RU2008101964A - Защита против окисления изделий из композиционного углеродосодержащего материала - Google Patents
Защита против окисления изделий из композиционного углеродосодержащего материала Download PDFInfo
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- RU2008101964A RU2008101964A RU2008101964/03A RU2008101964A RU2008101964A RU 2008101964 A RU2008101964 A RU 2008101964A RU 2008101964/03 A RU2008101964/03 A RU 2008101964/03A RU 2008101964 A RU2008101964 A RU 2008101964A RU 2008101964 A RU2008101964 A RU 2008101964A
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- powder
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- heat treatment
- coating composition
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- 239000002131 composite material Substances 0.000 title claims abstract 3
- 239000000463 material Substances 0.000 title claims 2
- 230000003647 oxidation Effects 0.000 title claims 2
- 238000007254 oxidation reaction Methods 0.000 title claims 2
- 239000000843 powder Substances 0.000 claims abstract 9
- 239000008199 coating composition Substances 0.000 claims abstract 6
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052799 carbon Inorganic materials 0.000 claims abstract 2
- 239000007788 liquid Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 12
- 239000000243 solution Substances 0.000 claims 6
- 238000010438 heat treatment Methods 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910033181 TiB2 Inorganic materials 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 150000007514 bases Chemical class 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 230000035876 healing Effects 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- PSUYMGPLEJLSPA-UHFFFAOYSA-N vanadium zirconium Chemical compound [V].[V].[Zr] PSUYMGPLEJLSPA-UHFFFAOYSA-N 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 230000003064 anti-oxidating effect Effects 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- -1 phosphate compound Chemical class 0.000 abstract 1
- 239000012255 powdered metal Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/83—Carbon fibres in a carbon matrix
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- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D65/00—Parts or details
- F16D65/02—Braking members; Mounting thereof
- F16D65/12—Discs; Drums for disc brakes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
- F16D69/023—Composite materials containing carbon and carbon fibres or fibres made of carbonizable material
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00362—Friction materials, e.g. used as brake linings, anti-skid materials
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5252—Fibers having a specific pre-form
- C04B2235/5256—Two-dimensional, e.g. woven structures
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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Abstract
1. Способ защиты от окисления детали, изготовленной из композиционного углеродсодержащего материала, имеющего открытые внутренние поры, включающий: ! импрегнирование детали жидкой импрегнирующей композицией, содержащей по меньшей мере одно соединение фосфатного типа, через посредство по меньшей мере части наружной поверхности детали; ! нанесение покрывающей композиции на указанную часть внешней поверхности детали, при этом покрывающая композиция содержит коллоидный раствор по меньшей мере одного огнеупорного оксида в воде, по меньшей мере одно соединение по существу боросиликатного типа в порошкообразной форме и обладающее свойствами залечивания, и по меньшей мере один борид металла в порошкообразной форме; и ! осуществление термической обработки после нанесения покрывающей композиции. ! 2. Способ по п.1, где коллоидный раствор является щелочным. ! 3. Способ по п.2, в котором используют коллоидный раствор, стабилизированный основным соединением. ! 4. Способ по любому из пп.1-3, где покрывающая композиция включает: ! от 25 до 50% водного коллоидного раствора огнеупорного оксида с концентрацией огнеупорного оксида в пределах от 25 до 50%; ! от 5 до 20% порошка стекловидного соединения, по существу, боросиликатного типа; ! от 30 до 60% порошка борида металла, и ! возможный остаток составляет вода. ! 5. Способ по любому из пп.1-3, где формируют покрытие, имеющее после термической обработки толщину в пределах от 50 до 250 мкм. ! 6. Способ по п.5, где формируют покрытие, имеющее толщину в пределах от 50 до 100 мкм. ! 7. Способ по любому из пп.1-3, где первую термическую обработку проводят после импрегнирования импрегнирующей композицией, а вторую те�
Claims (12)
1. Способ защиты от окисления детали, изготовленной из композиционного углеродсодержащего материала, имеющего открытые внутренние поры, включающий:
импрегнирование детали жидкой импрегнирующей композицией, содержащей по меньшей мере одно соединение фосфатного типа, через посредство по меньшей мере части наружной поверхности детали;
нанесение покрывающей композиции на указанную часть внешней поверхности детали, при этом покрывающая композиция содержит коллоидный раствор по меньшей мере одного огнеупорного оксида в воде, по меньшей мере одно соединение по существу боросиликатного типа в порошкообразной форме и обладающее свойствами залечивания, и по меньшей мере один борид металла в порошкообразной форме; и
осуществление термической обработки после нанесения покрывающей композиции.
2. Способ по п.1, где коллоидный раствор является щелочным.
3. Способ по п.2, в котором используют коллоидный раствор, стабилизированный основным соединением.
4. Способ по любому из пп.1-3, где покрывающая композиция включает:
от 25 до 50% водного коллоидного раствора огнеупорного оксида с концентрацией огнеупорного оксида в пределах от 25 до 50%;
от 5 до 20% порошка стекловидного соединения, по существу, боросиликатного типа;
от 30 до 60% порошка борида металла, и
возможный остаток составляет вода.
5. Способ по любому из пп.1-3, где формируют покрытие, имеющее после термической обработки толщину в пределах от 50 до 250 мкм.
6. Способ по п.5, где формируют покрытие, имеющее толщину в пределах от 50 до 100 мкм.
7. Способ по любому из пп.1-3, где первую термическую обработку проводят после импрегнирования импрегнирующей композицией, а вторую термическую обработку проводят после нанесения покрывающей композиции.
8. Способ по п.7, где вторую термическую обработку проводят в окисляющей атмосфере при высокой температуре в течение относительно короткого времени.
9. Способ по любому из пп.1-3, где коллоидный раствор содержит по меньшей мере один оксид, выбранный из оксидов кремния, титана, ванадия циркония и иттрия.
10. Способ по п.9, где коллоидный раствор представляет собой водный раствор коллоидной окиси кремния.
11. Способ по любому из пп.1-3, где порошок по меньшей мере одного борида металла включает порошок по меньшей мере одного борида, выбранного из боридов титана, ванадия, циркония и гафния.
12. Способ по п.4, где порошок по меньшей мере одного из боридов металла представляет собой порошок диборида титана (TiB2).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0508196 | 2005-08-01 | ||
FR0508196A FR2889186B1 (fr) | 2005-08-01 | 2005-08-01 | Procede anti-oxydation de pieces en un materiau composite contenant du carbone |
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Publication Number | Publication Date |
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RU2008101964A true RU2008101964A (ru) | 2009-09-10 |
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RU2008101964/03A RU2008101964A (ru) | 2005-08-01 | 2006-07-31 | Защита против окисления изделий из композиционного углеродосодержащего материала |
Country Status (16)
Country | Link |
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US (1) | US20070026153A1 (ru) |
EP (1) | EP1917453B1 (ru) |
JP (1) | JP2009502722A (ru) |
KR (1) | KR101168127B1 (ru) |
CN (1) | CN101233341B (ru) |
AT (1) | ATE528271T1 (ru) |
AU (1) | AU2006274791B2 (ru) |
BR (1) | BRPI0614786A2 (ru) |
CA (1) | CA2616155C (ru) |
FR (1) | FR2889186B1 (ru) |
IL (1) | IL188852A (ru) |
MX (1) | MX2008001632A (ru) |
RU (1) | RU2008101964A (ru) |
TW (1) | TW200710064A (ru) |
UA (1) | UA89414C2 (ru) |
WO (1) | WO2007015026A2 (ru) |
Families Citing this family (25)
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FR2932176B1 (fr) * | 2008-06-06 | 2012-02-03 | Snecma Propulsion Solide | Procede de realisation d'une couche auto-cicatrisante sur une piece en materiau composite c/c |
CN101866761B (zh) * | 2010-05-27 | 2012-12-19 | 福达合金材料股份有限公司 | 一种银石墨-银复合电触头材料的制备方法及其专用抗氧化剂涂料 |
FR2967170B1 (fr) * | 2010-11-10 | 2013-09-20 | Messier Bugatti | Procede de fabrication d'une piece de friction a base de materiau composite c/c |
CN102093083B (zh) * | 2010-12-06 | 2012-10-03 | 西北有色金属研究院 | 炭/炭复合材料HfC抗烧蚀涂层的制备方法 |
DE102011089125B4 (de) * | 2011-12-20 | 2021-10-21 | Robert Bosch Gmbh | Bremskörper |
CN103332962B (zh) * | 2013-06-19 | 2014-08-27 | 陕西科技大学 | 一种微波-超声-紫外法低温改性c/c 复合材料的方法 |
FR3019818B1 (fr) | 2014-04-10 | 2016-05-06 | Messier Bugatti Dowty | Protection contre l'oxydation de pieces en materiau composite contenant du carbone |
US9678029B2 (en) * | 2014-08-22 | 2017-06-13 | Honeywell International Inc. | Oxidation catalyst detector for aircraft components |
US10119585B2 (en) | 2016-01-07 | 2018-11-06 | Honeywell International Inc. | Carbon-carbon composite including hydrophobic coating |
CN105967684A (zh) * | 2016-03-23 | 2016-09-28 | 马鞍山金晟工业设计有限公司 | 一种耐紫外的复合陶瓷涂层材料 |
US10377675B2 (en) | 2016-05-31 | 2019-08-13 | Goodrich Corporation | High temperature oxidation protection for composites |
US10526253B2 (en) | 2016-12-15 | 2020-01-07 | Goodrich Corporation | High temperature oxidation protection for composites |
CN108178663B (zh) * | 2018-01-26 | 2020-09-22 | 河南省化工研究所有限责任公司 | 一种超高温抗氧化石墨模具的制备方法 |
FR3078331B1 (fr) * | 2018-02-23 | 2020-03-13 | Safran Landing Systems | Procede de protection contre l'oxydation d'une piece en materiau composite |
CN108794073A (zh) * | 2018-05-29 | 2018-11-13 | 绍兴市鼎泰节能环保科技有限公司 | 一种除尘剂及其制备方法 |
US11046619B2 (en) | 2018-08-13 | 2021-06-29 | Goodrich Corporation | High temperature oxidation protection for composites |
CN108975956B (zh) * | 2018-08-31 | 2021-05-18 | 武汉钢铁有限公司 | 提高硅钢连续退火炉用中温炭套抗氧化性能的方法 |
US11634213B2 (en) | 2018-11-14 | 2023-04-25 | Goodrich Corporation | High temperature oxidation protection for composites |
FR3095436B1 (fr) * | 2019-04-24 | 2021-04-02 | Safran Ceram | Procédé de protection contre l’oxydation d’une pièce en matériau composite comprenant du carbone |
US11472749B2 (en) | 2019-10-01 | 2022-10-18 | Goodrich Corporation | High temperature oxidation protection for composites |
GB2598269A (en) * | 2019-12-13 | 2022-03-02 | Mat I P Ltd | Composite material and method for making the same |
US20210198159A1 (en) * | 2019-12-27 | 2021-07-01 | Goodrich Corporation | High temperature oxidation protection for composites |
CN112430130B (zh) * | 2020-11-23 | 2022-11-01 | 江西信达航科新材料科技有限公司 | 一种耐高温复合涂层及其制备工艺 |
CN113683429B (zh) * | 2021-09-29 | 2022-05-20 | 湖北瑞宇空天高新技术有限公司 | 一种改性抗氧化复合磷酸盐涂层及其制备方法与应用 |
US12065380B2 (en) | 2021-11-16 | 2024-08-20 | Goodrich Corporation | High temperature oxidation protection for carbon-carbon composites |
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US2685539A (en) * | 1951-12-21 | 1954-08-03 | Great Lakes Carbon Corp | Refractory carbon and method of producing the same |
US3816330A (en) * | 1970-10-05 | 1974-06-11 | Du Pont | Method of protecting colloidal silica aquasols from bacterial degradation |
WO1988003519A1 (en) * | 1986-11-03 | 1988-05-19 | Weir Richard L | Glass ceramic precursor compositions containing titanium diboride |
US5364513A (en) * | 1992-06-12 | 1994-11-15 | Moltech Invent S.A. | Electrochemical cell component or other material having oxidation preventive coating |
FR2700773B1 (fr) * | 1993-01-28 | 1995-03-03 | Pechiney Recherche | Revêtements de protection des matériaux contre les réactions avec l'atmosphère à haute température. |
FR2726554B1 (fr) * | 1994-11-04 | 1997-01-31 | Europ Propulsion | Procede pour la protection contre l'oxydation de pieces en materiau composite contenant du carbone |
DE69701788T2 (de) * | 1996-01-18 | 2000-11-23 | Moltech Invent S.A., Luxemburg/Luxembourg | Schutz von porösen körpern gegen oxidation |
FR2838071B1 (fr) * | 2002-04-09 | 2004-07-09 | Snecma Propulsion Solide | Protection contre l'oxydation de pieces en materiau composite |
-
2005
- 2005-08-01 FR FR0508196A patent/FR2889186B1/fr not_active Expired - Fee Related
- 2005-11-15 US US11/280,588 patent/US20070026153A1/en not_active Abandoned
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2006
- 2006-07-31 MX MX2008001632A patent/MX2008001632A/es active IP Right Grant
- 2006-07-31 BR BRPI0614786-0A patent/BRPI0614786A2/pt not_active IP Right Cessation
- 2006-07-31 CN CN2006800280006A patent/CN101233341B/zh active Active
- 2006-07-31 AT AT06794510T patent/ATE528271T1/de active
- 2006-07-31 UA UAA200801223A patent/UA89414C2/ru unknown
- 2006-07-31 CA CA2616155A patent/CA2616155C/en not_active Expired - Fee Related
- 2006-07-31 AU AU2006274791A patent/AU2006274791B2/en not_active Ceased
- 2006-07-31 KR KR1020087002547A patent/KR101168127B1/ko active IP Right Grant
- 2006-07-31 RU RU2008101964/03A patent/RU2008101964A/ru not_active Application Discontinuation
- 2006-07-31 JP JP2008524556A patent/JP2009502722A/ja active Pending
- 2006-07-31 EP EP06794510A patent/EP1917453B1/fr active Active
- 2006-07-31 WO PCT/FR2006/050765 patent/WO2007015026A2/fr active Application Filing
- 2006-08-01 TW TW095128060A patent/TW200710064A/zh unknown
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Also Published As
Publication number | Publication date |
---|---|
AU2006274791B2 (en) | 2012-10-11 |
MX2008001632A (es) | 2008-04-07 |
EP1917453B1 (fr) | 2011-10-12 |
JP2009502722A (ja) | 2009-01-29 |
IL188852A (en) | 2012-02-29 |
CA2616155A1 (en) | 2007-02-08 |
KR101168127B1 (ko) | 2012-08-03 |
CN101233341A (zh) | 2008-07-30 |
AU2006274791A1 (en) | 2007-02-08 |
KR20080038144A (ko) | 2008-05-02 |
TW200710064A (en) | 2007-03-16 |
CN101233341B (zh) | 2012-10-31 |
BRPI0614786A2 (pt) | 2011-04-12 |
FR2889186A1 (fr) | 2007-02-02 |
WO2007015026A3 (fr) | 2007-05-10 |
IL188852A0 (en) | 2008-04-13 |
UA89414C2 (ru) | 2010-01-25 |
FR2889186B1 (fr) | 2008-01-04 |
EP1917453A2 (fr) | 2008-05-07 |
US20070026153A1 (en) | 2007-02-01 |
CA2616155C (en) | 2014-07-08 |
WO2007015026A2 (fr) | 2007-02-08 |
ATE528271T1 (de) | 2011-10-15 |
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