RU2004126865A - Композиция катализора для оксихлорирования - Google Patents
Композиция катализора для оксихлорирования Download PDFInfo
- Publication number
- RU2004126865A RU2004126865A RU2004126865/04A RU2004126865A RU2004126865A RU 2004126865 A RU2004126865 A RU 2004126865A RU 2004126865/04 A RU2004126865/04 A RU 2004126865/04A RU 2004126865 A RU2004126865 A RU 2004126865A RU 2004126865 A RU2004126865 A RU 2004126865A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst composition
- composition according
- catalyst
- salt
- metal
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 15
- 239000003054 catalyst Substances 0.000 claims 17
- 229910052751 metal Inorganic materials 0.000 claims 6
- 239000002184 metal Substances 0.000 claims 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- -1 alkali metal salt Chemical class 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 150000001805 chlorine compounds Chemical class 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 150000001879 copper Chemical class 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 159000000003 magnesium salts Chemical class 0.000 claims 1
- 229910001507 metal halide Inorganic materials 0.000 claims 1
- 150000005309 metal halides Chemical class 0.000 claims 1
- 229910052762 osmium Inorganic materials 0.000 claims 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 150000003303 ruthenium Chemical class 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/122—Halides of copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10204608.5 | 2002-02-05 | ||
| DE2002104608 DE10204608A1 (de) | 2002-02-05 | 2002-02-05 | Katalysatorzusammensetzung zur Oxychlorierung |
| DE2002136254 DE10236254A1 (de) | 2002-08-07 | 2002-08-07 | Katalysatorzusammensetzung zur Oxychlorierung |
| DE10236254.8 | 2002-08-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2004126865A true RU2004126865A (ru) | 2006-02-10 |
Family
ID=27735650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004126865/04A RU2004126865A (ru) | 2002-02-05 | 2003-02-04 | Композиция катализора для оксихлорирования |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US7126035B2 (enExample) |
| EP (2) | EP1474233A2 (enExample) |
| JP (2) | JP4121459B2 (enExample) |
| KR (1) | KR100976897B1 (enExample) |
| CN (1) | CN1627989A (enExample) |
| AU (1) | AU2003206831A1 (enExample) |
| RU (1) | RU2004126865A (enExample) |
| TW (1) | TWI255736B (enExample) |
| WO (1) | WO2003066214A2 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1885493A1 (en) * | 2005-05-12 | 2008-02-13 | Solvay (Societe Anomyme) | Oxychlorination catalyst and process using such a catalyst |
| TWI341218B (en) * | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
| EP2198958B1 (en) * | 2008-12-17 | 2017-11-08 | Clariant Prodotti (Italia) SpA | Catalysts for oxychlorination of ethylene to 1.2-dichloroethane |
| EP2208528A1 (en) * | 2008-12-23 | 2010-07-21 | Süd Chemie - Catalysts Italia S.R.L. | Catalysts for fixed bed oxychlorination of ethylene to 1.2-dichloroethane |
| US20100310441A1 (en) * | 2009-06-05 | 2010-12-09 | Basf Corporation | Catalytic Article for Removal of Volatile Organic Compounds in Low Temperature Applications |
| CN102188975B (zh) * | 2011-03-09 | 2013-01-23 | 浙江工业大学 | 一种负载型镍基双组分催化剂及其应用 |
| EP2914378B1 (en) * | 2012-11-05 | 2020-05-20 | BASF Corporation | Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane |
| WO2014145463A2 (en) * | 2013-03-15 | 2014-09-18 | Occidental Chemical Company | Catalyst and process for oxychlorination of ethylene to dichloroethane |
| CA2987508A1 (en) * | 2015-05-28 | 2016-12-01 | Evolva Sa | Biosynthesis of phenylpropanoids and phenylpropanoid derivatives |
| CN105126879B (zh) * | 2015-07-15 | 2018-01-02 | 内蒙古大学 | 一种负载型钙钛矿乙烷氧氯化制氯乙烯催化剂的制备方法 |
| CN108144632B (zh) * | 2018-01-22 | 2020-11-03 | 西安元创化工科技股份有限公司 | 一种甲烷氧氯化的二氧化钌催化剂及其制备方法 |
| KR102287846B1 (ko) * | 2018-12-21 | 2021-08-06 | 한화솔루션 주식회사 | 염소 제조를 위한 염화수소 산화반응용 촉매 및 이의 제조방법 |
| EP4182079A1 (en) * | 2020-07-14 | 2023-05-24 | SABIC Global Technologies B.V. | Catalysts for hydrogenation of aromatic containing polymers and uses thereof |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE206265C (enExample) | ||||
| NL134186C (enExample) * | 1963-10-07 | 1900-01-01 | ||
| NL130969C (enExample) * | 1964-06-01 | 1900-01-01 | ||
| IT958619B (it) * | 1971-06-30 | 1973-10-30 | Sumitomo Chemical Co | Procedimento per preparare idrocarburi clorurati |
| JPS5312485B2 (enExample) | 1973-03-22 | 1978-05-01 | ||
| ZA784827B (en) * | 1977-09-06 | 1979-08-29 | Ici Ltd | Oxyhalogenation process |
| US4300005A (en) * | 1977-12-02 | 1981-11-10 | Monsanto Co. | Preparation of vinyl chloride |
| US4446249A (en) | 1979-11-05 | 1984-05-01 | The B. F. Goodrich Company | Copper catalyst compositions for fluid-bed oxyhydrochlorination of ethylene |
| DE2949530A1 (de) * | 1979-12-08 | 1981-06-11 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von 1,2-dichlorethan |
| DE3522473A1 (de) | 1985-06-22 | 1987-01-02 | Basf Ag | Geformter katalysator, verfahren zu seiner herstellung und dessen verwendung bei der oxichlorierung von ethylen zu 1,2-dichlorethan |
| FR2600643B1 (fr) * | 1986-06-27 | 1988-09-23 | Solvay | Procede d'oxychloration de l'ethylene et compositions catalytiques pour l'oxychloration |
| GB8829706D0 (en) | 1988-12-20 | 1989-02-15 | Ici Plc | Oxychlorination catalyst composition |
| JP3092330B2 (ja) | 1992-06-30 | 2000-09-25 | 住友化学工業株式会社 | オキシ塩素化触媒、その製造方法およびそれを用いるオキシ塩素化方法 |
| US5292703A (en) * | 1992-07-28 | 1994-03-08 | The Geon Company | Catalyst and process for oxychlorination of ethylene to EDC |
| US5347046A (en) | 1993-05-25 | 1994-09-13 | Engelhard Corporation | Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters |
| BE1007818A3 (fr) | 1993-12-08 | 1995-10-31 | Solvay | Composition catalytique et procede d'oxychloration de l'ethylene utilisant une telle composition. |
| US6803342B1 (en) * | 1993-12-08 | 2004-10-12 | Solvay (Societe Anonyme) | Catalytic composition and process for the oxychlorination of ethylene using such a composition |
| DE19645047A1 (de) * | 1996-10-31 | 1998-05-07 | Basf Ag | Katalysatoren für die Aminierung von Alkylenoxiden, Alkoholen, Aldehyden und Ketonen |
| JPH11130702A (ja) * | 1997-10-27 | 1999-05-18 | Mitsui Chem Inc | エチレンのオキシクロル化方法及びその反応装置 |
| US6072078A (en) * | 1997-12-12 | 2000-06-06 | Celanese International Corporation | Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals |
| EP0931587A1 (en) * | 1998-01-08 | 1999-07-28 | Evc Technology Ag | Catalyst, process for its preparation, and its use in the synthesis of 1,2-dichloroethane |
| DE10009017A1 (de) | 2000-02-25 | 2001-09-06 | Basf Ag | Geformte Katalysatoren |
| DE10024928A1 (de) * | 2000-05-19 | 2001-11-22 | Basf Ag | Katalysatoren für heterogen katalysierte Reaktionen |
-
2003
- 2003-01-30 TW TW092102186A patent/TWI255736B/zh not_active IP Right Cessation
- 2003-02-04 WO PCT/EP2003/001093 patent/WO2003066214A2/de not_active Ceased
- 2003-02-04 KR KR1020047012024A patent/KR100976897B1/ko not_active Expired - Fee Related
- 2003-02-04 EP EP03704531A patent/EP1474233A2/de not_active Withdrawn
- 2003-02-04 CN CNA038032945A patent/CN1627989A/zh active Pending
- 2003-02-04 RU RU2004126865/04A patent/RU2004126865A/ru not_active Application Discontinuation
- 2003-02-04 EP EP10180596A patent/EP2314374A1/de not_active Withdrawn
- 2003-02-04 AU AU2003206831A patent/AU2003206831A1/en not_active Abandoned
- 2003-02-04 US US10/502,056 patent/US7126035B2/en not_active Expired - Fee Related
- 2003-02-04 JP JP2003565632A patent/JP4121459B2/ja not_active Expired - Fee Related
-
2006
- 2006-08-07 US US11/499,666 patent/US7902411B2/en not_active Expired - Fee Related
-
2008
- 2008-03-13 JP JP2008063861A patent/JP4741623B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7902411B2 (en) | 2011-03-08 |
| WO2003066214A3 (de) | 2004-02-05 |
| CN1627989A (zh) | 2005-06-15 |
| WO2003066214A2 (de) | 2003-08-14 |
| EP1474233A2 (de) | 2004-11-10 |
| US7126035B2 (en) | 2006-10-24 |
| JP2008194691A (ja) | 2008-08-28 |
| EP2314374A1 (de) | 2011-04-27 |
| AU2003206831A1 (en) | 2003-09-02 |
| KR100976897B1 (ko) | 2010-08-18 |
| KR20040073610A (ko) | 2004-08-19 |
| TWI255736B (en) | 2006-06-01 |
| TW200302752A (en) | 2003-08-16 |
| JP4121459B2 (ja) | 2008-07-23 |
| JP4741623B2 (ja) | 2011-08-03 |
| JP2005516757A (ja) | 2005-06-09 |
| AU2003206831A8 (en) | 2003-09-02 |
| US20050020864A1 (en) | 2005-01-27 |
| US20060270879A1 (en) | 2006-11-30 |
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| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20080508 |