PL129387B1 - Method of manufacture of anthraquinone,possibly substituted - Google Patents
Method of manufacture of anthraquinone,possibly substituted Download PDFInfo
- Publication number
- PL129387B1 PL129387B1 PL1981234238A PL23423881A PL129387B1 PL 129387 B1 PL129387 B1 PL 129387B1 PL 1981234238 A PL1981234238 A PL 1981234238A PL 23423881 A PL23423881 A PL 23423881A PL 129387 B1 PL129387 B1 PL 129387B1
- Authority
- PL
- Poland
- Prior art keywords
- pattern
- formula
- phthalic anhydride
- general formula
- catalyst
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/16—Quinones the quinoid structure being part of a condensed ring system containing three rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/32—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups
- C07C65/34—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups polycyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/24—Quinones containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Furan Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Claims (6)
1. Zastrzezenia patentowe 1. Sposób wytwarzania antraohinonu, ewentualnie podstawionego, o wzorze ogólnym 1, w którym R^ 9 R? , R^ i R^ oznaczaja niezaleznie atom wodoru lub chlorowca lub prosty lub rozgaleziony rodnik alkilowy o 1-5 atomach wegla, polegajacy na poddaniu reakcji bezwodni¬ ka ftalowego| ewentualnie podstawionego, o wzorze ogólnym 2 z pochodna benzenu o wzorze ogólnym 3, w którym R1 , R^, R^ 1 R, maja wyznj podane znaozenle, przy ozym stosunek molo¬ wy zwiazku o wzorze -3 do bezwodnika ftalowego wynosi 0,9-1,2, w obecnosci katalizatora, znamienny tym, ze stosuje sie katalizator skladajacy sie z mieszaniny kwasu fluorowodorowego i trójfluorku boru, a nastepnie otrzymany kwas ortobenzoilobenzoesowy o wzorze ogólnym 4» w którym R1 , R^ , L 1 R. maja wyzej podane znaczenie przeksztalca siej w zwiazek o wzorze 1 znanymi sposobami.1?9387 5
2. ?• Sposób wedlug zastrz. 1# znamienny t y m , ze stosuje sie katalizator, w którym stosunek HP/BP* wvnosi 0t?-1,5.
3. Sposób wedlug zastrz. 1 albo 2, znamienny tym, ze kondensacje prowa¬ dzi sie w temperaturze ci -60°C do +30°C i pod cisnieniem 5 • 105 - 60 • 10^ Pa.
4. « Sposób wedlug zastrz. 3» znamienny tyra, ze kondensacje prowadzi sie pod cisnieniem 15 • 10^ - 20 • 105 Pa i w temperaturze -40°C.
5. Sposób wedlug zastrz. 1# znamienny tym, ze kwas ortobenzoilobenzoesoj wy o wzorze 4 ekstrahuje sie z masy reakcyjnej wrzaca woda,
6. Sposób wedlug zastrz. 1f znamienny tyra, ze stosuje sie 5-20 moli BF- i 5-20 moli HF na jeden mol bezwodnika ftalowego. WZÓR 4 WZÓR 1 WZÓR 2 R2^ "3v RlT R1 "[i ^X00H^\R WZÓR 5 WZÓR 3 PL PL PL
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8026637A FR2496097A1 (fr) | 1980-12-16 | 1980-12-16 | Procede pour la preparation de l'anthraquinone et de ses derives substitues |
Publications (2)
Publication Number | Publication Date |
---|---|
PL234238A1 PL234238A1 (pl) | 1982-08-16 |
PL129387B1 true PL129387B1 (en) | 1984-05-31 |
Family
ID=9249130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL1981234238A PL129387B1 (en) | 1980-12-16 | 1981-12-14 | Method of manufacture of anthraquinone,possibly substituted |
Country Status (10)
Country | Link |
---|---|
US (1) | US4379092A (pl) |
EP (1) | EP0055951B1 (pl) |
JP (1) | JPS57123135A (pl) |
KR (1) | KR850001370B1 (pl) |
CS (1) | CS226041B2 (pl) |
DE (1) | DE3163926D1 (pl) |
EG (1) | EG15280A (pl) |
FR (1) | FR2496097A1 (pl) |
IN (1) | IN155771B (pl) |
PL (1) | PL129387B1 (pl) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2532303A1 (fr) * | 1982-09-01 | 1984-03-02 | Ugine Kuhlmann | Procede de decomposition d'un complexe d'acide ortho-benzoyl-benzoique, de fluorure d'hydrogene et de trifluorure de bore |
FR2543544B1 (fr) * | 1983-03-30 | 1986-01-17 | Ugine Kuhlmann | Procede de decomposition d'un complexe d'acide orthobenzoyl-benzoique, de fluorure d'hydrogene et de trifluorure de bore |
FR2572396B1 (fr) * | 1984-10-31 | 1986-12-19 | Atochem | Procede de preparation d'amyl-2-anthraquinone a partir d'amyl-benzene et d'anhydride phtalique |
US4666632A (en) * | 1986-07-08 | 1987-05-19 | The Halcon Sd Group, Inc. | Process for the preparation of anthraquinone |
US4781862A (en) * | 1986-07-08 | 1988-11-01 | Montvale Process Company, Inc. | Process for the preparation of anthraquinone |
JPH0256248A (ja) * | 1987-09-09 | 1990-02-26 | Yokoyama Yoshio | 接触的縮合反応によるアントラキノン化合物の製造方法 |
US5041571A (en) * | 1990-03-29 | 1991-08-20 | Hoechst Celanese Corporation | Process of producing anthraquinones in one step |
US5130448A (en) * | 1991-02-12 | 1992-07-14 | Hoechst Celanese Corporation | Synthesis of 1-aminoanthraquinone |
US5132437A (en) * | 1991-02-12 | 1992-07-21 | Hoechst Celanese Corporation | Synthesis of 1-aminoanthraquinone |
DE4232770A1 (de) * | 1992-09-30 | 1994-03-31 | Basf Ag | Verfahren zur Acylierung aromatischer Verbindungen |
FR2731705B1 (fr) * | 1995-03-15 | 1997-04-30 | Atochem Elf Sa | Procede de synthese de 2-ethyl-anthraquinone |
US6548722B1 (en) | 2000-10-10 | 2003-04-15 | Council Of Scientific And Industrial Research | Process for the preparation of substituted aromatic compound employing friedel-crafts reaction using a reusable basic anionic clay catalyst |
US7264886B2 (en) * | 2002-05-14 | 2007-09-04 | Viance, Llc | Water repellent compositions for wood preservatives |
US7658937B2 (en) * | 2004-05-11 | 2010-02-09 | Board Of Trustees Of Michigan State University | Anthraquinones and process for the preparation and method of use thereof |
CN103524323B (zh) * | 2013-10-17 | 2015-04-22 | 扬州大学 | 负载金属氧化物型固体超强酸催化合成邻苯甲酰苯甲酸的方法 |
CN104588087B (zh) * | 2013-11-03 | 2017-02-01 | 中国石油化工股份有限公司 | 一种用于制备2‑烷基蒽醌的催化剂及其制备方法和应用 |
CN104588088B (zh) * | 2013-11-03 | 2017-03-01 | 中国石油化工股份有限公司 | 用于制备2‑烷基蒽醌的催化剂及其制备方法和应用 |
CN105777525A (zh) * | 2016-04-11 | 2016-07-20 | 北京恒石尚德科技有限公司 | 一种2-(4-乙基苯甲酰基)苯甲酸的分离提纯方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1515325A (en) * | 1921-02-08 | 1924-11-11 | Barrett Co | Process of producing anthraquinone |
DE634987C (de) * | 1935-02-01 | 1936-09-09 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Azaverbindungen |
US2174118A (en) * | 1936-09-30 | 1939-09-26 | Du Pont | Ring closure of aromatic compounds with the aid of hydrofluoric acid |
US2401225A (en) * | 1944-03-07 | 1946-05-28 | Socony Vacuum Oil Co Inc | Production of anthraquinone |
US2842562A (en) * | 1953-10-30 | 1958-07-08 | Gen Aniline & Film Corp | Cyclization of aromatic carboxylic acid compounds |
US2871244A (en) * | 1955-06-24 | 1959-01-27 | Reynolds Metals Co | Process for the manufacture of anthraquinone and derivatives thereof |
US2967187A (en) * | 1958-12-31 | 1961-01-03 | Standard Oil Co | Production of anthraquinone |
DE2031430A1 (en) * | 1970-06-25 | 1972-02-10 | Deutsche Gold u Silber Scheide anstalt, vormals Roessler, 6000 Frank fürt | Substd anthraquinones prepn - using phosphorus cpd in ring closure |
IT1031586B (it) * | 1974-02-22 | 1979-05-10 | Sf Ag | Processo per la preparazione di o benziltolueni |
DE2616583A1 (de) * | 1975-04-18 | 1976-10-28 | Koppers Co Inc | Verfahren zum acylieren nicht- hydroxylierter aromatischer verbindungen |
JPS5929178B2 (ja) * | 1978-04-08 | 1984-07-18 | 丸善石油化学株式会社 | 2−アルキル−6−アシルナフタリンの製法 |
-
1980
- 1980-12-16 FR FR8026637A patent/FR2496097A1/fr active Granted
-
1981
- 1981-10-18 EG EG599/81A patent/EG15280A/xx active
- 1981-11-09 KR KR1019810004277A patent/KR850001370B1/ko active
- 1981-11-24 US US06/324,520 patent/US4379092A/en not_active Expired - Lifetime
- 1981-11-30 CS CS818861A patent/CS226041B2/cs unknown
- 1981-12-04 DE DE8181401932T patent/DE3163926D1/de not_active Expired
- 1981-12-04 EP EP81401932A patent/EP0055951B1/fr not_active Expired
- 1981-12-14 PL PL1981234238A patent/PL129387B1/pl unknown
- 1981-12-15 JP JP56202346A patent/JPS57123135A/ja active Granted
- 1981-12-26 IN IN1459/CAL/81A patent/IN155771B/en unknown
Also Published As
Publication number | Publication date |
---|---|
FR2496097B1 (pl) | 1982-12-17 |
JPH0124774B2 (pl) | 1989-05-15 |
JPS57123135A (en) | 1982-07-31 |
US4379092A (en) | 1983-04-05 |
DE3163926D1 (en) | 1984-07-05 |
FR2496097A1 (fr) | 1982-06-18 |
KR850001370B1 (ko) | 1985-09-24 |
KR830007488A (ko) | 1983-10-21 |
PL234238A1 (pl) | 1982-08-16 |
EP0055951B1 (fr) | 1984-05-30 |
IN155771B (pl) | 1985-03-09 |
EP0055951A1 (fr) | 1982-07-14 |
EG15280A (en) | 1985-12-31 |
CS226041B2 (en) | 1984-03-19 |
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