FR2361480A1 - Procede de preparation de carotenoides symetriques - Google Patents
Procede de preparation de carotenoides symetriquesInfo
- Publication number
- FR2361480A1 FR2361480A1 FR7724352A FR7724352A FR2361480A1 FR 2361480 A1 FR2361480 A1 FR 2361480A1 FR 7724352 A FR7724352 A FR 7724352A FR 7724352 A FR7724352 A FR 7724352A FR 2361480 A1 FR2361480 A1 FR 2361480A1
- Authority
- FR
- France
- Prior art keywords
- preparation
- carotenoids
- halves
- molecule
- phosphonium salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000021466 carotenoid Nutrition 0.000 title abstract 3
- 150000001747 carotenoids Chemical class 0.000 title abstract 3
- 150000004714 phosphonium salts Chemical class 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000006471 dimerization reaction Methods 0.000 abstract 1
- 238000006056 electrooxidation reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical class P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5428—Acyclic unsaturated phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Procédé de préparation de caroténoïdes symétriques à partir des sels de phosphonium des moitiés de molécule de ces caroténoïdes symétriques. On soumet les sels de phosphonium des moitiés de molécule à une oxydation électrochimique dans un solvant en présence d'une base, ce qui provoque la dimérisation des moitiés de molécule avec décomposition de l'oxyde de phosphine substitué.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2635802A DE2635802C2 (de) | 1976-08-09 | 1976-08-09 | Verfahren zur Herstellung von symmetrischen Carotinoiden |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2361480A1 true FR2361480A1 (fr) | 1978-03-10 |
FR2361480B1 FR2361480B1 (fr) | 1981-08-21 |
Family
ID=5985065
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7724352A Granted FR2361480A1 (fr) | 1976-08-09 | 1977-08-08 | Procede de preparation de carotenoides symetriques |
Country Status (8)
Country | Link |
---|---|
US (1) | US4127455A (fr) |
JP (1) | JPS5953357B2 (fr) |
BE (1) | BE857607A (fr) |
CA (1) | CA1105875A (fr) |
CH (1) | CH629257A5 (fr) |
DE (1) | DE2635802C2 (fr) |
FR (1) | FR2361480A1 (fr) |
GB (1) | GB1582042A (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5079172A (fr) * | 1973-11-14 | 1975-06-27 | ||
DE3000365A1 (de) * | 1980-01-07 | 1981-07-09 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von ((monotrichlor)-tetra(monikalium-dichlor))-penta-isocyanurat |
JPH066283B2 (ja) * | 1988-09-22 | 1994-01-26 | 日本碍子株式会社 | セラミックス多層構造体の押出成形方法 |
US5021132A (en) * | 1990-08-07 | 1991-06-04 | Sandoz Ltd. | Electrochemical process for preparing 4,4'-dinitrostilbene-2,2'-disulfonic acid and the salts thereof |
US7132458B2 (en) | 1994-08-10 | 2006-11-07 | Chemaphor Inc. | Oxidized carotenoid fractions and ketoaldehyde useful as cell-differentiation inducers, cytostatic agents, and anti-tumor agents |
US5475006A (en) * | 1994-08-10 | 1995-12-12 | National Research Council Of Canada | Extensively oxidized derivatives of carotenoids, retinoids and related conjugated polyenes useful as non-toxic cell-differentiation inducers, anti-proliferative agents, and anti-tumor agents |
ATE183500T1 (de) * | 1994-12-21 | 1999-09-15 | Hoffmann La Roche | Carotenoide ketone und ester |
US5827904A (en) * | 1996-09-27 | 1998-10-27 | Hahn; David | Medical implant composition |
NZ554476A (en) | 2004-09-28 | 2010-09-30 | Chemaphor Inc | Compositions and methods for promoting weight gain feed conversion |
JP2011500733A (ja) * | 2007-10-26 | 2011-01-06 | ケマファー インコーポレーテッド | 免疫応答を増強するための組成物および方法 |
AU2010242502B2 (en) | 2009-04-30 | 2016-11-10 | Avivagen Inc. | Methods and compositions for improving the health of animals |
CN107653459B (zh) * | 2017-09-19 | 2019-09-24 | 厦门金达威维生素有限公司 | 一种β-胡萝卜素的合成方法 |
CN110452147B (zh) * | 2019-07-30 | 2021-07-23 | 万华化学集团股份有限公司 | 一种β-胡萝卜素的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1068709B (de) * | 1959-11-12 | Badische Anilin- S. Soda-Faibrik Aktiengesellschaft, Ludwigshafen/Rhein | Verfahren zur Synthese von Verbindungen der Axerophtyliden-Reihe | |
DE1148542B (de) * | 1961-10-28 | 1963-05-16 | Hoechst Ag | Verfahren zur Herstellung von ª‰-Carotin |
DE1944278A1 (de) * | 1969-09-01 | 1971-03-04 | Basf Ag | Verfahren zur Herstellung von Butadien-Derivaten |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3480527A (en) * | 1967-06-22 | 1969-11-25 | Dow Chemical Co | Process for producing p,p'-dinitrobibenzyl compounds by the electroreduction of sulfonium compounds |
US3480525A (en) * | 1967-06-22 | 1969-11-25 | Dow Chemical Co | Process for producing polymers by the electroreduction of sulfonium compounds |
US3764492A (en) * | 1972-01-10 | 1973-10-09 | Monsanto Co | Electrolytic preparation of esters from organo halides |
US3859183A (en) * | 1973-11-07 | 1975-01-07 | Monsanto Co | Process for producing n-phosphonomethyl glycine triesters |
-
1976
- 1976-08-09 DE DE2635802A patent/DE2635802C2/de not_active Expired
-
1977
- 1977-07-19 CA CA283,093A patent/CA1105875A/fr not_active Expired
- 1977-07-20 US US05/817,252 patent/US4127455A/en not_active Expired - Lifetime
- 1977-08-03 JP JP52092609A patent/JPS5953357B2/ja not_active Expired
- 1977-08-05 CH CH964477A patent/CH629257A5/de not_active IP Right Cessation
- 1977-08-08 FR FR7724352A patent/FR2361480A1/fr active Granted
- 1977-08-08 GB GB33094/77A patent/GB1582042A/en not_active Expired
- 1977-08-09 BE BE180012A patent/BE857607A/fr not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1068709B (de) * | 1959-11-12 | Badische Anilin- S. Soda-Faibrik Aktiengesellschaft, Ludwigshafen/Rhein | Verfahren zur Synthese von Verbindungen der Axerophtyliden-Reihe | |
DE1148542B (de) * | 1961-10-28 | 1963-05-16 | Hoechst Ag | Verfahren zur Herstellung von ª‰-Carotin |
DE1944278A1 (de) * | 1969-09-01 | 1971-03-04 | Basf Ag | Verfahren zur Herstellung von Butadien-Derivaten |
Also Published As
Publication number | Publication date |
---|---|
JPS5321223A (en) | 1978-02-27 |
JPS5953357B2 (ja) | 1984-12-24 |
CH629257A5 (de) | 1982-04-15 |
DE2635802C2 (de) | 1984-03-01 |
DE2635802A1 (de) | 1978-02-16 |
GB1582042A (en) | 1980-12-31 |
US4127455A (en) | 1978-11-28 |
CA1105875A (fr) | 1981-07-28 |
FR2361480B1 (fr) | 1981-08-21 |
BE857607A (fr) | 1978-02-09 |
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