MX166107B - Metodo para reducir al minimo o impedir la precipitacion del rodio - Google Patents
Metodo para reducir al minimo o impedir la precipitacion del rodioInfo
- Publication number
- MX166107B MX166107B MX006566A MX656687A MX166107B MX 166107 B MX166107 B MX 166107B MX 006566 A MX006566 A MX 006566A MX 656687 A MX656687 A MX 656687A MX 166107 B MX166107 B MX 166107B
- Authority
- MX
- Mexico
- Prior art keywords
- rhodium
- phosphite
- solubilized
- aldehyde
- complex
- Prior art date
Links
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 229910052703 rhodium Inorganic materials 0.000 title abstract 4
- 239000010948 rhodium Substances 0.000 title abstract 4
- 150000001299 aldehydes Chemical class 0.000 abstract 5
- 239000000047 product Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- APVDIAOSUXFJNU-UHFFFAOYSA-N rhodium(3+) phosphite Chemical compound [Rh+3].[O-]P([O-])[O-] APVDIAOSUXFJNU-UHFFFAOYSA-N 0.000 abstract 3
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920000620 organic polymer Polymers 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/865,061 US4717775A (en) | 1984-12-28 | 1986-05-20 | Transition metal complex catalyzed reactions |
| US07/046,821 US4774361A (en) | 1986-05-20 | 1987-05-11 | Transition metal complex catalyzed reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX166107B true MX166107B (es) | 1992-12-21 |
Family
ID=26724327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX006566A MX166107B (es) | 1986-05-20 | 1987-05-20 | Metodo para reducir al minimo o impedir la precipitacion del rodio |
Country Status (12)
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4835299A (en) * | 1987-03-31 | 1989-05-30 | Union Carbide Corporation | Process for purifying tertiary organophosphites |
| IT1237530B (it) * | 1989-12-12 | 1993-06-08 | Eniricerche Spa | Procedimento per la sintesi diretta di alcoli da olefine,ossidi di carbonio e idrogeno,promossa da un catalizzatore di rodio supportato |
| US5210318A (en) * | 1990-05-04 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes |
| US5087763A (en) * | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
| JP2946790B2 (ja) * | 1991-03-14 | 1999-09-06 | 三菱化学株式会社 | アルデヒド類の製造法 |
| US5360938A (en) * | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
| GB9119955D0 (en) * | 1991-09-18 | 1991-10-30 | Imperial College | Treatment of aqueous supplies containing organic material |
| US5169981A (en) * | 1991-12-06 | 1992-12-08 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of alpha-substituted alkadienes |
| US5243099A (en) * | 1991-12-06 | 1993-09-07 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of alpha-substituted alkadienes |
| US5756855A (en) | 1994-08-19 | 1998-05-26 | Union Carbide Chemicals & Plastics Technology Corporation | Stabilization of phosphite ligands in hydroformylation process |
| US5672766A (en) * | 1994-12-12 | 1997-09-30 | Mitsubishi Chemical Corporation | Method for producing aldehydes |
| KR970703805A (ko) * | 1995-05-01 | 1997-08-09 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 | 막 분리방법(Membrane Separation) |
| US5739352A (en) * | 1995-10-19 | 1998-04-14 | United Carbide Chemicals & Plastics Technology Corporation | Process for preparing carboxylic acids |
| DE19605435A1 (de) * | 1996-02-14 | 1997-08-21 | Basf Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion |
| US6090987A (en) * | 1998-07-06 | 2000-07-18 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| JP3921853B2 (ja) * | 1998-12-10 | 2007-05-30 | 三菱化学株式会社 | アルデヒド類及びアルコール類の製造方法 |
| CN1163463C (zh) | 1998-12-10 | 2004-08-25 | 三菱化学株式会社 | 醛的制备方法 |
| GB9918229D0 (en) † | 1999-08-04 | 1999-10-06 | Ici Plc | Improvements relating to metal-compound catalysed processes |
| DE19954510A1 (de) | 1999-11-12 | 2001-05-17 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen |
| US6596360B2 (en) | 2000-06-27 | 2003-07-22 | Dai Nippon Printing Co., Ltd. | Multilayer volume hologram, and label for multilayer volume hologram fabrication |
| EP1249441A1 (en) | 2001-04-13 | 2002-10-16 | Dsm N.V. | Continuous hydroformylation process |
| DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
| US7317130B2 (en) * | 2002-08-31 | 2008-01-08 | Oxeno Olefinchemie Gmbh | Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters |
| BR0313814B1 (pt) * | 2002-08-31 | 2012-11-27 | processo para preparação de aldeìdos por hidroformilação de compostos olefinicamente insaturados, catalisado por complexos metálicos não modificados, na presença de ésteres de ácido carbÈnico cìclicos. | |
| EP1595984B1 (en) * | 2003-01-16 | 2010-06-09 | Teijin Fibers Limited | Differential-shrinkage polyester combined filament yarn |
| EP2308817B1 (en) | 2003-07-03 | 2016-10-05 | Dow Technology Investments LLC | Minimization of ligand degradation products, or reversion of same to useful phosphine ligands |
| DE10349343A1 (de) * | 2003-10-23 | 2005-06-02 | Basf Ag | Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden |
| ZA200701001B (en) | 2004-08-02 | 2008-05-28 | Union Carbide Chem Plastic | Stabilization of a hydroformylation process |
| JP5400627B2 (ja) * | 2007-03-20 | 2014-01-29 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 生成物異性体の制御が改善されたヒドロホルミル化方法 |
| CN101681776B (zh) * | 2007-04-09 | 2011-10-05 | Lg化学株式会社 | 含有亚磷酸酯配体的催化剂组合物和使用该催化剂组合物的加氢甲酰化方法 |
| KR101629043B1 (ko) | 2008-07-03 | 2016-06-09 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 재순환 촉매 스트림 중의 중질물 제어 방법 |
| CA2743720C (en) | 2008-11-14 | 2019-03-12 | University Of Kansas | Polymer-supported transition metal catalyst complexes and methods of use |
| MX2011010379A (es) | 2009-03-31 | 2011-10-17 | Dow Technology Investments Llc | Proceso de hidroformilacion con un ligando de biosfosfito doblemente de extremo abierto. |
| US7928267B1 (en) * | 2009-06-22 | 2011-04-19 | Eastman Chemical Company | Phosphite containing catalysts for hydroformylation processes |
| US8586800B2 (en) | 2009-10-16 | 2013-11-19 | Dow Technology Investments Llc | Gas phase hydroformylation process |
| EP2942343B1 (en) | 2009-12-22 | 2019-09-04 | Dow Technology Investments LLC | Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process |
| EP2516371B2 (en) | 2009-12-22 | 2022-08-17 | Dow Technology Investments LLC | Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure |
| KR101815328B1 (ko) | 2009-12-22 | 2018-01-04 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 합성가스 분압의 조절에 의한 혼합된 리간드 하이드로폼일화 공정에서의 노말:아이소 알데하이드 비의 조절 방법 |
| WO2012047514A1 (en) | 2010-10-05 | 2012-04-12 | Dow Technology Investments Llc | Hydroformylation process |
| SG190138A1 (en) | 2010-11-12 | 2013-06-28 | Dow Technology Investments Llc | Mitigation of fouling in hydroformylation processes by water addition |
| SA112330271B1 (ar) | 2011-04-18 | 2015-02-09 | داو تكنولوجى انفستمنتس ال ال سى | تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء |
| CN104144901B (zh) | 2012-03-07 | 2017-03-01 | 巴斯夫欧洲公司 | C3‑c20醛氢化和蒸馏中的热集成方法 |
| JP6516670B2 (ja) | 2012-04-12 | 2019-05-22 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 連続的ヒドロホルミル化の際に触媒を補充する方法 |
| US8889917B2 (en) | 2012-04-12 | 2014-11-18 | Basf Se | Method of supplementing the catalyst in continuous hydroformylation |
| CN104379258B (zh) | 2012-06-04 | 2017-05-03 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| BR112015003762B1 (pt) | 2012-08-29 | 2021-04-13 | Dow Technology Investments Llc | Processo para a formação de um catalisador de hidroformilação |
| BR112015006495B1 (pt) | 2012-09-25 | 2020-12-15 | Dow Technology Investments Llc | Processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação |
| EP2740535A1 (en) | 2012-12-04 | 2014-06-11 | Dow Technology Investments LLC | Bidentate ligands for hydroformylation of ethylene |
| KR102098429B1 (ko) | 2012-12-06 | 2020-04-07 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 하이드로포밀화 방법 |
| CN104045532B (zh) | 2013-03-15 | 2018-05-25 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| CN104725170B (zh) | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| US9688598B2 (en) | 2013-12-19 | 2017-06-27 | Dow Technology Investments Llc | Hydroformylation process |
| EP3126319B1 (en) | 2014-03-31 | 2019-07-17 | Dow Technology Investments LLC | Hydroformylation process |
| WO2015175158A1 (en) | 2014-05-14 | 2015-11-19 | Dow Technology Investments Llc | Stabilized organophosphorous compounds |
| MY184826A (en) * | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| TWI709566B (zh) | 2015-09-30 | 2020-11-11 | 美商陶氏科技投資公司 | 用於製造有機磷化合物的方法 |
| TWI709568B (zh) | 2015-09-30 | 2020-11-11 | 美商陶氏科技投資公司 | 用於製造有機磷化合物的方法 |
| KR102743230B1 (ko) | 2015-11-10 | 2024-12-17 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 알데하이드를 생산하는 방법 |
| RU2751511C9 (ru) | 2016-02-11 | 2021-08-18 | Дау Текнолоджи Инвестментс Ллк | Способы превращения олефинов в спирты, простые эфиры или их комбинации |
| WO2017160956A1 (en) | 2016-03-18 | 2017-09-21 | Dow Technology Investments Llc | Hydroformylation process |
| TW201840362A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TWI758353B (zh) | 2016-11-08 | 2022-03-21 | 美商陶氏科技投資有限公司 | 使去活化的氫甲醯化催化劑溶液再生的方法 |
| TW201840363A (zh) | 2016-11-08 | 2018-11-16 | 美商陶氏科技投資有限公司 | 處理氫甲醯化催化劑溶液之方法 |
| WO2019083700A1 (en) | 2017-10-25 | 2019-05-02 | Dow Technology Investments Llc | PROCESS FOR REDUCING THE FORMATION OF HEAVY MINERALS IN A SOLUTION COMPRISING ALDEHYDE COMPOUNDS FORMED DURING A HYDROFORMYLATION PROCESS |
| WO2019094290A1 (en) | 2017-11-13 | 2019-05-16 | Dow Technology Investments Llc | Processes for recovery of rhodium from a hydroformylation process |
| TWI793216B (zh) * | 2017-12-07 | 2023-02-21 | 美商陶氏科技投資公司 | 氫甲醯化方法 |
| EP3801899A1 (en) | 2018-05-30 | 2021-04-14 | Dow Technology Investments LLC | Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes |
| MX2020011380A (es) | 2018-05-30 | 2020-11-24 | Dow Technology Investments Llc | Metodos de control de procesos de hidroformilacion. |
| KR20210013703A (ko) | 2018-05-30 | 2021-02-05 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 모노포스핀, 테트라포스핀 리간드의 조합을 포함하는 촉매 조성물 및 이를 이용하는 하이드로포밀화 공정 |
| JP7447116B2 (ja) * | 2018-11-29 | 2024-03-11 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
| US20220143590A1 (en) | 2019-06-27 | 2022-05-12 | Dow Technology Investments Llc | Process to prepare solution from hydroformylation process for precious metal recovery |
| TWI874467B (zh) | 2019-11-05 | 2025-03-01 | 美商陶氏科技投資有限公司 | 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法 |
| WO2021126421A1 (en) | 2019-12-19 | 2021-06-24 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
| CN114478214B (zh) * | 2020-10-23 | 2024-05-17 | 中国石油化工股份有限公司 | 一种氢甲酰化方法和一种氢甲酰化产物的分离方法 |
| EP4259598A1 (en) | 2020-12-14 | 2023-10-18 | Dow Technology Investments LLC | Processes to improve catalytic metal accountability in hydroformylation processes |
| MX2024005136A (es) | 2021-11-11 | 2024-05-16 | Dow Technology Investments Llc | Procesos para recuperar rodio a partir de procesos de hidroformilacion. |
| CN118317834A (zh) | 2021-12-16 | 2024-07-09 | 陶氏技术投资有限责任公司 | 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法 |
| CN118338965A (zh) | 2021-12-16 | 2024-07-12 | 陶氏技术投资有限责任公司 | 包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法 |
| CN120282943A (zh) | 2022-12-13 | 2025-07-08 | 陶氏技术投资有限责任公司 | 通过利用降解产物使多膦使用最小化的方法 |
| WO2024228768A1 (en) | 2023-05-04 | 2024-11-07 | Dow Technology Investments Llc | Hydroformylation process |
| GB202307175D0 (en) | 2023-05-15 | 2023-06-28 | Johnson Matthey Davy Technologies Ltd | Process for hydrogenating a substrate |
| WO2025006020A1 (en) | 2023-06-26 | 2025-01-02 | Dow Technology Investments Llc | Methods of controlling hydroformylation processes |
| WO2025029369A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity |
| WO2025029349A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Hydroformylation process |
| GB202404300D0 (en) | 2024-03-26 | 2024-05-08 | Johnson Matthey Davy Technologies Ltd | Process for the production of 2-alkylalkanol |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE156528C (enrdf_load_html_response) * | ||||
| US4482748A (en) * | 1967-05-29 | 1984-11-13 | Celanese Corporation | Hydrocarbonylation |
| DE2145532C3 (de) * | 1971-09-11 | 1975-02-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Aufarbeitung von Hydroformylierungsgemischen |
| DE2326489A1 (de) * | 1973-05-24 | 1974-12-12 | Ernst Prof Dr Bayer | Verfahren zur katalyse unter verwendung von loeslichen metallverbindungen synthetischer polymerer |
| JPS5638576B2 (enrdf_load_html_response) * | 1974-07-25 | 1981-09-08 | ||
| US4148830A (en) * | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
| JPS6022688B2 (ja) * | 1976-12-29 | 1985-06-03 | 和光純薬工業株式会社 | アルデヒド化合物の蒸留方法 |
| DE2966350D1 (en) * | 1978-08-17 | 1983-12-01 | Heyl Chem Pharm | Polymeric hydrogenation catalysts, process for preparing these catalysts and their use for catalytic hydrogenations |
| US4235744A (en) * | 1978-10-30 | 1980-11-25 | Standard Oil Company (Ohio) | Carbonylation of olefinically unsaturated compounds |
| US4504684A (en) * | 1982-01-06 | 1985-03-12 | The Standard Oil Company | Metal coordination polymers as hydroformylation and hydrogenation catalysts |
| EP0096988B1 (en) * | 1982-06-11 | 1987-07-08 | DAVY McKEE (LONDON) LIMITED | Hydroformylation process |
| US4528403A (en) * | 1982-10-21 | 1985-07-09 | Mitsubishi Chemical Industries Ltd. | Hydroformylation process for preparation of aldehydes and alcohols |
| US4528404A (en) * | 1983-03-16 | 1985-07-09 | Exxon Research And Engineering Co. | High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems |
| GB8334359D0 (en) * | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
| US4599206A (en) * | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4599456A (en) * | 1984-12-20 | 1986-07-08 | Phillips Petroleum Company | Novel aldehyde-phosphine compositions and uses therefor |
| US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4613701A (en) * | 1985-09-19 | 1986-09-23 | Celanese Corporation | Recovery of rhodium from hydroformylation reaction product |
-
1987
- 1987-05-11 US US07/046,821 patent/US4774361A/en not_active Expired - Lifetime
- 1987-05-19 EP EP87903774A patent/EP0276231B1/en not_active Expired - Lifetime
- 1987-05-19 JP JP62503400A patent/JPS63503385A/ja active Granted
- 1987-05-19 AU AU74898/87A patent/AU613312B2/en not_active Ceased
- 1987-05-19 WO PCT/US1987/001124 patent/WO1987007261A2/en active IP Right Grant
- 1987-05-19 DE DE8787903774T patent/DE3773890D1/de not_active Expired - Lifetime
- 1987-05-20 MX MX006566A patent/MX166107B/es unknown
- 1987-05-20 CA CA000537549A patent/CA1312094C/en not_active Expired - Lifetime
- 1987-05-20 IN IN373/MAS/87A patent/IN169727B/en unknown
- 1987-05-20 CN CN87104311A patent/CN1010011B/zh not_active Expired
- 1987-05-20 ES ES8701486A patent/ES2004935A6/es not_active Expired
-
1988
- 1988-01-19 NO NO880207A patent/NO166583C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA1312094C (en) | 1992-12-29 |
| NO166583C (no) | 1991-08-14 |
| NO166583B (no) | 1991-05-06 |
| CN1010011B (zh) | 1990-10-17 |
| NO880207D0 (no) | 1988-01-19 |
| JPH0548215B2 (enrdf_load_html_response) | 1993-07-20 |
| WO1987007261A2 (en) | 1987-12-03 |
| US4774361A (en) | 1988-09-27 |
| EP0276231A1 (en) | 1988-08-03 |
| EP0276231B1 (en) | 1991-10-16 |
| NO880207L (no) | 1988-01-19 |
| DE3773890D1 (de) | 1991-11-21 |
| AU613312B2 (en) | 1991-08-01 |
| CN87104311A (zh) | 1988-06-08 |
| WO1987007261A3 (en) | 1988-04-07 |
| IN169727B (enrdf_load_html_response) | 1991-12-14 |
| JPS63503385A (ja) | 1988-12-08 |
| AU7489887A (en) | 1987-12-22 |
| ES2004935A6 (es) | 1989-02-16 |
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