FR3083922B1 - Accumulateur electrochimique a architecture bipolaire comportant une structure specifique - Google Patents

Accumulateur electrochimique a architecture bipolaire comportant une structure specifique Download PDF

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Publication number
FR3083922B1
FR3083922B1 FR1856389A FR1856389A FR3083922B1 FR 3083922 B1 FR3083922 B1 FR 3083922B1 FR 1856389 A FR1856389 A FR 1856389A FR 1856389 A FR1856389 A FR 1856389A FR 3083922 B1 FR3083922 B1 FR 3083922B1
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Prior art keywords
bipolar
negative electrode
positive electrode
polymerization
ion
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Active
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FR1856389A
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English (en)
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FR3083922A1 (fr
Inventor
Djamel Mourzagh
Julio Abusleme
Gaelle Besnard
Marc-David Braida
Elise Gutel
Helene Rouault
Daniel Tomasi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Specialty Polymers France SAS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Solvay Specialty Polymers France SAS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
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Priority to FR1856389A priority Critical patent/FR3083922B1/fr
Application filed by Commissariat a lEnergie Atomique CEA, Solvay Specialty Polymers France SAS, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to CN201980053911.1A priority patent/CN112567552A/zh
Priority to KR1020217003959A priority patent/KR20210029805A/ko
Priority to US17/258,855 priority patent/US20210328226A1/en
Priority to JP2021524122A priority patent/JP2021531637A/ja
Priority to PCT/FR2019/051733 priority patent/WO2020012123A1/fr
Priority to EP19748875.2A priority patent/EP3821488A1/fr
Publication of FR3083922A1 publication Critical patent/FR3083922A1/fr
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Publication of FR3083922B1 publication Critical patent/FR3083922B1/fr
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
    • H01M10/0418—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes with bipolar electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0436—Small-sized flat cells or batteries for portable equipment
    • H01M10/044—Small-sized flat cells or batteries for portable equipment with bipolar electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/023—Gel electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/029—Bipolar electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0085—Immobilising or gelification of electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0091—Composites in the form of mixtures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

L'invention se rapporte à un accumulateur à architecture bipolaire qui comprend deux collecteurs de courant terminaux entre lesquels est disposé un empilement de n cellules électrochimiques, n étant un entier au moins égal à 2, dans lequel : - chaque cellule électrochimique comprend une électrode positive, une électrode négative et une membrane conductrice d'ions qui est intercalée entre l'électrode positive et l'électrode négative et comprend un électrolyte liquide compris dans les électrodes et la membrane conductrice d'ions ; - les n cellules électrochimiques sont séparées les unes des autres par n-1 collecteurs de courant bipolaires ; et qui est caractérisé en ce que l'électrode positive et l'électrode négative de chaque cellule électrochimique sont des électrodes gélifiées comprenant un matériau composite comprenant une matrice polymérique en au moins un polymère gélifiant (FF), un matériau actif d'électrode et éventuellement un ou plusieurs additifs conducteurs électroniques, la matrice polymérique piégeant l'électrolyte liquide, le ou les polymères gélifiants (FF) étant choisi(s) parmi des polymères fluorés comprenant au moins une unité répétitive issue de la polymérisation d'un monomère fluoré et au moins une unité répétitive issue de la polymérisation d'un monomère comprenant au moins un groupe acide carboxylique, éventuellement sous forme d'un sel. Applications : tout domaine où des batteries à architecture bipolaire sont susceptibles d'être utilisées et, notamment, dans la production de véhicules électriques ou hybrides, de dispositifs de stockage stationnaire de l'énergie et de dispositifs électroniques portables (téléphones, tablettes tactiles, ordinateurs, appareils photographiques, caméscopes, etc).
FR1856389A 2018-07-11 2018-07-11 Accumulateur electrochimique a architecture bipolaire comportant une structure specifique Active FR3083922B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1856389A FR3083922B1 (fr) 2018-07-11 2018-07-11 Accumulateur electrochimique a architecture bipolaire comportant une structure specifique
KR1020217003959A KR20210029805A (ko) 2018-07-11 2019-07-10 특정 구조를 포함하는 바이폴라 아키텍처를 갖는 전기화학 축전지
US17/258,855 US20210328226A1 (en) 2018-07-11 2019-07-10 Electrochemical accumulator with bipolar architecture including a specific structure
JP2021524122A JP2021531637A (ja) 2018-07-11 2019-07-10 特定の構造を包含するバイポーラアーキテクチャを有する電気化学アキュムレータ
CN201980053911.1A CN112567552A (zh) 2018-07-11 2019-07-10 包括特定结构的具有双极构造的电化学蓄电池
PCT/FR2019/051733 WO2020012123A1 (fr) 2018-07-11 2019-07-10 Accumulateur électrochimique a architecture bipolaire comportant une structure specifique
EP19748875.2A EP3821488A1 (fr) 2018-07-11 2019-07-10 Accumulateur électrochimique a architecture bipolaire comportant une structure specifique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1856389 2018-07-11
FR1856389A FR3083922B1 (fr) 2018-07-11 2018-07-11 Accumulateur electrochimique a architecture bipolaire comportant une structure specifique

Publications (2)

Publication Number Publication Date
FR3083922A1 FR3083922A1 (fr) 2020-01-17
FR3083922B1 true FR3083922B1 (fr) 2020-10-16

Family

ID=65031409

Family Applications (1)

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FR1856389A Active FR3083922B1 (fr) 2018-07-11 2018-07-11 Accumulateur electrochimique a architecture bipolaire comportant une structure specifique

Country Status (7)

Country Link
US (1) US20210328226A1 (fr)
EP (1) EP3821488A1 (fr)
JP (1) JP2021531637A (fr)
KR (1) KR20210029805A (fr)
CN (1) CN112567552A (fr)
FR (1) FR3083922B1 (fr)
WO (1) WO2020012123A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3110776B1 (fr) * 2020-05-20 2022-08-12 Accumulateurs Fixes Electrolyte gelifie pour element electrochimique au lithium
FR3115934B1 (fr) 2020-11-02 2022-10-07 Commissariat Energie Atomique Accumulateur électrochimique à architecture bipolaire comportant, comme matériau actif d’électrode, un matériau commun à toutes les électrodes
FR3117273A1 (fr) * 2020-12-08 2022-06-10 Commissariat A L'energie Atomique Et Aux Energies Alternatives Module de batterie à pluralité d’accumulateurs électrochimique, comprenant un dispositif nébuliseur pour projeter des microgouttelettes en cas d’emballement thermique d’au moins un des accumulateurs.
US11643486B1 (en) * 2022-06-08 2023-05-09 Arkema Inc. Non-linear vinylidene fluoride copolymers
GB2621116A (en) * 2022-07-29 2024-02-07 Dyson Technology Ltd Electrode precursor composition
GB2622037A (en) * 2022-08-31 2024-03-06 Dyson Technology Ltd Energy storage devices and components thereof
CN115954449A (zh) * 2022-12-28 2023-04-11 广东微电新能源有限公司 阻燃凝胶聚合物电极材料的制备方法以及电池

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6203944B1 (en) 1998-03-26 2001-03-20 3M Innovative Properties Company Electrode for a lithium battery
US6255017B1 (en) 1998-07-10 2001-07-03 3M Innovative Properties Co. Electrode material and compositions including same
SE520007C8 (sv) 2001-09-19 2006-05-16 Nilar Europ Ab Ett bipolärt batteri, en metod för tillverkning av ett bipolärt batteri och bilplåtsammansättning
FR2832859B1 (fr) 2001-11-28 2004-01-09 Commissariat Energie Atomique Generateur electrochimique au lithium comprenant au moins une electrode bipolaire avec substrats conducteurs en aluminium ou alliage d'aluminium
JP4144312B2 (ja) 2002-10-08 2008-09-03 日産自動車株式会社 バイポーラ電池
TWI437009B (zh) * 2007-04-24 2014-05-11 Solvay Solexis Spa １，１－二氟乙烯共聚物類
FR2925768B1 (fr) * 2007-12-21 2012-06-08 Commissariat Energie Atomique Batterie multipolaire a etancheite interplaque amelioree
CN102201605A (zh) * 2010-03-22 2011-09-28 中国电子科技集团公司第十八研究所 具有双极性结构的电化学储能与能量转换装置
FR2961636B1 (fr) * 2010-06-17 2013-10-18 Commissariat Energie Atomique Accumulateur electrochimique au lithium a architecture bipolaire specifique
JP5685148B2 (ja) * 2011-06-03 2015-03-18 旭化成株式会社 バイポーラ電池
JP4957932B1 (ja) * 2011-08-30 2012-06-20 Ｊｓｒ株式会社 蓄電デバイス電極用バインダー組成物、蓄電デバイス電極用スラリー、蓄電デバイス電極、および蓄電デバイス
JP6385824B2 (ja) * 2011-11-17 2018-09-05 ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． 高分子電解質セパレータを製造するための方法およびそれにより得られる高分子電解質セパレータ
KR102088342B1 (ko) * 2012-04-23 2020-03-13 솔베이(소시에떼아노님) 플루오로중합체 필름
EP2688123B1 (fr) * 2012-07-16 2017-07-05 Commissariat à l'Énergie Atomique et aux Énergies Alternatives Procédé de fabrication d'une batterie au lithium-ion comprenant un séparateur de fluoropolymère
KR102388498B1 (ko) * 2014-05-07 2022-04-21 솔베이(소시에떼아노님) 복합 전극
WO2017017023A1 (fr) * 2015-07-27 2017-02-02 Solvay Sa Composition pour formation d'électrode
FR3044169B1 (fr) * 2015-11-24 2020-02-28 Commissariat A L'energie Atomique Et Aux Energies Alternatives Batterie bipolaire lithium-ion

Also Published As

Publication number Publication date
JP2021531637A (ja) 2021-11-18
US20210328226A1 (en) 2021-10-21
CN112567552A (zh) 2021-03-26
FR3083922A1 (fr) 2020-01-17
KR20210029805A (ko) 2021-03-16
WO2020012123A1 (fr) 2020-01-16
EP3821488A1 (fr) 2021-05-19

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