RU2006106282A - Металлический субстрат, покрытый оксидом алюминия, и каталитическая структура - Google Patents
Металлический субстрат, покрытый оксидом алюминия, и каталитическая структура Download PDFInfo
- Publication number
- RU2006106282A RU2006106282A RU2006106282/04A RU2006106282A RU2006106282A RU 2006106282 A RU2006106282 A RU 2006106282A RU 2006106282/04 A RU2006106282/04 A RU 2006106282/04A RU 2006106282 A RU2006106282 A RU 2006106282A RU 2006106282 A RU2006106282 A RU 2006106282A
- Authority
- RU
- Russia
- Prior art keywords
- alumina
- metal substrate
- ceramic layer
- layer
- metal
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims 9
- 239000002184 metal Substances 0.000 title claims 9
- 239000000758 substrate Substances 0.000 title claims 7
- 230000003197 catalytic effect Effects 0.000 title claims 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 title 1
- 238000000034 method Methods 0.000 claims 11
- 239000000919 ceramic Substances 0.000 claims 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 5
- 239000003054 catalyst Substances 0.000 claims 4
- 239000000725 suspension Substances 0.000 claims 3
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 239000011859 microparticle Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 238000005507 spraying Methods 0.000 claims 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011343 solid material Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0242—Coating followed by impregnation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (11)
1. Способ покрытия металлического субстрата слоем керамики, подходящей в качестве носителя для катализатора Фишера-Тропша, включающий образование суспензии, содержащей дисперсный оксид алюминия и оксид алюминия в виде микрочастиц, причем оксид алюминия в виде микрочастиц имеет размер частиц больший, чем 1 мкм, и доля дисперсного оксида алюминия находится между 5 и 35 мас.% от суммарного количества оксида алюминия, и напыление капелек суспензии на горячий металлический субстрат, причем субстрат находится при температуре от 500°С до 750°С.
2. Способ по п.1, в котором капельки содержат, по меньшей мере, 15% твердого материала.
3. Способ по п.1, в котором металлический субстрат содержит несущую алюминий ферритную сталь.
4. Способ по п.1, в котором керамический слой также включает в себя стабилизатор.
5. Способ по п.1, в котором покрытый субстрат потом прокаливают.
6. Способ по п.1, в котором слой создают последовательным напылением капелек суспензии различных композиций.
7. Способ по п.6, в котором композиции таковы, что пористость слоя возрастает в направлении подвергаемой воздействию поверхности.
8. Способ получения катализатора, включающий покрытие металлического субстрата слоем пористой керамики способом по любому из предыдущих пунктов и внедрение каталитического материала в керамический слой.
9. Способ по п.8, в котором материал катализатора представляет собой каталитический металл, и каталитический металл внедряют контактированием керамического слоя с раствором соли металла в растворителе, содержащем органическую жидкость, поверхностное натяжение и вязкость которой ниже, чем поверхностное натяжение и вязкость воды.
10. Способ по п.8 или 9, в котором керамический слой включает в себя каталитический металл, и его затем покрывают воском, чтобы предохранить от действия атмосферных условий.
11. Катализатор, полученный способом по любому из пп.8-10.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0318027.0A GB0318027D0 (en) | 2003-08-01 | 2003-08-01 | Catalyst structure and catalytic reactor |
| GB0318027.0 | 2003-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2006106282A true RU2006106282A (ru) | 2006-08-27 |
Family
ID=27799614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006106282/04A RU2006106282A (ru) | 2003-08-01 | 2004-07-28 | Металлический субстрат, покрытый оксидом алюминия, и каталитическая структура |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20070232482A1 (ru) |
| EP (1) | EP1654063A1 (ru) |
| JP (1) | JP2007501114A (ru) |
| KR (1) | KR20060066715A (ru) |
| CN (1) | CN1863598A (ru) |
| AU (1) | AU2004261481A1 (ru) |
| CA (1) | CA2534187A1 (ru) |
| GB (1) | GB0318027D0 (ru) |
| MX (1) | MXPA06001324A (ru) |
| NO (1) | NO20060504L (ru) |
| OA (1) | OA13226A (ru) |
| RU (1) | RU2006106282A (ru) |
| WO (1) | WO2005011864A1 (ru) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0515276D0 (en) | 2005-07-26 | 2005-08-31 | Accentus Plc | Catalyst |
| GB0602922D0 (en) * | 2006-02-14 | 2006-03-22 | Accentus Plc | Catalyst preparation |
| GB0608927D0 (en) | 2006-05-08 | 2006-06-14 | Accentus Plc | Catalytic Reactor |
| US8609206B2 (en) * | 2008-05-01 | 2013-12-17 | Maxim Seleznev | Continuous or discrete metallization layer on a ceramic substrate |
| DE102008050926A1 (de) * | 2008-10-10 | 2010-04-15 | Nanoscape Ag | Adsorberelement und Verfahren zur Herstellung eines Adsorberelements |
| GB201001144D0 (en) * | 2010-01-25 | 2010-03-10 | Compactgtl Plc | Catalytic reactor treatment process |
| CN102553596B (zh) | 2010-12-10 | 2013-07-31 | 中国石油天然气股份有限公司 | 一种在金属基板上制备催化剂涂层的方法 |
| CN102139215B (zh) * | 2011-03-03 | 2013-01-30 | 清华大学 | 一种合成气甲烷化催化剂的制备方法 |
| KR101297599B1 (ko) | 2011-04-26 | 2013-08-19 | 한국화학연구원 | 우수한 열전달 성능을 갖는 피셔-트롭시 합성용 촉매 |
| CN103084218A (zh) * | 2013-01-28 | 2013-05-08 | 江苏帕艾尼尔科技有限公司 | 一种在海绵金属上负载涂层的方法及由该方法制备的涂层 |
| US9676623B2 (en) | 2013-03-14 | 2017-06-13 | Velocys, Inc. | Process and apparatus for conducting simultaneous endothermic and exothermic reactions |
| KR101564162B1 (ko) | 2014-02-12 | 2015-10-28 | 영남대학교 산학협력단 | 다공성 지지체가 코팅된 촉매플레이트 제조방법 |
| CN105642297A (zh) * | 2015-12-29 | 2016-06-08 | 中国石油大学(北京) | 一种将大孔钙钛矿氧化物催化剂涂覆在堇青石表面的方法 |
| CN105642110A (zh) * | 2016-01-25 | 2016-06-08 | 芜湖美智空调设备有限公司 | 催化组件及其制备方法和空气调节设备 |
| CN107226719B (zh) * | 2017-05-12 | 2021-01-19 | 华南理工大学 | 一种氧化石墨烯膜的制备方法及其制备的氧化石墨烯膜在高浓度乙二醇溶液脱水中的应用 |
| CN114768886B (zh) * | 2022-03-17 | 2023-09-29 | 西安热工研究院有限公司 | 一种复合金属氧化物催化剂的涂覆方法 |
| CN117227272A (zh) * | 2023-08-15 | 2023-12-15 | 苏州晶瓷超硬材料有限公司 | 一种金属陶瓷复合材料及其制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA979180A (en) * | 1972-04-12 | 1975-12-09 | Janice L. Stiles | Process for depositing noble metal catalysts |
| FR2512004A1 (fr) * | 1981-08-27 | 1983-03-04 | Rhone Poulenc Spec Chim | Composition d'alumine pour le revetement d'un support de catalyseur, son procede de fabrication et le support de catalyseur obtenu |
| FR2556235A1 (fr) * | 1983-12-09 | 1985-06-14 | Pro Catalyse | Procede de fabrication d'un catalyseur a base d'alumine |
| US4921731A (en) * | 1986-02-25 | 1990-05-01 | University Of Florida | Deposition of ceramic coatings using sol-gel processing with application of a thermal gradient |
| FR2621498B1 (fr) * | 1987-10-07 | 1990-01-12 | Total France | Perfectionnements apportes aux catalyseurs solides en grains, procede de preparation de ces catalyseurs et applications de ceux-ci |
| US5032568A (en) * | 1989-09-01 | 1991-07-16 | Regents Of The University Of Minnesota | Deposition of superconducting thick films by spray inductively coupled plasma method |
| US5449452A (en) * | 1993-09-20 | 1995-09-12 | Sudhakar; Chakka | Hydrodearomatization of hydrocarbons |
| US6369000B1 (en) * | 1999-09-17 | 2002-04-09 | Phillips Petroleum Company | Process for producing a metal aluminate catalyst support |
| US6331574B1 (en) * | 1999-10-08 | 2001-12-18 | Exxonmobil Research And Engineering Company | Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions |
| JP3783530B2 (ja) * | 2000-06-22 | 2006-06-07 | ヤマハ株式会社 | 光酸化触媒 |
| US20020127455A1 (en) * | 2001-03-08 | 2002-09-12 | The Regents Of The University Of California | Ceria-based solid oxide fuel cells |
| AU2002331937B2 (en) * | 2001-10-12 | 2007-07-05 | Compactgtl Plc | Catalytic reactor |
| GB0125321D0 (en) * | 2001-10-22 | 2001-12-12 | Lattice Intellectual Property | Catalyst surfaces |
| US6753354B2 (en) * | 2002-01-29 | 2004-06-22 | Exxonmobil Research And Engineering Company | Fischer-tropsch catalyst enhancement |
-
2003
- 2003-08-01 GB GBGB0318027.0A patent/GB0318027D0/en not_active Ceased
-
2004
- 2004-07-28 MX MXPA06001324A patent/MXPA06001324A/es unknown
- 2004-07-28 KR KR1020067002246A patent/KR20060066715A/ko not_active Application Discontinuation
- 2004-07-28 JP JP2006522391A patent/JP2007501114A/ja active Pending
- 2004-07-28 CN CNA2004800288102A patent/CN1863598A/zh active Pending
- 2004-07-28 CA CA002534187A patent/CA2534187A1/en not_active Abandoned
- 2004-07-28 AU AU2004261481A patent/AU2004261481A1/en not_active Abandoned
- 2004-07-28 US US10/566,657 patent/US20070232482A1/en not_active Abandoned
- 2004-07-28 OA OA1200600033A patent/OA13226A/en unknown
- 2004-07-28 RU RU2006106282/04A patent/RU2006106282A/ru not_active Application Discontinuation
- 2004-07-28 EP EP04743606A patent/EP1654063A1/en not_active Ceased
- 2004-07-28 WO PCT/GB2004/003280 patent/WO2005011864A1/en active Application Filing
-
2006
- 2006-01-31 NO NO20060504A patent/NO20060504L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US20070232482A1 (en) | 2007-10-04 |
| CN1863598A (zh) | 2006-11-15 |
| KR20060066715A (ko) | 2006-06-16 |
| NO20060504L (no) | 2006-04-26 |
| OA13226A (en) | 2006-12-13 |
| AU2004261481A1 (en) | 2005-02-10 |
| CA2534187A1 (en) | 2005-02-10 |
| WO2005011864A1 (en) | 2005-02-10 |
| EP1654063A1 (en) | 2006-05-10 |
| JP2007501114A (ja) | 2007-01-25 |
| MXPA06001324A (es) | 2006-05-04 |
| GB0318027D0 (en) | 2003-09-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20081003 |
|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20081003 |
|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20081003 |