RO92794B - Procedeu pentru prepararea unor esteri de acid 2-brom-4-metilmidazol-5-carboxilic - Google Patents
Procedeu pentru prepararea unor esteri de acid 2-brom-4-metilmidazol-5-carboxilicInfo
- Publication number
- RO92794B RO92794B RO120425A RO12042585A RO92794B RO 92794 B RO92794 B RO 92794B RO 120425 A RO120425 A RO 120425A RO 12042585 A RO12042585 A RO 12042585A RO 92794 B RO92794 B RO 92794B
- Authority
- RO
- Romania
- Prior art keywords
- carbon atoms
- methylimidazole
- bromo
- preparation
- carboxylic acid
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- NCBRFNJSIVSEIW-UHFFFAOYSA-N 2-bromo-5-methyl-1h-imidazole-4-carboxylic acid Chemical class CC=1N=C(Br)NC=1C(O)=O NCBRFNJSIVSEIW-UHFFFAOYSA-N 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002460 imidazoles Chemical class 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/90—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor esteri de acid 2 brom-4 metilimidazol-5 carboxilic cu formula generala I : (vezi formula) în care R este alchil cu 1..10 atomi de carbon si Y este cicloalchialchil cu 3..8 atomi de carbon, în care alchilul are 1..6 atomi de carbon, alchil cu 1..6 atomi de carbon sau alchenil cu 3..6 atomi de carbon. Procedeul consta în aceea ca se trateaza un derivat de imidazol cu formula generala II: (vezi formula) în care R are semnificatiile de mai sus, cu o halogenura cu formula generala III : (vezi formula) în care Y are semnificatiile de mai sus, reactia avand loc în mediu de benzen sau toluen, în prezenta unei amine tertiare, la temperatura de reflux.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/662,009 US4595400A (en) | 1984-10-18 | 1984-10-18 | Herbicidal esters of 2-bromo-4-methylimidazole-5-carboxylic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO92794A RO92794A (ro) | 1987-11-30 |
| RO92794B true RO92794B (ro) | 1987-12-01 |
Family
ID=24656015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO120425A RO92794B (ro) | 1984-10-18 | 1985-10-17 | Procedeu pentru prepararea unor esteri de acid 2-brom-4-metilmidazol-5-carboxilic |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4595400A (ro) |
| EP (1) | EP0180787B1 (ro) |
| JP (1) | JPS6197269A (ro) |
| CN (1) | CN1007952B (ro) |
| AR (1) | AR240170A1 (ro) |
| AT (1) | ATE33643T1 (ro) |
| AU (1) | AU573911B2 (ro) |
| CA (1) | CA1258861A (ro) |
| DE (1) | DE3562245D1 (ro) |
| HU (1) | HU198607B (ro) |
| IL (1) | IL76698A (ro) |
| NZ (1) | NZ213864A (ro) |
| RO (1) | RO92794B (ro) |
| ZA (1) | ZA857970B (ro) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4770689A (en) * | 1986-03-10 | 1988-09-13 | Janssen Pharmaceutica N.V. | Herbicidal imidazole-5-carboxylic acid derivatives |
| DE3709206A1 (de) * | 1987-03-20 | 1988-09-29 | Standard Elektrik Lorenz Ag | Herstellverfahren fuer den leuchtschirm einer bildwiedergabevorrichtung |
| DE3902439A1 (de) * | 1989-01-27 | 1990-08-02 | Basf Ag | Pflanzenschuetzende mittel auf basis von 1-aryl- bzw. 1-hetarylimidazolcarbonsaeureestern |
| DE3902772A1 (de) * | 1989-01-31 | 1990-08-02 | Basf Ag | 4-aryl-2-halogenimidazol-5-carbonsaeureester, ihre herstellung und verwendung |
| US5211737A (en) * | 1989-01-31 | 1993-05-18 | Basf Aktiengesellschaft | 4-arryl-2-haloimidazole-5-carboxylic esters, the preparation and use thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2558517C2 (de) * | 1975-12-24 | 1983-11-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von 4-Methyl-imidazol-5-carbonsäureisopropylester |
| JPS5671073A (en) * | 1979-11-12 | 1981-06-13 | Takeda Chem Ind Ltd | Imidazole derivative |
| EP0127446B1 (en) * | 1983-06-01 | 1987-08-05 | Stauffer Chemical Company | Esters of 2-bromo-4-methylimidazole-5-carboxylic acid |
-
1984
- 1984-10-18 US US06/662,009 patent/US4595400A/en not_active Expired - Fee Related
-
1985
- 1985-10-07 EP EP85112680A patent/EP0180787B1/en not_active Expired
- 1985-10-07 DE DE8585112680T patent/DE3562245D1/de not_active Expired
- 1985-10-07 AT AT85112680T patent/ATE33643T1/de not_active IP Right Cessation
- 1985-10-14 IL IL76698A patent/IL76698A/xx unknown
- 1985-10-17 CN CN85109235A patent/CN1007952B/zh not_active Expired
- 1985-10-17 CA CA000493211A patent/CA1258861A/en not_active Expired
- 1985-10-17 HU HU854022A patent/HU198607B/hu not_active IP Right Cessation
- 1985-10-17 NZ NZ213864A patent/NZ213864A/xx unknown
- 1985-10-17 RO RO120425A patent/RO92794B/ro unknown
- 1985-10-17 AU AU48821/85A patent/AU573911B2/en not_active Ceased
- 1985-10-17 JP JP60230089A patent/JPS6197269A/ja active Pending
- 1985-10-17 ZA ZA857970A patent/ZA857970B/xx unknown
-
1986
- 1986-10-07 AR AR301856A patent/AR240170A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| CN1007952B (zh) | 1990-05-16 |
| AR240170A1 (es) | 1990-02-28 |
| IL76698A0 (en) | 1986-02-28 |
| IL76698A (en) | 1989-01-31 |
| JPS6197269A (ja) | 1986-05-15 |
| EP0180787B1 (en) | 1988-04-20 |
| EP0180787A1 (en) | 1986-05-14 |
| HUT39324A (en) | 1986-09-29 |
| CA1258861A (en) | 1989-08-29 |
| ATE33643T1 (de) | 1988-05-15 |
| CN85109235A (zh) | 1986-12-17 |
| AU573911B2 (en) | 1988-06-23 |
| NZ213864A (en) | 1988-11-29 |
| ZA857970B (en) | 1987-01-28 |
| DE3562245D1 (en) | 1988-05-26 |
| RO92794A (ro) | 1987-11-30 |
| US4595400A (en) | 1986-06-17 |
| HU198607B (en) | 1989-11-28 |
| AU4882185A (en) | 1986-04-24 |
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