NL194674C - Polymeersamenstelling en werkwijze voor het bereiden daarvan. - Google Patents
Polymeersamenstelling en werkwijze voor het bereiden daarvan. Download PDFInfo
- Publication number
- NL194674C NL194674C NL8903136A NL8903136A NL194674C NL 194674 C NL194674 C NL 194674C NL 8903136 A NL8903136 A NL 8903136A NL 8903136 A NL8903136 A NL 8903136A NL 194674 C NL194674 C NL 194674C
- Authority
- NL
- Netherlands
- Prior art keywords
- block
- blocks
- complete
- diene
- polymer
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims description 32
- 239000000203 mixture Substances 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title description 2
- 239000000178 monomer Substances 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 29
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- 150000001993 dienes Chemical class 0.000 claims description 17
- 229920002554 vinyl polymer Polymers 0.000 claims description 15
- 229920001400 block copolymer Polymers 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 9
- 239000004793 Polystyrene Substances 0.000 claims description 8
- 229920002223 polystyrene Polymers 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 229920002959 polymer blend Polymers 0.000 claims description 6
- 229920006216 polyvinyl aromatic Polymers 0.000 claims description 6
- 238000010539 anionic addition polymerization reaction Methods 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- -1 aryl metal compound Chemical class 0.000 claims description 4
- 229920005605 branched copolymer Polymers 0.000 claims description 4
- 230000002779 inactivation Effects 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 238000012661 block copolymerization Methods 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000008188 pellet Substances 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 18
- 239000003999 initiator Substances 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000001256 steam distillation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 238000010551 living anionic polymerization reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2308888 | 1988-12-23 | ||
| IT8823088A IT1227901B (it) | 1988-12-23 | 1988-12-23 | Composizioni polimeriche e loro metodo di preparazione |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NL8903136A NL8903136A (nl) | 1990-07-16 |
| NL194674B NL194674B (nl) | 2002-07-01 |
| NL194674C true NL194674C (nl) | 2002-11-04 |
Family
ID=11203654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8903136A NL194674C (nl) | 1988-12-23 | 1989-12-21 | Polymeersamenstelling en werkwijze voor het bereiden daarvan. |
Country Status (15)
| Country | Link |
|---|---|
| CN (2) | CN1036139C (fi) |
| BE (1) | BE1003108A3 (fi) |
| BR (1) | BR8906764A (fi) |
| CA (1) | CA2005285A1 (fi) |
| DE (1) | DE3942668C2 (fi) |
| DK (1) | DK623289A (fi) |
| ES (1) | ES2021927A6 (fi) |
| FI (1) | FI896042A0 (fi) |
| FR (1) | FR2640979A1 (fi) |
| GB (1) | GB2226322B (fi) |
| IT (1) | IT1227901B (fi) |
| MX (1) | MX169895B (fi) |
| NL (1) | NL194674C (fi) |
| NO (1) | NO177599C (fi) |
| SE (1) | SE502757C2 (fi) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW446733B (en) * | 1998-03-05 | 2001-07-21 | Japan Elastomer Co Ltd | Block copolymer composition for modifying asphalt and asphalt composition comprising the same |
| US6576686B1 (en) | 2000-06-27 | 2003-06-10 | Exxonmobil Chemical Patents Inc. | Road marking compound comprising linear tetrablock copolymers |
| EP1299475A1 (en) * | 2000-06-27 | 2003-04-09 | ExxonMobil Chemical Patents Inc. | Tetrablock copolymers |
| CN105377924B (zh) * | 2013-07-08 | 2018-08-10 | 苯领集团股份公司 | 单乙烯基芳族共轭二烯嵌段共聚物及含其和单乙烯基芳烃丙烯酸酯共聚物的聚合物组合物 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1130770A (en) * | 1965-12-29 | 1968-10-16 | Asahi Chemical Ind | Process for producing thermoplastic elastomers |
| DE2013986A1 (de) * | 1970-03-24 | 1971-10-14 | Huels Chemische Werke Ag | Verfahren zum Herstellen von trans parenten, schlagfesten Zwei Segment Copolymen säten |
| US4208356A (en) * | 1974-09-17 | 1980-06-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing mixture of block copolymers |
| DE2550226C2 (de) * | 1975-11-08 | 1984-12-13 | Basf Ag, 6700 Ludwigshafen | Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung |
| US4223190A (en) * | 1977-12-01 | 1980-09-16 | Olson Delwyn L | Mercury float switch |
| US4152370A (en) * | 1978-02-09 | 1979-05-01 | Phillips Petroleum Company | Preparation, composition, and use of block polymers |
| US4704435A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with resinous terminal blocks |
| LU86698A1 (fr) * | 1986-12-04 | 1988-07-14 | Labofina Sa | Procede pour fabriquer des copolymeres blocs transparents |
| IT1222429B (it) * | 1987-07-31 | 1990-09-05 | Enichem Elastromeri S P A | Copolimero a blocchi procedimento per la sua preparazione |
-
1988
- 1988-12-23 IT IT8823088A patent/IT1227901B/it active
-
1989
- 1989-12-08 SE SE8904152A patent/SE502757C2/sv not_active IP Right Cessation
- 1989-12-11 DK DK623289A patent/DK623289A/da not_active Application Discontinuation
- 1989-12-11 GB GB8927958A patent/GB2226322B/en not_active Expired - Fee Related
- 1989-12-12 CA CA002005285A patent/CA2005285A1/en not_active Abandoned
- 1989-12-14 MX MX018728A patent/MX169895B/es unknown
- 1989-12-18 FI FI896042A patent/FI896042A0/fi not_active Application Discontinuation
- 1989-12-18 NO NO895089A patent/NO177599C/no unknown
- 1989-12-21 NL NL8903136A patent/NL194674C/nl not_active IP Right Cessation
- 1989-12-21 BE BE8901371A patent/BE1003108A3/fr not_active IP Right Cessation
- 1989-12-21 BR BR898906764A patent/BR8906764A/pt not_active IP Right Cessation
- 1989-12-21 FR FR8916948A patent/FR2640979A1/fr active Granted
- 1989-12-22 DE DE3942668A patent/DE3942668C2/de not_active Expired - Lifetime
- 1989-12-22 ES ES9000114A patent/ES2021927A6/es not_active Expired - Fee Related
- 1989-12-23 CN CN89109475A patent/CN1036139C/zh not_active Expired - Lifetime
-
1996
- 1996-11-12 CN CN96114453A patent/CN1059216C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2640979B1 (fi) | 1993-08-06 |
| SE8904152D0 (sv) | 1989-12-08 |
| DE3942668A1 (de) | 1990-06-28 |
| ES2021927A6 (es) | 1991-11-16 |
| MX169895B (es) | 1993-07-29 |
| FI896042A0 (fi) | 1989-12-18 |
| SE502757C2 (sv) | 1996-01-08 |
| GB2226322B (en) | 1992-06-03 |
| BE1003108A3 (fr) | 1991-11-26 |
| DK623289A (da) | 1990-06-24 |
| BR8906764A (pt) | 1990-09-18 |
| NL8903136A (nl) | 1990-07-16 |
| NO177599C (no) | 1995-10-18 |
| IT8823088A0 (it) | 1988-12-23 |
| IT1227901B (it) | 1991-05-14 |
| GB8927958D0 (en) | 1990-02-14 |
| FR2640979A1 (en) | 1990-06-29 |
| SE8904152L (sv) | 1990-06-24 |
| CA2005285A1 (en) | 1990-06-23 |
| NO177599B (no) | 1995-07-10 |
| CN1158866A (zh) | 1997-09-10 |
| CN1043512A (zh) | 1990-07-04 |
| NO895089D0 (no) | 1989-12-18 |
| GB2226322A (en) | 1990-06-27 |
| CN1036139C (zh) | 1997-10-15 |
| DK623289D0 (da) | 1989-12-11 |
| NO895089L (no) | 1990-06-25 |
| CN1059216C (zh) | 2000-12-06 |
| DE3942668C2 (de) | 1994-10-13 |
| NL194674B (nl) | 2002-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BA | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| V4 | Discontinued because of reaching the maximum lifetime of a patent |
Effective date: 20091221 |