RU2005138025A - Катализаторы, содержащие серебро, получение таких катализаторов и их применение - Google Patents
Катализаторы, содержащие серебро, получение таких катализаторов и их применение Download PDFInfo
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- RU2005138025A RU2005138025A RU2005138025/04A RU2005138025A RU2005138025A RU 2005138025 A RU2005138025 A RU 2005138025A RU 2005138025/04 A RU2005138025/04 A RU 2005138025/04A RU 2005138025 A RU2005138025 A RU 2005138025A RU 2005138025 A RU2005138025 A RU 2005138025A
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- catalyst
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- outer diameter
- rhenium
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- 239000003054 catalyst Substances 0.000 title claims 22
- 229910052709 silver Inorganic materials 0.000 title claims 8
- 239000004332 silver Substances 0.000 title claims 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 7
- 229910052702 rhenium Inorganic materials 0.000 claims 7
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 239000002994 raw material Substances 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 238000006735 epoxidation reaction Methods 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 claims 1
- 150000002910 rare earth metals Chemical class 0.000 claims 1
- 229910052701 rubidium Inorganic materials 0.000 claims 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
Claims (18)
1. Катализатор, который содержит серебро, нанесенное на профилированный носитель с геометрической конфигурацией в виде полого цилиндра, в котором отношение длины к внешнему диаметру находится в интервале от 0,3 до 2 и внутренний диаметр составляет до 30% внешнего диаметра указанного профилированного носителя при допущении, что когда носитель содержит больше, чем один канал, то внутренним диаметром считается диаметр одного канала с площадью поперечного сечения, равной сумме площадей поперечных сечений всех каналов.
2. Катализатор по п.1, в котором серебро присутствует в количестве больше 15 мас.% от общей массы катализатора.
3. Катализатор по п.2, в котором серебро присутствует в количестве в интервале больше 20 мас.% до максимально 50 мас.% от общей массы катализатора.
4. Катализатор по любому из пп.1-3, в котором носитель поглощает воду в количестве больше 40%.
5. Катализатор по п.1, в котором носитель имеет площадь поверхности в интервале от 0,03 до 10 м2/г.
6. Катализатор по п.1, в котором носитель поглощает воду в количестве от 42,5 до 80% и площадь поверхности находится в интервале от 0,5 до 5 м2/г.
7. Катализатор по п.1, в котором отношение длины к внешнему диаметру находится в интервале от 0,5 до 1,6 и отношение внутреннего диаметра к внешнему диаметру находится в интервале от 0,01 до 0,25.
8. Катализатор по п.7, в котором отношение длины к внешнему диаметру находится в интервале от 0,9 до 1,1 и отношение внутреннего диаметра к внешнему диаметру находится в интервале от 0,02 до 0,2.
9. Катализатор по п.1, в котором внешний диаметр находится в интервале от 4 до 16 мм и диаметр канала меньше, чем 3,5 мм.
10. Катализатор по п.1, в котором внешний диаметр находится в интервале от 5 до 12 мм и диаметр канала находится в интервале от 0,1 до 3 мм.
11. Катализатор по п.1, в котором диаметр канала находится в интервале от 0,2 до 2 мм.
12. Катализатор по п.1, в котором катализатор дополнительно содержит промотор, представляющий собой редкоземельный металл, магний, рений или щелочной металл.
13. Катализатор по п.1, в котором катализатор дополнительно содержит промотор, представляющий собой рений, щелочной металл, который выбирают из лития, калия, рубидия и цезия, и кроме того сопромотор рения, содержащий серу, молибден, вольфрам или хром.
14. Способ, включающий получение профилированного носителя с геометрической конфигурацией, в которой отношение длины к внешнему диаметру находится в интервале от 0,3 до 2 и внутренний диаметр составляет до 30% внешнего диаметра указанного профилированного носителя для катализатора и нанесение серебра на профилированный носитель.
15. Способ по п.14, включающий нанесение на носитель помимо серебра, промотора, содержащего рений, и сопромотора рения, содержащего серу, молибден, вольфрам или хром, причем сопромотор рения наносят до или одновременно с нанесением серебра и рений наносят после того, как нанесена по меньшей мере часть серебра.
16. Способ получения этиленоксида, включающий контактирование в подходящих условиях эпоксидирования потока сырья, содержащего этилен и кислород, с катализатором по любому из пп.1-13.
17. Способ по п.16, в котором поток сырья, который контактирует с катализатором и который содержит этилен и кислород, содержит диоксид углерода в концентрации максимально 4 мол. %, в частности максимально 2 мол. %, чаще максимально 1 мол. % от всего сырья.
18. Способ применения этиленоксида для получения этиленгликоля, этиленгликолиевого эфира или 1,2-алканоламина, включающий превращение этиленоксида в этиленгликоль, этиленгликолиевый эфир или 1,2-алканоламин, причем этиленоксид получают по способу получения этиленоксида по п.16 или 17.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/431,189 US20040224841A1 (en) | 2003-05-07 | 2003-05-07 | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
US10/431,189 | 2003-05-07 | ||
US10/816,543 | 2004-04-01 | ||
US10/816,543 US7259129B2 (en) | 2003-05-07 | 2004-04-01 | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
Publications (2)
Publication Number | Publication Date |
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RU2005138025A true RU2005138025A (ru) | 2006-04-20 |
RU2342993C2 RU2342993C2 (ru) | 2009-01-10 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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RU2005138025/04A RU2342993C2 (ru) | 2003-05-07 | 2004-05-05 | Катализаторы, содержащие серебро, получение таких катализаторов и их применение |
Country Status (11)
Country | Link |
---|---|
US (1) | US7547795B2 (ru) |
EP (1) | EP1624964B1 (ru) |
KR (1) | KR20050120814A (ru) |
AU (1) | AU2004238820B2 (ru) |
BR (1) | BRPI0410090A (ru) |
CA (1) | CA2524890C (ru) |
IN (1) | IN2005DE05098A (ru) |
MX (1) | MX260863B (ru) |
RU (1) | RU2342993C2 (ru) |
TW (1) | TW200500351A (ru) |
WO (1) | WO2004101144A1 (ru) |
Families Citing this family (30)
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TW200602123A (en) * | 2004-04-01 | 2006-01-16 | Shell Int Research | Process for preparing a catalyst, the catalyst, and a use of the catalyst |
CN101072631B (zh) | 2004-09-24 | 2013-02-13 | 国际壳牌研究有限公司 | 用来选择成形颗粒的过程、用来安装系统的过程、用来在这样一种系统中使气体原料反应的过程、计算机程序产品、及计算机系统 |
CA2571808A1 (en) * | 2005-12-22 | 2007-06-22 | Shell Internationale Research Maatschappij B.V. | A method of installing an epoxidation catalyst in a reactor, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
US8357812B2 (en) | 2005-12-22 | 2013-01-22 | Shell Oil Company | Process for preparing a rejuvenated epoxidation catalyst |
US7704908B2 (en) | 2005-12-22 | 2010-04-27 | Shell Oil Company | Method for reusing rhenium from a donor spent epoxidation catalyst |
EP2679305A1 (en) * | 2006-04-10 | 2014-01-01 | Mitsubishi Chemical Corporation | Catalyst for producing ethylene oxide, process for producing the catalyst and process for producing ethylene oxide |
US7932408B2 (en) | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
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-
2004
- 2004-05-05 TW TW93112589A patent/TW200500351A/zh unknown
- 2004-05-05 RU RU2005138025/04A patent/RU2342993C2/ru active
- 2004-05-05 KR KR1020057020944A patent/KR20050120814A/ko not_active Application Discontinuation
- 2004-05-05 MX MXPA05011960 patent/MX260863B/es active IP Right Grant
- 2004-05-05 BR BRPI0410090-5A patent/BRPI0410090A/pt not_active IP Right Cessation
- 2004-05-05 AU AU2004238820A patent/AU2004238820B2/en not_active Ceased
- 2004-05-05 CA CA2524890A patent/CA2524890C/en not_active Expired - Lifetime
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- 2004-05-05 EP EP04760890.6A patent/EP1624964B1/en not_active Revoked
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2005
- 2005-11-07 IN IN5098DE2005 patent/IN2005DE05098A/en unknown
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2007
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KR20050120814A (ko) | 2005-12-23 |
IN2005DE05098A (ru) | 2009-10-09 |
WO2004101144A1 (en) | 2004-11-25 |
US7547795B2 (en) | 2009-06-16 |
CA2524890C (en) | 2012-09-11 |
RU2342993C2 (ru) | 2009-01-10 |
AU2004238820A1 (en) | 2004-11-25 |
EP1624964B1 (en) | 2019-07-31 |
MXPA05011960A (es) | 2006-02-02 |
US20080015393A1 (en) | 2008-01-17 |
TW200500351A (en) | 2005-01-01 |
CA2524890A1 (en) | 2004-11-25 |
EP1624964A1 (en) | 2006-02-15 |
AU2004238820B2 (en) | 2008-01-31 |
MX260863B (es) | 2008-09-26 |
BRPI0410090A (pt) | 2006-05-16 |
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