RO81212B - Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilide - Google Patents

Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilide

Info

Publication number
RO81212B
RO81212B RO100898A RO10089880A RO81212B RO 81212 B RO81212 B RO 81212B RO 100898 A RO100898 A RO 100898A RO 10089880 A RO10089880 A RO 10089880A RO 81212 B RO81212 B RO 81212B
Authority
RO
Romania
Prior art keywords
general formula
dialkyl
same
dialkylaniline
reaction
Prior art date
Application number
RO100898A
Other languages
English (en)
Other versions
RO81212A (ro
Inventor
Janos Domjan
Gyorgy Huezak
Zoltan Kolonics
Laszlo Lendvai
Jeno Pelyva
Endre Sumegi
Elemer Tomordi
Bela Gyorfi
J. Laszlo Szabo
Andras Haas
Miklos Kovacs
Laszlo Kulcsar
Miklos Nadasy
Balint Nagy
Andras Vass
Ervin Vertesi
Original Assignee
Nitrokemia Ipartelepek Fuzfogyartelep, Nehezvegyipari Kutato Intezet, Veszprem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitrokemia Ipartelepek Fuzfogyartelep, Nehezvegyipari Kutato Intezet, Veszprem filed Critical Nitrokemia Ipartelepek Fuzfogyartelep, Nehezvegyipari Kutato Intezet, Veszprem
Publication of RO81212A publication Critical patent/RO81212A/ro
Publication of RO81212B publication Critical patent/RO81212B/ro

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/24—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • C07C233/25—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Inventia se refera la un procedeu pentru prepararea unor 2',6-dialchil-N-(alcoximetil)-2-cloracetanilide cu formula generala I: (vezi formula) în care R1, R2 si R3, care pot fi identici sau diferiti, reprezinta radicali alchil liniari sau ramificati cu 1 pîna la 4 atomi de carbon, pornind de la 2,6-dialchilanilina cu formula generala II: (vezi formula) în care R1 si R2 au semnificatiile de mai sus, trecînd printr-o baza Schiff cu formula generala III: (vezi formula) în care R1 si R2 au semnificatiile de mai sus, prin reactia 2,6-dialchilanilinei avînd formula generala II într-un mediu de solvent apolar, la temperaturi ridicate, cu o solutie de formaldehida în exces, reactia bazei Schiff avînd formula generala III cu clorura de cloracetil în aceleasi mediu de solvent apolar cu formarea 2,6-dialchil-N-(clormetil)-2-cloracetaninei corespunzatoare avînd formula generala IV: (vezi formula) în care R1 si R2 au semnificatiile de mai sus si reactia într-o treapta a ultimului compus în acelasi mediu avînd formula generala V: (vezi formula) în care R3 are semnificatiile de mai sus, într-un exces suficient pentru legarea acidului clorhidric format fara adaugarea unui acceptor de acid.........
RO100898A 1979-04-24 1980-04-19 Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilide RO81212B (ro)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
HU79NI225A HU177876B (en) 1979-04-24 1979-04-24 Process for preparing 2,6-dialkyl-n-/alkoxy-methyl/-chloro-acetanilide derivatives

Publications (2)

Publication Number Publication Date
RO81212A RO81212A (ro) 1983-02-15
RO81212B true RO81212B (ro) 1983-02-28

Family

ID=11000009

Family Applications (1)

Application Number Title Priority Date Filing Date
RO100898A RO81212B (ro) 1979-04-24 1980-04-19 Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilide

Country Status (31)

Country Link
US (1) US4399306A (ro)
JP (1) JPS55143942A (ro)
AR (1) AR222075A1 (ro)
AT (1) AT367739B (ro)
AU (1) AU532840B2 (ro)
BE (1) BE880509A (ro)
BG (1) BG34610A3 (ro)
BR (1) BR8002193A (ro)
CA (1) CA1130317A (ro)
CH (1) CH647500A5 (ro)
CS (1) CS215057B2 (ro)
DD (1) DD150741A5 (ro)
DE (1) DE3015641C2 (ro)
DK (1) DK153543C (ro)
ES (1) ES8200327A1 (ro)
FR (1) FR2455032A1 (ro)
GB (1) GB2048868B (ro)
GR (1) GR74072B (ro)
HU (1) HU177876B (ro)
IE (1) IE49091B1 (ro)
IL (1) IL58529A (ro)
IN (1) IN151405B (ro)
IT (1) IT1146228B (ro)
LU (1) LU82242A1 (ro)
NL (1) NL185920C (ro)
NO (1) NO150601C (ro)
PL (1) PL122687B1 (ro)
PT (1) PT70537A (ro)
RO (1) RO81212B (ro)
TR (1) TR20505A (ro)
YU (1) YU41899B (ro)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5155272A (en) * 1976-12-29 1992-10-13 Monsanto Company Process for the production of haloacylamides
HU190681B (en) * 1982-01-15 1986-10-28 Eszakmagyar Vegyimuevek Process for production of n-alcoxi-alkyl-2,6-dialkylchlor-acetanilids
ES2102503T3 (es) * 1991-04-04 1997-08-01 Zeneca Ltd Proceso para efectuar reacciones quimicas con formaldehido.
ES2148791T3 (es) * 1995-09-22 2000-10-16 Zeneca Ltd Procedimiento para la produccion de azometinas y alfa-haloacetanilidas.
JP4957768B2 (ja) 2009-09-02 2012-06-20 トヨタ自動車株式会社 冷却風導入構造
CN107868020A (zh) * 2017-10-30 2018-04-03 安徽富田农化有限公司 一种甲草胺的制备方法
CN109970599A (zh) * 2017-12-28 2019-07-05 山东侨昌化学有限公司 一种连续合成乙草胺中间体n-2-甲基-6-乙基苯基甲亚胺的方法
CN114031519B (zh) * 2021-12-08 2024-04-26 浙江工业大学 一种合成n-芳基亚胺的方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3347858A (en) * 1967-10-17 Tertiary aminoethyl
US2863752A (en) * 1953-10-30 1958-12-09 Monsanto Chemicals Herbicides
NL142872C (ro) * 1963-03-28
FR1458932A (fr) * 1963-08-22 1966-04-29 Monsanto Co Procédés de préparation d'azométhines et de leurs dérivés et nouveaux produits ainsi obtenus
US3268324A (en) * 1965-10-11 1966-08-23 Monsanto Co Herbicidal composition and method employing oxa aliphatic acetamide
US3442945A (en) * 1967-05-22 1969-05-06 Monsanto Co Phytotoxic alpha-halo-acetanilides
DE1903198A1 (de) * 1969-01-23 1970-08-06 Basf Ag Substituierte Anilide
US3547620A (en) * 1969-01-23 1970-12-15 Monsanto Co N-(oxamethyl)alpha-halo-acetanilide herbicides
US3637847A (en) * 1969-09-03 1972-01-25 Monsanto Co N-haloalkyl-anilides
US3630716A (en) * 1969-09-03 1971-12-28 Monsanto Co Herbicidal compositions
BE788215A (fr) * 1971-09-01 1973-02-28 Ciba Geigy Haloacetanilides utiles comme herbicides
US3952056A (en) * 1972-02-07 1976-04-20 Ciba-Geigy Corporation Plant growth regulating agent
BE795197A (fr) * 1972-02-11 1973-08-09 Ciba Geigy Acylamines d'hydrocarbures bicycliques agissant sur la croissance des plantes
US3937730A (en) * 1972-06-06 1976-02-10 Ciba-Geigy Corporation Plant growth regulating agent
US4070179A (en) * 1973-02-07 1978-01-24 Ciba-Geigy Corporation Plant growth regulation with N-(2-alkoxy-ethyl)-N-chloroacetyl-2,3,6-trimethyl-anilines
CH579348A5 (ro) * 1973-02-08 1976-09-15 Ciba Geigy Ag
PL103793B1 (pl) * 1976-03-19 1979-07-31 Monsanto Co Srodek chwastobojczy
ES465723A1 (es) * 1976-12-29 1978-10-01 Monsanto Co Procedimiento para la preparacion y recuperacion de haloge- noacilamidas.
FR2376801A1 (fr) * 1977-01-07 1978-08-04 Lequeux Christian Perfectionnements aux dispositifs de protection mecanique des tranches annulaires de tubes ou embouts tubulaires
US4261733A (en) * 1978-11-30 1981-04-14 Monsanto Company Herbicidal compounds and method of preparation and use
ZA811810B (en) * 1980-03-25 1982-04-28 Monsanto Co A process for the in-solvent,in-situ generation of haloalkyl alkyl ethers useful ot produce n-subsituted-2-haloacetanilides

Also Published As

Publication number Publication date
ES490316A0 (es) 1981-10-16
PL122687B1 (en) 1982-08-31
AU5772280A (en) 1980-10-30
JPS55143942A (en) 1980-11-10
CA1130317A (en) 1982-08-24
PL223655A1 (ro) 1981-02-13
NO150601C (no) 1984-11-14
IL58529A0 (en) 1980-01-31
CS215057B2 (en) 1982-07-30
IN151405B (ro) 1983-04-09
IE49091B1 (en) 1985-07-24
NO801179L (no) 1980-10-27
NL185920B (nl) 1990-03-16
DE3015641A1 (de) 1980-11-06
DD150741A5 (de) 1981-09-16
YU298779A (en) 1983-01-21
DK174380A (da) 1980-10-25
IE792029L (en) 1980-10-24
DK153543C (da) 1988-12-05
BG34610A3 (en) 1983-10-15
YU41899B (en) 1988-02-29
BE880509A (fr) 1980-06-10
CH647500A5 (de) 1985-01-31
GR74072B (ro) 1984-06-06
AU532840B2 (en) 1983-10-13
ATA175880A (de) 1981-12-15
IT1146228B (it) 1986-11-12
BR8002193A (pt) 1980-11-25
NL7908591A (nl) 1980-10-28
FR2455032B1 (ro) 1983-04-01
ES8200327A1 (es) 1981-10-16
NO150601B (no) 1984-08-06
AR222075A1 (es) 1981-04-15
DE3015641C2 (de) 1986-07-17
DK153543B (da) 1988-07-25
TR20505A (tr) 1981-09-03
GB2048868B (en) 1983-05-25
JPS6155902B2 (ro) 1986-11-29
GB2048868A (en) 1980-12-17
LU82242A1 (de) 1980-06-06
US4399306A (en) 1983-08-16
FR2455032A1 (fr) 1980-11-21
NL185920C (nl) 1990-08-16
IL58529A (en) 1983-03-31
HU177876B (en) 1982-01-28
PT70537A (en) 1980-01-01
IT8048476A0 (it) 1980-04-22
RO81212A (ro) 1983-02-15
AT367739B (de) 1982-07-26

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