TWI255736B - A catalyst composition for the oxychlorination of ethylene and its use - Google Patents

A catalyst composition for the oxychlorination of ethylene and its use

Info

Publication number
TWI255736B
TWI255736B TW092102186A TW92102186A TWI255736B TW I255736 B TWI255736 B TW I255736B TW 092102186 A TW092102186 A TW 092102186A TW 92102186 A TW92102186 A TW 92102186A TW I255736 B TWI255736 B TW I255736B
Authority
TW
Taiwan
Prior art keywords
weight
catalyst composition
oxychlorination
ethylene
metal
Prior art date
Application number
TW092102186A
Other languages
English (en)
Other versions
TW200302752A (en
Inventor
Christian Kuhrs
Ruprecht Meibner
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2002104608 external-priority patent/DE10204608A1/de
Priority claimed from DE2002136254 external-priority patent/DE10236254A1/de
Application filed by Basf Ag filed Critical Basf Ag
Publication of TW200302752A publication Critical patent/TW200302752A/zh
Application granted granted Critical
Publication of TWI255736B publication Critical patent/TWI255736B/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW092102186A 2002-02-05 2003-01-30 A catalyst composition for the oxychlorination of ethylene and its use TWI255736B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2002104608 DE10204608A1 (de) 2002-02-05 2002-02-05 Katalysatorzusammensetzung zur Oxychlorierung
DE2002136254 DE10236254A1 (de) 2002-08-07 2002-08-07 Katalysatorzusammensetzung zur Oxychlorierung

Publications (2)

Publication Number Publication Date
TW200302752A TW200302752A (en) 2003-08-16
TWI255736B true TWI255736B (en) 2006-06-01

Family

ID=27735650

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092102186A TWI255736B (en) 2002-02-05 2003-01-30 A catalyst composition for the oxychlorination of ethylene and its use

Country Status (9)

Country Link
US (2) US7126035B2 (zh)
EP (2) EP1474233A2 (zh)
JP (2) JP4121459B2 (zh)
KR (1) KR100976897B1 (zh)
CN (1) CN1627989A (zh)
AU (1) AU2003206831A1 (zh)
RU (1) RU2004126865A (zh)
TW (1) TWI255736B (zh)
WO (1) WO2003066214A2 (zh)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008540093A (ja) * 2005-05-12 2008-11-20 ソルヴェイ（ソシエテ アノニム） オキシ塩素化触媒及び該触媒を用いる方法
TWI341218B (en) * 2005-11-14 2011-05-01 Oxy Vinyls Lp Catalyst compositions and process for oxychlorination
EP2198958B1 (en) * 2008-12-17 2017-11-08 Clariant Prodotti (Italia) SpA Catalysts for oxychlorination of ethylene to 1.2-dichloroethane
EP2208528A1 (en) * 2008-12-23 2010-07-21 Süd Chemie - Catalysts Italia S.R.L. Catalysts for fixed bed oxychlorination of ethylene to 1.2-dichloroethane
US20100310441A1 (en) * 2009-06-05 2010-12-09 Basf Corporation Catalytic Article for Removal of Volatile Organic Compounds in Low Temperature Applications
CN102188975B (zh) * 2011-03-09 2013-01-23 浙江工业大学 一种负载型镍基双组分催化剂及其应用
WO2014071423A1 (en) * 2012-11-05 2014-05-08 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane
US9073046B2 (en) * 2013-03-15 2015-07-07 Occidental Chemical Corporation Catalyst and process for oxychlorination of ethylene to dichloroethane
EP3303601B1 (en) * 2015-05-28 2022-05-11 Evolva SA Biosynthesis of phenylpropanoids and phenylpropanoid derivatives
CN105126879B (zh) * 2015-07-15 2018-01-02 内蒙古大学 一种负载型钙钛矿乙烷氧氯化制氯乙烯催化剂的制备方法
CN108144632B (zh) * 2018-01-22 2020-11-03 西安元创化工科技股份有限公司 一种甲烷氧氯化的二氧化钌催化剂及其制备方法
CN116018206A (zh) * 2020-07-14 2023-04-25 沙特基础工业全球技术公司 用于氢化含芳香环的聚合物的催化剂及其用途

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE206265C (zh)
NL134186C (zh) * 1963-10-07 1900-01-01
NL130969C (zh) * 1964-06-01 1900-01-01
IT958619B (it) * 1971-06-30 1973-10-30 Sumitomo Chemical Co Procedimento per preparare idrocarburi clorurati
JPS5312485B2 (zh) * 1973-03-22 1978-05-01
ZA784827B (en) * 1977-09-06 1979-08-29 Ici Ltd Oxyhalogenation process
US4300005A (en) * 1977-12-02 1981-11-10 Monsanto Co. Preparation of vinyl chloride
US4446249A (en) * 1979-11-05 1984-05-01 The B. F. Goodrich Company Copper catalyst compositions for fluid-bed oxyhydrochlorination of ethylene
DE2949530A1 (de) * 1979-12-08 1981-06-11 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von 1,2-dichlorethan
DE3522473A1 (de) * 1985-06-22 1987-01-02 Basf Ag Geformter katalysator, verfahren zu seiner herstellung und dessen verwendung bei der oxichlorierung von ethylen zu 1,2-dichlorethan
FR2600643B1 (fr) * 1986-06-27 1988-09-23 Solvay Procede d'oxychloration de l'ethylene et compositions catalytiques pour l'oxychloration
GB8829706D0 (en) 1988-12-20 1989-02-15 Ici Plc Oxychlorination catalyst composition
JP3092330B2 (ja) * 1992-06-30 2000-09-25 住友化学工業株式会社 オキシ塩素化触媒、その製造方法およびそれを用いるオキシ塩素化方法
US5292703A (en) * 1992-07-28 1994-03-08 The Geon Company Catalyst and process for oxychlorination of ethylene to EDC
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
BE1007818A3 (fr) 1993-12-08 1995-10-31 Solvay Composition catalytique et procede d'oxychloration de l'ethylene utilisant une telle composition.
US6803342B1 (en) * 1993-12-08 2004-10-12 Solvay (Societe Anonyme) Catalytic composition and process for the oxychlorination of ethylene using such a composition
DE19645047A1 (de) * 1996-10-31 1998-05-07 Basf Ag Katalysatoren für die Aminierung von Alkylenoxiden, Alkoholen, Aldehyden und Ketonen
JPH11130702A (ja) * 1997-10-27 1999-05-18 Mitsui Chem Inc エチレンのオキシクロル化方法及びその反応装置
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
EP0931587A1 (en) * 1998-01-08 1999-07-28 Evc Technology Ag Catalyst, process for its preparation, and its use in the synthesis of 1,2-dichloroethane
DE10009017A1 (de) 2000-02-25 2001-09-06 Basf Ag Geformte Katalysatoren
DE10024928A1 (de) * 2000-05-19 2001-11-22 Basf Ag Katalysatoren für heterogen katalysierte Reaktionen

Also Published As

Publication number Publication date
US20060270879A1 (en) 2006-11-30
AU2003206831A8 (en) 2003-09-02
JP4741623B2 (ja) 2011-08-03
CN1627989A (zh) 2005-06-15
JP2005516757A (ja) 2005-06-09
US7902411B2 (en) 2011-03-08
AU2003206831A1 (en) 2003-09-02
WO2003066214A2 (de) 2003-08-14
EP1474233A2 (de) 2004-11-10
US20050020864A1 (en) 2005-01-27
WO2003066214A3 (de) 2004-02-05
KR20040073610A (ko) 2004-08-19
JP4121459B2 (ja) 2008-07-23
JP2008194691A (ja) 2008-08-28
US7126035B2 (en) 2006-10-24
RU2004126865A (ru) 2006-02-10
EP2314374A1 (de) 2011-04-27
KR100976897B1 (ko) 2010-08-18
TW200302752A (en) 2003-08-16

Similar Documents

Publication Publication Date Title
TWI255736B (en) A catalyst composition for the oxychlorination of ethylene and its use
EP2338886A3 (en) Naphthalene derivatives
AU4304796A (en) Preparation of aliphatic alpha, omega-aminonitriles
ID30345A (id) Katalis-katalis untuk memproduksi asam asetat atau asam asetat dan etil asetat, proses untuk memproduksinya dan proses untuk memproduksi asam asetat atau asam asetat dan etil asetat menggunakan katalis tersebut
WO2007107336A3 (en) A silicoaluminophospahte isomerisation catalyst
UA87561C2 (ru) Способ получения замещенных бифенилов
MXPA04003858A (es) Antagonistas de mch para el tratamiento de obesidad.
EP1857178A3 (en) Metal modified Pd/Ni catalysts
MY140018A (en) Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
EP1627936A3 (en) Article protected by a strong local coating
WO2005000888A3 (en) NOVEL β-ACTIN AND RPS21 PROMOTERS AND USES THEREOF
JP2007511343A5 (zh)
EP1137413A4 (en) NON-PEPTIDE GLP-1 RECEPTOR ANTAGONISTS AND TECHNIQUES FOR USE
HUP0401595A2 (hu) Eljárás 2-halogén-piridinkarboxamidok előállítására
JP2005516757A5 (zh)
EP1157739A4 (en) CATALYST FOR PRODUCING ACETIC ACID, PROCESS FOR PREPARING THE SAME, AND METHOD FOR PRODUCING ACETIC ACID USING THE CATALYST
WO2003075944A3 (en) Interferon beta-like molecules for treatment of stroke
CA2086110A1 (en) Method for producing hydrochloromethanes
HK1130850A1 (en) Platinum alloy for jewelry
HUP0004005A2 (hu) Eljárás (+)-transz-krizantém-monokarbonsav előállítására
HK1071144A1 (en) Platinum complexes containing chemically modified bile acids, having antitumor activity
JP2006117676A5 (zh)
TH74912A (th) ตัวเร่งปฏิกิริยาที่มีพัลลาเดียมผสมและวิธีการผลิตสิ่งเดียวกันนี้
EA200001017A1 (ru) КОНВЕРГЕНТНЫЙ СИНТЕЗ α-АРИЛ-β-КЕТОНИТРИЛОВ
TH46075A (zh)

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees