NO313556B1 - Bionedbrytbart termoplastisk materiale - Google Patents
Bionedbrytbart termoplastisk materiale Download PDFInfo
- Publication number
- NO313556B1 NO313556B1 NO19960100A NO960100A NO313556B1 NO 313556 B1 NO313556 B1 NO 313556B1 NO 19960100 A NO19960100 A NO 19960100A NO 960100 A NO960100 A NO 960100A NO 313556 B1 NO313556 B1 NO 313556B1
- Authority
- NO
- Norway
- Prior art keywords
- starch
- cellulose
- acid
- esters
- plasticizer
- Prior art date
Links
- 239000012815 thermoplastic material Substances 0.000 title claims description 4
- 229920002472 Starch Polymers 0.000 claims description 74
- 235000019698 starch Nutrition 0.000 claims description 74
- 239000008107 starch Substances 0.000 claims description 66
- 229920002678 cellulose Polymers 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 30
- 239000004014 plasticizer Substances 0.000 claims description 24
- 150000002148 esters Chemical class 0.000 claims description 22
- 229920003086 cellulose ether Polymers 0.000 claims description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 150000002170 ethers Chemical class 0.000 claims description 16
- 239000001913 cellulose Substances 0.000 claims description 14
- 229920002301 cellulose acetate Polymers 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- 238000006467 substitution reaction Methods 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 4
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 3
- 235000019443 glyceryl diacetate Nutrition 0.000 claims description 3
- 235000019871 vegetable fat Nutrition 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- 235000019737 Animal fat Nutrition 0.000 claims description 2
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 claims description 2
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004348 Glyceryl diacetate Substances 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000021314 Palmitic acid Nutrition 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 2
- 229920003232 aliphatic polyester Polymers 0.000 claims description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims description 2
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 claims description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229960004488 linolenic acid Drugs 0.000 claims description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 2
- 229960003656 ricinoleic acid Drugs 0.000 claims description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- 230000009918 complex formation Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- -1 aliphatic epoxides Chemical class 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 229920001169 thermoplastic Polymers 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 150000001242 acetic acid derivatives Chemical class 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- MKRNVBXERAPZOP-UHFFFAOYSA-N Starch acetate Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OC(C)=O)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 MKRNVBXERAPZOP-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000032798 delamination Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- UNVGBIALRHLALK-UHFFFAOYSA-N 1,5-Hexanediol Chemical compound CC(O)CCCCO UNVGBIALRHLALK-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229920000945 Amylopectin Polymers 0.000 description 2
- 229920000856 Amylose Polymers 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical group 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229920001727 cellulose butyrate Polymers 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002314 glycerols Chemical class 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000012948 isocyanate Chemical group 0.000 description 2
- 150000002513 isocyanates Chemical group 0.000 description 2
- 239000000594 mannitol Substances 0.000 description 2
- 235000010355 mannitol Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- HDDLVZWGOPWKFW-UHFFFAOYSA-N trimethyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical group COC(=O)CC(O)(C(=O)OC)CC(=O)OC HDDLVZWGOPWKFW-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- BZANQLIRVMZFOS-ZKZCYXTQSA-N (3r,4s,5s,6r)-2-butoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound CCCCOC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O BZANQLIRVMZFOS-ZKZCYXTQSA-N 0.000 description 1
- FQYIVQJZLGXHRW-DAQCVMAMSA-N (4s,5r,6r,7r)-3,4,5,6,7,8-hexahydroxyoctanoic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)CC(O)=O FQYIVQJZLGXHRW-DAQCVMAMSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MLQBTMWHIOYKKC-KTKRTIGZSA-N (z)-octadec-9-enoyl chloride Chemical class CCCCCCCC\C=C/CCCCCCCC(Cl)=O MLQBTMWHIOYKKC-KTKRTIGZSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- FCJKZKYOELZWNI-UHFFFAOYSA-N 2-(2-ethoxyethoxycarbonyl)benzoic acid Chemical compound CCOCCOC(=O)C1=CC=CC=C1C(O)=O FCJKZKYOELZWNI-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical group CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Chemical group 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- VQQZLJFQCJMNLN-UHFFFAOYSA-N N=C=O.N=C=O.NCCCCCCN Chemical compound N=C=O.N=C=O.NCCCCCCN VQQZLJFQCJMNLN-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 101710186154 S-adenosylmethionine synthase 1 Proteins 0.000 description 1
- 101710186153 S-adenosylmethionine synthase 2 Proteins 0.000 description 1
- 102100026115 S-adenosylmethionine synthase isoform type-1 Human genes 0.000 description 1
- 101710167538 S-adenosylmethionine synthase isoform type-1 Proteins 0.000 description 1
- 102100035947 S-adenosylmethionine synthase isoform type-2 Human genes 0.000 description 1
- 101710167557 S-adenosylmethionine synthase isoform type-2 Proteins 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005011 alkyl ether group Chemical group 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical class CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000006911 enzymatic reaction Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- GFMIDCCZJUXASS-UHFFFAOYSA-N hexane-1,1,6-triol Chemical compound OCCCCCC(O)O GFMIDCCZJUXASS-UHFFFAOYSA-N 0.000 description 1
- WJSATVJYSKVUGV-UHFFFAOYSA-N hexane-1,3,5-triol Chemical compound CC(O)CC(O)CCO WJSATVJYSKVUGV-UHFFFAOYSA-N 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002485 inorganic esters Chemical class 0.000 description 1
- 239000006101 laboratory sample Substances 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 150000002632 lipids Chemical group 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229940067631 phospholipid Drugs 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/04—Starch derivatives, e.g. crosslinked derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI950023A IT1272871B (it) | 1995-01-10 | 1995-01-10 | Composizioni termoplastiche compredenti amido ed altre componenti di origine naturale |
Publications (3)
Publication Number | Publication Date |
---|---|
NO960100D0 NO960100D0 (no) | 1996-01-09 |
NO960100L NO960100L (no) | 1996-07-11 |
NO313556B1 true NO313556B1 (no) | 2002-10-21 |
Family
ID=11370152
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO19960100A NO313556B1 (no) | 1995-01-10 | 1996-01-09 | Bionedbrytbart termoplastisk materiale |
Country Status (26)
Country | Link |
---|---|
US (1) | US6506824B1 (ja) |
EP (1) | EP0722980B1 (ja) |
JP (1) | JPH08231762A (ja) |
KR (1) | KR100408337B1 (ja) |
CN (1) | CN1125118C (ja) |
AR (1) | AR000641A1 (ja) |
AT (1) | ATE208804T1 (ja) |
AU (1) | AU705176B2 (ja) |
CA (1) | CA2166921A1 (ja) |
CZ (1) | CZ7796A3 (ja) |
DE (1) | DE69616840T2 (ja) |
DK (1) | DK0722980T3 (ja) |
ES (1) | ES2164788T3 (ja) |
FI (1) | FI960097A (ja) |
HU (1) | HU220791B1 (ja) |
IL (1) | IL116698A (ja) |
IN (1) | IN186693B (ja) |
IT (1) | IT1272871B (ja) |
MX (1) | MX9600162A (ja) |
NO (1) | NO313556B1 (ja) |
NZ (1) | NZ280798A (ja) |
PL (1) | PL184475B1 (ja) |
PT (1) | PT722980E (ja) |
SK (1) | SK3596A3 (ja) |
TW (1) | TW394788B (ja) |
ZA (1) | ZA96184B (ja) |
Families Citing this family (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69730852T2 (de) | 1996-11-05 | 2005-09-22 | Novamont S.P.A. | Biologisch abbaubare polymerzusammensetzungen, die stärke und ein thermoplastisches polymer enthalten |
IT1303553B1 (it) * | 1998-09-01 | 2000-11-14 | Novamont Spa | Composizioni biodegradabili comprendenti amido ed esteri di cellulosa. |
NZ503232A (en) | 1999-03-08 | 2001-11-30 | Humatro Corp | Melt processable starch compositions comprising amylopectin and a high polymer (such as polyacrylamide) |
US6811740B2 (en) | 2000-11-27 | 2004-11-02 | The Procter & Gamble Company | Process for making non-thermoplastic starch fibers |
US7029620B2 (en) | 2000-11-27 | 2006-04-18 | The Procter & Gamble Company | Electro-spinning process for making starch filaments for flexible structure |
US20030203196A1 (en) * | 2000-11-27 | 2003-10-30 | Trokhan Paul Dennis | Flexible structure comprising starch filaments |
KR100445835B1 (ko) * | 2001-05-25 | 2004-08-25 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 |
WO2003014217A1 (fr) * | 2001-08-07 | 2003-02-20 | Eiko Yamaguchi | Melange polymere biodegradable |
US7276201B2 (en) | 2001-09-06 | 2007-10-02 | The Procter & Gamble Company | Process for making non-thermoplastic starch fibers |
EP1465944B1 (en) * | 2002-01-16 | 2015-02-25 | Eastman Chemical Company | Novel carbohydrate esters and polyol esters as plasticizers for polymers, compositions and articles including such plasticizers and methods of using the same |
US6723160B2 (en) | 2002-02-01 | 2004-04-20 | The Procter & Gamble Company | Non-thermoplastic starch fibers and starch composition for making same |
FI113875B (fi) * | 2002-02-15 | 2004-06-30 | Valtion Teknillinen | Uudet tärkkelysjohdannaiset ja menetelmä niiden valmistamiseksi |
DE10258227A1 (de) * | 2002-12-09 | 2004-07-15 | Biop Biopolymer Technologies Ag | Biologisch abbaubare Mehrschichtfolie |
CN1307246C (zh) * | 2003-11-07 | 2007-03-28 | 李小鲁 | 含淀粉的全生物降解的吹塑成型树脂组合物及其制备方法 |
EP1580228A1 (en) * | 2004-03-24 | 2005-09-28 | Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO | Process for gelatinising starch using a biodegradable polymer material bearing aldehyde groups |
US6955850B1 (en) | 2004-04-29 | 2005-10-18 | The Procter & Gamble Company | Polymeric structures and method for making same |
US6977116B2 (en) * | 2004-04-29 | 2005-12-20 | The Procter & Gamble Company | Polymeric structures and method for making same |
US7253221B2 (en) * | 2004-04-30 | 2007-08-07 | Board Of Trustees Of Michigan State University | Compositions of cellulose esters and layered silicates and process for the preparation thereof |
CN100352845C (zh) * | 2004-08-10 | 2007-12-05 | 北京林业大学 | 植物多酚保水剂及其制备方法 |
US7629405B2 (en) | 2004-11-19 | 2009-12-08 | Board Of Trustees Of Michigan State University | Starch-polyester biodegradable graft copolyers and a method of preparation thereof |
TW200712120A (en) * | 2005-07-28 | 2007-04-01 | Biograde Hong Kong Pty Ltd | Biodegradable polymer composition |
US20070082982A1 (en) * | 2005-10-11 | 2007-04-12 | The Procter & Gamble Company | Water stable compositions and articles comprising starch and methods of making the same |
US20070129467A1 (en) * | 2005-12-02 | 2007-06-07 | Frederic Scheer | Bio based biodegradable polymer compositions and use of same |
JP5128595B2 (ja) * | 2006-07-28 | 2013-01-23 | バイオグレード・(ホンコン)・ピーティーワイ・リミテッド | マスターバッチおよびポリマー組成物 |
US7909003B2 (en) * | 2006-08-07 | 2011-03-22 | J. W. Pet Company, Inc. | Chew toys comprising biologically degradable material |
US20100256445A1 (en) * | 2006-12-07 | 2010-10-07 | International Polymer Engineering, Inc. | Endoscopic Working Channel and Method of Making Same |
FR2934272B1 (fr) * | 2008-07-24 | 2013-08-16 | Roquette Freres | Procede de preparation de compositions a base de matiere amylacee et de polymere synthetique. |
BRPI0921678A2 (pt) * | 2008-11-06 | 2016-02-16 | Tristano Pty Ltd | composição de polímero biodegradável, folha de película, método para preparar uma composição de polímero biodegradável, e, mistura padrão |
WO2010105076A1 (en) * | 2009-03-11 | 2010-09-16 | Nuvision Bioplastics, Llc | Biodegradable resin composition utilized in the manufacture of biodegradable containers, biodegradable containers, and method of manufacture |
EA201290246A1 (ru) | 2009-10-30 | 2012-12-28 | Стихтинг Кеннис Эксплоитати Рб | Биоразлагаемый полимер на основе крахмала, способ получения и изделия из него |
US8586821B2 (en) * | 2009-12-23 | 2013-11-19 | Kimberly-Clark Worldwide, Inc. | Melt-processed films of thermoplastic cellulose and microbial aliphatic polyester |
US20110319531A1 (en) * | 2010-06-29 | 2011-12-29 | Eastman Chemical Company | Cellulose ester compositions |
US9273195B2 (en) | 2010-06-29 | 2016-03-01 | Eastman Chemical Company | Tires comprising cellulose ester/elastomer compositions |
GB201112402D0 (en) * | 2011-07-19 | 2011-08-31 | British American Tobacco Co | Cellulose acetate compositions |
JP5796393B2 (ja) * | 2011-07-29 | 2015-10-21 | 富士ゼロックス株式会社 | 樹脂組成物および樹脂成形体 |
US20130150484A1 (en) | 2011-12-07 | 2013-06-13 | Eastman Chemical Company | Cellulose esters in pneumatic tires |
CN103756018B (zh) * | 2014-01-09 | 2016-08-17 | 优势塑胶(安吉)有限公司 | 热塑性乙酰化淀粉与聚乳酸的共混物及其制作方法 |
CN103992518B (zh) * | 2014-04-30 | 2017-02-08 | 天津市天塑科技集团有限公司包装材料分公司 | 一种可生物降解的包装材料 |
CN104861597A (zh) * | 2015-04-29 | 2015-08-26 | 安徽国泰印务有限公司 | 一种环保型包装材料 |
WO2017109043A1 (en) * | 2015-12-22 | 2017-06-29 | Solvay Acetow Gmbh | New plasticized compositions comprising cellulose acetate |
US10077342B2 (en) | 2016-01-21 | 2018-09-18 | Eastman Chemical Company | Elastomeric compositions comprising cellulose ester additives |
JP6369529B2 (ja) | 2016-12-15 | 2018-08-08 | 富士ゼロックス株式会社 | 樹脂組成物及び樹脂成形体 |
JP6573006B2 (ja) * | 2018-07-06 | 2019-09-11 | 富士ゼロックス株式会社 | 樹脂組成物及び樹脂成形体 |
JP2020026499A (ja) * | 2018-08-14 | 2020-02-20 | 株式会社ダイセル | セルロースアセテート組成物及び成形体 |
US11512183B2 (en) * | 2018-08-14 | 2022-11-29 | Daicel Corporation | Cellulose acetate composition for thermoforming, molded article, and method for producing cellulose acetate composition for thermoforming |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5614544A (en) * | 1979-07-14 | 1981-02-12 | Nippon Synthetic Chem Ind Co Ltd:The | High polymer composition with excellent compatibility |
PL286006A1 (ja) * | 1989-07-18 | 1991-03-11 | Warner Lambert Co | |
IT1245408B (it) * | 1991-02-20 | 1994-09-20 | Butterfly Srl | Composizioni polimeriche biodegradabili a base di amido e di polimero termoplastico |
SG47625A1 (en) * | 1991-11-14 | 1998-04-17 | Bio Tech Biolog Naturverparkun | Biodegradable mould material |
US5288318A (en) * | 1993-07-01 | 1994-02-22 | The United States Of America As Represented By The Secretary Of The Army | Cellulose acetate and starch based biodegradable injection molded plastics compositions and methods of manufacture |
JPH07102114A (ja) * | 1993-10-04 | 1995-04-18 | Teijin Ltd | 生分解性組成物 |
US5500465A (en) * | 1994-03-10 | 1996-03-19 | Board Of Trustees Operating Michigan State University | Biodegradable multi-component polymeric materials based on unmodified starch-like polysaccharides |
IT1274603B (it) * | 1994-08-08 | 1997-07-18 | Novamont Spa | Materiali espansi plastici biodegradabili |
-
1995
- 1995-01-10 IT ITMI950023A patent/IT1272871B/it active IP Right Grant
-
1996
- 1996-01-03 PT PT96100035T patent/PT722980E/pt unknown
- 1996-01-03 EP EP96100035A patent/EP0722980B1/en not_active Expired - Lifetime
- 1996-01-03 AT AT96100035T patent/ATE208804T1/de not_active IP Right Cessation
- 1996-01-03 DE DE69616840T patent/DE69616840T2/de not_active Expired - Lifetime
- 1996-01-03 DK DK96100035T patent/DK0722980T3/da active
- 1996-01-03 ES ES96100035T patent/ES2164788T3/es not_active Expired - Lifetime
- 1996-01-05 IN IN22CA1996 patent/IN186693B/en unknown
- 1996-01-08 AR AR33495796A patent/AR000641A1/es unknown
- 1996-01-08 IL IL11669896A patent/IL116698A/xx not_active IP Right Cessation
- 1996-01-09 MX MX9600162A patent/MX9600162A/es not_active IP Right Cessation
- 1996-01-09 NZ NZ280798A patent/NZ280798A/en unknown
- 1996-01-09 FI FI960097A patent/FI960097A/fi not_active IP Right Cessation
- 1996-01-09 SK SK35-96A patent/SK3596A3/sk unknown
- 1996-01-09 AU AU40917/96A patent/AU705176B2/en not_active Ceased
- 1996-01-09 NO NO19960100A patent/NO313556B1/no unknown
- 1996-01-10 HU HU9600062A patent/HU220791B1/hu not_active IP Right Cessation
- 1996-01-10 JP JP8002460A patent/JPH08231762A/ja active Pending
- 1996-01-10 ZA ZA96184A patent/ZA96184B/xx unknown
- 1996-01-10 CN CN96104325A patent/CN1125118C/zh not_active Expired - Fee Related
- 1996-01-10 PL PL96312236A patent/PL184475B1/pl not_active IP Right Cessation
- 1996-01-10 CZ CZ9677A patent/CZ7796A3/cs unknown
- 1996-01-10 CA CA002166921A patent/CA2166921A1/en not_active Abandoned
- 1996-01-10 KR KR1019960000380A patent/KR100408337B1/ko not_active IP Right Cessation
- 1996-03-04 TW TW085102628A patent/TW394788B/zh not_active IP Right Cessation
-
1997
- 1997-10-17 US US08/953,076 patent/US6506824B1/en not_active Expired - Lifetime
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO313556B1 (no) | Bionedbrytbart termoplastisk materiale | |
AU755074B2 (en) | Biodegradable compositions comprising starch and polysaccharide esters | |
US11168203B2 (en) | Thermoplastic starch | |
JP3112127B2 (ja) | 高い耐水性を有する、生物学的に分解可能な成形材料ないしはポリマーブレンド及びその製造方法並びに成形材料ないしは押出成形体 | |
US5844023A (en) | Biologically degradable polymer mixture | |
CN1044002C (zh) | 制备可生物降解的组合物的方法及制得的组合物和有关薄膜 | |
JP5544303B2 (ja) | 可塑化デンプンベース熱可塑性組成物を調製する方法および結果として生じる組成物 | |
JP2002523598A5 (ja) | ||
AU2009274349A1 (en) | Process for preparing compositions based on a starchy component and on a synthetic polymer | |
EP2493975B1 (en) | Starch-based biodegradable polymer; method of manufacture and articles thereof | |
Ayoub et al. | An overview on the technology of cross-linking of starch for nonfood applications | |
US20220356310A1 (en) | Thermoplastic starch | |
WO2023224593A1 (ru) | Способ получения сополимеров олигосахаридов | |
Grimaut et al. | Effect of Addition of Cross-Linked Starch on the Properties of Degraded PBAT Poly (butylene adipate-co-terephthalate) Films. Polymers 2023, 15, 3106 | |
Hassan et al. | Tapioca Starch: Xylan Derived Bioplastics |