KR880006147A - 방향족 화합물의 측쇄의 광염소화 방법 - Google Patents
방향족 화합물의 측쇄의 광염소화 방법 Download PDFInfo
- Publication number
- KR880006147A KR880006147A KR870010564A KR870010564A KR880006147A KR 880006147 A KR880006147 A KR 880006147A KR 870010564 A KR870010564 A KR 870010564A KR 870010564 A KR870010564 A KR 870010564A KR 880006147 A KR880006147 A KR 880006147A
- Authority
- KR
- South Korea
- Prior art keywords
- reaction
- ester
- carried out
- temperature
- photochlorination
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
- C07B37/02—Addition
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/78—Benzoic acid esters
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 염소화 된 산 또는 에스테르의 분해 온도 이하의 반응온도에서 화학방사선의 존재하에 염소를 첨가하기 전에 벤조산 또는 에스테르에 염화수소를 첨가하여 이루어지는 2-알킬벤조산 또는 에스테르의 2-알킬기의 선택적 염소화 방법.
- 제1항에 있어서, 2-알킬기는 탄소수가 1 내지 20인 상기 염소화 방법.
- 제1항에 있어서, 반응은 약 -20℃ 내지 약 60℃의 온도에서 행하여지는 상기 염소화 방법.
- 제1항에 있어서, 반응은 실온 이하에서 행하여지는 상기 염소화 방법.
- 제1항에 있어서, 반응은 약 -20℃ 내지 20℃의 온도에서 행하여지는 상기 염소화 방법.
- 제5항에 있어서, 반응은 자유기 개시제의 존재하에 행하여지는 상기 염소화 방법.
- 제1항에 있어서, 에스테르는 메틸 2-메틸벤조에이트인 상기 염소화 방법.
- 제7항에 있어서, 반응은 약 -20℃ 내지 20℃의 온도에서 행하여지는 상기 염소화 방법.
- 제8항에 있어서, 반응은 자유기 개시제의 존재하에 행하여지는 상기 염소화 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/927,477 US4689425A (en) | 1986-11-06 | 1986-11-06 | Photochlorination of aromatic compounds in the side chain |
US927477 | 1986-11-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR880006147A true KR880006147A (ko) | 1988-07-21 |
Family
ID=25454792
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR870010564A KR880006147A (ko) | 1986-11-06 | 1987-09-24 | 방향족 화합물의 측쇄의 광염소화 방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4689425A (ko) |
EP (1) | EP0268322A1 (ko) |
JP (1) | JPS63130559A (ko) |
KR (1) | KR880006147A (ko) |
CN (1) | CN87107637A (ko) |
AU (1) | AU589301B2 (ko) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4861887A (en) * | 1988-01-27 | 1989-08-29 | American Cyanamid Company | Herbicidal o-(substituted, aminomethylbenzoic, nicotinic and quinoline-3-carboxylic acids, esters, and salts |
JPH01313453A (ja) * | 1988-06-13 | 1989-12-18 | Nippon Nohyaku Co Ltd | クロロメチル安息香酸の製造法 |
US5300201A (en) * | 1991-04-22 | 1994-04-05 | Occidental Chemical Corporation | Photochlorination of phthalic anhydride |
IT1263960B (it) * | 1993-02-24 | 1996-09-05 | Enichem Sintesi | Procedimento per la fotoclorurazione di composti alchilaromatici |
WO1999016743A1 (en) | 1997-09-30 | 1999-04-08 | Korea Research Institute Of Chemical Technology | A PROCESS FOR PREPARING o-(CARBOALKOXY) PHENYLMETHANESULFONYL CHLORIDE DERIVATIVES |
DE10313228A1 (de) * | 2003-03-25 | 2004-10-21 | Aventis Pharma Deutschland Gmbh | Synthese von 2-Chlormethyl-6-methylbenzoesäureestern |
CN102643180B (zh) * | 2012-03-23 | 2015-04-15 | 广东药学院 | 一种2-卤代-2-(2-氟苯基)-1-环丙基乙酮的制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE847887C (de) * | 1944-07-22 | 1952-08-28 | Basf Ag | Verfahren zur Chlorierung organischer Verbindungen |
GB773131A (en) * | 1954-10-20 | 1957-04-24 | Perfogit Spa | Improvements in and relating to the preparation of esters of chloromethyl benzoic acids |
US3113084A (en) * | 1956-10-15 | 1963-12-03 | Monsanto Chemicals | Chlorination |
US3152055A (en) * | 1959-06-27 | 1964-10-06 | Chemische Werke Witten | Process for the production of aromatic chlorocarboxylic acid chlorides |
GB884114A (en) * | 1959-10-28 | 1961-12-06 | Chemische Werke Witten Gmbh | A process for the preparation of ºg-monochloro-methyl-benzoic acid |
NL254063A (ko) * | 1959-10-28 | |||
US3230268A (en) * | 1962-04-09 | 1966-01-18 | Fuso Chemical Co Ltd | Preparation of chloro-substituted benzene derivatives |
GB1133133A (en) * | 1966-02-15 | 1968-11-06 | Tenneco Chem | Improvements in or relating to production of o-alkylchlorobenzoic acid |
DE1909523C3 (de) * | 1969-02-26 | 1981-02-05 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Benzoylchlorid und Benzotrichlorid |
JPS5324414B2 (ko) * | 1972-11-15 | 1978-07-20 | ||
JPS525727A (en) * | 1975-07-03 | 1977-01-17 | Dai Ichi Seiyaku Co Ltd | Process for preparation of alpha,alpha-dichloro-o-toluic acid |
CH609959A5 (ko) * | 1976-12-17 | 1979-03-30 | Basf Ag |
-
1986
- 1986-11-06 US US06/927,477 patent/US4689425A/en not_active Expired - Fee Related
-
1987
- 1987-09-24 KR KR870010564A patent/KR880006147A/ko not_active IP Right Cessation
- 1987-10-29 JP JP62271958A patent/JPS63130559A/ja active Pending
- 1987-11-05 CN CN198787107637A patent/CN87107637A/zh active Pending
- 1987-11-05 AU AU80831/87A patent/AU589301B2/en not_active Expired - Fee Related
- 1987-11-05 EP EP87202147A patent/EP0268322A1/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
US4689425A (en) | 1987-08-25 |
EP0268322A1 (en) | 1988-05-25 |
JPS63130559A (ja) | 1988-06-02 |
AU589301B2 (en) | 1989-10-05 |
CN87107637A (zh) | 1988-07-13 |
AU8083187A (en) | 1988-05-12 |
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SUBM | Surrender of laid-open application requested |