MX369759B - Preparación combinada de buteno y octeno a partir de eteno. - Google Patents
Preparación combinada de buteno y octeno a partir de eteno.Info
- Publication number
- MX369759B MX369759B MX2016000511A MX2016000511A MX369759B MX 369759 B MX369759 B MX 369759B MX 2016000511 A MX2016000511 A MX 2016000511A MX 2016000511 A MX2016000511 A MX 2016000511A MX 369759 B MX369759 B MX 369759B
- Authority
- MX
- Mexico
- Prior art keywords
- solvent
- hexene
- ethene
- feed mixture
- reaction mixture
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title abstract 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 title abstract 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000002904 solvent Substances 0.000 abstract 10
- 239000000203 mixture Substances 0.000 abstract 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 6
- 239000011541 reaction mixture Substances 0.000 abstract 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 5
- 238000003786 synthesis reaction Methods 0.000 abstract 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 4
- 238000009835 boiling Methods 0.000 abstract 4
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/10—Catalytic processes with metal oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/24—Catalytic processes with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Materials Engineering (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La preparación combinada, catalizada de manera heterogénea de buteno y octeno a partir de eteno, comprende llevar a cabo de manera simultánea dos reacciones, a saber, una primera reacción de C2 para formar C4 y una segunda reacción de C2 y C6 para formar C8. Las dos reacciones se llevan a cabo físicamente de manera separada una de la otra y en la presencia de un solvente inerte, cuyo punto de ebullición está entre aquél de los butenos y aquél de los octenos. El hexeno formado como subproducto en la primera síntesis se utiliza como materia prima para la segunda síntesis. Ahí, reacciona con el eteno para formar octeno. El solvente se hace circular de manera continua. Esto hace posible llevar a cabo ambas síntesis en la fase líquida y controlar su selectividad. Puesto que el punto de ebullición del solvente corresponde esencialmente con aquél del subproducto hexeno, el subproducto puede separarse junto con el solvente como una fracción intermedia de la caldera de la primera mezcla de reacción y transferirse a la segunda reacción.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15151621 | 2015-01-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2016000511A MX2016000511A (es) | 2016-07-18 |
| MX369759B true MX369759B (es) | 2019-11-20 |
Family
ID=52432650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016000511A MX369759B (es) | 2015-01-19 | 2016-01-14 | Preparación combinada de buteno y octeno a partir de eteno. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10407366B2 (es) |
| EP (1) | EP3045439B1 (es) |
| JP (1) | JP6095809B2 (es) |
| KR (1) | KR101829117B1 (es) |
| CN (1) | CN105801332B (es) |
| CA (1) | CA2918122C (es) |
| ES (1) | ES2652549T3 (es) |
| MX (1) | MX369759B (es) |
| MY (1) | MY172711A (es) |
| NO (1) | NO3045439T3 (es) |
| PL (1) | PL3045439T3 (es) |
| SG (1) | SG10201600375RA (es) |
| TW (1) | TWI600635B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2701843T3 (es) | 2015-11-19 | 2019-02-26 | Evonik Degussa Gmbh | Influencia de la viscosidad de mezclas de ésteres basadas en n-buteno mediante empleo selectivo de eteno en la obtención de productos previos de ésteres |
| PL3255029T3 (pl) | 2016-06-10 | 2019-04-30 | Evonik Degussa Gmbh | Oligomeryzacja etenu w warunkach nadkrytycznych |
| EP3266757B1 (de) | 2016-07-08 | 2019-12-25 | Evonik Operations GmbH | Herstellung von zumindest 1-hexen und octen aus ethen |
| CN108080021B (zh) * | 2017-12-18 | 2020-11-17 | 陕西省石油化工研究设计院 | 一种用于丁烯歧化低聚制备1-己烯的催化剂及其制备方法和应用 |
| EP3686177A1 (de) * | 2019-01-28 | 2020-07-29 | Linde GmbH | Verfahren und anlage zur herstellung von alpha-olefinen |
| KR102780340B1 (ko) * | 2019-03-13 | 2025-03-11 | 티피씨 그룹 엘엘씨 | 상이한 선형 알파 올레핀을 선택적으로 생산하기 위한 유연 제조 시스템 |
| KR102585400B1 (ko) | 2019-08-21 | 2023-10-05 | 주식회사 엘지화학 | 올리고머 제조 방법 및 올리고머 제조 장치 |
| CN112657482B (zh) * | 2020-11-24 | 2023-06-13 | 大连理工大学 | 一种固体酸催化剂及其使用该催化剂得到的丙烯齐聚物 |
| US11230514B1 (en) * | 2021-05-25 | 2022-01-25 | Chevron Phillips Chemical Company, Lp | Methods for recycling ethylene in an ethylene oligomerization reactor system |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB619231A (en) | 1945-06-15 | 1949-03-07 | Phillips Petroleum Co | Improvements in or relating to catalytic polymerization of olefins |
| GB8728156D0 (en) | 1987-12-02 | 1988-01-06 | Davy Mckee Ltd | Process |
| DE4445680A1 (de) | 1994-12-21 | 1996-06-27 | Huels Chemische Werke Ag | Katalysator und Verfahren zur Isomerisierung von aliphatischen C¶4¶-C¶1¶¶0¶-Monoolefinen |
| DE19906518A1 (de) | 1999-02-17 | 2000-08-31 | Oxeno Olefinchemie Gmbh | Verfahren zur Fraktionierung von Dibuten |
| US6531555B2 (en) * | 2000-12-19 | 2003-03-11 | Univation Technologies, Llp | Olefin oligomerization catalysts, their production and use |
| JP2003326169A (ja) * | 2002-03-08 | 2003-11-18 | Rikogaku Shinkokai | オリゴマー化触媒及びそれを用いたオリゴマーの製造方法 |
| CA2510194C (en) * | 2002-12-20 | 2012-01-31 | Sasol Technology (Pty) Ltd | Tetramerization of olefins |
| WO2005123884A2 (en) | 2004-06-18 | 2005-12-29 | Sasol Technology (Pty) Limited | Oligomerisation in the presence of both a tetramerisation catalyst and a further oligomerisation catalyst |
| EP1756024B1 (en) | 2004-06-18 | 2018-08-15 | Sasol Technology (Pty) Ltd | Oligomerisation of olefinic compounds in an aliphatic medium |
| US7425661B2 (en) * | 2005-03-09 | 2008-09-16 | Exxonmobil Chemicals Patents Inc. | Methods for oligomerizing olefins |
| EP1948578B1 (en) | 2005-09-30 | 2011-06-22 | ExxonMobil Chemical Patents Inc. | Oligomerization reaction |
| EP1987047B1 (en) | 2006-02-03 | 2015-07-01 | ExxonMobil Chemical Patents Inc. | Process for generating alpha olefin comonomers |
| CN101460428B (zh) * | 2006-06-07 | 2013-08-28 | 巴斯夫欧洲公司 | 共二聚烯烃的方法 |
| DE102008007081B4 (de) | 2008-01-31 | 2018-12-06 | Evonik Degussa Gmbh | Verfahren zur Herstellung von n-Buten-Oligomeren und 1-Buten aus technischen Mischungen I von C4-Kohlenwasserstoffen |
| CN102099113A (zh) | 2008-07-23 | 2011-06-15 | 三井化学株式会社 | 乙烯低聚催化剂及其用途 |
| EP2196444A1 (en) | 2008-12-11 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to make alpha olefins from ethanol |
| US8227653B2 (en) | 2009-03-27 | 2012-07-24 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization reaction processes exhibiting reduced fouling |
| CN102448913B (zh) | 2009-03-31 | 2015-01-28 | 环球油品公司 | 稀乙烯的低聚方法 |
| EP2582648B1 (de) | 2010-06-15 | 2014-04-30 | Basf Se | Verfahren zur co-oligomerisierung von olefinen |
| US9394212B2 (en) * | 2010-06-15 | 2016-07-19 | Basf Se | Process for the cooligomerization of olefins |
| FR2979836B1 (fr) | 2011-09-08 | 2014-08-08 | IFP Energies Nouvelles | Nouvelle composition catalytique a base de nickel et procede d'oligomerisation des olefines utilisant ladite composition |
| FR2984311B1 (fr) * | 2011-12-20 | 2015-01-30 | IFP Energies Nouvelles | Procede de production d'octenes mettant en oeuvre la dimerisation de l'ethylene en butenes et la dimerisation des butenes en octenes |
| FR2992962B1 (fr) * | 2012-07-04 | 2015-06-26 | Axens | Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene |
| EP2684857A1 (en) | 2012-07-10 | 2014-01-15 | Saudi Basic Industries Corporation | Method for oligomerization of ethylene |
| WO2014154798A1 (en) * | 2013-03-28 | 2014-10-02 | Bp P.L.C. | Production of middle distillate hydrocarbon composition |
| DE102013212481A1 (de) | 2013-06-27 | 2014-12-31 | Evonik Industries Ag | Oligomerisierung von C4-Strömen mit geringstem Gehalt an 1-Buten |
| DE102013226370A1 (de) | 2013-12-18 | 2015-06-18 | Evonik Industries Ag | Herstellung von Butadien durch oxidative Dehydrierung von n-Buten nach vorhergehender Isomerisierung |
-
2016
- 2016-01-14 MX MX2016000511A patent/MX369759B/es active IP Right Grant
- 2016-01-15 ES ES16151490.6T patent/ES2652549T3/es active Active
- 2016-01-15 NO NO16151490A patent/NO3045439T3/no unknown
- 2016-01-15 PL PL16151490T patent/PL3045439T3/pl unknown
- 2016-01-15 TW TW105101236A patent/TWI600635B/zh not_active IP Right Cessation
- 2016-01-15 EP EP16151490.6A patent/EP3045439B1/de not_active Not-in-force
- 2016-01-18 CA CA2918122A patent/CA2918122C/en not_active Expired - Fee Related
- 2016-01-18 KR KR1020160006130A patent/KR101829117B1/ko not_active Expired - Fee Related
- 2016-01-18 MY MYPI2016700165A patent/MY172711A/en unknown
- 2016-01-18 SG SG10201600375RA patent/SG10201600375RA/en unknown
- 2016-01-19 US US15/000,807 patent/US10407366B2/en not_active Expired - Fee Related
- 2016-01-19 CN CN201610035375.0A patent/CN105801332B/zh not_active Expired - Fee Related
- 2016-01-19 JP JP2016008043A patent/JP6095809B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105801332A (zh) | 2016-07-27 |
| EP3045439A1 (de) | 2016-07-20 |
| CA2918122C (en) | 2018-02-20 |
| NO3045439T3 (es) | 2018-04-07 |
| US10407366B2 (en) | 2019-09-10 |
| SG10201600375RA (en) | 2016-08-30 |
| CA2918122A1 (en) | 2016-07-19 |
| PL3045439T3 (pl) | 2018-03-30 |
| TWI600635B (zh) | 2017-10-01 |
| JP6095809B2 (ja) | 2017-03-15 |
| EP3045439B1 (de) | 2017-11-08 |
| MY172711A (en) | 2019-12-11 |
| JP2016132671A (ja) | 2016-07-25 |
| KR101829117B1 (ko) | 2018-02-13 |
| CN105801332B (zh) | 2019-01-08 |
| TW201641474A (zh) | 2016-12-01 |
| US20160207848A1 (en) | 2016-07-21 |
| KR20160089289A (ko) | 2016-07-27 |
| MX2016000511A (es) | 2016-07-18 |
| ES2652549T3 (es) | 2018-02-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |