BE871814A - Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation - Google Patents

Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation

Info

Publication number
BE871814A
BE871814A BE191570A BE191570A BE871814A BE 871814 A BE871814 A BE 871814A BE 191570 A BE191570 A BE 191570A BE 191570 A BE191570 A BE 191570A BE 871814 A BE871814 A BE 871814A
Authority
BE
Belgium
Prior art keywords
hydroformylation
hydrogenation catalyst
rhodium complex
binuclear rhodium
binuclear
Prior art date
Application number
BE191570A
Other languages
English (en)
French (fr)
Original Assignee
Ugine Kuhlmann
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ugine Kuhlmann filed Critical Ugine Kuhlmann
Publication of BE871814A publication Critical patent/BE871814A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
BE191570A 1977-11-10 1978-11-07 Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation BE871814A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7733865A FR2408388A1 (fr) 1977-11-10 1977-11-10 Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation

Publications (1)

Publication Number Publication Date
BE871814A true BE871814A (fr) 1979-05-07

Family

ID=9197475

Family Applications (1)

Application Number Title Priority Date Filing Date
BE191570A BE871814A (fr) 1977-11-10 1978-11-07 Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation

Country Status (11)

Country Link
US (2) US4215066A (xx)
JP (1) JPS5475490A (xx)
BE (1) BE871814A (xx)
CA (1) CA1110643A (xx)
DE (1) DE2848335C2 (xx)
ES (1) ES474950A1 (xx)
FR (1) FR2408388A1 (xx)
GB (1) GB2009750B (xx)
IT (1) IT1100886B (xx)
LU (1) LU80488A1 (xx)
NL (1) NL7811126A (xx)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4288380A (en) * 1979-11-01 1981-09-08 Union Carbide Corporation Heteronuclear-bridged rhodium clusters
IL59647A (en) * 1980-03-14 1984-01-31 Yeda Res & Dev Organo-metallic catalytic system
PT76061A (en) * 1982-12-30 1983-01-01 Stable homogeneous hydrogenation rhodium catalyst - useful in high yield prodn. of doxycycline by stereospecific hydrogenation
US4605751A (en) * 1984-01-17 1986-08-12 The Board Of Regents Acting For And On Behalf Of The University Of Michigan Bimetallic cluster catalysts
FR2571725B1 (fr) * 1984-10-16 1987-09-18 Rhone Poulenc Chim Base Complexes rhodies, dinucleaires et hydrosolubles et leur utilisation comme catalyseur d'hydroformylation
FR2634209B1 (fr) * 1988-07-13 1990-10-19 Toulouse Inst Nat Polytech Nouveau compose organometallique supporte, procede de preparation, et application comme catalyseur d'hydroformylation
US5047132A (en) * 1988-10-17 1991-09-10 University Of Houston Apparatus for catalytically reducing dioxygen using dirhodium complexes
GB9118603D0 (en) * 1991-08-30 1991-10-16 Shell Int Research Process for the preparation of alcohols
ATE236913T1 (de) * 1997-10-14 2003-04-15 Lonza Ag Zweikernige iridium(i)-phosphinkomplexe und ihre verwendung als katalysator in der asymmetrischen hydroaminierung von olefinen
US6229052B1 (en) * 1998-05-29 2001-05-08 E. I. Du Pont De Nemours And Company Hydroformylation of olefins using supported bis(phosphorus) ligands
CN100395250C (zh) * 2004-11-25 2008-06-18 友达光电股份有限公司 有机金属络合物以及包括该有机金属络合物的有机电致发光装置
CN109180845B (zh) * 2018-07-20 2020-12-15 北京理工大学 一种双核铑金属催化剂、制备方法及应用
CN111686817B (zh) * 2019-03-14 2024-02-09 上海博腾智拓医药科技有限公司 一种铜负载催化剂、其制备方法及应用
CN111729687B (zh) * 2020-07-08 2022-08-05 万华化学集团股份有限公司 一种氢甲酰化催化剂的制备方法和应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3501531A (en) * 1964-12-15 1970-03-17 Ethyl Corp Hydroformylation process
US3933919A (en) * 1964-12-15 1976-01-20 Geoffrey Wilkinson Hydroformylation of mono-α-olefins and mono-α-acetylenes
US3954877A (en) * 1967-10-12 1976-05-04 Jefferson Chemical Co., Inc. Hydroformylation of olefins
GB1220506A (en) * 1968-06-18 1971-01-27 Ici Ltd Transition metal compounds
US3859359A (en) * 1970-04-27 1975-01-07 Ethyl Corp Compound and method
US3907847A (en) * 1970-04-27 1975-09-23 Ethyl Corp Compound and method
GB1368431A (en) * 1970-07-22 1974-09-25 Johnson Matthey Co Ltd Rhodium complex and methods of preparing the complex
US3956177A (en) * 1971-08-20 1976-05-11 Phillips Petroleum Company Rhodium hydroformylation catalyst
US3939188A (en) * 1972-03-24 1976-02-17 Exxon Research And Engineering Company Preparation of zerovalent phosphine substituted rhodium compounds and their use in the selective carbonylation of olefins
GB1420928A (en) * 1972-05-10 1976-01-14 Dow Corning Ltd Complexes containing phosphorus
FR2211002A5 (xx) * 1972-12-20 1974-07-12 Rhone Progil
GB1448826A (en) * 1973-02-07 1976-09-08 Dow Corning Ltd Rhodium complexes containing sulphur and use as catalysts
DE2453229A1 (de) * 1974-11-09 1976-05-13 Bayer Ag Rhodiumhaltige komplexverbindungen

Also Published As

Publication number Publication date
IT7829293A0 (it) 1978-10-31
DE2848335C2 (de) 1982-11-04
JPS5475490A (en) 1979-06-16
DE2848335A1 (de) 1979-06-13
US4481375A (en) 1984-11-06
FR2408388B1 (xx) 1983-03-18
GB2009750B (en) 1982-05-26
CA1110643A (fr) 1981-10-13
LU80488A1 (fr) 1980-06-05
ES474950A1 (es) 1979-10-16
IT1100886B (it) 1985-09-28
NL7811126A (nl) 1979-05-14
FR2408388A1 (fr) 1979-06-08
GB2009750A (en) 1979-06-20
US4215066A (en) 1980-07-29

Similar Documents

Publication Publication Date Title
BE871814A (fr) Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation
BE865548A (fr) Procede d'hydroformylation utilisant un complexe catalytique a base de rhodium et de ligands diphosphino
FR2418025B1 (fr) Catalyseur d'hydrogenation
IT1102348B (it) Idrogenazione catalitica
JPS5671032A (en) Improved hydroformylation using stable rhodium catalyst
SE7806284L (sv) Katalysatoranordning
FR2351077A1 (fr) Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
BE862719A (fr) Catalyseurs macroscopiques
NL7807671A (nl) Hydroformuleringswerkwijze met behulp van een kataly- sator op rhodiumbasis.
JPS5541894A (en) Alpha aluminaametal rhodium catalyst
BR7706517A (pt) Revestidor de fios
DE2861830D1 (en) Hydroformylation of formaldehyde with rhodium catalyst
SE421536B (sv) Ferritisk legering
FR2276873A1 (fr) Catalyseur d'hydrogenation partielle
FR2320776A1 (fr) Catalyseur d'hydrogenation des alcools acetyleniques
DK116280A (da) Lyddaempende guld til koeretoejer isaer skinnekoeretoejer
AR211112A1 (es) Catalizador que contiene rodio.
LU79177A1 (fr) Dispositif avertisseur de parturition
FR2504534B1 (fr) Phosphines, leur preparation, complexes de rhodium de ces phosphines et leur utilisation en tant que catalyseurs
IT1115585B (it) Catalizzatore esente da cromo
NO773186L (no) Fremgangsmaate ved utluting av malt nikkelholdig sulfidmatte
BE872854A (fr) Hydrogenation selective
BR7707226A (pt) Conjunto de bocais de saida de ar
TR19348A (tr) Islah edilmis katalitik alkillendirme usulue
DK521478A (da) Platinkatalysator

Legal Events

Date Code Title Description
RE Patent lapsed

Owner name: PRODUITS CHIMIQUES UGINE KUHLMANN

Effective date: 19851130