MX339729B - Procedimiento continuo de escision oxidativa de aceites vegetales. - Google Patents
Procedimiento continuo de escision oxidativa de aceites vegetales.Info
- Publication number
- MX339729B MX339729B MX2012007719A MX2012007719A MX339729B MX 339729 B MX339729 B MX 339729B MX 2012007719 A MX2012007719 A MX 2012007719A MX 2012007719 A MX2012007719 A MX 2012007719A MX 339729 B MX339729 B MX 339729B
- Authority
- MX
- Mexico
- Prior art keywords
- acid function
- carboxylic acids
- saturated
- triglycerides
- vegetable oils
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/126—Acids containing more than four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
- C11C1/08—Refining
- C11C1/10—Refining by distillation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
- C11C1/02—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids from fats or fatty oils
- C11C1/04—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids from fats or fatty oils by hydrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Microbiology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Fats And Perfumes (AREA)
Abstract
Se describe un procedimiento continuo para la escisión oxidativa de aceites vegetales que contienen triglicéridos de ácidos carboxílicos insaturados, para la obtención de ácidos carboxílicos saturados, que comprende los pasos de: a) alimentar a un primer reactor continuo al menos un aceite vegetal, un compuesto oxidante y un catalizador capaz de catalizar la reacción de oxidación del enlace doble olefínico, para obtener un compuesto intermediario que contiene dioles vecinales, y de b) alimentar a un segundo reactor continuo el compuesto intermediario, un compuesto que contiene oxígeno y un catalizador capaz de catalizar la reacción de oxidación de los dioles vecinales a los grupos carboxílicos, para obtener ácidos monocarboxílicos saturados (i) y triglicéridos que contienen ácidos carboxílicos saturados con más de una función ácida (ii); c) separar los ácidos monocarboxílicos saturados (i) de los triglicéridos que tienen más de una función ácida (ii), d) hidrolizar en un tercer reactor, los triglicéridos que tienen más de una función ácida (ii) para obtener glicerol y ácidos carboxílicos saturados con más de una función ácida.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2009A002360A IT1397378B1 (it) | 2009-12-30 | 2009-12-30 | Processo continuo di scissione ossidativa di oli vegetali |
| PCT/EP2010/070843 WO2011080296A1 (en) | 2009-12-30 | 2010-12-29 | Continuous process of oxidative cleavage of vegetable oils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2012007719A MX2012007719A (es) | 2012-07-25 |
| MX339729B true MX339729B (es) | 2016-06-06 |
Family
ID=42712513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2012007719A MX339729B (es) | 2009-12-30 | 2010-12-29 | Procedimiento continuo de escision oxidativa de aceites vegetales. |
Country Status (15)
| Country | Link |
|---|---|
| US (4) | US8835662B2 (es) |
| EP (4) | EP3112341B1 (es) |
| KR (1) | KR101770851B1 (es) |
| CN (1) | CN102725257B (es) |
| AU (1) | AU2010338206B2 (es) |
| BR (1) | BR112012016249B1 (es) |
| CA (1) | CA2783443C (es) |
| EA (1) | EA019934B1 (es) |
| ES (3) | ES2934867T3 (es) |
| IT (1) | IT1397378B1 (es) |
| MX (1) | MX339729B (es) |
| PL (2) | PL3112341T3 (es) |
| UA (1) | UA108871C2 (es) |
| WO (1) | WO2011080296A1 (es) |
| ZA (1) | ZA201205574B (es) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1403273B1 (it) | 2010-12-20 | 2013-10-17 | Novamont Spa | Derivati di oli vegetali come oli estensori per composizioni elastomeriche |
| ITNO20120002A1 (it) | 2012-03-20 | 2013-09-21 | Novamont Spa | Processo per la produzione di composti organici a partire da specie vegetali |
| ITMI20121070A1 (it) | 2012-06-19 | 2013-12-20 | Novamont Spa | Processo di preparazione di strutture oligomeriche complesse |
| FR2994178B1 (fr) | 2012-07-31 | 2015-08-07 | Interoleagineuse D Assistance Et De Dev S I A Soc | Procede de preparation d'un acide carboxylique ou d'un aldehyde |
| ITNO20130005A1 (it) * | 2013-06-27 | 2014-12-28 | Novamont Spa | Processo per l'idrogenazione selettiva di oli vegetali |
| BR112016016232B1 (pt) | 2014-01-13 | 2021-06-01 | Novamont S.P.A. | Composições de polímeros e uso de ésteres alifáticos como plastificantes |
| US9695105B2 (en) | 2014-03-11 | 2017-07-04 | Novamont S.P.A. | Process for the preparation of complex oligomeric structures |
| US9862671B2 (en) | 2014-03-11 | 2018-01-09 | Novamont S.P.A. | Process for the synthesis of aliphatic dialkyl esters from vegetable oils |
| US20170362343A1 (en) | 2014-12-19 | 2017-12-21 | Novamont S P A. | Use of destructured starch derivatives as hysteresis reduction additives for elastomer compositions |
| US10889655B2 (en) | 2014-12-19 | 2021-01-12 | Novamont S.P.A. | Destructured starch derivatives and elastomer compositions containing them |
| CN107108437B (zh) * | 2014-12-22 | 2021-07-16 | 诺瓦蒙特股份公司 | 选择性氢化植物油的改进方法 |
| EP3444032A1 (en) * | 2015-01-22 | 2019-02-20 | Novamont S.p.A. | Process for the recovery of cobalt and tungstic acid and/or its derivatives from aqueous solutions |
| WO2016124732A1 (en) | 2015-02-05 | 2016-08-11 | Novamont S.P.A. | Method for the cultivation of pluriennial plants belonging to the cardueae tribe and for the integrated recovery of inulin, seeds and biomass from the said plants. |
| PT3307857T (pt) | 2015-06-12 | 2019-11-18 | Novamont Spa | Ésteres de trimetilolpropano com baixo ponto de escoamento |
| ITUB20153490A1 (it) | 2015-09-08 | 2017-03-08 | Novamont Spa | Miscele di esteri dell?acido pelargonico |
| ITUB20153460A1 (it) | 2015-09-08 | 2017-03-08 | Novamont Spa | Composizioni cosmetiche acquose contenenti esteri dell?acido pelargonico |
| ITUB20153461A1 (it) | 2015-09-08 | 2017-03-08 | Novamont Spa | Composizioni cosmetiche lipofile contenenti esteri dell?acido pelargonico |
| ITUB20160866A1 (it) | 2016-02-18 | 2017-08-18 | Versalis Spa | Inibitore di corrosione comprendente strutture oligomeriche complesse derivanti da oli vegetali |
| ITUA20163227A1 (it) | 2016-05-06 | 2017-11-06 | Novamont Spa | Composizioni cosmetiche contenenti diglicerolo tetrapelargonato. |
| ITUA20164118A1 (it) * | 2016-06-06 | 2017-12-06 | Novamont Spa | Processo di preparazione di acidi dicarbossilici purificati. |
| ITUA20164110A1 (it) | 2016-06-06 | 2017-12-06 | Novamont Spa | Processo di scissione ossidativa di dioli vicinali. |
| ITUA20164114A1 (it) | 2016-06-06 | 2017-12-06 | Novamont Spa | Processo migliorato di idrolisi di trigliceridi di acidi dicarbossilici. |
| ITUA20164552A1 (it) | 2016-06-21 | 2017-12-21 | Novamont Spa | Processo per l’idrogenazione selettiva di oli vegetali con catalizzatori tipo egg-shell. |
| IT201700088554A1 (it) | 2017-08-02 | 2019-02-02 | Novamont Spa | Composizioni erbicide a base di acido pelargonico e altri acidi |
| IT201700088474A1 (it) | 2017-08-02 | 2019-02-02 | Novamont Spa | Composizioni erbicide a base di acido pelargonico |
| EP3469906A1 (en) | 2017-10-16 | 2019-04-17 | Belchim Crop Protection NV | Synergistically effective herbicide composition comprising pelargonic acid and flazasulfuron |
| WO2019101856A1 (en) | 2017-11-22 | 2019-05-31 | Novamont S.P.A. | Production of carboxylic acids from vicinal diols |
| FI128827B2 (en) * | 2018-12-14 | 2023-03-30 | Upm Kymmene Corp | Process for cleaning renewable feedstocks that include fatty acids |
| FI128504B (en) * | 2018-12-14 | 2020-06-30 | Upm Kymmene Corp | A process for purifying a renewable feed comprising triglycerides |
| KR102303532B1 (ko) * | 2020-01-08 | 2021-09-23 | 애경유화주식회사 | 펠라르곤산 및 아젤라인산의 제조방법 |
| IT202000003635A1 (it) | 2020-02-21 | 2021-08-21 | Novamont Spa | Composizioni erbicide a base di acido pelargonico |
| CN111943839A (zh) * | 2020-08-26 | 2020-11-17 | 德州市晟昊生物科技有限公司 | 一种氧化裂解不饱和脂肪酸制备二元酸的两步氧化方法 |
| CN112110815B (zh) * | 2020-09-27 | 2021-05-07 | 禾大西普化学（四川）有限公司 | 采用高芥酸菜籽油制备壬二酸、十三碳二元酸等长链二元酸的方法 |
| IT202100006410A1 (it) | 2021-03-17 | 2022-09-17 | Novamont Spa | Recupero di acidi dicarbossilici da trigliceridi |
| EP4355723A1 (en) | 2021-06-18 | 2024-04-24 | Evonik Operations GmbH | Nonanic acid esters |
| BE1030433B1 (nl) | 2022-04-08 | 2023-11-13 | Belchim Crop Prot Nv | Herbicidesamenstelling voor het bestrijden van ongewenste vegetatie |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA934389A (en) * | 1970-06-29 | 1973-09-25 | The Procter & Gamble Company | Preparation of carboxylic acids by the oxidation of vicinal glycols |
| NL7109931A (es) * | 1970-10-28 | 1972-05-03 | ||
| US4353499A (en) * | 1981-04-27 | 1982-10-12 | Edward Simonds | Centrifugal separator |
| US4606863A (en) * | 1983-06-02 | 1986-08-19 | New Japan Chemical Co., Ltd. | Process for preparing carboxylic acid |
| IT1256989B (it) * | 1992-10-29 | 1995-12-27 | Novamont Spa | Procedimento per la preparazione di acidi carbossilici o loro esteri mediante scissione ossidativa di acidi grassi insaturi o loro esteri. |
| DE10105528A1 (de) | 2001-02-07 | 2002-08-08 | Basf Ag | Verfahren zur Online-Bestimmung von Wasserstoffperoxid |
| ITMI20051779A1 (it) * | 2005-09-23 | 2007-03-24 | Novamont Spa | Processo migliorato per la produzione di derivati di acidi carbossilici saturi |
| ITMI20070953A1 (it) * | 2007-05-10 | 2008-11-11 | Novamont Spa | Processo di scissione catalitica di oli vegetali |
-
2009
- 2009-12-30 IT ITMI2009A002360A patent/IT1397378B1/it active
-
2010
- 2010-12-29 EP EP16182535.1A patent/EP3112341B1/en active Active
- 2010-12-29 PL PL16182535T patent/PL3112341T3/pl unknown
- 2010-12-29 EP EP20204446.7A patent/EP3792243B1/en active Active
- 2010-12-29 CN CN201080059652.2A patent/CN102725257B/zh active Active
- 2010-12-29 EP EP22202723.7A patent/EP4148036A1/en active Pending
- 2010-12-29 WO PCT/EP2010/070843 patent/WO2011080296A1/en active Application Filing
- 2010-12-29 ES ES20204446T patent/ES2934867T3/es active Active
- 2010-12-29 US US13/520,020 patent/US8835662B2/en active Active
- 2010-12-29 KR KR1020127019893A patent/KR101770851B1/ko active IP Right Grant
- 2010-12-29 MX MX2012007719A patent/MX339729B/es active IP Right Grant
- 2010-12-29 EP EP10803252.5A patent/EP2519489B1/en active Active
- 2010-12-29 AU AU2010338206A patent/AU2010338206B2/en active Active
- 2010-12-29 BR BR112012016249A patent/BR112012016249B1/pt active IP Right Grant
- 2010-12-29 PL PL20204446.7T patent/PL3792243T3/pl unknown
- 2010-12-29 EA EA201290591A patent/EA019934B1/ru not_active IP Right Cessation
- 2010-12-29 UA UAA201209255A patent/UA108871C2/ru unknown
- 2010-12-29 CA CA2783443A patent/CA2783443C/en active Active
- 2010-12-29 ES ES16182535T patent/ES2845219T3/es active Active
- 2010-12-29 ES ES10803252.5T patent/ES2606132T3/es active Active
-
2012
- 2012-07-24 ZA ZA2012/05574A patent/ZA201205574B/en unknown
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2014
- 2014-08-11 US US14/456,243 patent/US9346732B2/en active Active
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2016
- 2016-05-02 US US15/143,838 patent/US9790160B2/en active Active
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2017
- 2017-09-07 US US15/697,515 patent/US10150725B2/en active Active
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |