RU2014111254A - Способ снижения содержания галогенов в полимере - Google Patents
Способ снижения содержания галогенов в полимере Download PDFInfo
- Publication number
- RU2014111254A RU2014111254A RU2014111254/04A RU2014111254A RU2014111254A RU 2014111254 A RU2014111254 A RU 2014111254A RU 2014111254/04 A RU2014111254/04 A RU 2014111254/04A RU 2014111254 A RU2014111254 A RU 2014111254A RU 2014111254 A RU2014111254 A RU 2014111254A
- Authority
- RU
- Russia
- Prior art keywords
- compounds
- polymer
- oxyl
- group
- meth
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 34
- 229920000642 polymer Polymers 0.000 title claims abstract 24
- 229910052736 halogen Inorganic materials 0.000 title claims abstract 11
- 150000002367 halogens Chemical class 0.000 title claims abstract 7
- -1 benzyl halide Chemical class 0.000 claims abstract 15
- 238000006116 polymerization reaction Methods 0.000 claims abstract 12
- 239000003112 inhibitor Substances 0.000 claims abstract 10
- 238000010560 atom transfer radical polymerization reaction Methods 0.000 claims abstract 6
- 239000010949 copper Substances 0.000 claims abstract 5
- 239000005749 Copper compound Substances 0.000 claims abstract 4
- 238000006243 chemical reaction Methods 0.000 claims abstract 4
- 150000001875 compounds Chemical class 0.000 claims abstract 4
- 150000001880 copper compounds Chemical class 0.000 claims abstract 4
- 125000005843 halogen group Chemical group 0.000 claims abstract 4
- 239000003999 initiator Substances 0.000 claims abstract 4
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract 4
- 229910021589 Copper(I) bromide Inorganic materials 0.000 claims abstract 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims abstract 2
- 229940045985 antineoplastic platinum compound Drugs 0.000 claims abstract 2
- 150000001845 chromium compounds Chemical class 0.000 claims abstract 2
- 150000001869 cobalt compounds Chemical class 0.000 claims abstract 2
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 claims abstract 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims abstract 2
- DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000002504 iridium compounds Chemical class 0.000 claims abstract 2
- 150000002506 iron compounds Chemical class 0.000 claims abstract 2
- 150000002697 manganese compounds Chemical class 0.000 claims abstract 2
- 239000005078 molybdenum compound Substances 0.000 claims abstract 2
- 150000002752 molybdenum compounds Chemical class 0.000 claims abstract 2
- 150000002816 nickel compounds Chemical class 0.000 claims abstract 2
- 150000002941 palladium compounds Chemical class 0.000 claims abstract 2
- 150000003058 platinum compounds Chemical class 0.000 claims abstract 2
- 150000003282 rhenium compounds Chemical class 0.000 claims abstract 2
- 150000003284 rhodium compounds Chemical class 0.000 claims abstract 2
- 150000003304 ruthenium compounds Chemical class 0.000 claims abstract 2
- 150000003317 samarium compounds Chemical class 0.000 claims abstract 2
- 229940100890 silver compound Drugs 0.000 claims abstract 2
- 150000003379 silver compounds Chemical class 0.000 claims abstract 2
- 150000003623 transition metal compounds Chemical class 0.000 claims abstract 2
- 150000003748 yttrium compounds Chemical class 0.000 claims abstract 2
- 150000003752 zinc compounds Chemical class 0.000 claims abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 3
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 claims 2
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical group CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 150000001491 aromatic compounds Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 150000002832 nitroso derivatives Chemical class 0.000 claims 2
- 150000002989 phenols Chemical class 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 claims 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims 1
- VUZNLSBZRVZGIK-UHFFFAOYSA-N 2,2,6,6-Tetramethyl-1-piperidinol Chemical group CC1(C)CCCC(C)(C)N1O VUZNLSBZRVZGIK-UHFFFAOYSA-N 0.000 claims 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 claims 1
- OQYKKQQLTKPGSG-UHFFFAOYSA-N 2,5-dimethylhexane-1,6-diol Chemical compound OCC(C)CCC(C)CO OQYKKQQLTKPGSG-UHFFFAOYSA-N 0.000 claims 1
- JFGVTUJBHHZRAB-UHFFFAOYSA-N 2,6-Di-tert-butyl-1,4-benzenediol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1O JFGVTUJBHHZRAB-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 claims 1
- DHNFGUDLVOSIKJ-UHFFFAOYSA-N 3-methyl-1-(3-methylbuta-1,3-dienoxy)buta-1,3-diene Chemical class CC(=C)C=COC=CC(C)=C DHNFGUDLVOSIKJ-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- UBUCNCOMADRQHX-UHFFFAOYSA-N N-Nitrosodiphenylamine Chemical compound C=1C=CC=CC=1N(N=O)C1=CC=CC=C1 UBUCNCOMADRQHX-UHFFFAOYSA-N 0.000 claims 1
- RPDUDBYMNGAHEM-UHFFFAOYSA-N PROXYL Chemical group CC1(C)CCC(C)(C)N1[O] RPDUDBYMNGAHEM-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims 1
- 239000003463 adsorbent Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229940087168 alpha tocopherol Drugs 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 239000003456 ion exchange resin Substances 0.000 claims 1
- 229920003303 ion-exchange polymer Polymers 0.000 claims 1
- OWFXIOWLTKNBAP-UHFFFAOYSA-N isoamyl nitrite Chemical compound CC(C)CCON=O OWFXIOWLTKNBAP-UHFFFAOYSA-N 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 150000002689 maleic acids Chemical class 0.000 claims 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- PYYXCLLGYQVCJB-UHFFFAOYSA-N n-cyclohexyl-n-hydroxynitramide Chemical compound [O-][N+](=O)N(O)C1CCCCC1 PYYXCLLGYQVCJB-UHFFFAOYSA-N 0.000 claims 1
- DAHPIMYBWVSMKQ-UHFFFAOYSA-N n-hydroxy-n-phenylnitrous amide Chemical compound O=NN(O)C1=CC=CC=C1 DAHPIMYBWVSMKQ-UHFFFAOYSA-N 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 239000012454 non-polar solvent Substances 0.000 claims 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims 1
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims 1
- 229960000984 tocofersolan Drugs 0.000 claims 1
- 229920001567 vinyl ester resin Polymers 0.000 claims 1
- 235000004835 α-tocopherol Nutrition 0.000 claims 1
- 239000002076 α-tocopherol Substances 0.000 claims 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161527800P | 2011-08-26 | 2011-08-26 | |
| US61/527,800 | 2011-08-26 | ||
| PCT/EP2012/062885 WO2013029837A1 (en) | 2011-08-26 | 2012-07-03 | Method for reducing the halogen content of a polymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2014111254A true RU2014111254A (ru) | 2015-10-10 |
Family
ID=46420215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014111254/04A RU2014111254A (ru) | 2011-08-26 | 2012-07-03 | Способ снижения содержания галогенов в полимере |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20140206823A1 (enExample) |
| EP (1) | EP2748209A1 (enExample) |
| JP (1) | JP2014525484A (enExample) |
| KR (1) | KR20140051340A (enExample) |
| CN (1) | CN103732633A (enExample) |
| BR (1) | BR112014001355A2 (enExample) |
| CA (1) | CA2846371A1 (enExample) |
| IN (1) | IN2014CN02026A (enExample) |
| MX (1) | MX2014002143A (enExample) |
| RU (1) | RU2014111254A (enExample) |
| WO (1) | WO2013029837A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273707A (zh) * | 2014-11-07 | 2016-01-27 | 中国石油化工股份有限公司 | 一种具有荧光特性的粘弹性颗粒驱油剂及其制备方法 |
| BR112018074348A2 (pt) * | 2016-06-22 | 2019-03-06 | Dow Global Technologies Llc | método para tratar uma resina aromática vinílica. |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58225085A (ja) * | 1982-06-24 | 1983-12-27 | Nippon Kayaku Co Ltd | アセタ−ルグリコ−ルジアクリレ−トおよびその製造法 |
| GB9213904D0 (en) | 1992-06-30 | 1992-08-12 | Exxon Chemical Patents Inc | Oil additives and compositions |
| GB9315205D0 (en) | 1993-07-22 | 1993-09-08 | Exxon Chemical Patents Inc | Additives and fuel compositions |
| US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
| CA2258006C (en) | 1996-06-12 | 2008-07-29 | University Of Warwick | Polymerisation catalyst and process |
| DE69729843T2 (de) * | 1996-11-28 | 2005-08-25 | Kaneka Corp. | Verfahren zur Herstellung eines (Meth)acrylpolymers mit endständiger Hydroxylgruppe und dieses Polymer |
| TW593347B (en) | 1997-03-11 | 2004-06-21 | Univ Carnegie Mellon | Improvements in atom or group transfer radical polymerization |
| US7157537B2 (en) * | 1999-01-21 | 2007-01-02 | Ciba Specialty Chemicals Corporation | α-Halogenated acid esters with polyvalent alcohols as atom transfer radical polymerization initiators |
| US7030194B1 (en) * | 1999-04-02 | 2006-04-18 | Kaneka Corporation | Method of treating polymer |
| US6857126B2 (en) | 2000-07-24 | 2005-02-15 | Matsushita Electric Industrial Co., Ltd. | Objective lens driving apparatus with reinforcing rib and restraining part for focusing coil or tracking coil |
| US6746993B2 (en) | 2001-04-06 | 2004-06-08 | Sanyo Chemical Industries, Ltd. | Viscosity index improver and lube oil containing the same |
| US6689844B2 (en) * | 2001-05-29 | 2004-02-10 | Rohmax Additives Gmbh | Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition |
| US20040077509A1 (en) | 2002-08-02 | 2004-04-22 | Tsuyoshi Yuki | Viscosity index improver and lube oil containing the same |
| JP4543178B2 (ja) | 2005-09-01 | 2010-09-15 | 国立大学法人京都大学 | 新規リビングラジカル重合法 |
| DE102006037350A1 (de) * | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von halogenfreien ATRP-Produkten |
| DE102006048154A1 (de) * | 2006-10-10 | 2008-04-17 | Evonik Röhm Gmbh | Verfahren zur Herstellung von silyltelechelen Polymeren |
| DE102007046223A1 (de) | 2007-09-26 | 2009-04-02 | Evonik Rohmax Additives Gmbh | Verwendung von Kammpolymeren zur Verringerung des Kraftstoffverbrauchs |
| DE102007032120A1 (de) | 2007-07-09 | 2009-01-15 | Evonik Rohmax Additives Gmbh | Verwendung von Kammpolymeren zur Verringerung des Kraftstoffverbrauchs |
| WO2009136510A1 (ja) | 2008-05-09 | 2009-11-12 | 国立大学法人京都大学 | アルコールを触媒として用いた新規リビングラジカル重合法 |
| MX2012001681A (es) * | 2009-08-07 | 2012-05-08 | Basf Se | Composicion lubricante que contiene acido alquileter carboxilico. |
-
2012
- 2012-07-03 IN IN2026CHN2014 patent/IN2014CN02026A/en unknown
- 2012-07-03 RU RU2014111254/04A patent/RU2014111254A/ru not_active Application Discontinuation
- 2012-07-03 KR KR1020147004540A patent/KR20140051340A/ko not_active Withdrawn
- 2012-07-03 US US14/131,086 patent/US20140206823A1/en not_active Abandoned
- 2012-07-03 EP EP12730987.0A patent/EP2748209A1/en not_active Withdrawn
- 2012-07-03 BR BR112014001355A patent/BR112014001355A2/pt not_active Application Discontinuation
- 2012-07-03 WO PCT/EP2012/062885 patent/WO2013029837A1/en not_active Ceased
- 2012-07-03 CA CA2846371A patent/CA2846371A1/en not_active Abandoned
- 2012-07-03 JP JP2014527539A patent/JP2014525484A/ja active Pending
- 2012-07-03 CN CN201280035436.3A patent/CN103732633A/zh active Pending
- 2012-07-03 MX MX2014002143A patent/MX2014002143A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014001355A2 (pt) | 2017-02-21 |
| CA2846371A1 (en) | 2013-03-07 |
| CN103732633A (zh) | 2014-04-16 |
| KR20140051340A (ko) | 2014-04-30 |
| EP2748209A1 (en) | 2014-07-02 |
| IN2014CN02026A (enExample) | 2015-05-29 |
| US20140206823A1 (en) | 2014-07-24 |
| MX2014002143A (es) | 2014-03-27 |
| JP2014525484A (ja) | 2014-09-29 |
| WO2013029837A1 (en) | 2013-03-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20150706 |