MX2012012899A - Composicion de resina de poliamida. - Google Patents
Composicion de resina de poliamida.Info
- Publication number
- MX2012012899A MX2012012899A MX2012012899A MX2012012899A MX2012012899A MX 2012012899 A MX2012012899 A MX 2012012899A MX 2012012899 A MX2012012899 A MX 2012012899A MX 2012012899 A MX2012012899 A MX 2012012899A MX 2012012899 A MX2012012899 A MX 2012012899A
- Authority
- MX
- Mexico
- Prior art keywords
- polyamide
- polyamide resin
- concentration
- resin composition
- âμeq
- Prior art date
Links
- 229920006122 polyamide resin Polymers 0.000 title abstract 4
- 239000011342 resin composition Substances 0.000 title abstract 3
- 239000004952 Polyamide Substances 0.000 abstract 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 3
- 229920002647 polyamide Polymers 0.000 abstract 3
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical group 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004427 diamine group Chemical group 0.000 abstract 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
- Y10T428/1383—Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31736—Next to polyester
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
La presente invención se refiere a una composición de resma de poliamida que comprende la poliamida (X) que comprende una unidad de diamina que contiene 70% en mol b más de una unidad de metaxililendiamina y una unidad de ácido dicarboxílico y un compuesto alcalino (A), en donde se satisfacen las siguientes ecuaciones (1) a (4) 10 =( [COOH] - [NH2])= 80 (1) 0.32 = P < 6.46 (2) 0.50 = M < 17.00 (3) 2 = M/P = 3 (4) en donde [COOH] representa una concentración (µeq/g) de un grupo carboxilo terminal en la poliamida (X); [NH2] representa una concentración (µeq/g) de un grupo amino terminal en la poliamida (X); P representa una concentración en mol (µmol/g) de un átomo de fósforo contenido por g de la composición de resma de poliamida; y M representa una suma (µmol/g) de valores obtenidos al multiplicar una concentración en mol de un átomo de metal alcalino y una concentración en mol de un átomo de metal alcalinotérreo cada uno contenido por g de la composición de resma de poliamida por las valencias de los mismos respectivamente.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010113028 | 2010-05-17 | ||
JP2010168081 | 2010-07-27 | ||
PCT/JP2011/060846 WO2011145498A1 (ja) | 2010-05-17 | 2011-05-11 | ポリアミド樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2012012899A true MX2012012899A (es) | 2013-04-11 |
MX340610B MX340610B (es) | 2016-07-18 |
Family
ID=44991604
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012012899A MX340610B (es) | 2010-05-17 | 2011-05-11 | Composicion de resina de poliamida. |
Country Status (12)
Country | Link |
---|---|
US (2) | US20130065004A1 (es) |
EP (1) | EP2573140B1 (es) |
JP (1) | JP5825255B2 (es) |
KR (1) | KR101819899B1 (es) |
CN (1) | CN102892835B (es) |
BR (1) | BR112012029200A2 (es) |
CA (1) | CA2798162A1 (es) |
MX (1) | MX340610B (es) |
RU (1) | RU2565691C2 (es) |
TW (1) | TWI525126B (es) |
WO (1) | WO2011145498A1 (es) |
ZA (1) | ZA201208571B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130065005A1 (en) | 2010-05-17 | 2013-03-14 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin composition |
KR101823560B1 (ko) * | 2011-02-24 | 2018-01-30 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 마스터 배치, 및 마스터 배치를 이용한 폴리아미드 수지 조성물의 제조 방법 |
CN103154088B (zh) | 2011-09-12 | 2014-06-25 | 三菱瓦斯化学株式会社 | 薄壁成型品 |
CN103865057A (zh) * | 2012-12-17 | 2014-06-18 | 东丽先端材料研究开发(中国)有限公司 | 一种聚酰胺树脂及其制备方法以及聚酰胺树脂组合物 |
EP2957514B1 (en) * | 2013-02-13 | 2021-08-04 | Mitsubishi Gas Chemical Company, Inc. | Multi-layer bottle and method for producing same |
TWI645965B (zh) * | 2013-08-09 | 2019-01-01 | 日商三菱瓦斯化學股份有限公司 | 多層成形體 |
JP6822766B2 (ja) * | 2015-01-22 | 2021-01-27 | 旭化成株式会社 | ポリアミド樹脂組成物を含む成形体 |
JP2016169027A (ja) * | 2015-03-12 | 2016-09-23 | 三菱瓦斯化学株式会社 | 多層ボトル及びその製造方法 |
JP2016169291A (ja) * | 2015-03-12 | 2016-09-23 | 三菱瓦斯化学株式会社 | ポリアミド樹脂組成物及びその製造方法、フィルム、並びに多層フィルム |
WO2017131008A1 (ja) * | 2016-01-29 | 2017-08-03 | 東洋紡株式会社 | 耐熱性ポリアミド樹脂組成物 |
JP6493638B1 (ja) * | 2017-07-31 | 2019-04-03 | 三菱瓦斯化学株式会社 | 易裂性フィルム、多層フィルム、包装材料および容器 |
WO2021006257A1 (ja) * | 2019-07-11 | 2021-01-14 | 東レ株式会社 | ポリアミド樹脂組成物およびそれを成形してなる成形品 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3872055A (en) * | 1972-08-19 | 1975-03-18 | Toyo Boseki | Polyamide composition having decreased gel-forming property in molten state |
JPS5124297B2 (es) * | 1972-08-19 | 1976-07-23 | ||
JPS5141906B2 (es) * | 1972-09-07 | 1976-11-12 | ||
US5116919A (en) * | 1990-12-05 | 1992-05-26 | E. I. Du Pont De Nemours And Company | Process for increasing the relative viscosity of polyamides with reduced thermal degradation |
JP3375414B2 (ja) * | 1994-02-28 | 2003-02-10 | 旭化成株式会社 | 熱黄変性の改善されたポリアミド組成物 |
US6166171A (en) * | 1998-03-06 | 2000-12-26 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin composition |
JP4906015B2 (ja) * | 1999-02-16 | 2012-03-28 | 三菱瓦斯化学株式会社 | ポリメタキシリレンアジパミドの固相重合方法 |
DE60006169T2 (de) * | 1999-02-16 | 2004-08-12 | Mitsubishi Gas Chemical Co., Inc. | Festphasen-polymerisierte Polyamide und Verfahren zu deren Herstellung |
JP2000234022A (ja) | 1999-02-16 | 2000-08-29 | Mitsubishi Gas Chem Co Inc | ポリアミドの固相重合体 |
JP2001164109A (ja) | 1999-12-03 | 2001-06-19 | Mitsubishi Gas Chem Co Inc | ポリアミド樹脂組成物 |
EP1354906B1 (en) * | 2002-04-19 | 2012-12-05 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin |
JP3808847B2 (ja) | 2002-10-25 | 2006-08-16 | 株式会社興人 | ポリアミド系多層2軸延伸フィルム |
JP2005194328A (ja) | 2003-12-26 | 2005-07-21 | Toyobo Co Ltd | ポリアミド樹脂組成物 |
JP2005194330A (ja) | 2003-12-26 | 2005-07-21 | Toyobo Co Ltd | ポリアミド樹脂組成物 |
JP4579569B2 (ja) * | 2004-04-16 | 2010-11-10 | 株式会社クレハ | 多層二軸延伸ブローボトル及びその製造方法 |
CN101163746B (zh) * | 2005-04-13 | 2011-05-25 | 旭化成化学株式会社 | 聚酰胺-聚苯醚树脂组合物 |
JP4857634B2 (ja) * | 2005-07-22 | 2012-01-18 | 三菱瓦斯化学株式会社 | ポリアミド樹脂 |
JP4983135B2 (ja) * | 2005-08-08 | 2012-07-25 | 三菱瓦斯化学株式会社 | バリア性に優れた熱可塑性樹脂組成物成形体 |
DE602006008866D1 (de) | 2005-08-08 | 2009-10-15 | Mitsubishi Gas Chemical Co | Brennstoffundurchlässige thermoplastische Harzzusammensetzungen und Artikel |
JP2007092054A (ja) | 2005-09-01 | 2007-04-12 | Toyobo Co Ltd | ポリアミドおよびそれからなるポリアミド組成物 |
JP2007092053A (ja) | 2005-09-01 | 2007-04-12 | Toyobo Co Ltd | ポリアミド及びそれからなるポリアミド組成物 |
DE102005051400A1 (de) * | 2005-10-25 | 2007-04-26 | Basf Ag | Polyamide aus meta-Xylylendiamin und Adipinsäure mit einem Aminoendgruppengehalt kleiner als 15 mmol/kg |
RU2415164C2 (ru) * | 2006-03-10 | 2011-03-27 | Мицубиси Гэс Кемикал Компани, Инк. | Сложнополиэфирная полимерная композиция, способ ее получения и формованное изделие |
PL2532712T3 (pl) * | 2006-05-31 | 2014-04-30 | Mitsubishi Gas Chemical Co | Kompozycja żywicy poliamidowej |
JP2008056841A (ja) * | 2006-09-01 | 2008-03-13 | Toyobo Co Ltd | ポリアミド組成物及びそれからなるポリアミド成形体 |
KR101509828B1 (ko) * | 2007-04-05 | 2015-04-06 | 도요세이칸 그룹 홀딩스 가부시키가이샤 | 다층 폴리에스테르 용기 및 그 제조 방법 |
JP5194573B2 (ja) * | 2007-06-12 | 2013-05-08 | 三菱瓦斯化学株式会社 | ポリアミド樹脂組成物 |
JP5531409B2 (ja) * | 2009-01-07 | 2014-06-25 | 三菱瓦斯化学株式会社 | ポリアミド樹脂組成物 |
US20130065005A1 (en) | 2010-05-17 | 2013-03-14 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin composition |
KR101823560B1 (ko) | 2011-02-24 | 2018-01-30 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 마스터 배치, 및 마스터 배치를 이용한 폴리아미드 수지 조성물의 제조 방법 |
-
2011
- 2011-05-11 BR BR112012029200A patent/BR112012029200A2/pt not_active Application Discontinuation
- 2011-05-11 KR KR1020127029631A patent/KR101819899B1/ko active IP Right Grant
- 2011-05-11 MX MX2012012899A patent/MX340610B/es active IP Right Grant
- 2011-05-11 CN CN201180024280.4A patent/CN102892835B/zh active Active
- 2011-05-11 WO PCT/JP2011/060846 patent/WO2011145498A1/ja active Application Filing
- 2011-05-11 RU RU2012154320/05A patent/RU2565691C2/ru active
- 2011-05-11 JP JP2012515851A patent/JP5825255B2/ja active Active
- 2011-05-11 EP EP11783432.5A patent/EP2573140B1/en active Active
- 2011-05-11 US US13/698,143 patent/US20130065004A1/en not_active Abandoned
- 2011-05-11 CA CA2798162A patent/CA2798162A1/en not_active Abandoned
- 2011-05-12 TW TW100116740A patent/TWI525126B/zh active
-
2012
- 2012-11-14 ZA ZA2012/08571A patent/ZA201208571B/en unknown
-
2015
- 2015-07-13 US US14/797,659 patent/US9657159B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
TWI525126B (zh) | 2016-03-11 |
JPWO2011145498A1 (ja) | 2013-07-22 |
US9657159B2 (en) | 2017-05-23 |
BR112012029200A2 (pt) | 2016-11-29 |
CN102892835B (zh) | 2015-07-01 |
RU2012154320A (ru) | 2014-06-27 |
TW201144358A (en) | 2011-12-16 |
EP2573140B1 (en) | 2018-12-12 |
CA2798162A1 (en) | 2011-11-24 |
WO2011145498A1 (ja) | 2011-11-24 |
US20150315357A1 (en) | 2015-11-05 |
KR20130114565A (ko) | 2013-10-17 |
MX340610B (es) | 2016-07-18 |
EP2573140A1 (en) | 2013-03-27 |
JP5825255B2 (ja) | 2015-12-02 |
EP2573140A4 (en) | 2013-12-25 |
CN102892835A (zh) | 2013-01-23 |
ZA201208571B (en) | 2014-03-26 |
KR101819899B1 (ko) | 2018-01-19 |
US20130065004A1 (en) | 2013-03-14 |
RU2565691C2 (ru) | 2015-10-20 |
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