MX171629B - Cloracion de carbohidratos y otros alcoholes - Google Patents

Cloracion de carbohidratos y otros alcoholes

Info

Publication number
MX171629B
MX171629B MX004087A MX408786A MX171629B MX 171629 B MX171629 B MX 171629B MX 004087 A MX004087 A MX 004087A MX 408786 A MX408786 A MX 408786A MX 171629 B MX171629 B MX 171629B
Authority
MX
Mexico
Prior art keywords
penta
saccharose
acetyl
acetate
phosgene
Prior art date
Application number
MX004087A
Other languages
English (en)
Inventor
Leroy High
Eleanor A O'brien
Thomas O'connor
Mathew R J Tuite
Original Assignee
Johnson & Johnson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson & Johnson filed Critical Johnson & Johnson
Publication of MX171629B publication Critical patent/MX171629B/es

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
    • C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H5/00—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium
    • C07H5/02—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium to halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Saccharide Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención se refiere a un procedimiento para la preparación de 1,6-dicloro-1,6-didesoxi-B-D-fructofuranosil-4-cloro-4-desoxi- -galactopiranósido, que comrpende los pasos de: a) hacer reaccionar sacarosa con un agente tritilador; b) acetilar el producto de reacción tritilado con un agente acetilador para obtener el penta-acetato de 6,1',6'-tri-0-tritilsacaros; c) destritilar el penta-acetato de 6,1',6'-tri-O-tritilsacarosa para obtener 2,3,4,3',4'-penta-O-acetilsacarosa; d) isomerizar la 2,3,4,3',4'-penta-O-acetilsacarosa para obtener 2,3,6,3',4'-penta-O-acetilsacarosa; e) clorar 2,3,6,3',4'-penta-O-acetilsacarosa con un reactivo clorador para obtener penta-acetato de 4,1',6'-tricloro-4,1',6'-tridesoxigalactosacarosa; y f) desacetilar el producto clorado; caracterizado porque la etapa de cloración se efectúa empleando un reactivo clorador seleccionado del grupo que consiste de óxido de trifenilfosfina/cloruro de tionilo, óxido de trifenilfosfina/fosgeno, sulfuro de trifenilfosfina/fosgeno, en presencia de un solvente de hidrocarburo aromático a una temperatura de hasta aproximadamente 120 grados C.
MX004087A 1985-10-21 1986-10-20 Cloracion de carbohidratos y otros alcoholes MX171629B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB858525954A GB8525954D0 (en) 1985-10-21 1985-10-21 Chlorination of carbohydrates &c alcohols

Publications (1)

Publication Number Publication Date
MX171629B true MX171629B (es) 1993-11-10

Family

ID=10587019

Family Applications (1)

Application Number Title Priority Date Filing Date
MX004087A MX171629B (es) 1985-10-21 1986-10-20 Cloracion de carbohidratos y otros alcoholes

Country Status (21)

Country Link
US (1) US4783526A (es)
EP (1) EP0223421B1 (es)
JP (1) JPH0830073B2 (es)
KR (1) KR940000483B1 (es)
AR (1) AR243197A1 (es)
AT (1) ATE101856T1 (es)
AU (1) AU595250B2 (es)
CA (1) CA1284495C (es)
DE (1) DE3689662T2 (es)
DK (1) DK174926B1 (es)
ES (1) ES2051262T3 (es)
FI (1) FI88912C (es)
GB (2) GB8525954D0 (es)
IE (1) IE59558B1 (es)
IL (1) IL80370A (es)
MX (1) MX171629B (es)
NO (1) NO167034C (es)
NZ (1) NZ218009A (es)
PT (1) PT83580B (es)
SU (1) SU1634139A3 (es)
ZA (1) ZA867948B (es)

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DE4116365A1 (de) * 1991-05-18 1992-11-19 Basf Ag Verfahren zur herstellung von alkyl-, alkenyl- und alkinylchloriden
DE19523641A1 (de) * 1995-06-29 1997-01-02 Bayer Ag Verfahren zur Herstellung von substituierten Chloraromaten
JP2003531184A (ja) * 2000-04-21 2003-10-21 ローディア／カイレックス・インコーポレイテッド （ｒ）−１−（アリールオキシ）プロパン−２−オールの製造方法
EP1339728B1 (en) * 2000-11-17 2013-02-27 Tate & Lyle Technology Limited Improved sucralose composition and process for the crystallization thereof
DE10218862A1 (de) 2002-04-26 2003-11-06 Gruenenthal Gmbh Verfahren zur Chlorierung tertiärer Alkohole
US6943248B2 (en) * 2003-04-30 2005-09-13 Tate & Lyle Public Limited Company Crystalline form of sucralose, and method for producing it
US20060247180A1 (en) * 2005-04-29 2006-11-02 Bergey James L Purgative composition and uses thereof
US20100222568A1 (en) * 2005-08-30 2010-09-02 Rakesh Ratnam Removal of pyridine and pyridine analogs from reaction mass containing sucrose esters
DE102005043141A1 (de) * 2005-09-10 2007-03-15 Basf Ag Verfahren zur Chlorierung von Alkoholen
US7741477B2 (en) * 2006-01-10 2010-06-22 Alembic Limited Process for purification of sucralose
CN100418976C (zh) * 2006-04-03 2008-09-17 广州科宏食品添加物有限公司 一种三氯蔗糖的制备方法
US20090312538A1 (en) * 2006-07-06 2009-12-17 Alembic Limited process for the preparation of sucralose of high purity
BRPI0719916A2 (pt) * 2006-12-05 2014-03-04 Tate & Lyle Technology Ltd Recuperação de cloreto de tritila
CN100591684C (zh) * 2006-12-27 2010-02-24 盐城捷康三氯蔗糖制造有限公司 三氯蔗糖结晶方法
JP2008180466A (ja) * 2007-01-25 2008-08-07 Hoshizaki Electric Co Ltd 電装箱
CN101012253B (zh) * 2007-02-06 2010-04-14 启东东岳药业有限公司 6-pas的制备方法
CN101260126B (zh) * 2007-03-06 2010-12-22 盐城捷康三氯蔗糖制造有限公司 三氯蔗糖的结晶方法
CN101245085B (zh) 2007-12-19 2012-02-01 上海同辰生物科技有限公司 一种三氯蔗糖的合成及纯化工艺
WO2009087677A1 (en) * 2007-12-24 2009-07-16 Alembic Limited An improved process for the preparation of 1, 6-dichloro-1, 6-dide0xy-beta-d-fruct0furan0syl-4-chl0r0-4-de0xy-alpha-galact0py ranoside
US8436156B2 (en) * 2008-01-04 2013-05-07 Tate & Lyle Technology Limited Method for the production of sucralose
KR20100130219A (ko) * 2008-03-20 2010-12-10 테이트 앤드 라일 테크놀러지 리미티드 ３급 아미드 용매로부터 산을 제거하는 방법
US8436157B2 (en) * 2008-03-26 2013-05-07 Tate & Lyle Technology Limited Method for the production of sucralose
US20090299055A1 (en) * 2008-04-03 2009-12-03 Tate & Lyle Technology Limited Purification of Sucralose Containing Feed Streams for Sucralose Crystallization
US8497367B2 (en) * 2008-04-03 2013-07-30 Tate & Lyle Technology Limited Sucralose purification process
WO2009124113A1 (en) * 2008-04-03 2009-10-08 Tate & Lyle Technology Ltd. Extraction of less polar impurities from sucralose containing aqueous feed streams
AR071134A1 (es) * 2008-04-03 2010-05-26 Tate & Lyle Technology Ltd Cristalizacion de sucralosa a partir de chorros que contienen sucralosa
EP2260049B1 (en) * 2008-04-03 2013-02-27 Tate & Lyle Technology Limited Effect of carbohydrate concentration on sucralose extraction efficiency
GB2469157B (en) 2009-03-30 2011-07-06 John Kerr Process for removing dimethylamine during sucralose production
GB2469158B (en) 2009-03-31 2011-09-28 Peter J Seaberg Base-assisted formation of tin-sucrose adducts
GB2471348B (en) 2009-06-22 2011-12-14 Tate & Lyle Technology Ltd A method for producing sucralose-6-acylate
GB2474310B (en) 2009-10-12 2012-02-29 Tate & Lyle Technology Ltd Process for the production of sucrose-6-ester
GB2474311B (en) * 2009-10-12 2012-10-17 Tate & Lyle Technology Ltd Low temperature, single solvent process for the production of sucrose-6-ester
IT1403290B1 (it) * 2010-12-27 2013-10-17 Polimeri Europa Spa Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine
GB201110520D0 (en) 2011-05-10 2011-08-03 Tate & Lyle Technology Ltd Extraction of carboxylic acids with tin compounds
CN105829332B (zh) 2013-12-16 2018-10-02 塔特和莱利技术有限公司 蔗糖-6-酯的氯化
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CN114052236B (zh) * 2020-07-29 2023-08-22 盐城捷康三氯蔗糖制造有限公司 高甜度、低热量的复合甜味剂晶体及其制备方法

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GB2065648B (en) * 1979-12-20 1983-08-17 Tate & Lyle Ltd Preparation of 4,1',6'-trichloro-4,1',6'-trideoxgalactosucrose
EP0031651B1 (en) * 1979-12-20 1983-03-23 TATE & LYLE PUBLIC LIMITED COMPANY Process for the preparation of 4,1',6'-trichloro-4,1',6'-trideoxy-galactosucrose
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Also Published As

Publication number Publication date
DE3689662T2 (de) 1994-06-23
IL80370A0 (en) 1987-01-30
AU595250B2 (en) 1990-03-29
GB2182039B (en) 1989-10-25
DE3689662D1 (de) 1994-03-31
KR940000483B1 (ko) 1994-01-21
IE862762L (en) 1987-04-21
GB8525954D0 (en) 1985-11-27
NO167034B (no) 1991-06-17
ES2051262T3 (es) 1994-06-16
PT83580B (pt) 1989-05-31
GB8625108D0 (en) 1986-11-26
FI88912C (fi) 1993-07-26
ZA867948B (en) 1988-05-25
EP0223421A3 (en) 1988-12-07
NO864191D0 (no) 1986-10-20
NO864191L (no) 1987-04-22
NO167034C (no) 1991-09-25
DK174926B1 (da) 2004-03-01
AR243197A1 (es) 1993-07-30
ATE101856T1 (de) 1994-03-15
CA1284495C (en) 1991-05-28
GB2182039A (en) 1987-05-07
IE59558B1 (en) 1994-03-09
SU1634139A3 (ru) 1991-03-07
JPS62135487A (ja) 1987-06-18
KR870003717A (ko) 1987-05-04
AU6421386A (en) 1987-04-30
DK503186D0 (da) 1986-10-20
EP0223421A2 (en) 1987-05-27
IL80370A (en) 1992-01-15
FI88912B (fi) 1993-04-15
NZ218009A (en) 1988-11-29
PT83580A (en) 1986-11-01
DK503186A (da) 1987-04-22
FI864236A0 (fi) 1986-10-20
JPH0830073B2 (ja) 1996-03-27
FI864236A (fi) 1987-04-22
US4783526A (en) 1988-11-08
EP0223421B1 (en) 1994-02-23

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