IT1263960B - Procedimento per la fotoclorurazione di composti alchilaromatici - Google Patents
Procedimento per la fotoclorurazione di composti alchilaromaticiInfo
- Publication number
- IT1263960B IT1263960B ITMI930346A ITMI930346A IT1263960B IT 1263960 B IT1263960 B IT 1263960B IT MI930346 A ITMI930346 A IT MI930346A IT MI930346 A ITMI930346 A IT MI930346A IT 1263960 B IT1263960 B IT 1263960B
- Authority
- IT
- Italy
- Prior art keywords
- compound
- photocloruration
- alchylaromatic
- compounds
- procedure
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- XEMRAKSQROQPBR-UHFFFAOYSA-N (trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=CC=C1 XEMRAKSQROQPBR-UHFFFAOYSA-N 0.000 abstract 1
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 abstract 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 abstract 1
- 229940073608 benzyl chloride Drugs 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 230000001419 dependent effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
- C07C17/14—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the side-chain of aromatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00139—Controlling the temperature using electromagnetic heating
- B01J2219/00144—Sunlight; Visible light
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un composto alchilaromatico viene selettivamente fotoclorurato in catena laterale in un sistema di reazione ciclico nel quale detto composto viene fatto circolare continuamente tra un recipiente di contenimento ed un reattore di fotoclorurazione.Il composto viene clorurato parzialmente ad ogni passaggio del reattore di fotoclorurazione, il numero di passaggi essendo dipendente dall'entità di clorurazione desiderata.Il procedimento è particolarmente utile per la preparazione di cloruro di benzile, cloruro di benzale e benzotricloruro, e dei corrispondenti derivati alogeno-sostituiti nel nucleo.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI930346A IT1263960B (it) | 1993-02-24 | 1993-02-24 | Procedimento per la fotoclorurazione di composti alchilaromatici |
ES94200350T ES2104260T5 (es) | 1993-02-24 | 1994-02-16 | Procedimiento para la fotocloracion de compuestos alquil-aromaticos. |
EP94200350A EP0612707B2 (en) | 1993-02-24 | 1994-02-16 | Procedure for the photochlorination of alkyl-aromatic compounds |
DE69403829T DE69403829T3 (de) | 1993-02-24 | 1994-02-16 | Verfahren zur Photochlorierung von alkylaromatischen Verbindungen |
AT94200350T ATE154580T1 (de) | 1993-02-24 | 1994-02-16 | Verfahren zur photochlorierung von alkylaromatischen verbindungen |
DK94200350T DK0612707T4 (da) | 1993-02-24 | 1994-02-16 | Fremgangsmåde til fotochlorering af alkylaromatiske forbindelser |
US08/198,576 US5514254A (en) | 1993-02-24 | 1994-02-18 | Procedure for the photochlorination of alkyl-aromatic compounds |
JP6046321A JP3049409B2 (ja) | 1993-02-24 | 1994-02-21 | アルキル芳香族化合物の光塩素化法 |
GR970401910T GR3024262T3 (en) | 1993-02-24 | 1997-07-30 | Procedure for the photochlorination of alkyl-aromatic compounds. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI930346A IT1263960B (it) | 1993-02-24 | 1993-02-24 | Procedimento per la fotoclorurazione di composti alchilaromatici |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI930346A0 ITMI930346A0 (it) | 1993-02-24 |
ITMI930346A1 ITMI930346A1 (it) | 1994-08-24 |
IT1263960B true IT1263960B (it) | 1996-09-05 |
Family
ID=11365130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITMI930346A IT1263960B (it) | 1993-02-24 | 1993-02-24 | Procedimento per la fotoclorurazione di composti alchilaromatici |
Country Status (9)
Country | Link |
---|---|
US (1) | US5514254A (it) |
EP (1) | EP0612707B2 (it) |
JP (1) | JP3049409B2 (it) |
AT (1) | ATE154580T1 (it) |
DE (1) | DE69403829T3 (it) |
DK (1) | DK0612707T4 (it) |
ES (1) | ES2104260T5 (it) |
GR (1) | GR3024262T3 (it) |
IT (1) | IT1263960B (it) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2133606T3 (es) * | 1994-03-23 | 1999-09-16 | Hoechst Ag | Procedimiento para la preparacion de un 2,2'-bis(halogenometil)-1,1'-binaftilo. |
NL1006654C2 (nl) * | 1997-07-24 | 1999-01-26 | Dsm Nv | Werkwijze voor de bereiding van 3-methoxymethylchinoline en derivaten daarvan. |
CN100415700C (zh) * | 2006-04-14 | 2008-09-03 | 浙江巍华化工有限公司 | 一种光氯化生产氯苄的方法 |
DE602007003830D1 (de) * | 2006-05-31 | 2010-01-28 | Calaire Chimie Sas | Verfahren zur herstellung von lamotrigin und dessen zwischenprodukt 2,3-dichlorbenzoylchlorid |
CN102060654B (zh) * | 2011-01-10 | 2013-06-12 | 武汉理工大学 | 苯环上烷基侧链的选择性氯化方法 |
JP6311946B2 (ja) | 2013-09-13 | 2018-04-18 | ファイニングス シーオー. エルティーディーFinings Co. Ltd | トリクロロメチル置換ベンゼンを調製するための方法 |
CN104447298B (zh) * | 2014-12-12 | 2016-03-30 | 山东凯盛新材料有限公司 | 苯甲酰氯的制备方法 |
CN104592000B (zh) | 2014-12-22 | 2017-01-11 | 上海方纶新材料科技有限公司 | 制备氯甲酰基取代苯的清洁工艺 |
CN105435726A (zh) * | 2015-12-09 | 2016-03-30 | 安徽华业香料股份有限公司 | 专用于合成丙位内酯的连续式反应装置 |
CN107417490B (zh) * | 2017-05-23 | 2021-09-10 | 方圆化工有限公司 | 塔式连续光氯化法制氯苄 |
CN108250033A (zh) * | 2018-01-12 | 2018-07-06 | 潜江新亿宏有机化工有限公司 | 一种环保级氯化苄的生产方法和设备 |
CN108101731A (zh) * | 2018-01-29 | 2018-06-01 | 江苏佳麦化工有限公司 | 2,4-二氯三氯苄的制备方法 |
CN108101730A (zh) * | 2018-01-29 | 2018-06-01 | 江苏佳麦化工有限公司 | 制备3,4-二氯三氯苄的方法 |
CN108409528A (zh) * | 2018-01-31 | 2018-08-17 | 青岛和兴精细化学有限公司 | 一种采用新型反应设备制备对二氯苄的新工艺 |
CN108794307B (zh) * | 2018-07-18 | 2022-11-11 | 山东道可化学有限公司 | 一种溶剂法合成4-溴-3-甲基苯甲醚的微反应系统和方法 |
CN109776255B (zh) * | 2019-02-26 | 2021-12-07 | 南京工业大学 | 一种低温光氯化法制备2,6-二氯苄叉二氯的方法 |
CN110876916A (zh) * | 2019-10-22 | 2020-03-13 | 浙江大洋生物科技集团股份有限公司 | 1000l光催化反应釜工程放大与生产氯苄与氟苯的光催化反应釜及方法 |
CN111004095A (zh) * | 2019-12-27 | 2020-04-14 | 大连奇凯医药科技有限公司 | 连续/半连续制备三氯甲氧基苯类化合物的方法 |
CN113416114A (zh) * | 2021-07-22 | 2021-09-21 | 浙江解氏新材料股份有限公司 | 一种负载三氯化磷催化2-氯-4氟甲苯光氯化制备2-氯-4-氟-三氯甲苯的方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE590772A (it) * | 1959-05-12 | 1900-01-01 | ||
US3392098A (en) * | 1962-12-07 | 1968-07-09 | Atlas Chem Ind | Chlorination of hydrocarbons |
DE2530094C2 (de) * | 1975-07-05 | 1979-06-07 | Hoechst Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von Mono- oder DKtrichlormethyl)benzolen |
EP0009787B2 (de) * | 1978-10-11 | 1986-07-09 | Bayer Ag | Verfahren zur Monohalogenierung von Alkylbenzolen in alpha-Stellung |
US4268457A (en) * | 1979-06-28 | 1981-05-19 | Hooker Chemicals & Plastics Corp. | Process for the preparation of paraphenoxybenzoylchloride |
US4348265A (en) * | 1981-03-27 | 1982-09-07 | The Dow Chemical Company | Process for the selective aliphatic chlorination of alkylbenzenes |
IT1169421B (it) * | 1982-06-03 | 1987-05-27 | Givaudan & Cie Sa | Procedimento per la preparazione di benzen-derivati |
FR2579593B1 (fr) * | 1985-03-29 | 1987-06-05 | Rhone Poulenc Spec Chim | Procede de preparation de derives dichlorotrifluoroethoxy et ethylthiobenzeniques |
US4689425A (en) * | 1986-11-06 | 1987-08-25 | Stauffer Chemical Company | Photochlorination of aromatic compounds in the side chain |
JP2745087B2 (ja) * | 1991-11-08 | 1998-04-28 | 呉羽化学工業株式会社 | メチル化芳香族化合物の塩素化方法 |
-
1993
- 1993-02-24 IT ITMI930346A patent/IT1263960B/it active IP Right Grant
-
1994
- 1994-02-16 EP EP94200350A patent/EP0612707B2/en not_active Expired - Lifetime
- 1994-02-16 ES ES94200350T patent/ES2104260T5/es not_active Expired - Lifetime
- 1994-02-16 DK DK94200350T patent/DK0612707T4/da active
- 1994-02-16 DE DE69403829T patent/DE69403829T3/de not_active Expired - Fee Related
- 1994-02-16 AT AT94200350T patent/ATE154580T1/de not_active IP Right Cessation
- 1994-02-18 US US08/198,576 patent/US5514254A/en not_active Expired - Fee Related
- 1994-02-21 JP JP6046321A patent/JP3049409B2/ja not_active Expired - Fee Related
-
1997
- 1997-07-30 GR GR970401910T patent/GR3024262T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
GR3024262T3 (en) | 1997-10-31 |
DE69403829T2 (de) | 1997-11-27 |
ITMI930346A1 (it) | 1994-08-24 |
EP0612707A1 (en) | 1994-08-31 |
DE69403829T3 (de) | 2003-02-27 |
JP3049409B2 (ja) | 2000-06-05 |
EP0612707B2 (en) | 2002-08-07 |
DE69403829D1 (de) | 1997-07-24 |
US5514254A (en) | 1996-05-07 |
ES2104260T5 (es) | 2003-01-01 |
ATE154580T1 (de) | 1997-07-15 |
DK0612707T3 (da) | 1997-12-01 |
DK0612707T4 (da) | 2002-09-16 |
ES2104260T3 (es) | 1997-10-01 |
JPH06298671A (ja) | 1994-10-25 |
EP0612707B1 (en) | 1997-06-18 |
ITMI930346A0 (it) | 1993-02-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970218 |