MX355156B - Metodo para la elaboracion de un separador polimerico con electrolito, y el separador polimerico con electrolito resultante. - Google Patents

Metodo para la elaboracion de un separador polimerico con electrolito, y el separador polimerico con electrolito resultante.

Info

Publication number
MX355156B
MX355156B MX2014005959A MX2014005959A MX355156B MX 355156 B MX355156 B MX 355156B MX 2014005959 A MX2014005959 A MX 2014005959A MX 2014005959 A MX2014005959 A MX 2014005959A MX 355156 B MX355156 B MX 355156B
Authority
MX
Mexico
Prior art keywords
groups
polymer
polymer electrolyte
compound
electrolyte separator
Prior art date
Application number
MX2014005959A
Other languages
English (en)
Other versions
MX2014005959A (es
Inventor
A Abusleme Julio
Pieri Riccardo
Fossati Paolo
Original Assignee
Solvay Specialty Polymers It
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay Specialty Polymers It filed Critical Solvay Specialty Polymers It
Publication of MX2014005959A publication Critical patent/MX2014005959A/es
Publication of MX355156B publication Critical patent/MX355156B/es

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/186—Monomers containing fluorine with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C08F214/225—Vinylidene fluoride with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/403—Manufacturing processes of separators, membranes or diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cell Separators (AREA)
  • Secondary Cells (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Un proceso para la elaboración de un separador conformado por polímero y electrolito basado en un material compuesto híbrido orgánico/inorgánico de fluoropolímero, donde dicho proceso comprende: (i) proveer una mezcla de: - por lo menos un fluoropolímero que comprende unidades repetitivas que se obtienen a partir de por lo menos un monómero (met)acrílico [monómero (MA)] con la fórmula: (ver Fórmula) donde R1, R2, R3, son iguales o diferentes entre sí, y cada uno de ellos es independientemente un átomo de hidrógeno o un grupo C1-C3 hidrocarburo, y ROH es una unidad C1-C5 hidrocarburo que comprende por lo menos un grupo hidroxilo [polímero (F)]; - por lo menos un compuesto de metal [compuesto (M)] con la fórmula: X4-mAYm donde m es un número entero entre 1 y 4, A es un metal que se selecciona entre el grupo que consiste en Si, Ti y Zr, Y es un grupo hidrolizable, X es un grupo hidrocarburo, que opcionalmente comprende uno o más grupos funcionales; y - por lo menos un electrolito (E); y - por lo menos un plastificante líquido (S); (ii) hacer reaccionar por lo menos una fracción de los grupos hidroxilo de los grupos ROH de dicho monómero (MA) de dicho polímero (F) con por lo menos una fracción de dicho compuesto (M), de manera tal de obtener un polímero injertado que comprende grupos pendientes -Ym-1AX4-m, donde m, Y, A y X tienen el mismo significado que se detalló anteriormente; (iii) hidrolizar y/o policondensar el compuesto (M) y/o los grupos pendientes -Ym-1AX4-m, como se detalló anteriormente para obtener una mezcla líquida que comprende el material compuesto híbrido orgánico/inorgánico de fluoropolímero que comprende dominios inorgánicos y el solvente (S) y el electrolito (E) incorporados, y (iv) hacer por colada una película a partir de la mezcla líquida que se obtuvo en (iii); (v) secar la película que se obtuvo en (iv) para obtener el separador polimérico con electrolito.
MX2014005959A 2011-11-17 2012-11-06 Metodo para la elaboracion de un separador polimerico con electrolito, y el separador polimerico con electrolito resultante. MX355156B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11189620 2011-11-17
PCT/EP2012/071881 WO2013072216A1 (en) 2011-11-17 2012-11-06 Method for manufacturing a polymer electrolyte separator and polymer electrolyte separator therefrom

Publications (2)

Publication Number Publication Date
MX2014005959A MX2014005959A (es) 2015-02-04
MX355156B true MX355156B (es) 2018-04-06

Family

ID=47143100

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014005959A MX355156B (es) 2011-11-17 2012-11-06 Metodo para la elaboracion de un separador polimerico con electrolito, y el separador polimerico con electrolito resultante.

Country Status (8)

Country Link
US (1) US10840542B2 (es)
EP (1) EP2780404B1 (es)
JP (1) JP6385824B2 (es)
KR (1) KR101981825B1 (es)
CN (1) CN104039874B (es)
CA (1) CA2854223C (es)
MX (1) MX355156B (es)
WO (1) WO2013072216A1 (es)

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JP7245648B2 (ja) * 2015-07-27 2023-03-24 ソルヴェイ（ソシエテ アノニム） 電極形成組成物
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CN108701794A (zh) * 2015-12-23 2018-10-23 索尔维特殊聚合物意大利有限公司 复合材料
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Also Published As

Publication number Publication date
JP6385824B2 (ja) 2018-09-05
US10840542B2 (en) 2020-11-17
EP2780404B1 (en) 2016-04-06
CA2854223A1 (en) 2013-05-23
CN104039874A (zh) 2014-09-10
JP2015502636A (ja) 2015-01-22
EP2780404A1 (en) 2014-09-24
CN104039874B (zh) 2017-05-03
CA2854223C (en) 2020-04-28
KR101981825B1 (ko) 2019-05-23
MX2014005959A (es) 2015-02-04
WO2013072216A1 (en) 2013-05-23
KR20140097349A (ko) 2014-08-06
US20140315080A1 (en) 2014-10-23

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