NO313875B1 - FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel - Google Patents
FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel Download PDFInfo
- Publication number
- NO313875B1 NO313875B1 NO19951078A NO951078A NO313875B1 NO 313875 B1 NO313875 B1 NO 313875B1 NO 19951078 A NO19951078 A NO 19951078A NO 951078 A NO951078 A NO 951078A NO 313875 B1 NO313875 B1 NO 313875B1
- Authority
- NO
- Norway
- Prior art keywords
- nickel
- aqueous solution
- nickel hydroxide
- hydroxide
- elemental
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 147
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 title claims description 60
- 229910052759 nickel Inorganic materials 0.000 title claims description 54
- 238000000034 method Methods 0.000 title claims description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 53
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 239000007864 aqueous solution Substances 0.000 claims description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 11
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- 229940075397 calomel Drugs 0.000 claims description 7
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 35
- 239000000843 powder Substances 0.000 description 21
- 229910021529 ammonia Inorganic materials 0.000 description 19
- 238000012360 testing method Methods 0.000 description 14
- 239000000725 suspension Substances 0.000 description 12
- 230000004913 activation Effects 0.000 description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 8
- 235000011130 ammonium sulphate Nutrition 0.000 description 8
- 239000002002 slurry Substances 0.000 description 7
- 230000001105 regulatory effect Effects 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 150000002815 nickel Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 235000019257 ammonium acetate Nutrition 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 3
- 239000005695 Ammonium acetate Substances 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229940043376 ammonium acetate Drugs 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- NPURPEXKKDAKIH-UHFFFAOYSA-N iodoimino(oxo)methane Chemical compound IN=C=O NPURPEXKKDAKIH-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000013101 initial test Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000007885 magnetic separation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- -1 thiosulphate anions Chemical class 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 239000004133 Sodium thiosulphate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000029219 regulation of pH Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21603694A | 1994-03-22 | 1994-03-22 | |
| US08/402,368 US5545392A (en) | 1994-03-22 | 1995-03-13 | Process for producing nickel hydroxide from elemental nickel |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO951078D0 NO951078D0 (no) | 1995-03-21 |
| NO951078L NO951078L (no) | 1995-09-25 |
| NO313875B1 true NO313875B1 (no) | 2002-12-16 |
Family
ID=26910582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19951078A NO313875B1 (no) | 1994-03-22 | 1995-03-21 | FremgangsmÕte for fremstilling av nikkelhydroksyd fra elementirt nikkel |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5545392A (fr) |
| EP (1) | EP0673882B1 (fr) |
| JP (1) | JP2758574B2 (fr) |
| CN (1) | CN1041193C (fr) |
| AT (1) | ATE161803T1 (fr) |
| AU (1) | AU678097B2 (fr) |
| CA (1) | CA2145155C (fr) |
| DE (1) | DE69501348T2 (fr) |
| ES (1) | ES2111369T3 (fr) |
| FI (1) | FI107801B (fr) |
| NO (1) | NO313875B1 (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5824283A (en) * | 1997-04-28 | 1998-10-20 | Inco Limited | Process for producing nickel hydroxide from elemental nickel |
| US6015538A (en) * | 1998-06-16 | 2000-01-18 | Inco Limited | Methods for doping and coating nickel hydroxide |
| JP2001031429A (ja) * | 1999-07-16 | 2001-02-06 | Matsushita Electric Ind Co Ltd | 水酸化ニッケルの製造方法 |
| US6652603B2 (en) | 2001-06-29 | 2003-11-25 | Inco Limited | Process for removing sodium sulfate from nickel hydroxide effluent streams |
| US6576205B2 (en) | 2001-09-04 | 2003-06-10 | Inco Limited | Method for reducing the crystallinity of nickel hydroxide powders |
| JP4880909B2 (ja) * | 2005-03-03 | 2012-02-22 | 大平洋金属株式会社 | ニッケル化合物またはコバルト化合物から硫黄などを除去する精製方法、フェロニッケルの製造方法 |
| JP2007103111A (ja) * | 2005-10-03 | 2007-04-19 | Matsushita Electric Ind Co Ltd | アルカリ一次電池およびオキシ水酸化ニッケルの製造方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA623339A (en) * | 1961-07-04 | B. Beer Henri | Method of precipitating or co-precipitating metal oxides, metal hydroxides or metal salts | |
| FR1441749A (fr) * | 1965-04-30 | 1966-06-10 | Nickel Le | Nouveau procédé de fabrication d'hydrate de nickel pur |
| DE3029898A1 (de) * | 1980-08-07 | 1982-03-04 | Varta Batterie Ag, 3000 Hannover | Verfahren zur herstellung von nickel (ii)-hydroxid |
| EP0388809B1 (fr) * | 1989-03-17 | 1996-04-24 | E.I. Du Pont De Nemours And Company | Résine de polyacétals contenant des stabilisants polymères ou cellulosiques non fusibles |
| CA2012423C (fr) * | 1989-03-20 | 2000-07-25 | Victor Alexander Ettel | Hydroxyde de nickel |
| US5281494A (en) * | 1990-05-04 | 1994-01-25 | Inco Limited | Nickel hydroxide |
| JP2673078B2 (ja) * | 1992-05-27 | 1997-11-05 | 東芝電池株式会社 | アルカリ二次電池用のペースト式電極 |
| DE69313936T2 (de) * | 1992-06-15 | 1998-04-09 | Inco Ltd | Verfahren zur Herstellung von Nickelhydroxyd |
| DE4239295C2 (de) * | 1992-11-23 | 1995-05-11 | Starck H C Gmbh Co Kg | Verfahren zur Herstellung von reinem Nickelhydroxid sowie dessen Verwendung |
| JP3225129B2 (ja) * | 1993-03-31 | 2001-11-05 | 東芝電池株式会社 | アルカリ二次電池の製造方法 |
| JPH06295727A (ja) * | 1993-04-09 | 1994-10-21 | Toshiba Battery Co Ltd | 密閉式アルカリ蓄電池 |
| CN1075697A (zh) * | 1993-04-09 | 1993-09-01 | 河南师范大学 | 球形微粒氢氧化镍制造法 |
-
1995
- 1995-03-13 US US08/402,368 patent/US5545392A/en not_active Expired - Lifetime
- 1995-03-21 AU AU14964/95A patent/AU678097B2/en not_active Ceased
- 1995-03-21 NO NO19951078A patent/NO313875B1/no unknown
- 1995-03-21 CN CN95114810A patent/CN1041193C/zh not_active Expired - Fee Related
- 1995-03-21 FI FI951326A patent/FI107801B/fi not_active IP Right Cessation
- 1995-03-21 CA CA002145155A patent/CA2145155C/fr not_active Expired - Fee Related
- 1995-03-22 AT AT95301902T patent/ATE161803T1/de not_active IP Right Cessation
- 1995-03-22 JP JP7063184A patent/JP2758574B2/ja not_active Expired - Fee Related
- 1995-03-22 EP EP95301902A patent/EP0673882B1/fr not_active Expired - Lifetime
- 1995-03-22 DE DE69501348T patent/DE69501348T2/de not_active Expired - Fee Related
- 1995-03-22 ES ES95301902T patent/ES2111369T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2145155C (fr) | 1999-01-19 |
| DE69501348D1 (de) | 1998-02-12 |
| AU1496495A (en) | 1995-09-28 |
| CA2145155A1 (fr) | 1995-09-23 |
| FI107801B (fi) | 2001-10-15 |
| FI951326A0 (fi) | 1995-03-21 |
| DE69501348T2 (de) | 1998-07-23 |
| JPH0834618A (ja) | 1996-02-06 |
| FI951326A (fi) | 1995-09-23 |
| EP0673882B1 (fr) | 1998-01-07 |
| EP0673882A1 (fr) | 1995-09-27 |
| CN1041193C (zh) | 1998-12-16 |
| NO951078D0 (no) | 1995-03-21 |
| ATE161803T1 (de) | 1998-01-15 |
| AU678097B2 (en) | 1997-05-15 |
| CN1112521A (zh) | 1995-11-29 |
| JP2758574B2 (ja) | 1998-05-28 |
| US5545392A (en) | 1996-08-13 |
| ES2111369T3 (es) | 1998-03-01 |
| NO951078L (no) | 1995-09-25 |
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