащее сополимер, вводимый, по меньшей мере, на часть поверхности устройства, которая находится в контакте с биологическим компонентом.
9. Разделительный мембранный модуль медицинского назначения, включающий разделительную мембрану, содержащую сополимер по любому одному из пп. 1-6.
10. Разделительный мембранный модуль медицинского назначения по п. 9, в котором разделительная мембрана содержит полимер на основе полисульфона в качестве основного исходного материала.
11. Устройство для очистки крови, содержащее сополимер по любому одному из пп. 1-6.
12. Устройство для очистки крови по п. 11, которое представляет собой устройство для непрерывной заместительной почечной терапии.
13. Устройство для очистки крови по п. 11 или 12, содержащее сополимер, вводимый, по меньшей мере, на часть поверхности устройства, которая находится в контакте с кровью или биологическим компонентом.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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JP2015072340 | 2015-03-31 | ||
JP2015-072340 | 2015-03-31 | ||
PCT/JP2016/058162 WO2016158388A1 (ja) | 2015-03-31 | 2016-03-15 | 共重合体並びにそれを用いた医療デバイス、医療用分離膜モジュール、および血液浄化器 |
Publications (3)
Publication Number | Publication Date |
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RU2017132153A true RU2017132153A (ru) | 2019-04-05 |
RU2017132153A3 RU2017132153A3 (ru) | 2019-06-14 |
RU2705399C2 RU2705399C2 (ru) | 2019-11-07 |
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RU2017132153A RU2705399C2 (ru) | 2015-03-31 | 2016-03-15 | Сополимер и медицинское устройство, разделительный мембранный модуль медицинского назначения и устройство для очистки крови, включающее этот сополимер |
Country Status (10)
Country | Link |
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US (1) | US10308745B2 (ru) |
EP (1) | EP3279227B1 (ru) |
JP (1) | JP6874371B2 (ru) |
KR (1) | KR102496897B1 (ru) |
CN (1) | CN107406551B (ru) |
CA (1) | CA2975588C (ru) |
ES (1) | ES2751578T3 (ru) |
RU (1) | RU2705399C2 (ru) |
TW (1) | TWI686216B (ru) |
WO (1) | WO2016158388A1 (ru) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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AU2017307699B2 (en) * | 2016-08-05 | 2022-03-24 | Toray Industries, Inc. | Biological component adhesion-suppressing material |
JP6950528B2 (ja) * | 2016-08-05 | 2021-10-13 | 東レ株式会社 | 共重合体並びにそれを用いた分離膜、医療デバイス及び血液浄化器 |
WO2018043209A1 (ja) * | 2016-08-31 | 2018-03-08 | 東レ株式会社 | 医療用材料、医療用分離膜、および血液浄化器 |
TWI749071B (zh) * | 2016-09-30 | 2021-12-11 | 日商東麗股份有限公司 | 分離膜模組 |
CN109790259B (zh) * | 2016-09-30 | 2021-12-07 | 东丽株式会社 | 共聚物和使用其的医疗材料 |
JP2019130522A (ja) * | 2018-02-02 | 2019-08-08 | 東レ株式会社 | 中空糸膜、中空糸膜の製造方法、および中空糸膜を用いたビール、ワインまたは日本酒の製造方法 |
KR20210011372A (ko) * | 2018-05-24 | 2021-02-01 | 도레이 카부시키가이샤 | 다공질 중공사막 |
JPWO2020158451A1 (ru) * | 2019-01-29 | 2020-08-06 | ||
CN113613776B (zh) * | 2019-03-29 | 2023-06-23 | 旭化成医疗株式会社 | 血液净化器 |
JPWO2021182608A1 (ru) | 2020-03-12 | 2021-09-16 |
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TWI293897B (en) * | 2002-08-21 | 2008-03-01 | Toray Industries | Modified substrates and process for producing the same |
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JP4888559B2 (ja) * | 2008-03-31 | 2012-02-29 | 東レ株式会社 | 血液浄化用分離膜および血液浄化用分離膜モジュールならびに血液浄化用中空糸膜および血液浄化用中空糸膜モジュール |
JP5338431B2 (ja) | 2008-03-31 | 2013-11-13 | 東レ株式会社 | ポリスルホン系分離膜およびポリスルホン系分離膜モジュールの製造方法 |
KR20130036188A (ko) * | 2010-03-02 | 2013-04-11 | 바스프 에스이 | 블록 공중합체 및 이의 용도 |
US9867917B2 (en) * | 2010-12-28 | 2018-01-16 | Toray Industries, Inc. | Medical material and hollow fiber membrane module |
TW201309354A (zh) * | 2011-06-23 | 2013-03-01 | Toray Industries | 醫療材料 |
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CN102898594B (zh) * | 2012-09-03 | 2015-07-01 | 西达(无锡)生物科技有限公司 | 脂肪族水性聚酯接枝共聚物、改善淀粉浆料对涤纶纤维粘合强度的粘合促进剂及制备方法 |
CN103816816B (zh) * | 2014-02-28 | 2016-02-03 | 中国科学院长春应用化学研究所 | 一种聚合物膜材料及其制备方法 |
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2016
- 2016-03-15 CN CN201680017624.1A patent/CN107406551B/zh active Active
- 2016-03-15 RU RU2017132153A patent/RU2705399C2/ru active
- 2016-03-15 ES ES16772271T patent/ES2751578T3/es active Active
- 2016-03-15 WO PCT/JP2016/058162 patent/WO2016158388A1/ja active Application Filing
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- 2016-03-15 EP EP16772271.9A patent/EP3279227B1/en active Active
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Also Published As
Publication number | Publication date |
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CN107406551B (zh) | 2020-01-07 |
RU2017132153A3 (ru) | 2019-06-14 |
CA2975588A1 (en) | 2016-10-06 |
EP3279227A4 (en) | 2018-10-10 |
CA2975588C (en) | 2022-08-30 |
RU2705399C2 (ru) | 2019-11-07 |
EP3279227B1 (en) | 2019-08-07 |
TW201642913A (zh) | 2016-12-16 |
EP3279227A1 (en) | 2018-02-07 |
ES2751578T3 (es) | 2020-04-01 |
KR20170133341A (ko) | 2017-12-05 |
KR102496897B1 (ko) | 2023-02-07 |
WO2016158388A1 (ja) | 2016-10-06 |
CN107406551A (zh) | 2017-11-28 |
US20180162977A1 (en) | 2018-06-14 |
JPWO2016158388A1 (ja) | 2018-01-25 |
US10308745B2 (en) | 2019-06-04 |
JP6874371B2 (ja) | 2021-05-19 |
TWI686216B (zh) | 2020-03-01 |
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