ES2104260T3 - Procedimiento para la fotocloracion de compuestos alquil-aromaticos. - Google Patents
Procedimiento para la fotocloracion de compuestos alquil-aromaticos.Info
- Publication number
- ES2104260T3 ES2104260T3 ES94200350T ES94200350T ES2104260T3 ES 2104260 T3 ES2104260 T3 ES 2104260T3 ES 94200350 T ES94200350 T ES 94200350T ES 94200350 T ES94200350 T ES 94200350T ES 2104260 T3 ES2104260 T3 ES 2104260T3
- Authority
- ES
- Spain
- Prior art keywords
- photocloration
- procedure
- compound
- alkyl
- aromatic compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- XEMRAKSQROQPBR-UHFFFAOYSA-N (trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=CC=C1 XEMRAKSQROQPBR-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
- C07C17/14—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the side-chain of aromatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00139—Controlling the temperature using electromagnetic heating
- B01J2219/00144—Sunlight; Visible light
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
UN COMPUESTO AROMATICO DE ALKILO QUE SE FOTOCLORA SELECTIVAMENTE EN LA CADENA LATERAL DE UN SISTEMA DE REACCION CICLICO EN DONDE SE HACE CIRCULAR CONTINUAMENTE A DICHO COMPUESTO ENTRE UN RECIPIENTE (1) Y UN REACTOR DE FOTOCLORACION (2). EL COMPUESTO SE CLORA PARCIALMENTE TRAS CADA PASADA A TRAVES DEL REACTOR DE FOTOCLORACION (2), DEPENDIENDO DEL NUMERO DE PASADAS DEL GRADO DE CLORACION DESEADO. EL PROCEDIMIENTO ES PARTICULARMENTE UTIL PARA LA PREPARACION DE BENCILCLORURO, BENZALCLORURO Y BENZOTRICLORURO Y LOS DERIVADOS DEL NUCLEO SUSTITUIDOS POR HALOGENO CORRESPONDIENTES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI930346A IT1263960B (it) | 1993-02-24 | 1993-02-24 | Procedimento per la fotoclorurazione di composti alchilaromatici |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2104260T3 true ES2104260T3 (es) | 1997-10-01 |
ES2104260T5 ES2104260T5 (es) | 2003-01-01 |
Family
ID=11365130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94200350T Expired - Lifetime ES2104260T5 (es) | 1993-02-24 | 1994-02-16 | Procedimiento para la fotocloracion de compuestos alquil-aromaticos. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5514254A (es) |
EP (1) | EP0612707B2 (es) |
JP (1) | JP3049409B2 (es) |
AT (1) | ATE154580T1 (es) |
DE (1) | DE69403829T3 (es) |
DK (1) | DK0612707T4 (es) |
ES (1) | ES2104260T5 (es) |
GR (1) | GR3024262T3 (es) |
IT (1) | IT1263960B (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2133606T3 (es) * | 1994-03-23 | 1999-09-16 | Hoechst Ag | Procedimiento para la preparacion de un 2,2'-bis(halogenometil)-1,1'-binaftilo. |
NL1006654C2 (nl) * | 1997-07-24 | 1999-01-26 | Dsm Nv | Werkwijze voor de bereiding van 3-methoxymethylchinoline en derivaten daarvan. |
CN100415700C (zh) * | 2006-04-14 | 2008-09-03 | 浙江巍华化工有限公司 | 一种光氯化生产氯苄的方法 |
ES2337415T3 (es) * | 2006-05-31 | 2010-04-23 | Calaire Chimie Sas | Metodo para la preparacion de lamotrigina y su producto intermedio cloruro de 2,3-diclorobenzoilo. |
CN102060654B (zh) * | 2011-01-10 | 2013-06-12 | 武汉理工大学 | 苯环上烷基侧链的选择性氯化方法 |
ES2744453T3 (es) | 2013-09-13 | 2020-02-25 | Finings Co Ltd | Método para la preparación de benceno sustituido con un grupo triclorometilo |
CN104447298B (zh) * | 2014-12-12 | 2016-03-30 | 山东凯盛新材料有限公司 | 苯甲酰氯的制备方法 |
CN104592000B (zh) | 2014-12-22 | 2017-01-11 | 上海方纶新材料科技有限公司 | 制备氯甲酰基取代苯的清洁工艺 |
CN105435726A (zh) * | 2015-12-09 | 2016-03-30 | 安徽华业香料股份有限公司 | 专用于合成丙位内酯的连续式反应装置 |
CN107417490B (zh) * | 2017-05-23 | 2021-09-10 | 方圆化工有限公司 | 塔式连续光氯化法制氯苄 |
CN108250033A (zh) * | 2018-01-12 | 2018-07-06 | 潜江新亿宏有机化工有限公司 | 一种环保级氯化苄的生产方法和设备 |
CN108101730A (zh) * | 2018-01-29 | 2018-06-01 | 江苏佳麦化工有限公司 | 制备3,4-二氯三氯苄的方法 |
CN108101731A (zh) * | 2018-01-29 | 2018-06-01 | 江苏佳麦化工有限公司 | 2,4-二氯三氯苄的制备方法 |
CN108409528B (zh) * | 2018-01-31 | 2024-08-02 | 青岛和兴精细化学有限公司 | 一种采用新型反应设备制备对二氯苄的新工艺 |
CN108794307B (zh) * | 2018-07-18 | 2022-11-11 | 山东道可化学有限公司 | 一种溶剂法合成4-溴-3-甲基苯甲醚的微反应系统和方法 |
CN109776255B (zh) * | 2019-02-26 | 2021-12-07 | 南京工业大学 | 一种低温光氯化法制备2,6-二氯苄叉二氯的方法 |
CN110876916B (zh) * | 2019-10-22 | 2024-07-26 | 浙江大洋生物科技集团股份有限公司 | 1000l光催化反应釜工程放大与生产氯苄与氟苯的光催化反应釜及方法 |
CN111004095A (zh) * | 2019-12-27 | 2020-04-14 | 大连奇凯医药科技有限公司 | 连续/半连续制备三氯甲氧基苯类化合物的方法 |
CN113416114A (zh) * | 2021-07-22 | 2021-09-21 | 浙江解氏新材料股份有限公司 | 一种负载三氯化磷催化2-氯-4氟甲苯光氯化制备2-氯-4-氟-三氯甲苯的方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE590772A (es) * | 1959-05-12 | 1900-01-01 | ||
US3392098A (en) * | 1962-12-07 | 1968-07-09 | Atlas Chem Ind | Chlorination of hydrocarbons |
DE2530094C2 (de) * | 1975-07-05 | 1979-06-07 | Hoechst Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von Mono- oder DKtrichlormethyl)benzolen |
EP0009787B2 (de) * | 1978-10-11 | 1986-07-09 | Bayer Ag | Verfahren zur Monohalogenierung von Alkylbenzolen in alpha-Stellung |
US4268457A (en) * | 1979-06-28 | 1981-05-19 | Hooker Chemicals & Plastics Corp. | Process for the preparation of paraphenoxybenzoylchloride |
US4348265A (en) * | 1981-03-27 | 1982-09-07 | The Dow Chemical Company | Process for the selective aliphatic chlorination of alkylbenzenes |
IT1169421B (it) * | 1982-06-03 | 1987-05-27 | Givaudan & Cie Sa | Procedimento per la preparazione di benzen-derivati |
FR2579593B1 (fr) * | 1985-03-29 | 1987-06-05 | Rhone Poulenc Spec Chim | Procede de preparation de derives dichlorotrifluoroethoxy et ethylthiobenzeniques |
US4689425A (en) * | 1986-11-06 | 1987-08-25 | Stauffer Chemical Company | Photochlorination of aromatic compounds in the side chain |
JP2745087B2 (ja) * | 1991-11-08 | 1998-04-28 | 呉羽化学工業株式会社 | メチル化芳香族化合物の塩素化方法 |
-
1993
- 1993-02-24 IT ITMI930346A patent/IT1263960B/it active IP Right Grant
-
1994
- 1994-02-16 EP EP94200350A patent/EP0612707B2/en not_active Expired - Lifetime
- 1994-02-16 AT AT94200350T patent/ATE154580T1/de not_active IP Right Cessation
- 1994-02-16 ES ES94200350T patent/ES2104260T5/es not_active Expired - Lifetime
- 1994-02-16 DK DK94200350T patent/DK0612707T4/da active
- 1994-02-16 DE DE69403829T patent/DE69403829T3/de not_active Expired - Fee Related
- 1994-02-18 US US08/198,576 patent/US5514254A/en not_active Expired - Fee Related
- 1994-02-21 JP JP6046321A patent/JP3049409B2/ja not_active Expired - Fee Related
-
1997
- 1997-07-30 GR GR970401910T patent/GR3024262T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
DE69403829T3 (de) | 2003-02-27 |
EP0612707B1 (en) | 1997-06-18 |
ITMI930346A0 (it) | 1993-02-24 |
DE69403829D1 (de) | 1997-07-24 |
US5514254A (en) | 1996-05-07 |
JPH06298671A (ja) | 1994-10-25 |
ITMI930346A1 (it) | 1994-08-24 |
ATE154580T1 (de) | 1997-07-15 |
JP3049409B2 (ja) | 2000-06-05 |
DK0612707T4 (da) | 2002-09-16 |
DE69403829T2 (de) | 1997-11-27 |
DK0612707T3 (da) | 1997-12-01 |
GR3024262T3 (en) | 1997-10-31 |
EP0612707B2 (en) | 2002-08-07 |
IT1263960B (it) | 1996-09-05 |
EP0612707A1 (en) | 1994-08-31 |
ES2104260T5 (es) | 2003-01-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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