ES474950A1 - Mejoras en un procedimiento de hidroformilacion o de hidro- genacion - Google Patents

Mejoras en un procedimiento de hidroformilacion o de hidro- genacion

Info

Publication number
ES474950A1
ES474950A1 ES474950A ES474950A ES474950A1 ES 474950 A1 ES474950 A1 ES 474950A1 ES 474950 A ES474950 A ES 474950A ES 474950 A ES474950 A ES 474950A ES 474950 A1 ES474950 A1 ES 474950A1
Authority
ES
Spain
Prior art keywords
hydroformylation
rhodium complex
hydrogenation catalyst
binuclear rhodium
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES474950A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Publication of ES474950A1 publication Critical patent/ES474950A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Mejoraos en una procedimiento de hidroformilación o de hidrogenación que comprende hacer reaccionar una olefina con hidrógeno y, en el caso de la hidroformilación, con hidrógeno y con óxido de carbono, en fase homogénea o heterogénea, con o sin disolvente, a una temperatura comprendida entre 20 y 250ºC aproximadamente; cuyas mejoras se caracterizan porque comprenden efectuar la reacción en presencia de 10-6 a 10-2 moles, por mol de compuesto orgánico insaturado, de un catalizador de fórmula: ***1 en la cual: . L y L¿ idénticos representan un fosfito terciario orgánico o L y L¿ diferentes representan para L el grupo CO y para L¿ un fosfito terciario orgánico o una fosfina aromática. . (SY) representa un grupo tiolato.
ES474950A 1977-11-10 1978-11-08 Mejoras en un procedimiento de hidroformilacion o de hidro- genacion Expired ES474950A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7733865A FR2408388A1 (fr) 1977-11-10 1977-11-10 Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation

Publications (1)

Publication Number Publication Date
ES474950A1 true ES474950A1 (es) 1979-10-16

Family

ID=9197475

Family Applications (1)

Application Number Title Priority Date Filing Date
ES474950A Expired ES474950A1 (es) 1977-11-10 1978-11-08 Mejoras en un procedimiento de hidroformilacion o de hidro- genacion

Country Status (11)

Country Link
US (2) US4215066A (es)
JP (1) JPS5475490A (es)
BE (1) BE871814A (es)
CA (1) CA1110643A (es)
DE (1) DE2848335C2 (es)
ES (1) ES474950A1 (es)
FR (1) FR2408388A1 (es)
GB (1) GB2009750B (es)
IT (1) IT1100886B (es)
LU (1) LU80488A1 (es)
NL (1) NL7811126A (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4288380A (en) * 1979-11-01 1981-09-08 Union Carbide Corporation Heteronuclear-bridged rhodium clusters
IL59647A (en) * 1980-03-14 1984-01-31 Yeda Res & Dev Organo-metallic catalytic system
PT76061A (en) * 1982-12-30 1983-01-01 Stable homogeneous hydrogenation rhodium catalyst - useful in high yield prodn. of doxycycline by stereospecific hydrogenation
US4605751A (en) * 1984-01-17 1986-08-12 The Board Of Regents Acting For And On Behalf Of The University Of Michigan Bimetallic cluster catalysts
FR2571725B1 (fr) * 1984-10-16 1987-09-18 Rhone Poulenc Chim Base Complexes rhodies, dinucleaires et hydrosolubles et leur utilisation comme catalyseur d'hydroformylation
FR2634209B1 (fr) * 1988-07-13 1990-10-19 Toulouse Inst Nat Polytech Nouveau compose organometallique supporte, procede de preparation, et application comme catalyseur d'hydroformylation
US5047132A (en) * 1988-10-17 1991-09-10 University Of Houston Apparatus for catalytically reducing dioxygen using dirhodium complexes
GB9118603D0 (en) * 1991-08-30 1991-10-16 Shell Int Research Process for the preparation of alcohols
JP4218088B2 (ja) * 1997-10-14 2009-02-04 ロンザ リミテッド 二核型イリジウム（ｉ）フォスフィン錯化合物およびオレフィンの不整ハイドロアミネーションの触媒としての使用
US6229052B1 (en) * 1998-05-29 2001-05-08 E. I. Du Pont De Nemours And Company Hydroformylation of olefins using supported bis(phosphorus) ligands
CN100395250C (zh) * 2004-11-25 2008-06-18 友达光电股份有限公司 有机金属络合物以及包括该有机金属络合物的有机电致发光装置
CN109180845B (zh) * 2018-07-20 2020-12-15 北京理工大学 一种双核铑金属催化剂、制备方法及应用
CN111686817B (zh) * 2019-03-14 2024-02-09 上海博腾智拓医药科技有限公司 一种铜负载催化剂、其制备方法及应用
CN111729687B (zh) * 2020-07-08 2022-08-05 万华化学集团股份有限公司 一种氢甲酰化催化剂的制备方法和应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3501531A (en) * 1964-12-15 1970-03-17 Ethyl Corp Hydroformylation process
US3933919A (en) * 1964-12-15 1976-01-20 Geoffrey Wilkinson Hydroformylation of mono-α-olefins and mono-α-acetylenes
US3954877A (en) * 1967-10-12 1976-05-04 Jefferson Chemical Co., Inc. Hydroformylation of olefins
GB1220506A (en) * 1968-06-18 1971-01-27 Ici Ltd Transition metal compounds
US3859359A (en) * 1970-04-27 1975-01-07 Ethyl Corp Compound and method
US3907847A (en) * 1970-04-27 1975-09-23 Ethyl Corp Compound and method
GB1368431A (en) * 1970-07-22 1974-09-25 Johnson Matthey Co Ltd Rhodium complex and methods of preparing the complex
US3956177A (en) * 1971-08-20 1976-05-11 Phillips Petroleum Company Rhodium hydroformylation catalyst
US3939188A (en) * 1972-03-24 1976-02-17 Exxon Research And Engineering Company Preparation of zerovalent phosphine substituted rhodium compounds and their use in the selective carbonylation of olefins
GB1420928A (en) * 1972-05-10 1976-01-14 Dow Corning Ltd Complexes containing phosphorus
FR2211002A5 (es) * 1972-12-20 1974-07-12 Rhone Progil
GB1448826A (en) * 1973-02-07 1976-09-08 Dow Corning Ltd Rhodium complexes containing sulphur and use as catalysts
DE2453229A1 (de) * 1974-11-09 1976-05-13 Bayer Ag Rhodiumhaltige komplexverbindungen

Also Published As

Publication number Publication date
GB2009750B (en) 1982-05-26
FR2408388B1 (es) 1983-03-18
DE2848335A1 (de) 1979-06-13
GB2009750A (en) 1979-06-20
IT1100886B (it) 1985-09-28
JPS5475490A (en) 1979-06-16
CA1110643A (fr) 1981-10-13
NL7811126A (nl) 1979-05-14
BE871814A (fr) 1979-05-07
US4215066A (en) 1980-07-29
DE2848335C2 (de) 1982-11-04
IT7829293A0 (it) 1978-10-31
US4481375A (en) 1984-11-06
FR2408388A1 (fr) 1979-06-08
LU80488A1 (fr) 1980-06-05

Similar Documents

Publication Publication Date Title
ES474950A1 (es) Mejoras en un procedimiento de hidroformilacion o de hidro- genacion
NZ297842A (en) carbonylation of ethylene; catalyst contains group VIII metal and a bidentate phosphine compound
GB2055839B (en) Ferrocene compounds suitable as ligands for rhodium based catalysts
CA2093084A1 (en) Ferrocenyl diphosphines as ligands for homogeneous catalysts
AU513201B2 (en) CO. Catalyst of palladium on carrier
EP0305012A3 (en) Catalytic compositions for the polymerization of carbon monoxide with an olefin
DE59408907D1 (de) Neue Bisphosphine für asymmetrische Hydrierkatalysatoren
PL264408A1 (en) A catalyst and a method of production of co-polymers of carbon monoxide olefine unsaturated organic compounds by the use of this with catalyst
CA2155574A1 (en) Non-acidic palladium-based catalyst system and its use in carbonylation
TW427994B (en) New bisphosphines as catalysts for asymmetric reactions
JPS53144552A (en) Palladium complexes
JPS5462190A (en) Carried ruthenium catalyst
GB1536025A (en) Supported ruthenium catalyst
GB1420992A (en) Emission-control catalysts and a process for their production
ES8102842A1 (es) Procedimiento de estabilizacion y regeneracion del cataliza-dor de hidroformilacion del propeno
GB2038658B (en) Supported nickel-cobalt-silica coprecipitated hydrogenation catalyst
ZA773638B (en) Vapor catalyst system for combustion
ATE113579T1 (de) Verfahren zur hydrierung von olefinischen ungesättigten verbindungen ud ruthenium- katalysatoren zu ihrer durchführung.
DE3856098D1 (de) Verfahren zur selektiven Reduktion von 2-Chinoxalinol-4-Oxiden zu 2-Chinoxalinolen
DE3060678D1 (en) Supported cobalt-silica coprecipitated hydrogenation catalyst
DE69000265D1 (de) Verfahren zur selektiven hydrogenolyse von perhalogenethanderivaten.
EP0212287A3 (en) Process for producing aliphatic diamine dimers
GB2006038B (en) Combustion catalyst system
JPS5441984A (en) Rhodium carbonyl cluster-containing polymer, its preparation and its use
EP0295815A3 (en) Process for production of 2-quinoxalines

Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20001204