RU2006106051A - Катализатор для окисления в газовой фазе - Google Patents
Катализатор для окисления в газовой фазе Download PDFInfo
- Publication number
- RU2006106051A RU2006106051A RU2006106051/04A RU2006106051A RU2006106051A RU 2006106051 A RU2006106051 A RU 2006106051A RU 2006106051/04 A RU2006106051/04 A RU 2006106051/04A RU 2006106051 A RU2006106051 A RU 2006106051A RU 2006106051 A RU2006106051 A RU 2006106051A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- calculated
- copolymer
- catalytically active
- vinyl
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract 12
- 230000003647 oxidation Effects 0.000 title claims abstract 3
- 238000007254 oxidation reaction Methods 0.000 title claims abstract 3
- 229920001577 copolymer Polymers 0.000 claims abstract 7
- 239000011230 binding agent Substances 0.000 claims abstract 4
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract 4
- 239000007864 aqueous solution Substances 0.000 claims abstract 2
- 239000007900 aqueous suspension Substances 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- 239000006185 dispersion Substances 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 239000002243 precursor Substances 0.000 claims abstract 2
- 239000000725 suspension Substances 0.000 claims abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract 2
- 229920002554 vinyl polymer Polymers 0.000 claims abstract 2
- 239000004711 α-olefin Substances 0.000 claims abstract 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- -1 Cesium compound Chemical class 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 229940078552 o-xylene Drugs 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims 1
- 229910010413 TiO 2 Inorganic materials 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 229910000410 antimony oxide Inorganic materials 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 claims 1
- 229910001882 dioxygen Inorganic materials 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 229910001935 vanadium oxide Inorganic materials 0.000 claims 1
- 239000012041 precatalyst Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0219—Coating the coating containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0232—Coating by pulverisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10335346.1 | 2003-08-01 | ||
| DE10335346A DE10335346A1 (de) | 2003-08-01 | 2003-08-01 | Katalysator für Gasphasenoxidationen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2006106051A true RU2006106051A (ru) | 2007-09-10 |
Family
ID=34089027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006106051/04A RU2006106051A (ru) | 2003-08-01 | 2004-07-30 | Катализатор для окисления в газовой фазе |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20060235232A1 (https=) |
| EP (1) | EP1654061B1 (https=) |
| JP (1) | JP4518423B2 (https=) |
| KR (1) | KR20060056974A (https=) |
| CN (1) | CN100377785C (https=) |
| AT (1) | ATE360480T1 (https=) |
| BR (1) | BRPI0413184A (https=) |
| DE (2) | DE10335346A1 (https=) |
| IL (1) | IL173186A0 (https=) |
| IN (1) | IN2006CH00411A (https=) |
| MX (1) | MXPA06001043A (https=) |
| RU (1) | RU2006106051A (https=) |
| TW (1) | TW200510066A (https=) |
| UA (1) | UA79905C2 (https=) |
| WO (1) | WO2005011862A1 (https=) |
| ZA (1) | ZA200601747B (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10334132A1 (de) | 2003-07-25 | 2005-04-07 | Basf Ag | Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung |
| EP1814660A1 (de) * | 2004-11-18 | 2007-08-08 | Basf Aktiengesellschaft | Verwendung von titandioxidgemischen zur herstellung von katalysatoren |
| DE102005026360A1 (de) * | 2005-06-07 | 2006-12-28 | Basf Ag | Verfahren zur Präformierung von Oxidationskatalysatoren |
| WO2007059974A1 (de) * | 2005-11-23 | 2007-05-31 | Süd-Chemie AG | Schalenkatalysator, insbesondere zur oxidation von methanol zu formaldehyd sowie verfahren zu dessen herstellung |
| JP2009537316A (ja) * | 2006-05-19 | 2009-10-29 | ビーエーエスエフ ソシエタス・ヨーロピア | カルボン酸および／またはカルボン酸無水物を製造するための触媒系 |
| EP1860091A1 (de) * | 2006-05-23 | 2007-11-28 | Süd-Chemie Ag | Katalysator enthaltend Titandioxid, insbesondere zur Herstellung von Phthalsäurenanhydrid |
| US9212157B2 (en) * | 2010-07-30 | 2015-12-15 | Basf Se | Catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride |
| JP6173458B2 (ja) * | 2012-08-24 | 2017-08-02 | クリスタル ユーエスエー インコーポレイテッド | 触媒支持体材料、触媒、ならびにそれらの製造方法および使用 |
| CN105339338B (zh) | 2013-06-26 | 2017-11-21 | 巴斯夫欧洲公司 | 起动气相氧化反应器的方法 |
| IT202100021746A1 (it) | 2021-08-11 | 2023-02-11 | Polynt S P A | Letto catalitico multistrato per la produzione di anidride ftalica. |
| CN115646494B (zh) * | 2022-11-16 | 2024-03-26 | 上海化工研究院有限公司 | 一种过渡金属改性大比表面积整体式催化剂及其制备和应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1745570C3 (de) * | 1968-02-20 | 1973-10-04 | Wacker-Chemie Gmbh, 8000 Muenchen | Verwendung von Aldehyden zur Herstellung von quallenfrei löslichen Copolymeren |
| DE2238067C3 (de) * | 1972-08-02 | 1979-04-12 | Wacker-Chemie Gmbh, 8000 Muenchen | Verfahren zur Herstellung von Phthalsäureanhydrid |
| US4172209A (en) * | 1978-08-23 | 1979-10-23 | Uop Inc. | Process for producing dicarboxylic acids by the oxidation of xylene |
| JPS592474B2 (ja) * | 1979-12-19 | 1984-01-18 | 電気化学工業株式会社 | 接着剤組成物 |
| DE3010710A1 (de) * | 1980-03-20 | 1981-09-24 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von katalysatoren fuer die gasphaseoxidation von gesaettigten und/oder ungesaettigten c(pfeil abwaerts)4(pfeil abwaerts)-kohlenwasserstoffen zu maleinsaeureanhydrid |
| US4397768A (en) * | 1981-02-26 | 1983-08-09 | Oxidaciones Organicas, C.A. "Oxidor" | Supported catalyst for the preparation of phthalic anhydride |
| DE3125062C2 (de) * | 1981-06-26 | 1984-11-22 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von abriebfesten Schalenkatalysatoren und Verwendung eines so erhaltenen Katalysators |
| DE19519172A1 (de) * | 1995-05-24 | 1996-11-28 | Consortium Elektrochem Ind | Trägerkatalysator für Gasphasenoxidationsreaktoren |
| DE19649426A1 (de) * | 1996-11-28 | 1998-06-04 | Consortium Elektrochem Ind | Schalenkatalysator zur Herstellung von Essigsäure durch Gasphasenoxidation von ungesättigten C¶4¶-Kohlenwasserstoffen |
| SE9700655L (sv) * | 1997-02-25 | 1998-05-11 | Neste Oy | Förfarande för framställning av ftalsyraanhydrid |
| DE19823052A1 (de) * | 1998-05-22 | 1999-11-25 | Consortium Elektrochem Ind | Schalenkatalysator zur Herstellung von Essigsäure durch Gasphasenoxidation von gesättigten und/oder ungesättigten C4-Kohlenwasserstoffen |
| DE19823262A1 (de) * | 1998-05-26 | 1999-12-02 | Basf Ag | Verfahren zur Herstellung von Phthalsäureanhydrid |
| DE19824532A1 (de) * | 1998-06-03 | 1999-12-09 | Basf Ag | Verfahren zur Herstellung von Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen und so erhältliche Katalysatoren |
| DE19839001A1 (de) * | 1998-08-27 | 2000-03-02 | Basf Ag | Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen |
| DE19851786A1 (de) * | 1998-11-10 | 2000-05-11 | Basf Ag | Silber- und Vanadiumoxid enthaltendes Multimetalloxid und dessen Verwendung |
| DE19931902A1 (de) * | 1999-07-08 | 2001-01-18 | Consortium Elektrochem Ind | Verfahren zur Herstellung von monolithischen Oxidationskatalysatoren und deren Verwendung bei der Gasphasenoxidation von Kohlenwasserstoffen |
-
2003
- 2003-08-01 DE DE10335346A patent/DE10335346A1/de not_active Withdrawn
-
2004
- 2004-07-29 TW TW093122751A patent/TW200510066A/zh unknown
- 2004-07-30 RU RU2006106051/04A patent/RU2006106051A/ru not_active Application Discontinuation
- 2004-07-30 EP EP04763675A patent/EP1654061B1/de not_active Expired - Lifetime
- 2004-07-30 AT AT04763675T patent/ATE360480T1/de not_active IP Right Cessation
- 2004-07-30 CN CNB200480022282XA patent/CN100377785C/zh not_active Expired - Fee Related
- 2004-07-30 UA UAA200602257A patent/UA79905C2/uk unknown
- 2004-07-30 DE DE502004003631T patent/DE502004003631D1/de not_active Expired - Lifetime
- 2004-07-30 BR BRPI0413184-3A patent/BRPI0413184A/pt not_active IP Right Cessation
- 2004-07-30 JP JP2006522301A patent/JP4518423B2/ja not_active Expired - Fee Related
- 2004-07-30 US US10/565,731 patent/US20060235232A1/en not_active Abandoned
- 2004-07-30 WO PCT/EP2004/008596 patent/WO2005011862A1/de not_active Ceased
- 2004-07-30 KR KR1020067002240A patent/KR20060056974A/ko not_active Withdrawn
- 2004-07-30 MX MXPA06001043A patent/MXPA06001043A/es unknown
-
2006
- 2006-01-17 IL IL173186A patent/IL173186A0/en unknown
- 2006-02-01 IN IN411CH2006 patent/IN2006CH00411A/en unknown
- 2006-02-28 ZA ZA200601747A patent/ZA200601747B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN2006CH00411A (https=) | 2007-07-06 |
| TW200510066A (en) | 2005-03-16 |
| DE502004003631D1 (de) | 2007-06-06 |
| JP4518423B2 (ja) | 2010-08-04 |
| EP1654061B1 (de) | 2007-04-25 |
| KR20060056974A (ko) | 2006-05-25 |
| MX221695B (es) | 2004-07-26 |
| BRPI0413184A (pt) | 2006-10-03 |
| JP2007500592A (ja) | 2007-01-18 |
| IL173186A0 (en) | 2006-06-11 |
| WO2005011862A1 (de) | 2005-02-10 |
| DE10335346A1 (de) | 2005-02-24 |
| US20060235232A1 (en) | 2006-10-19 |
| MXPA06001043A (es) | 2006-04-24 |
| CN1832803A (zh) | 2006-09-13 |
| UA79905C2 (en) | 2007-07-25 |
| WO2005011862A8 (de) | 2006-11-16 |
| EP1654061A1 (de) | 2006-05-10 |
| ATE360480T1 (de) | 2007-05-15 |
| ZA200601747B (en) | 2007-05-30 |
| CN100377785C (zh) | 2008-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA94 | Acknowledgement of application withdrawn (non-payment of fees) |
Effective date: 20080723 |