EA201290591A1 - Непрерывный способ окислительного расщепления растительных масел - Google Patents

Непрерывный способ окислительного расщепления растительных масел

Info

Publication number
EA201290591A1
EA201290591A1 EA201290591A EA201290591A EA201290591A1 EA 201290591 A1 EA201290591 A1 EA 201290591A1 EA 201290591 A EA201290591 A EA 201290591A EA 201290591 A EA201290591 A EA 201290591A EA 201290591 A1 EA201290591 A1 EA 201290591A1
Authority
EA
Eurasian Patent Office
Prior art keywords
triglycerides
functional group
acid functional
carboxylic acids
vegetable oils
Prior art date
Application number
EA201290591A
Other languages
English (en)
Other versions
EA019934B1 (ru
Inventor
Арно Бьесер
Джампьетро Борсотти
Франческа Диджоя
Адриано Феррари
Алессандро Пирокко
Original Assignee
НОВАМОНТ С.п.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by НОВАМОНТ С.п.А. filed Critical НОВАМОНТ С.п.А.
Publication of EA201290591A1 publication Critical patent/EA201290591A1/ru
Publication of EA019934B1 publication Critical patent/EA019934B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/126—Acids containing more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
    • C11C1/08—Refining
    • C11C1/10—Refining by distillation
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
    • C11C1/02—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids from fats or fatty oils
    • C11C1/04—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids from fats or fatty oils by hydrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Microbiology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

Описан непрерывный способ окислительного расщепления растительных масел, содержащих триглицериды ненасыщенных карбоновых кислот, для получения насыщенных карбоновых кислот, включающий стадии: а) подачи в первый реактор непрерывного действия по меньшей мере растительного масла, окисляющего соединения и катализатора, способного катализировать реакцию окисления олефиновой двойной связи с получением промежуточного соединения, содержащего вицинальные диолы, и b) подачи во второй реактор непрерывного действия этого промежуточного соединения, соединения, содержащего кислород, и катализатора, способного катализировать реакцию окисления вицинальных диолов до карбоксильных групп, с получением насыщенных монокарбоновых кислот (i) и триглицеридов, содержащих насыщенные карбоновые кислоты с более чем одной кислотной функциональной группой (ii); с) отделения насыщенных монокарбоновых кислот (i) от триглицеридов, имеющих более чем одну кислотную функциональную группу (ii), d) гидролиза в третьем реакторе триглицеридов, имеющих более чем одну кислотную функциональную группу (ii), с получением глицерина и насыщенных карбоновых кислот с более чем одной кислотной функциональной группой.
EA201290591A 2009-12-30 2010-12-29 Непрерывный способ окислительного расщепления растительных масел EA019934B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2009A002360A IT1397378B1 (it) 2009-12-30 2009-12-30 Processo continuo di scissione ossidativa di oli vegetali
PCT/EP2010/070843 WO2011080296A1 (en) 2009-12-30 2010-12-29 Continuous process of oxidative cleavage of vegetable oils

Publications (2)

Publication Number Publication Date
EA201290591A1 true EA201290591A1 (ru) 2013-01-30
EA019934B1 EA019934B1 (ru) 2014-07-30

Family

ID=42712513

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290591A EA019934B1 (ru) 2009-12-30 2010-12-29 Непрерывный способ окислительного расщепления растительных масел

Country Status (15)

Country Link
US (4) US8835662B2 (ru)
EP (4) EP4148036A1 (ru)
KR (1) KR101770851B1 (ru)
CN (1) CN102725257B (ru)
AU (1) AU2010338206B2 (ru)
BR (1) BR112012016249B1 (ru)
CA (1) CA2783443C (ru)
EA (1) EA019934B1 (ru)
ES (3) ES2606132T3 (ru)
IT (1) IT1397378B1 (ru)
MX (1) MX339729B (ru)
PL (2) PL3112341T3 (ru)
UA (1) UA108871C2 (ru)
WO (1) WO2011080296A1 (ru)
ZA (1) ZA201205574B (ru)

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ITNO20120002A1 (it) 2012-03-20 2013-09-21 Novamont Spa Processo per la produzione di composti organici a partire da specie vegetali
ITMI20121070A1 (it) 2012-06-19 2013-12-20 Novamont Spa Processo di preparazione di strutture oligomeriche complesse
FR2994178B1 (fr) 2012-07-31 2015-08-07 Interoleagineuse D Assistance Et De Dev S I A Soc Procede de preparation d'un acide carboxylique ou d'un aldehyde
ITNO20130005A1 (it) 2013-06-27 2014-12-28 Novamont Spa Processo per l'idrogenazione selettiva di oli vegetali
US10144813B2 (en) 2014-01-13 2018-12-04 Novamont S.P.A. Aliphatic esters and polymer compositions containing them
US9695105B2 (en) 2014-03-11 2017-07-04 Novamont S.P.A. Process for the preparation of complex oligomeric structures
TR201901558T4 (tr) 2014-03-11 2019-02-21 Novamont Spa Bitkisel yağlardan alifatik dialkil esterlerin sentezine yönelik proses.
WO2016097149A1 (en) 2014-12-19 2016-06-23 Novamont S.P.A. Use of destructured starch derivatives as hysteresis reduction additivesfor elastomer compositions
US10889655B2 (en) 2014-12-19 2021-01-12 Novamont S.P.A. Destructured starch derivatives and elastomer compositions containing them
PL3237369T3 (pl) 2014-12-22 2021-01-25 Novamont S.P.A. Ulepszony sposób selektywnego uwodorniania olejów roślinnych
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HUE046459T2 (hu) 2015-06-12 2020-03-30 Novamont Spa Alacsony dermedéspontú trimetilolpropán-észterek
ITUB20153490A1 (it) 2015-09-08 2017-03-08 Novamont Spa Miscele di esteri dell?acido pelargonico
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ITUB20153461A1 (it) 2015-09-08 2017-03-08 Novamont Spa Composizioni cosmetiche lipofile contenenti esteri dell?acido pelargonico
ITUB20160866A1 (it) 2016-02-18 2017-08-18 Versalis Spa Inibitore di corrosione comprendente strutture oligomeriche complesse derivanti da oli vegetali
ITUA20163227A1 (it) 2016-05-06 2017-11-06 Novamont Spa Composizioni cosmetiche contenenti diglicerolo tetrapelargonato.
ITUA20164110A1 (it) 2016-06-06 2017-12-06 Novamont Spa Processo di scissione ossidativa di dioli vicinali.
ITUA20164118A1 (it) 2016-06-06 2017-12-06 Novamont Spa Processo di preparazione di acidi dicarbossilici purificati.
ITUA20164114A1 (it) 2016-06-06 2017-12-06 Novamont Spa Processo migliorato di idrolisi di trigliceridi di acidi dicarbossilici.
ITUA20164552A1 (it) 2016-06-21 2017-12-21 Novamont Spa Processo per l’idrogenazione selettiva di oli vegetali con catalizzatori tipo egg-shell.
IT201700088554A1 (it) 2017-08-02 2019-02-02 Novamont Spa Composizioni erbicide a base di acido pelargonico e altri acidi
IT201700088474A1 (it) 2017-08-02 2019-02-02 Novamont Spa Composizioni erbicide a base di acido pelargonico
EP3469906A1 (en) 2017-10-16 2019-04-17 Belchim Crop Protection NV Synergistically effective herbicide composition comprising pelargonic acid and flazasulfuron
US11453634B2 (en) * 2017-11-22 2022-09-27 Novamont S.P.A. Production of carboxylic acids from vicinal diols
FI128504B (en) * 2018-12-14 2020-06-30 Upm Kymmene Corp A process for purifying a renewable feed comprising triglycerides
FI128827B2 (en) * 2018-12-14 2023-03-30 Upm Kymmene Corp Process for cleaning renewable feedstocks that include fatty acids
KR102303532B1 (ko) * 2020-01-08 2021-09-23 애경유화주식회사 펠라르곤산 및 아젤라인산의 제조방법
IT202000003635A1 (it) 2020-02-21 2021-08-21 Novamont Spa Composizioni erbicide a base di acido pelargonico
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CN112110815B (zh) * 2020-09-27 2021-05-07 禾大西普化学（四川）有限公司 采用高芥酸菜籽油制备壬二酸、十三碳二元酸等长链二元酸的方法
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Also Published As

Publication number Publication date
EA019934B1 (ru) 2014-07-30
IT1397378B1 (it) 2013-01-10
EP3112341A1 (en) 2017-01-04
US8835662B2 (en) 2014-09-16
ES2845219T3 (es) 2021-07-26
UA108871C2 (uk) 2015-06-25
US20160244394A1 (en) 2016-08-25
EP3112341B1 (en) 2020-12-09
KR20120120937A (ko) 2012-11-02
EP3792243A1 (en) 2021-03-17
US20180044277A1 (en) 2018-02-15
US20150005521A1 (en) 2015-01-01
ES2606132T3 (es) 2017-03-22
US9790160B2 (en) 2017-10-17
EP4148036A1 (en) 2023-03-15
MX339729B (es) 2016-06-06
AU2010338206B2 (en) 2015-11-26
ES2934867T3 (es) 2023-02-27
EP2519489B1 (en) 2016-09-14
PL3112341T3 (pl) 2021-05-17
WO2011080296A1 (en) 2011-07-07
US10150725B2 (en) 2018-12-11
BR112012016249B1 (pt) 2019-10-22
KR101770851B1 (ko) 2017-08-23
EP3792243B1 (en) 2022-11-30
MX2012007719A (es) 2012-07-25
CN102725257A (zh) 2012-10-10
ITMI20092360A1 (it) 2011-06-30
CN102725257B (zh) 2014-11-05
AU2010338206A1 (en) 2012-07-05
US20120323028A1 (en) 2012-12-20
US9346732B2 (en) 2016-05-24
CA2783443C (en) 2017-12-19
CA2783443A1 (en) 2011-07-07
PL3792243T3 (pl) 2023-03-13
EP2519489A1 (en) 2012-11-07
ZA201205574B (en) 2013-04-24
BR112012016249A2 (pt) 2018-10-23

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