MX2022000601A - Copolimeros de etileno y peliculas con excelentes propiedades de sellado. - Google Patents
Copolimeros de etileno y peliculas con excelentes propiedades de sellado.Info
- Publication number
- MX2022000601A MX2022000601A MX2022000601A MX2022000601A MX2022000601A MX 2022000601 A MX2022000601 A MX 2022000601A MX 2022000601 A MX2022000601 A MX 2022000601A MX 2022000601 A MX2022000601 A MX 2022000601A MX 2022000601 A MX2022000601 A MX 2022000601A
- Authority
- MX
- Mexico
- Prior art keywords
- ethylene copolymer
- density
- 10min
- melt index
- mil
- Prior art date
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/327—Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
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- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
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- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
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- C—CHEMISTRY; METALLURGY
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- B32B2307/30—Properties of the layers or laminate having particular thermal properties
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
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- B32B2307/00—Properties of the layers or laminate
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/72—Density
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/10—Short chain branches
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- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C08L2314/00—Polymer mixtures characterised by way of preparation
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Una composición de copolímero de etileno comprende: un primer copolímero de etileno que tiene una densidad de 0.855 a 0.913 g/cm3, una distribución de peso molecular, Mw/Mn de 1.7 a 2.3, y un índice de fusión, I2 desde 0.1 hasta 20 g/10min.; un segundo copolímero de etileno que tiene una densidad desde 0.875 hasta 0.936 g/cm3, una distribución de peso molecular, Mw/Mn desde 2.3 hasta 6.0, y un índice de fusión, I2 desde 0.3 hasta 100 g/10min; y opcionalmente un tercer copolímero de etileno; en donde el primer copolímero de etileno tiene más ramificaciones de cadena corta por mil átomos de carbono que el segundo copolímero de etileno y la densidad del segundo copolímero de etileno es igual o mayor que la densidad del primer copolímero de etileno. La composición de copolímero de etileno tiene una densidad desde 0.865 hasta 0.913 g/cm3; un índice de fusión, I2 desde 0.5 hasta 10 g/10min; y una fracción que eluye entre 90 y 105°C, que tiene un área integrada de más del 4 por ciento en peso en un análisis CTREF; y al menos 0.0015 partes por millón (ppm) de hafnio. La película soplada hecha de la composición de copolímero de etileno tiene una ventana de adherencia en caliente (HTW) de al menos 45°C (con un espesor de película de aproximadamente 50.08 µm (2 mil)) y una temperatura de inicio de sellado (SIT) de menos de 95°C (en una película espesor de aproximadamente 50.08 µm (2 mil)).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/524,600 US11046843B2 (en) | 2019-07-29 | 2019-07-29 | Ethylene copolymers and films with excellent sealing properties |
PCT/IB2020/056903 WO2021019370A1 (en) | 2019-07-29 | 2020-07-22 | Ethylene copolymers and films with excellent sealing properties |
Publications (1)
Publication Number | Publication Date |
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MX2022000601A true MX2022000601A (es) | 2022-03-11 |
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Application Number | Title | Priority Date | Filing Date |
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MX2022000601A MX2022000601A (es) | 2019-07-29 | 2020-07-22 | Copolimeros de etileno y peliculas con excelentes propiedades de sellado. |
Country Status (8)
Country | Link |
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US (1) | US11046843B2 (es) |
EP (1) | EP4004067A1 (es) |
JP (1) | JP7526253B2 (es) |
KR (1) | KR102691359B1 (es) |
CN (1) | CN114144463B (es) |
BR (1) | BR112022000362A2 (es) |
MX (1) | MX2022000601A (es) |
WO (1) | WO2021019370A1 (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US11046843B2 (en) * | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
EP4323189A1 (en) * | 2021-04-14 | 2024-02-21 | Nova Chemicals (International) S.A. | Biaxially oriented film |
CN116396549A (zh) | 2022-01-04 | 2023-07-07 | 韩华道达尔能源有限公司 | 聚乙烯树脂组合物、其制造方法及包含其的模制品 |
WO2023227969A1 (en) | 2022-05-25 | 2023-11-30 | Nova Chemicals (International) S.A. | Polymer blend and multilayer film structure |
WO2024062315A1 (en) | 2022-09-23 | 2024-03-28 | Nova Chemicals (International) S.A. | Ethylene copolymer composition and film applications |
WO2024153971A1 (en) | 2023-01-18 | 2024-07-25 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
KR102681289B1 (ko) * | 2023-02-27 | 2024-07-04 | 주식회사 아주 | 가스차단성 및 방충 기능을 갖는 식품 포장용 필름 |
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-
2019
- 2019-07-29 US US16/524,600 patent/US11046843B2/en active Active
-
2020
- 2020-07-22 KR KR1020227003230A patent/KR102691359B1/ko active IP Right Grant
- 2020-07-22 EP EP20747130.1A patent/EP4004067A1/en active Pending
- 2020-07-22 JP JP2022506080A patent/JP7526253B2/ja active Active
- 2020-07-22 CN CN202080054820.2A patent/CN114144463B/zh active Active
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- 2020-07-22 WO PCT/IB2020/056903 patent/WO2021019370A1/en active Application Filing
- 2020-07-22 MX MX2022000601A patent/MX2022000601A/es unknown
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BR112022000362A2 (pt) | 2022-05-10 |
WO2021019370A1 (en) | 2021-02-04 |
EP4004067A1 (en) | 2022-06-01 |
CN114144463A (zh) | 2022-03-04 |
US20210032450A1 (en) | 2021-02-04 |
JP7526253B2 (ja) | 2024-07-31 |
US11046843B2 (en) | 2021-06-29 |
JP2022542309A (ja) | 2022-09-30 |
KR102691359B1 (ko) | 2024-08-05 |
CN114144463B (zh) | 2023-03-21 |
KR20220035399A (ko) | 2022-03-22 |
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