MX2015000216A - Procedimiento para oligomerizacion de etileno. - Google Patents

Procedimiento para oligomerizacion de etileno.

Info

Publication number
MX2015000216A
MX2015000216A MX2015000216A MX2015000216A MX2015000216A MX 2015000216 A MX2015000216 A MX 2015000216A MX 2015000216 A MX2015000216 A MX 2015000216A MX 2015000216 A MX2015000216 A MX 2015000216A MX 2015000216 A MX2015000216 A MX 2015000216A
Authority
MX
Mexico
Prior art keywords
ethylene
reactor
butene
oligomerization
solvent
Prior art date
Application number
MX2015000216A
Other languages
English (en)
Other versions
MX362715B (es
Inventor
Anina Wöhl
Wolfgang Müller
Heinz Bölt
Andreas Meiswinkel
Marco Harff
Shahid Azam
Anton Wellenhofer
Karl-Heinz Hofmann
Hans-Jörg Zander
Abduljelil Iliyas
Shahid Khurram
Abdullah Al-Qahtani
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Publication of MX2015000216A publication Critical patent/MX2015000216A/es
Publication of MX362715B publication Critical patent/MX362715B/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1885—Ligands comprising two different formal oxidation states of phosphorus in one at least bidentate ligand, e.g. phosphite/phosphinite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C07C2/22—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un procedimiento para oligomerización de etileno, que comprende las etapas: a) alimentar etileno, disolvente y una composición catalítica que comprende catalizador y cocatalizador en un reactor, b) oligomerizar etileno en el reactor, c) descargar un efluente del reactor que comprende alfaolefinas lineales incluyendo 1-buteno, disolvente, etileno no consumido disuelto en el efluente del reactor, y composición catalítica del reactor, d) separar el etileno y el 1-buteno colectivamente del efluente del reactor restante, y e) reciclar al menos una parte del etileno y el 1-buteno separados en la etapa d) al reactor.
MX2015000216A 2012-07-10 2013-06-05 Procedimiento para oligomerización de etileno. MX362715B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12175732.2A EP2684857A1 (en) 2012-07-10 2012-07-10 Method for oligomerization of ethylene
PCT/EP2013/001658 WO2014008964A1 (en) 2012-07-10 2013-06-05 Method for oligomerization of ethylene

Publications (2)

Publication Number Publication Date
MX2015000216A true MX2015000216A (es) 2015-04-10
MX362715B MX362715B (es) 2019-01-25

Family

ID=48577680

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015000216A MX362715B (es) 2012-07-10 2013-06-05 Procedimiento para oligomerización de etileno.

Country Status (14)

Country Link
US (1) US9896392B2 (es)
EP (2) EP2684857A1 (es)
JP (1) JP6081590B2 (es)
KR (1) KR101719221B1 (es)
CN (1) CN104661989B (es)
BR (1) BR112015000387B1 (es)
CA (1) CA2878634C (es)
ES (1) ES2651154T3 (es)
IN (1) IN2014DN10972A (es)
MX (1) MX362715B (es)
RU (1) RU2616602C2 (es)
SG (1) SG11201408518WA (es)
TW (1) TWI582063B (es)
WO (1) WO2014008964A1 (es)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2684857A1 (en) 2012-07-10 2014-01-15 Saudi Basic Industries Corporation Method for oligomerization of ethylene
EP2738151B8 (en) 2012-11-28 2014-12-17 Saudi Basic Industries Corporation Process for oligomerization of ethylene
EP2764914A1 (en) * 2013-02-11 2014-08-13 Linde AG Metalated PNPNH ligand, catalyst composition and use thereof in the oligomerization of ethylene
CN105085132A (zh) * 2014-05-08 2015-11-25 中国石油化工股份有限公司 一种优化乙烯齐聚工艺的方法及装置
MX369759B (es) 2015-01-19 2019-11-20 Evonik Operations Gmbh Preparación combinada de buteno y octeno a partir de eteno.
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
CN108025996A (zh) * 2015-09-16 2018-05-11 沙特基础工业全球技术有限公司 用于烯烃低聚催化剂的失活的方法
CN108430956B (zh) * 2015-12-22 2020-09-22 沙特基础工业全球技术有限公司 用于从线性α烯烃生产中回收甲苯的方法
US20190010100A1 (en) * 2015-12-30 2019-01-10 Sabic Global Technologies B.V. Method of separating hexene
WO2017187289A1 (en) * 2016-04-25 2017-11-02 Sabic Global Technologies B.V. Process for removing heat from an oligomerization reaction
US9707549B1 (en) 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
US10414699B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Process improvements in selective ethylene oligomerizations
US10329212B2 (en) 2016-05-27 2019-06-25 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10414698B2 (en) 2016-05-27 2019-09-17 Chevron Phillips Chemical Company Lp Reduced polymer formation for selective ethylene oligomerizations
US10280125B2 (en) * 2016-12-07 2019-05-07 Sumitomo Chemical Company, Limited Process for selective ethylene oligomerization with antifouling components
WO2018116183A1 (en) * 2016-12-20 2018-06-28 Sabic Global Technologies B.V. Method of column control
WO2018116176A1 (en) * 2016-12-22 2018-06-28 Sabic Global Technologies B.V. Methods of producing linear alpha olefins
CN110114132A (zh) * 2016-12-30 2019-08-09 沙特基础工业全球技术有限公司 用于选择性1-己烯生产的鼓泡塔反应器中的温度控制方法
KR20190100964A (ko) * 2016-12-30 2019-08-29 사빅 글로벌 테크놀러지스 비.브이. 선형 알파 올레핀의 생산 방법
KR102266927B1 (ko) * 2017-03-14 2021-06-21 사우디 아라비안 오일 컴퍼니 알파-올레핀을 제조하기 위한 에틸렌 올리고머화 공정
US10295685B2 (en) 2017-04-06 2019-05-21 Saudi Arabian Oil Company Generating common image gather using wave-field separation
US11016212B2 (en) 2017-04-11 2021-05-25 Saudi Arabian Oil Company Compressing seismic wavefields in three-dimensional reverse time migration
US10232339B2 (en) 2017-06-06 2019-03-19 Chevron Phillips Chemical Company Lp Fouling protection for an oligomerization reactor inlet
CN107746365A (zh) * 2017-08-30 2018-03-02 中国石油化工股份有限公司 一种选择性乙烯齐聚生产α‑烯烃的工艺方法及系统
US10294171B2 (en) 2017-09-22 2019-05-21 Chevron Phillips Chemical Company Lp Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene
US10493442B2 (en) 2017-09-22 2019-12-03 Chevron Phillips Chemical Company Lp Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10183960B1 (en) 2017-09-22 2019-01-22 Chevron Phillips Chemical Company Lp Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene
US10464862B2 (en) 2017-09-28 2019-11-05 Chevron Phillips Chemical Company Lp Oligomerization reactions using aluminoxanes
KR102334373B1 (ko) * 2017-11-30 2021-12-02 에스케이이노베이션 주식회사 올레핀의 올리고머화 방법
US11275190B2 (en) 2018-05-16 2022-03-15 Saudi Arabian Oil Company Generating diffraction images based on wave equations
CN113597419A (zh) * 2019-03-13 2021-11-02 Tpc集团有限责任公司 选择性地生产不同线性α-烯烃的弹性制造系统
KR20210012217A (ko) 2019-07-24 2021-02-03 에스케이이노베이션 주식회사 에틸렌 올리고머화 공정의 미반응 에틸렌 회수 방법
FR3099476B1 (fr) * 2019-07-31 2021-07-30 Ifp Energies Now Procede d’oligomerisation mettant en œuvre un recycle du ciel gazeux
KR102577661B1 (ko) 2019-08-21 2023-09-11 주식회사 엘지화학 올리고머 제조 방법 및 올리고머 제조 장치
KR102592638B1 (ko) 2019-08-21 2023-10-23 주식회사 엘지화학 알파 올레핀 제조 방법 및 알파 올레핀 제조 장치
US11681043B2 (en) 2019-09-03 2023-06-20 Saudi Arabian Oil Company Diffraction imaging using pseudo dip-angle gather
CN112745179A (zh) * 2019-10-30 2021-05-04 中国石油化工股份有限公司 乙烯齐聚生产α-烯烃的方法
CN112745185A (zh) * 2019-10-30 2021-05-04 中国石油化工股份有限公司 乙烯齐聚连续生产α-烯烃的方法
US11313988B2 (en) 2019-12-13 2022-04-26 Saudi Arabian Oil Company Identifying geologic features in a subterranean formation using seismic diffraction imaging
US11098140B2 (en) 2020-01-03 2021-08-24 Saudi Arabian Oil Company Production of 1-butene and ultra-high-molecular-weight polyethylene
US11402529B2 (en) 2020-01-09 2022-08-02 Saudi Arabian Oil Company Identifying geologic features in a subterranean formation using seismic diffraction and refraction imaging
US11467303B2 (en) 2020-03-09 2022-10-11 Saudi Arabian Oil Company Identifying geologic features in a subterranean formation using a post-stack seismic diffraction imaging condition
US11320557B2 (en) 2020-03-30 2022-05-03 Saudi Arabian Oil Company Post-stack time domain image with broadened spectrum
US11656378B2 (en) 2020-06-08 2023-05-23 Saudi Arabian Oil Company Seismic imaging by visco-acoustic reverse time migration
FR3112969B1 (fr) * 2020-07-30 2022-08-05 Ifp Energies Now Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1
JP7366486B2 (ja) 2020-09-07 2023-10-23 エルジー・ケム・リミテッド オリゴマーの製造方法
JP7265571B2 (ja) * 2021-03-05 2023-04-26 本田技研工業株式会社 炭素化合物の製造装置及び炭素化合物の製造方法
JP7176027B2 (ja) * 2021-03-11 2022-11-21 本田技研工業株式会社 二酸化炭素処理装置及び炭素化合物の製造方法
US11230514B1 (en) 2021-05-25 2022-01-25 Chevron Phillips Chemical Company, Lp Methods for recycling ethylene in an ethylene oligomerization reactor system
US11505513B1 (en) 2021-11-08 2022-11-22 Chevron Phillips Chemical Company, Lp Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene
US11583843B1 (en) 2021-11-08 2023-02-21 Chevron Phillips Chemical Company, Lp Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene
US11492305B1 (en) 2021-11-08 2022-11-08 Chevron Phillips Chemical Company, Lp Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene
CN116328838A (zh) * 2021-12-24 2023-06-27 中国石油化工股份有限公司 一种金属有机骨架负载型乙烯齐聚催化剂组合物及应用
CN116328839A (zh) * 2021-12-24 2023-06-27 中国石油化工股份有限公司 一种负载型乙烯齐聚主催化剂及乙烯齐聚催化剂组合物及应用
CN116328837A (zh) * 2021-12-24 2023-06-27 中国石油化工股份有限公司 一种乙烯齐聚催化剂组合物及应用
CN115028508B (zh) * 2022-06-30 2023-05-26 万华化学集团股份有限公司 一种pe生成量降低的乙烯四聚工艺

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020121A (en) * 1975-12-15 1977-04-26 Shell Oil Company Oligomerization reaction system
US4370456A (en) 1981-11-23 1983-01-25 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
FR2565591B1 (fr) * 1984-06-08 1986-08-29 Inst Francais Du Petrole Procede de fabrication d'un copolymere ethylene-butene-1 a partir d'ethylene
US4777315A (en) * 1987-06-01 1988-10-11 Union Carbide Corporation Process for trimerization
JPH09143228A (ja) 1995-11-22 1997-06-03 Sumitomo Chem Co Ltd エチレン−α−オレフィン共重合体の製造方法
US7300904B2 (en) 2001-12-20 2007-11-27 Sasol Technology (Pty) Ltd. Trimerisation and oligomerisation of olefins using a chromium based catalyst
CA2470888C (en) * 2001-12-20 2011-01-25 Sasol Technology (Pty) Ltd. Trimerisation and oligomerisation of olefins using a chromium based catalyst
DE602005019239D1 (de) 2005-10-20 2010-03-25 Linde Ag Verfahren zur Oligomerisierung von Ethylen und Reaktorsystem dafür mit Kühlvorrichtung
WO2007092136A2 (en) 2006-02-03 2007-08-16 Exxonmobil Chemical Patents, Inc. Process for generating alpha olefin comonomers
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
US20070196005A1 (en) 2006-02-23 2007-08-23 White Christopher A Feature Tracing Process for M-mode Images
RU2456078C2 (ru) 2007-07-11 2012-07-20 Линде Аг Каталитическая композиция и способ ди-, три- и/или тетрамеризации этилена
JP5462179B2 (ja) * 2007-11-28 2014-04-02 リンデ アーゲー エチレンのオリゴマー化のための触媒組成物およびプロセス
EP2106854B1 (en) * 2008-04-04 2011-05-25 Saudi Basic Industries Corporation Catalyst for oligomerization of ethylene, method for preparation thereof and process for oligomerization using it
ES2371218T3 (es) 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
EP2684857A1 (en) 2012-07-10 2014-01-15 Saudi Basic Industries Corporation Method for oligomerization of ethylene
EP2738151B8 (en) * 2012-11-28 2014-12-17 Saudi Basic Industries Corporation Process for oligomerization of ethylene

Also Published As

Publication number Publication date
SG11201408518WA (en) 2015-02-27
CA2878634A1 (en) 2014-01-16
JP6081590B2 (ja) 2017-02-15
EP2872468A1 (en) 2015-05-20
BR112015000387B1 (pt) 2020-11-10
CN104661989A (zh) 2015-05-27
KR101719221B1 (ko) 2017-03-23
BR112015000387A2 (pt) 2017-06-27
EP2872468B1 (en) 2017-11-15
RU2015104130A (ru) 2016-08-27
MX362715B (es) 2019-01-25
KR20150043313A (ko) 2015-04-22
BR112015000387A8 (pt) 2019-02-19
TW201406704A (zh) 2014-02-16
EP2684857A1 (en) 2014-01-15
WO2014008964A1 (en) 2014-01-16
ES2651154T3 (es) 2018-01-24
CA2878634C (en) 2019-07-16
WO2014008964A8 (en) 2015-02-19
TWI582063B (zh) 2017-05-11
IN2014DN10972A (es) 2015-09-18
US9896392B2 (en) 2018-02-20
US20150203418A1 (en) 2015-07-23
JP2015527311A (ja) 2015-09-17
RU2616602C2 (ru) 2017-04-18
CN104661989B (zh) 2018-05-22

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