MXPA05004127A - Elastomeros de poliuretano, procedimiento para su fabricacion y su uso. - Google Patents
Elastomeros de poliuretano, procedimiento para su fabricacion y su uso.Info
- Publication number
- MXPA05004127A MXPA05004127A MXPA05004127A MXPA05004127A MXPA05004127A MX PA05004127 A MXPA05004127 A MX PA05004127A MX PA05004127 A MXPA05004127 A MX PA05004127A MX PA05004127 A MXPA05004127 A MX PA05004127A MX PA05004127 A MXPA05004127 A MX PA05004127A
- Authority
- MX
- Mexico
- Prior art keywords
- mol
- average
- molecular weight
- groups
- polyol
- Prior art date
Links
- 229920003225 polyurethane elastomer Polymers 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims description 17
- 229920005862 polyol Polymers 0.000 claims abstract description 68
- 229920000570 polyether Polymers 0.000 claims abstract description 39
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 34
- 229920001971 elastomer Polymers 0.000 claims abstract description 9
- 239000000806 elastomer Substances 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims description 63
- 150000002148 esters Chemical class 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 43
- 239000005056 polyisocyanate Substances 0.000 claims description 29
- 229920001228 polyisocyanate Polymers 0.000 claims description 29
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 229920005906 polyester polyol Polymers 0.000 claims description 13
- 239000004970 Chain extender Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000006068 polycondensation reaction Methods 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 125000004185 ester group Chemical group 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 7
- 125000001033 ether group Chemical group 0.000 claims description 7
- 239000004971 Cross linker Substances 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 claims description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims 2
- -1 ester polyols Chemical class 0.000 abstract description 25
- 239000004814 polyurethane Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 11
- 239000012948 isocyanate Substances 0.000 description 11
- 229920000728 polyester Polymers 0.000 description 11
- 229920002635 polyurethane Polymers 0.000 description 11
- 150000002513 isocyanates Chemical class 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 150000002009 diols Chemical class 0.000 description 9
- 238000009472 formulation Methods 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000004604 Blowing Agent Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 238000005452 bending Methods 0.000 description 5
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000009661 fatigue test Methods 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000004872 foam stabilizing agent Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 150000004072 triols Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 2
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 2
- PQXKWPLDPFFDJP-UHFFFAOYSA-N 2,3-dimethyloxirane Chemical compound CC1OC1C PQXKWPLDPFFDJP-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical group NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 230000001408 fungistatic effect Effects 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical group OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical class C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 1
- FCQPNTOQFPJCMF-UHFFFAOYSA-N 1,3-bis[3-(dimethylamino)propyl]urea Chemical compound CN(C)CCCNC(=O)NCCCN(C)C FCQPNTOQFPJCMF-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- XNDHQMLXHGSDHT-UHFFFAOYSA-N 1,4-bis(2-hydroxyethyl)cyclohexa-2,5-diene-1,4-diol Chemical compound OCCC1(O)C=CC(O)(CCO)C=C1 XNDHQMLXHGSDHT-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- NFDXQGNDWIPXQL-UHFFFAOYSA-N 1-cyclooctyldiazocane Chemical compound C1CCCCCCC1N1NCCCCCC1 NFDXQGNDWIPXQL-UHFFFAOYSA-N 0.000 description 1
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 1
- TZBAIMGBDFXZMO-UHFFFAOYSA-N 1-isocyanatomethyl-1,3,3-trimethylcyclohexane Chemical compound CC1(C)CCCC(C)(CN=C=O)C1 TZBAIMGBDFXZMO-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- JPSKCQCQZUGWNM-UHFFFAOYSA-N 2,7-Oxepanedione Chemical compound O=C1CCCCC(=O)O1 JPSKCQCQZUGWNM-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- DHSITKCGHVUAKI-UHFFFAOYSA-N 2-[ethyl-[ethyl(dimethyl)silyl]oxy-methylsilyl]ethanamine Chemical compound CC[Si](C)(C)O[Si](C)(CC)CCN DHSITKCGHVUAKI-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- WADSJYLPJPTMLN-UHFFFAOYSA-N 3-(cycloundecen-1-yl)-1,2-diazacycloundec-2-ene Chemical compound C1CCCCCCCCC=C1C1=NNCCCCCCCC1 WADSJYLPJPTMLN-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/48—Polyethers
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/08—Processes
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10248949A DE10248949B4 (de) | 2002-10-21 | 2002-10-21 | Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| PCT/EP2003/011107 WO2004037882A1 (de) | 2002-10-21 | 2003-10-08 | Polyurethanelastomere, verfahren zu ihrer herstellung und ihre verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA05004127A true MXPA05004127A (es) | 2005-06-22 |
Family
ID=32087055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA05004127A MXPA05004127A (es) | 2002-10-21 | 2003-10-08 | Elastomeros de poliuretano, procedimiento para su fabricacion y su uso. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6858699B2 (enExample) |
| EP (1) | EP1556429B1 (enExample) |
| JP (1) | JP2006503941A (enExample) |
| KR (1) | KR101135269B1 (enExample) |
| CN (1) | CN1307227C (enExample) |
| AT (1) | ATE534681T1 (enExample) |
| AU (1) | AU2003268924A1 (enExample) |
| BR (1) | BR0314871A (enExample) |
| CA (1) | CA2502666A1 (enExample) |
| DE (1) | DE10248949B4 (enExample) |
| ES (1) | ES2375956T3 (enExample) |
| MX (1) | MXPA05004127A (enExample) |
| PL (1) | PL375894A1 (enExample) |
| WO (1) | WO2004037882A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10319393A1 (de) * | 2003-04-30 | 2004-11-18 | Bayer Materialscience Ag | Flexible Formteile aus geschäumten Polyurethan und ihre Verwendung |
| DE102005031975A1 (de) * | 2005-07-08 | 2007-01-11 | Bayer Materialscience Ag | PUR-Polyesterweichschaumstoffe auf Basis von Polyetheresterpolyolen |
| EP1933902B1 (en) * | 2005-09-26 | 2014-12-17 | Asante Solutions, Inc. | Infusion pump with a drive having a ratchet and pawl combination |
| MX2009002122A (es) * | 2006-08-30 | 2009-03-09 | Bayer Materialscience Ag | Piezas de moldeo elastomericas rellenas, no expandidas, macizas y procedimiento para su fabricacion. |
| CN101641385A (zh) * | 2006-12-29 | 2010-02-03 | 鲁贝莱特公司 | 含聚氨酯弹性体的闭孔泡沫体 |
| US8445556B2 (en) * | 2006-12-29 | 2013-05-21 | Rubberlite, Inc. | Cellular elastomer compositions |
| JP5368716B2 (ja) * | 2007-03-01 | 2013-12-18 | 花王株式会社 | ポリウレタン成形品の製造方法 |
| JP2010540737A (ja) * | 2007-10-02 | 2010-12-24 | ビーエーエスエフ ソシエタス・ヨーロピア | 低密度ポリウレタンフォーム及びこれを靴底に使用する方法 |
| MX2010004701A (es) | 2007-11-14 | 2010-05-20 | Basf Se | Poliuretano espumado con propiedades de resistencia a la flexion mejoradas. |
| DE102008051882A1 (de) | 2008-10-16 | 2010-04-29 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetheresterpolyolen |
| CN102432907B (zh) * | 2011-08-17 | 2013-01-23 | 浙江恒泰源聚氨酯有限公司 | 抗低温耐寒聚氨酯双组分鞋底原料的制备方法 |
| CN102504223A (zh) * | 2011-10-27 | 2012-06-20 | 山东东大一诺威聚氨酯有限公司 | 聚醚酯多元醇及其使用方法 |
| SG11201402998PA (en) | 2011-12-20 | 2014-10-30 | Bayer Ip Gmbh | Hydroxy-aminopolymers and method for producing same |
| EP3129332B1 (en) * | 2014-04-10 | 2020-11-18 | Sika Technology AG | Polyurethane hybrid system combining high compressive strength and early water resistance |
| EP2952531A1 (de) * | 2014-06-02 | 2015-12-09 | Basf Se | Kompakte Elastomerformteile auf Basis von Polyurethan |
| CN104231205B (zh) * | 2014-08-27 | 2017-01-11 | 旭川化学（昆山）有限公司 | 一种易加工聚氨酯鞋底材料的原液 |
| CN104479343A (zh) * | 2014-12-19 | 2015-04-01 | 淄博正大节能新材料有限公司 | 3d打印用聚氨酯材料及其制备方法 |
| EP3037449A1 (de) | 2014-12-22 | 2016-06-29 | Covestro Deutschland AG | Dipol-modifiziertes Polyurethan, Verfahren zu dessen Herstellung und Verwendung zur Herstellung von elektroaktiven Polyurethan-basierten Gießelastomerfolien |
| CN104945593B (zh) * | 2015-05-13 | 2017-12-29 | 吕涛 | 一种薄膜级tpu切片的制备方法 |
| EP3098248A1 (de) | 2015-05-29 | 2016-11-30 | Covestro Deutschland AG | Polymeres, nicht angebundenes additiv zur erhöhung der dielektrizitätskonstante in elektroaktiven polyurethan polymeren |
| CN106866922A (zh) * | 2015-12-10 | 2017-06-20 | 上海凯众材料科技股份有限公司 | 聚氨酯微孔弹性体的制备方法 |
| CN105504213A (zh) * | 2016-01-29 | 2016-04-20 | 李善军 | 合成革用无溶剂聚氨酯组合物 |
| CN106674465B (zh) * | 2016-12-30 | 2021-07-06 | 浙江华峰新材料有限公司 | 聚氨酯鞋底用树脂及制备方法和应用 |
| CN107090174A (zh) * | 2017-06-15 | 2017-08-25 | 海洋石油工程股份有限公司 | 一种防滑耐磨的浇注型聚氨酯复合胶层的制备方法 |
| CN109897155B (zh) * | 2017-12-08 | 2021-07-20 | 上海凯众材料科技股份有限公司 | 含氟聚氨酯微孔弹性体的制备方法 |
| US12297149B2 (en) * | 2018-07-04 | 2025-05-13 | China Petroleum And Chemical Corporation | Multiphase particle, manufacturing process and use thereof |
| CN109265641A (zh) * | 2018-07-05 | 2019-01-25 | 山东诺威聚氨酯股份有限公司 | 耐低温低密度聚氨酯鞋底制品组合料及其制备方法 |
| CN109456458A (zh) * | 2018-09-28 | 2019-03-12 | 山东诺威聚氨酯股份有限公司 | 用于鞋材的聚醚酯型tpu及其制备方法 |
| KR101983509B1 (ko) * | 2018-10-10 | 2019-05-30 | 대한폴리텍(주) | 고난연 단열재 및 이의 제조방법 |
| KR102065294B1 (ko) * | 2019-02-25 | 2020-01-13 | 대한폴리텍(주) | 고난연성과 상온 장기저장안성이 우수한 방향족 폴리에스테를 폴리올 |
| US12319778B2 (en) * | 2019-07-22 | 2025-06-03 | Dow Global Technologies Llc | Polyurethane compositions, products prepared with same and preparation methods thereof |
| CN110964169B (zh) * | 2019-12-23 | 2023-05-09 | 山东一诺威聚氨酯股份有限公司 | 直接成型的高透气型聚氨酯鞋垫组合料及其制备方法 |
| CN118931462B (zh) * | 2024-10-15 | 2024-12-20 | 山东一诺威聚氨酯股份有限公司 | 椰糠砖用的生物基聚氨酯粘合剂及其制备方法和椰糠砖 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370996A (en) * | 1964-05-28 | 1968-02-27 | Air Force Usa | Polyurethane elastomer |
| DE2110278A1 (en) | 1970-03-06 | 1972-07-20 | Takeda Chemical Industries Ltd | Polyetherpoly esterpolyols - used in mfe of polyurethanes for laminating |
| DE3215908A1 (de) * | 1982-04-29 | 1983-11-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von foermkoerpern auf basis von polyurethan- oder polyurethan-polyharnstoff-elastomeren mit verbesserter licht- und witterungsbestaendigkeit |
| US4487853A (en) | 1983-12-27 | 1984-12-11 | Basf Wyandotte Corporation | Low ethylene oxide/high primary hydroxyl content polyether-ester polyols and polyurethane foams based thereon |
| JPS6126612A (ja) * | 1984-07-17 | 1986-02-05 | Kuraray Co Ltd | 耐加水分解性の良好なポリウレタンの製法 |
| DE3437915A1 (de) * | 1984-10-17 | 1986-04-17 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von polyetheresterpolyolen, entsprechende verfahrensprodukte und ihre verwendung |
| DE3613650A1 (de) | 1986-04-23 | 1987-10-29 | Basf Ag | Verfahren zur herstellung von elastischen, kompakten oder zelligen polyurethan- oder polyurethan-polyharnstoff-formkoerpern |
| US5001166A (en) * | 1989-01-25 | 1991-03-19 | Robson Mafoti | Novel polyetherester based prepolymers and elastomers made therefrom |
| JP3082212B2 (ja) * | 1990-06-25 | 2000-08-28 | 大日本インキ化学工業株式会社 | ウレタンポリオール及びそれを用いるポリウレタンフォーム用組成物 |
| DE4241415A1 (de) * | 1992-12-09 | 1994-06-16 | Basf Schwarzheide Gmbh | Polyetheresterole, ein Verfahren zu ihrer Herstellung sowie ihre Anwendung in Polyurethanen |
| US5436314A (en) | 1994-04-18 | 1995-07-25 | Arco Chemical Technology, L.P. | Process for making a polyetherester by insertion of a carboxylic acid into a polyether |
| DE19521798A1 (de) | 1995-06-16 | 1996-12-19 | Bayer Ag | Polyurethanelastomere aus aliphatischen Polyisocyanaten und Polyesteretherpolyolen |
| JPH09208653A (ja) * | 1996-02-01 | 1997-08-12 | Kuraray Co Ltd | 硬化型ポリウレタンの製造方法 |
| JPH11302355A (ja) * | 1998-04-23 | 1999-11-02 | Dainippon Ink & Chem Inc | 発泡ポリウレタンエラストマー組成物及び防振材 |
| DE19858104A1 (de) | 1998-12-16 | 2000-06-21 | Basf Ag | Polyetheresterpolyol, Verfahren zu dessen Herstellung und daraus hergestelltes Polyurethanpräpolymeres |
| DE19927188A1 (de) | 1999-06-15 | 2000-12-21 | Bayer Ag | Polyharnstoffpolyurethane mit verbesserten physikalischen Eigenschaften |
| DE19949091A1 (de) | 1999-10-12 | 2001-04-26 | Basf Ag | Polyester-Polyetherblockcopolymere |
| DE10063496A1 (de) | 2000-12-20 | 2002-07-04 | Bayer Ag | Polyurethanelastomere mit verbesserter Hydrolysestabilität |
-
2002
- 2002-10-21 DE DE10248949A patent/DE10248949B4/de not_active Expired - Fee Related
-
2003
- 2003-10-08 CN CNB2003801017531A patent/CN1307227C/zh not_active Expired - Fee Related
- 2003-10-08 ES ES03750695T patent/ES2375956T3/es not_active Expired - Lifetime
- 2003-10-08 JP JP2004545811A patent/JP2006503941A/ja active Pending
- 2003-10-08 AT AT03750695T patent/ATE534681T1/de active
- 2003-10-08 WO PCT/EP2003/011107 patent/WO2004037882A1/de not_active Ceased
- 2003-10-08 AU AU2003268924A patent/AU2003268924A1/en not_active Abandoned
- 2003-10-08 KR KR1020057006779A patent/KR101135269B1/ko not_active Expired - Fee Related
- 2003-10-08 PL PL03375894A patent/PL375894A1/xx not_active Application Discontinuation
- 2003-10-08 MX MXPA05004127A patent/MXPA05004127A/es active IP Right Grant
- 2003-10-08 CA CA002502666A patent/CA2502666A1/en not_active Abandoned
- 2003-10-08 BR BR0314871-8A patent/BR0314871A/pt not_active IP Right Cessation
- 2003-10-08 EP EP03750695A patent/EP1556429B1/de not_active Expired - Lifetime
- 2003-10-20 US US10/687,959 patent/US6858699B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE10248949B4 (de) | 2006-09-28 |
| US20040082677A1 (en) | 2004-04-29 |
| CA2502666A1 (en) | 2004-05-06 |
| PL375894A1 (en) | 2005-12-12 |
| EP1556429A1 (de) | 2005-07-27 |
| EP1556429B1 (de) | 2011-11-23 |
| ATE534681T1 (de) | 2011-12-15 |
| ES2375956T3 (es) | 2012-03-07 |
| CN1705693A (zh) | 2005-12-07 |
| WO2004037882A1 (de) | 2004-05-06 |
| AU2003268924A1 (en) | 2004-05-13 |
| US6858699B2 (en) | 2005-02-22 |
| CN1307227C (zh) | 2007-03-28 |
| JP2006503941A (ja) | 2006-02-02 |
| KR20050065610A (ko) | 2005-06-29 |
| DE10248949A1 (de) | 2004-05-06 |
| BR0314871A (pt) | 2005-08-02 |
| KR101135269B1 (ko) | 2012-04-12 |
| HK1086290A1 (en) | 2006-09-15 |
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