PL1735352T3 - Latentne katalizatory metatezy olefin o wysokiej aktywności zawierające karbenowy n-heterocykliczny ligand - Google Patents
Latentne katalizatory metatezy olefin o wysokiej aktywności zawierające karbenowy n-heterocykliczny ligandInfo
- Publication number
- PL1735352T3 PL1735352T3 PL05743168T PL05743168T PL1735352T3 PL 1735352 T3 PL1735352 T3 PL 1735352T3 PL 05743168 T PL05743168 T PL 05743168T PL 05743168 T PL05743168 T PL 05743168T PL 1735352 T3 PL1735352 T3 PL 1735352T3
- Authority
- PL
- Poland
- Prior art keywords
- latent
- olefin metathesis
- catalysts containing
- heterocyclic carbene
- metathesis catalysts
- Prior art date
Links
- ADLVDYMTBOSDFE-UHFFFAOYSA-N 5-chloro-6-nitroisoindole-1,3-dione Chemical compound C1=C(Cl)C([N+](=O)[O-])=CC2=C1C(=O)NC2=O ADLVDYMTBOSDFE-UHFFFAOYSA-N 0.000 title 1
- 238000005865 alkene metathesis reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 239000003446 ligand Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F132/00—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F132/08—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/11—Homopolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/418—Ring opening metathesis polymerisation [ROMP]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55774204P | 2004-03-29 | 2004-03-29 | |
| US60415804P | 2004-08-23 | 2004-08-23 | |
| EP05743168.6A EP1735352B1 (en) | 2004-03-29 | 2005-03-29 | Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand |
| PCT/US2005/010548 WO2005094345A2 (en) | 2004-03-29 | 2005-03-29 | Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL1735352T3 true PL1735352T3 (pl) | 2020-06-29 |
Family
ID=35064307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL05743168T PL1735352T3 (pl) | 2004-03-29 | 2005-03-29 | Latentne katalizatory metatezy olefin o wysokiej aktywności zawierające karbenowy n-heterocykliczny ligand |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US20050261451A1 (enExample) |
| EP (1) | EP1735352B1 (enExample) |
| JP (2) | JP2007530706A (enExample) |
| AU (1) | AU2005228434A1 (enExample) |
| BR (1) | BRPI0509322A (enExample) |
| MX (1) | MXPA06011302A (enExample) |
| PL (1) | PL1735352T3 (enExample) |
| WO (1) | WO2005094345A2 (enExample) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19815275B4 (de) * | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| CN1802341A (zh) * | 2003-01-13 | 2006-07-12 | 卡吉尔公司 | 制备工业化学品的方法 |
| US7037987B2 (en) | 2004-03-26 | 2006-05-02 | Rohn And Haas Company | Olefin polymerization catalyst and polymerization process |
| WO2007081987A2 (en) * | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Method of making hydrogenated metathesis products |
| PL379879A1 (pl) | 2006-06-07 | 2007-12-10 | Umicore Ag & Co.Kg. | Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy |
| EP2044095B1 (en) * | 2006-06-30 | 2009-08-26 | F. Hoffmann-Roche AG | New ruthenium complexes as catalysts for metathesis reactions |
| JP5361715B2 (ja) | 2006-07-12 | 2013-12-04 | エレバンス リニューアブル サイエンシーズ， インク． | 環状オレフィンと種子油および類似物との開環交差メタセシス反応 |
| WO2008010961A2 (en) | 2006-07-13 | 2008-01-24 | Elevance Renewable Sciences, Inc. | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
| WO2008140468A2 (en) * | 2006-10-13 | 2008-11-20 | Elevance Renewable Sciences, Inc. | METHODS OF MAKING α, ω -DICARBOXYLIC ACID ALKENE DERIVATIVES BY METATHESIS |
| EP2076483A4 (en) | 2006-10-13 | 2013-12-04 | Elevance Renewable Sciences | METHODS FOR PRODUCING ORGANIC COMPOUNDS BY METATHESIS AND HYDROCYANATION |
| WO2008046106A2 (en) | 2006-10-13 | 2008-04-17 | Elevance Renewable Sciences, Inc. | Synthesis of terminal alkenes from internal alkenes via olefin metathesis |
| CN101594937B (zh) * | 2006-11-21 | 2014-04-30 | 加州理工学院 | 含有亚噻唑-2-基配体的烯烃复分解反应引发剂 |
| DE102007020694A1 (de) | 2007-05-03 | 2008-11-06 | Evonik Degussa Gmbh | Schwefelhaltige Metathesekatalysatoren |
| WO2008156451A1 (en) * | 2007-06-20 | 2008-12-24 | Agency For Science, Technology And Research | N-heterocyclic carbene metallacycle catalysts and methods |
| JP5365625B2 (ja) * | 2008-03-31 | 2013-12-11 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
| RU2375379C1 (ru) * | 2008-05-22 | 2009-12-10 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Катализатор метатезисной полимеризации дициклопентадиена, способ его получения (варианты) и способ его полимеризации |
| EP2280033B1 (en) * | 2008-05-22 | 2014-03-12 | Limited Liability Company "United Research and Development Centre" | Dicyclopentadiene metathesis polymerisation catalyst |
| RU2377257C1 (ru) * | 2008-07-31 | 2009-12-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Способ получения катализатора метатезисной полимеризации дициклопентадиена |
| RU2393171C1 (ru) * | 2008-12-10 | 2010-06-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Катализатор метатезисной полимеризации дициклопентадиена, способы его получения и способ его полимеризации |
| WO2010096445A2 (en) * | 2009-02-18 | 2010-08-26 | Henkel Corporation | Thermally switchable ruthenium initiators |
| AR078041A1 (es) * | 2009-05-05 | 2011-10-12 | Stepan Co | Tensioactivo de olefinas internas sulfonadas para recuperacion mejorada de petroleo |
| EP2255877B1 (en) | 2009-05-07 | 2014-09-24 | Umicore AG & Co. KG | Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands |
| RU2402572C1 (ru) | 2009-07-09 | 2010-10-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Способ получения полидициклопентадиена и материалов на его основе |
| RU2409420C1 (ru) * | 2009-08-21 | 2011-01-20 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Рутениевый катализатор метатезисной полимеризации дициклопентадиена и способ его получения |
| US8961776B2 (en) * | 2009-10-08 | 2015-02-24 | The Regents Of The University Of California | Molecular metal-Oxo catalysts for generating hydrogen from water |
| RU2436801C1 (ru) * | 2010-05-27 | 2011-12-20 | Закрытое Акционерное Общество "Сибур Холдинг" | Рутениевый катализатор метатезисной полимеризации дициклопентадиена (варианты) и способ получения полидициклопентадиена (варианты) |
| CN103415546A (zh) * | 2011-03-08 | 2013-11-27 | 日本瑞翁株式会社 | 聚合性组合物、树脂成形体及层叠体 |
| US8993819B2 (en) | 2011-07-12 | 2015-03-31 | Basf Se | Process for preparing cycloheptene |
| US9181360B2 (en) | 2011-08-12 | 2015-11-10 | Exxonmobil Chemical Patents Inc. | Polymers prepared by ring opening / cross metathesis |
| WO2013025284A1 (en) * | 2011-08-12 | 2013-02-21 | Exxonmobil Chemical Patents Inc. | Polymers prepared by ring opening/cross metathesis |
| US8987531B2 (en) | 2012-03-05 | 2015-03-24 | California Institute Of Technology | Syntheses of Z-olefin-containing lepidopteran insect pheromones |
| EP2639219B1 (en) * | 2012-03-14 | 2016-08-10 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts and precursors for their preparation |
| WO2014134333A1 (en) * | 2013-02-27 | 2014-09-04 | Materia, Inc. | Metal carbene olefin metathesis two catalyst composition |
| US9598531B2 (en) * | 2013-02-27 | 2017-03-21 | Materia, Inc. | Olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts |
| ES2992740T3 (en) | 2013-07-03 | 2024-12-17 | Materia Inc | Liquid molding compositions |
| WO2015076958A1 (en) * | 2013-11-22 | 2015-05-28 | Exxonmobil Chemical Patents Inc. | Novel polyesters containing polyolefin arms |
| US9382354B2 (en) | 2013-11-22 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyesters containing polyolefin arms |
| RU2545176C1 (ru) * | 2014-01-29 | 2015-03-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Катализатор метатезисной полимеризации дициклопентадиена и способ его получения |
| RU2560151C1 (ru) * | 2014-01-29 | 2015-08-20 | Открытое акционерное общество "Нефтяная компания Роснефть" | Рутениевый катализатор метатезисной полимеризации дициклопентадиена в форме катионного комплекса и способ его получения |
| RU2545179C1 (ru) * | 2014-01-29 | 2015-03-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Катализатор метатезисной полимеризации дициклопентадиена в форме рутениевого комплекса и способ его получения |
| MX2018003639A (es) | 2015-09-24 | 2019-04-25 | Umicore Ag & Co Kg | Catalizadores metálicos de metátesis olefínica de carbeno. |
| HUE053613T2 (hu) | 2015-11-18 | 2021-07-28 | Provivi Inc | Mikroorganizmusok rovarferomonok és kapcsolódó vegyületek elõállítására |
| AU2016357756B2 (en) | 2015-11-18 | 2021-09-30 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
| WO2017100585A1 (en) * | 2015-12-10 | 2017-06-15 | Materia, Inc. | Olefin metathesis catalysts |
| JP2019517797A (ja) | 2016-06-06 | 2019-06-27 | プロヴィヴィ インコーポレイテッド | 脂肪アルコールおよび脂肪アルデヒドの半生合成的生産 |
| US10792651B2 (en) * | 2016-10-19 | 2020-10-06 | Umicore Ag & Co. Kg | Synthesis and characterization of Ru alkylidene complexes |
| JP7153937B2 (ja) | 2017-02-17 | 2022-10-17 | プロビビ インコーポレイテッド | オレフィンメタセシスによるフェロモンおよび関連材料の合成方法 |
| US11104921B2 (en) | 2017-05-17 | 2021-08-31 | Provivi, Inc. | Microorganisms for the production of insect pheromones and related compounds |
| JP7416428B2 (ja) * | 2017-12-01 | 2024-01-17 | ユニバーシティ オブ フロリダ リサーチ ファンデーション インコーポレーティッド | 立体規則性環拡大メタセシス重合のための組成物および方法 |
| CN109794292B (zh) * | 2019-01-10 | 2021-12-07 | 天津大学 | Z-选择性钌卡宾烯烃复分解催化剂及其制备方法与应用 |
| PL429476A1 (pl) | 2019-04-02 | 2020-10-05 | Apeiron Synthesis Spółka Akcyjna | Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin |
| US12440831B2 (en) * | 2019-11-11 | 2025-10-14 | The Trustees of the California State University | Longer-lived ruthenium olefin metathesis catalysts supported by hemi-labile carbene ligands |
| WO2021242636A1 (en) | 2020-05-29 | 2021-12-02 | Exxonmobil Chemical Patents Inc. | Processes for producing cyclic olefins from polymers and re-polymerization thereof |
| CN111777647A (zh) * | 2020-07-31 | 2020-10-16 | 山东京博中聚新材料有限公司 | 一种共轭二烯烃聚合物中碳-碳双键的连续氢化生产装置和方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| EP0773948A4 (en) * | 1992-04-03 | 1998-09-02 | California Inst Of Techn | HIGHLY ACTIVE RUTHENIUM OR OSMIUM METAL CARBEN COMPLEXES FOR OLEFIN METHETHESE REACTIONS AND THEIR SYNTHESIS |
| US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| WO1998039346A1 (en) * | 1997-03-06 | 1998-09-11 | Ciba Specialty Chemicals Holding Inc. | New catalysts |
| MX210210B (es) * | 1997-06-27 | 2002-09-06 | Ciba Sc Holding Ag | Nuevos catalizadores |
| EP1036081B1 (en) * | 1997-12-04 | 2002-07-17 | Ciba SC Holding AG | Heterocyclyl ligand containing ruthenium and osmium catalysts |
| DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| US6107420A (en) * | 1998-07-31 | 2000-08-22 | California Institute Of Technology | Thermally initiated polymerization of olefins using Ruthenium or osmium vinylidene complexes |
| CN1213032C (zh) | 1999-05-24 | 2005-08-03 | 加州理工学院 | 咪唑烷基金属卡宾易位催化剂 |
| CA2419485C (en) * | 2000-08-10 | 2007-10-30 | The Trustees Of Boston College | Recyclable metathesis catalysts |
| US6759537B2 (en) * | 2001-03-23 | 2004-07-06 | California Institute Of Technology | Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts |
| JP4271942B2 (ja) * | 2001-03-30 | 2009-06-03 | カリフォルニア インスティチュート オブ テクノロジー | シクロオレフィンの選択的開環クロス−メタセシス |
| EP1421121A4 (en) * | 2001-08-29 | 2007-05-23 | California Inst Of Techn | RING-OPENING METETHESEPOLYMERIZATION OF BROKEN BICYCLIC AND POLYCLYCLINIC OLEFINS WITH TWO OR MORE HETEROATOMES |
| CN101172952B (zh) * | 2002-04-29 | 2013-03-27 | 陶氏环球技术有限责任公司 | 关于种子油工业应用的综合化学方法 |
-
2005
- 2005-03-29 WO PCT/US2005/010548 patent/WO2005094345A2/en not_active Ceased
- 2005-03-29 AU AU2005228434A patent/AU2005228434A1/en not_active Abandoned
- 2005-03-29 US US11/094,102 patent/US20050261451A1/en not_active Abandoned
- 2005-03-29 MX MXPA06011302A patent/MXPA06011302A/es active IP Right Grant
- 2005-03-29 JP JP2007506479A patent/JP2007530706A/ja not_active Withdrawn
- 2005-03-29 EP EP05743168.6A patent/EP1735352B1/en not_active Expired - Lifetime
- 2005-03-29 PL PL05743168T patent/PL1735352T3/pl unknown
- 2005-03-29 BR BRPI0509322-8A patent/BRPI0509322A/pt not_active Application Discontinuation
-
2011
- 2011-12-08 JP JP2011269459A patent/JP5622711B2/ja not_active Expired - Fee Related
-
2013
- 2013-02-27 US US13/779,190 patent/US8871879B2/en not_active Expired - Lifetime
-
2014
- 2014-09-26 US US14/497,387 patent/US9238709B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP5622711B2 (ja) | 2014-11-12 |
| US20050261451A1 (en) | 2005-11-24 |
| EP1735352A4 (en) | 2011-05-11 |
| WO2005094345A3 (en) | 2006-06-22 |
| EP1735352A2 (en) | 2006-12-27 |
| EP1735352B1 (en) | 2019-08-21 |
| US20150141603A1 (en) | 2015-05-21 |
| US8871879B2 (en) | 2014-10-28 |
| AU2005228434A1 (en) | 2005-10-13 |
| US9238709B2 (en) | 2016-01-19 |
| BRPI0509322A (pt) | 2007-09-04 |
| JP2007530706A (ja) | 2007-11-01 |
| MXPA06011302A (es) | 2007-01-16 |
| WO2005094345A2 (en) | 2005-10-13 |
| US20130296511A1 (en) | 2013-11-07 |
| JP2012082435A (ja) | 2012-04-26 |
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