MXPA05001224A - Proceso para controlar las propiedades fisicas del polivinilbutiral controlando la estereoquimica del mismo. - Google Patents
Proceso para controlar las propiedades fisicas del polivinilbutiral controlando la estereoquimica del mismo.Info
- Publication number
- MXPA05001224A MXPA05001224A MXPA05001224A MXPA05001224A MXPA05001224A MX PA05001224 A MXPA05001224 A MX PA05001224A MX PA05001224 A MXPA05001224 A MX PA05001224A MX PA05001224 A MXPA05001224 A MX PA05001224A MX PA05001224 A MXPA05001224 A MX PA05001224A
- Authority
- MX
- Mexico
- Prior art keywords
- pvb
- composition
- weight
- parts
- pva
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 title claims description 285
- 230000008569 process Effects 0.000 title claims description 24
- 230000000704 physical effect Effects 0.000 title abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 181
- 239000011347 resin Substances 0.000 claims abstract description 181
- 239000000203 mixture Substances 0.000 claims abstract description 126
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 139
- 239000004014 plasticizer Substances 0.000 claims description 76
- 239000004094 surface-active agent Substances 0.000 claims description 70
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 62
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 38
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 30
- 238000004519 manufacturing process Methods 0.000 claims description 22
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims description 18
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 17
- 239000011541 reaction mixture Substances 0.000 claims description 17
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 15
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 13
- 150000007513 acids Chemical class 0.000 claims description 13
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 11
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 claims description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 239000011342 resin composition Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 239000012445 acidic reagent Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 description 54
- 238000006116 polymerization reaction Methods 0.000 description 51
- 239000000243 solution Substances 0.000 description 50
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 48
- 229960000878 docusate sodium Drugs 0.000 description 27
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 27
- 239000002253 acid Substances 0.000 description 22
- 235000011007 phosphoric acid Nutrition 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- -1 cyclic acetals Chemical class 0.000 description 7
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 150000005690 diesters Chemical class 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 125000003827 glycol group Chemical group 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- OJXOOFXUHZAXLO-UHFFFAOYSA-M magnesium;1-bromo-3-methanidylbenzene;bromide Chemical compound [Mg+2].[Br-].[CH2-]C1=CC=CC(Br)=C1 OJXOOFXUHZAXLO-UHFFFAOYSA-M 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000012431 aqueous reaction media Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000010961 commercial manufacture process Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical class C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- MIOXMKPJKUKMNV-UHFFFAOYSA-M dicyclohexyl(diethyl)azanium;dodecyl sulfate Chemical compound CCCCCCCCCCCCOS([O-])(=O)=O.C1CCCCC1[N+](CC)(CC)C1CCCCC1 MIOXMKPJKUKMNV-UHFFFAOYSA-M 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- HXOSOIUOLGXZFL-UHFFFAOYSA-L disodium;2-decyl-6-(2-sulfonatophenoxy)benzenesulfonate Chemical compound [Na+].[Na+].CCCCCCCCCCC1=CC=CC(OC=2C(=CC=CC=2)S([O-])(=O)=O)=C1S([O-])(=O)=O HXOSOIUOLGXZFL-UHFFFAOYSA-L 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/18—Plasticising macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40067202P | 2002-08-02 | 2002-08-02 | |
| PCT/US2003/024380 WO2004013191A1 (en) | 2002-08-02 | 2003-08-04 | A process for controlling polyvinylbutyral physical properties by controlling stereochemistry of same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA05001224A true MXPA05001224A (es) | 2005-06-08 |
Family
ID=31495855
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA05001224A MXPA05001224A (es) | 2002-08-02 | 2003-08-04 | Proceso para controlar las propiedades fisicas del polivinilbutiral controlando la estereoquimica del mismo. |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US7709565B2 (enExample) |
| EP (1) | EP1539831B1 (enExample) |
| JP (1) | JP4335805B2 (enExample) |
| CN (1) | CN100384887C (enExample) |
| AU (1) | AU2003257166B2 (enExample) |
| CA (1) | CA2494510A1 (enExample) |
| DE (1) | DE60329401D1 (enExample) |
| MX (1) | MXPA05001224A (enExample) |
| WO (1) | WO2004013191A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440690A (zh) * | 2018-04-23 | 2018-08-24 | 浙江德斯泰新材料股份有限公司 | 一种3d打印专用聚乙烯醇缩丁醛树脂及其制备方法 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004013191A1 (en) | 2002-08-02 | 2004-02-12 | E. I. Du Pont De Nemours And Company | A process for controlling polyvinylbutyral physical properties by controlling stereochemistry of same |
| US7297407B2 (en) * | 2004-09-20 | 2007-11-20 | E. I. Du Pont De Nemours And Company | Glass laminates for reduction of sound transmission |
| JP5317696B2 (ja) * | 2006-05-31 | 2013-10-16 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
| FR2905067B1 (fr) * | 2006-08-23 | 2008-10-31 | Oreal | Procede de peeling avec des tensioactifs |
| FR2934289B1 (fr) * | 2008-07-24 | 2013-01-11 | Weber & Broutin Sa | Carreau pour revetement a proprietes d'amelioration acoustique. |
| JP5873368B2 (ja) * | 2011-11-07 | 2016-03-01 | 積水化学工業株式会社 | 無機質焼結体製造用バインダー |
| DE102013101407A1 (de) * | 2013-02-13 | 2014-08-14 | Khs Gmbh | Verfahren zum Verpacken von flüssigen Produkten unter Druck in Flaschen aus Kunststoff oder dgl. Behälter |
| JP6262975B2 (ja) * | 2013-09-27 | 2018-01-17 | 積水化学工業株式会社 | ポリビニルアセタール樹脂 |
| US10603882B2 (en) | 2016-04-08 | 2020-03-31 | Kuraray Europe Gmbh | Multilayer film comprising layer of plasticized polyvinyl acetal with reduced flowability |
| WO2017174684A1 (en) | 2016-04-08 | 2017-10-12 | Kuraray Europe Gmbh | Polyvinyl acetal with reduced flowability |
| US20190390051A1 (en) | 2018-06-22 | 2019-12-26 | Kuraray America, Inc. | Reduction of edge yellowing of polyvinylacetal laminates |
| JP2023527773A (ja) | 2020-05-22 | 2023-06-30 | クラレイ ユーロップ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 制御された剥離区画処理を伴い、強化された性能を有する、中間層ならびに積層体 |
| EP4263739A2 (en) | 2020-12-16 | 2023-10-25 | Kuraray Europe GmbH | Laminated structures with composite adhesive polymeric interlayer comprising cohesive debonding zones for enhanced performance |
| CN112745407B (zh) * | 2020-12-31 | 2022-11-22 | 安徽皖维先进功能膜材料研究院有限公司 | 一种聚乙烯醇缩醛树脂的制备方法及其应用 |
| CN113861315B (zh) * | 2021-09-18 | 2022-07-01 | 忠信(清远)光伏材料科技有限公司 | 一种具有隔音性能的聚乙烯醇缩丁醛及其制备方法 |
| EP4437057A1 (en) | 2021-11-23 | 2024-10-02 | Kuraray Europe GmbH | Interlayer and laminate with controlled debonding zone treatments |
| CN115490792B (zh) * | 2022-09-29 | 2024-07-09 | 安徽皖维先进功能膜材料研究院有限公司 | 一种高内消旋比例聚乙烯醇缩醛树脂的制备方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1247663C2 (de) * | 1961-02-24 | 1975-11-27 | E.I. Du Pont De Nemours And Company, Wilmington, Del. (V.St.A.) | Verfahren zur herstellung von polyvinylacetalen |
| DE2732717C3 (de) * | 1977-07-20 | 1980-06-04 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Polyvinylbutyral mit verbesserten Eigenschaften |
| FR2442251A1 (fr) * | 1978-11-21 | 1980-06-20 | Saint Gobain | Plastifiant pour polyvinylbutyral et application a la realisation d'intercalaires pour verre feuillete de securite |
| US4297262A (en) * | 1979-08-31 | 1981-10-27 | E. I. Du Pont De Nemours And Company | Polyvinyl butyral plasticized with tetraethyleneglycol di-n-heptanoate |
| US4276351A (en) * | 1980-06-30 | 1981-06-30 | E. I. Du Pont De Nemours And Company | Polyvinyl butyral plasticized with tetraethyleneglycol di-2-ethylhexanoate |
| JPS58191701A (ja) * | 1982-05-01 | 1983-11-09 | Dai Ichi Kogyo Seiyaku Co Ltd | カルボン酸変性ポリビニルアセタ−ルの製造法 |
| FR2547589B1 (fr) | 1983-06-14 | 1986-03-21 | Saint Gobain Vitrage | Procede de fabrication de polyvinylbutyral et produits obtenus |
| DE3429441A1 (de) * | 1984-08-10 | 1986-02-20 | Hoechst Ag, 6230 Frankfurt | Thermoplastische, weichmacherhaltige polyvinylbutyralformmassen |
| FR2613370B1 (fr) * | 1987-04-02 | 1989-10-20 | Saint Gobain Vitrage | Procede de fabrication d'un polyvinylbutyral plastifie pour le collage d'une embase sur un vitrage et produits obtenus |
| JPH01319506A (ja) * | 1988-06-21 | 1989-12-25 | Sekisui Chem Co Ltd | ポリビニルアセトアセタール樹脂の製造方法 |
| US4920162A (en) * | 1988-12-22 | 1990-04-24 | Clark Peter D | Electrocoating composition of a polyamine self-condensed epoxy adduct and coatings produced thereby |
| FR2648139A1 (fr) * | 1989-06-08 | 1990-12-14 | Saint Gobain Vitrage | Procede de fabrication de polyvinylbutyral et produits obtenus |
| ZA925727B (en) * | 1991-08-09 | 1993-03-10 | Bristol Myers Squibb Co | Glass cleaning composition. |
| US5238994A (en) * | 1991-09-09 | 1993-08-24 | Monsanto Company | Forming polyvinyl butyral |
| DE4235151A1 (de) * | 1992-10-19 | 1994-04-21 | Hoechst Ag | Polyvinylacetale, die emulgatorfreie wäßrige Dispersionen und redispergierbare trockene Pulver bilden können, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5543439A (en) * | 1994-06-02 | 1996-08-06 | International Flavors & Fragrances Inc. | Extruded fragrance-containing polyvinyl alcohol and use thereof |
| JP4057071B2 (ja) * | 1994-11-24 | 2008-03-05 | 積水化学工業株式会社 | ポリビニルアセタールの製造方法、ポリビニルアセタール、合わせガラス用中間膜及び合わせガラス |
| ATE194638T1 (de) | 1995-03-14 | 2000-07-15 | Du Pont | Verfahren zur herstellung von polyvinylbutyralfolien |
| CN1172153A (zh) * | 1995-11-24 | 1998-02-04 | 国际香味香料和芳香公司 | 凝挤态含香精的聚乙烯醇及其衍生用途 |
| JPH11310440A (ja) * | 1998-04-28 | 1999-11-09 | Sekisui Chem Co Ltd | 合わせガラス用中間膜及び合わせガラス |
| US6455132B1 (en) * | 1999-02-04 | 2002-09-24 | Kodak Polychrome Graphics Llc | Lithographic printing printable media and process for the production thereof |
| US6255033B1 (en) * | 1999-07-30 | 2001-07-03 | Creo, Ltd. | Positive acting photoresist compositions and imageable element |
| KR100491571B1 (ko) * | 1999-10-01 | 2005-05-27 | 세키스이가가쿠 고교가부시키가이샤 | 합판 유리용 중간층 필름 및 합판 유리 |
| WO2004013191A1 (en) | 2002-08-02 | 2004-02-12 | E. I. Du Pont De Nemours And Company | A process for controlling polyvinylbutyral physical properties by controlling stereochemistry of same |
-
2003
- 2003-08-04 WO PCT/US2003/024380 patent/WO2004013191A1/en not_active Ceased
- 2003-08-04 EP EP03767167A patent/EP1539831B1/en not_active Expired - Lifetime
- 2003-08-04 JP JP2004526416A patent/JP4335805B2/ja not_active Expired - Lifetime
- 2003-08-04 AU AU2003257166A patent/AU2003257166B2/en not_active Ceased
- 2003-08-04 US US10/519,661 patent/US7709565B2/en not_active Expired - Lifetime
- 2003-08-04 CA CA002494510A patent/CA2494510A1/en not_active Abandoned
- 2003-08-04 DE DE60329401T patent/DE60329401D1/de not_active Expired - Lifetime
- 2003-08-04 CN CNB038186152A patent/CN100384887C/zh not_active Expired - Lifetime
- 2003-08-04 MX MXPA05001224A patent/MXPA05001224A/es active IP Right Grant
-
2010
- 2010-03-18 US US12/726,439 patent/US8053504B1/en not_active Expired - Fee Related
-
2011
- 2011-09-23 US US13/242,502 patent/US8329793B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440690A (zh) * | 2018-04-23 | 2018-08-24 | 浙江德斯泰新材料股份有限公司 | 一种3d打印专用聚乙烯醇缩丁醛树脂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US8053504B1 (en) | 2011-11-08 |
| US7709565B2 (en) | 2010-05-04 |
| JP4335805B2 (ja) | 2009-09-30 |
| JP2005534778A (ja) | 2005-11-17 |
| EP1539831A1 (en) | 2005-06-15 |
| AU2003257166B2 (en) | 2009-01-15 |
| CN1675258A (zh) | 2005-09-28 |
| EP1539831B1 (en) | 2009-09-23 |
| US20050288429A1 (en) | 2005-12-29 |
| US20120016064A1 (en) | 2012-01-19 |
| WO2004013191A1 (en) | 2004-02-12 |
| CA2494510A1 (en) | 2004-02-12 |
| DE60329401D1 (de) | 2009-11-05 |
| AU2003257166A1 (en) | 2004-02-23 |
| US8329793B2 (en) | 2012-12-11 |
| CN100384887C (zh) | 2008-04-30 |
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