ATE282645T1 - Herstellung von polyethylenen - Google Patents
Herstellung von polyethylenenInfo
- Publication number
- ATE282645T1 ATE282645T1 AT00967006T AT00967006T ATE282645T1 AT E282645 T1 ATE282645 T1 AT E282645T1 AT 00967006 T AT00967006 T AT 00967006T AT 00967006 T AT00967006 T AT 00967006T AT E282645 T1 ATE282645 T1 AT E282645T1
- Authority
- AT
- Austria
- Prior art keywords
- olefins
- alpha
- ethylene
- blends
- process conditions
- Prior art date
Links
- -1 POLYETHYLENE Polymers 0.000 title abstract 2
- 239000004698 Polyethylene Substances 0.000 title abstract 2
- 229920000573 polyethylene Polymers 0.000 title abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 3
- 239000004711 α-olefin Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006384 oligomerization reaction Methods 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/607—Catalysts containing a specific non-metal or metal-free compound
- C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15658899P | 1999-09-29 | 1999-09-29 | |
PCT/US2000/026643 WO2001023443A1 (en) | 1999-09-29 | 2000-09-28 | Manufacture of polyethylenes |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE282645T1 true ATE282645T1 (de) | 2004-12-15 |
Family
ID=22560194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00967006T ATE282645T1 (de) | 1999-09-29 | 2000-09-28 | Herstellung von polyethylenen |
Country Status (11)
Country | Link |
---|---|
US (3) | US6555631B1 (de) |
EP (1) | EP1228110B1 (de) |
JP (1) | JP2003510427A (de) |
KR (1) | KR20020037364A (de) |
CN (2) | CN1939934B (de) |
AT (1) | ATE282645T1 (de) |
AU (1) | AU7726800A (de) |
BR (2) | BR0017587B1 (de) |
CA (1) | CA2379607A1 (de) |
DE (1) | DE60016014T2 (de) |
WO (1) | WO2001023443A1 (de) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6458979B1 (en) * | 1999-04-29 | 2002-10-01 | E. I. Du Pont De Nemours And Company | Polymerization of ethylene |
BR0306719B1 (pt) * | 2002-01-09 | 2014-03-18 | Du Pont | Catalisador de polimerização, processo para a polimerização de olefinas, produto e processo para moldagem por sopro |
US7081506B2 (en) * | 2003-10-23 | 2006-07-25 | Fina Technology, Inc. | Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components |
US7410926B2 (en) * | 2003-12-30 | 2008-08-12 | Univation Technologies, Llc | Polymerization process using a supported, treated catalyst system |
DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
DE102004020525A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
EP1773895B1 (de) * | 2004-07-09 | 2011-12-28 | E.I. Du Pont De Nemours And Company | Katalysatoren zur olefin-polymerisierung oder -oligomerisierung |
EP1650231A1 (de) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Polyolefine hergestellt mit Metallocen- und neuen Single-Site-Katalysatorkomponenten in einem Reaktor |
US20070010626A1 (en) * | 2005-07-11 | 2007-01-11 | Shankernarayanan Manivakkam J | Polyethylene compositions |
US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US20070255026A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Process for polyolefin production using fluorinated transition metal catalysts having a low pH |
WO2009114661A1 (en) | 2008-03-13 | 2009-09-17 | Dow Global Technologies Inc. | Long chain branched (lcb), block or interconnected copolymers of ethylene in combination with one other polymer |
WO2011022373A1 (en) | 2009-08-17 | 2011-02-24 | E. I. Du Pont De Nemours And Company | Improved olefin polymerization process |
CN102712715B (zh) * | 2010-01-21 | 2014-10-29 | 巴塞尔聚烯烃股份有限公司 | 在低聚催化剂存在下制备乙烯共聚物组合物的方法 |
EP2552863A1 (de) | 2010-03-29 | 2013-02-06 | E.I. Du Pont De Nemours And Company | Schmiermittelkomponente |
JP2012224842A (ja) * | 2011-03-30 | 2012-11-15 | Sumitomo Chemical Co Ltd | エチレン系重合体製造用触媒およびエチレン系重合体の製造方法 |
US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
MX2014011729A (es) | 2012-05-09 | 2015-01-20 | Sasol Tech Pty Ltd | Tetramerizacion de etileno. |
WO2016063205A2 (en) | 2014-10-21 | 2016-04-28 | Nova Chemicals (International) S.A. | Dilution index |
CA2868640C (en) | 2014-10-21 | 2021-10-26 | Nova Chemicals Corporation | Solution polymerization process |
US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
US10329412B2 (en) | 2017-02-16 | 2019-06-25 | Nova Chemicals (International) S.A. | Caps and closures |
US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
JP7050544B2 (ja) * | 2018-03-27 | 2022-04-08 | Eneos株式会社 | ワックス異性化油の製造方法 |
US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
DE3621763A1 (de) | 1986-06-28 | 1988-01-21 | Bayer Ag | Verfahren zur herstellung von verzweigtem niederdruckpolyethen, neue niederdruckpolyethene und praeformierte bifunktionelle katalysatoren |
FI85588C (fi) | 1989-06-05 | 1992-05-11 | Neste Oy | Foerfarande foer reglering av molekylviktsfoerdelningen och molekylvikten av oligomerisations- eller polymerisationsprodukter av eten. |
US5071927A (en) | 1990-10-09 | 1991-12-10 | Phillips Petroleum Company | High-temperature slurry polymerization of ethylene |
US5137994A (en) | 1991-05-23 | 1992-08-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the simultaneous trimerization and copolymerization of ethylene |
ES2082274T3 (es) * | 1991-05-27 | 1996-03-16 | Hoechst Ag | Procedimiento para la preparacion de poliolefinas sindiotacticas con amplia distribucion de masas moleculares. |
WO1995011264A1 (en) * | 1993-10-21 | 1995-04-27 | Mobil Oil Corporation | Polyolefin blends of bimodal molecular weight distribution |
JPH09143228A (ja) | 1995-11-22 | 1997-06-03 | Sumitomo Chem Co Ltd | エチレン−α−オレフィン共重合体の製造方法 |
JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
JP2000513399A (ja) | 1996-06-17 | 2000-10-10 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の混合遷移金属触媒系 |
US5753785A (en) | 1996-12-16 | 1998-05-19 | Fina Technology, Inc. | Production of E-B copolymers with a single metallocene catalyst and a single monomer |
US6214761B1 (en) * | 1996-12-17 | 2001-04-10 | E. I. Du Pont De Nemours And Company | Iron catalyst for the polymerization of olefins |
IL129929A0 (en) * | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
US6177377B1 (en) * | 1996-12-18 | 2001-01-23 | Amherst Polymer Technology, Inc. | Polymer blends and process for preparation |
DE19707236A1 (de) * | 1997-02-24 | 1998-08-27 | Targor Gmbh | Katalysatorzusammensetzung |
US6103946A (en) * | 1997-07-15 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Manufacture of α-olefins |
US6114483A (en) * | 1997-08-27 | 2000-09-05 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
ATE253087T1 (de) * | 1998-03-30 | 2003-11-15 | Du Pont | Olefinpolymerisation |
CA2330151A1 (en) * | 1998-05-29 | 1999-12-09 | E.I. Du Pont De Nemours And Company | Copolymerization of olefins |
GB9819847D0 (en) * | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
-
2000
- 2000-09-28 CA CA002379607A patent/CA2379607A1/en not_active Abandoned
- 2000-09-28 AU AU77268/00A patent/AU7726800A/en not_active Abandoned
- 2000-09-28 CN CN2006101423259A patent/CN1939934B/zh not_active Expired - Lifetime
- 2000-09-28 CN CN00813383A patent/CN1377377A/zh active Pending
- 2000-09-28 KR KR1020027004026A patent/KR20020037364A/ko not_active Application Discontinuation
- 2000-09-28 US US09/672,612 patent/US6555631B1/en not_active Expired - Lifetime
- 2000-09-28 DE DE60016014T patent/DE60016014T2/de not_active Expired - Lifetime
- 2000-09-28 BR BRPI0017587-0B1A patent/BR0017587B1/pt not_active IP Right Cessation
- 2000-09-28 JP JP2001526591A patent/JP2003510427A/ja active Pending
- 2000-09-28 AT AT00967006T patent/ATE282645T1/de not_active IP Right Cessation
- 2000-09-28 EP EP00967006A patent/EP1228110B1/de not_active Expired - Lifetime
- 2000-09-28 WO PCT/US2000/026643 patent/WO2001023443A1/en active IP Right Grant
- 2000-09-28 BR BRPI0014639-0A patent/BR0014639B1/pt not_active IP Right Cessation
-
2003
- 2003-02-06 US US10/359,336 patent/US6921795B2/en not_active Expired - Lifetime
- 2003-09-10 US US10/659,169 patent/US20040048989A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CN1377377A (zh) | 2002-10-30 |
DE60016014T2 (de) | 2005-11-24 |
BR0014639B1 (pt) | 2011-02-22 |
AU7726800A (en) | 2001-04-30 |
CN1939934B (zh) | 2010-09-01 |
DE60016014D1 (de) | 2004-12-23 |
BR0014639A (pt) | 2002-06-11 |
KR20020037364A (ko) | 2002-05-18 |
EP1228110B1 (de) | 2004-11-17 |
US20030149182A1 (en) | 2003-08-07 |
CA2379607A1 (en) | 2001-04-05 |
US6555631B1 (en) | 2003-04-29 |
EP1228110A1 (de) | 2002-08-07 |
WO2001023443A1 (en) | 2001-04-05 |
US6921795B2 (en) | 2005-07-26 |
JP2003510427A (ja) | 2003-03-18 |
CN1939934A (zh) | 2007-04-04 |
BR0017587B1 (pt) | 2013-07-16 |
US20040048989A1 (en) | 2004-03-11 |
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